LU87055A1 - Verre desalcalinise en feuilles et procede de fabrication d'un tel verre - Google Patents

Verre desalcalinise en feuilles et procede de fabrication d'un tel verre Download PDF

Info

Publication number: LU87055A1
Authority: LU; Luxembourg
Prior art keywords: glass; concentration; depth; temperature; sodium ions
Prior art date: 1986-12-04

Application number

LU87055A

Other languages

English (en)

French (fr)

Inventor

Andre Hecq

Camille Dupont

Karel Van Baelen

Original Assignee

Glaverbel

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1986-12-04

Filing date

1987-11-30

Publication date

1988-06-13

1987-11-30 Application filed by Glaverbel filed Critical Glaverbel

1988-06-13 Publication of LU87055A1 publication Critical patent/LU87055A1/fr

Links

238000000034 method Methods 0.000 title claims description 45
230000008569 process Effects 0.000 title claims description 14
239000011521 glass Substances 0.000 claims description 260
229910001415 sodium ion Inorganic materials 0.000 claims description 74
RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 claims description 72
238000011282 treatment Methods 0.000 claims description 30
AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 claims description 26
239000002253 acid Substances 0.000 claims description 22
238000000576 coating method Methods 0.000 claims description 22
238000007254 oxidation reaction Methods 0.000 claims description 19
230000003647 oxidation Effects 0.000 claims description 18
239000011248 coating agent Substances 0.000 claims description 16
FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 claims description 13
239000003054 catalyst Substances 0.000 claims description 13
GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 claims description 12
238000004519 manufacturing process Methods 0.000 claims description 12
230000001737 promoting effect Effects 0.000 claims description 9
229910052731 fluorine Inorganic materials 0.000 claims description 6
239000011737 fluorine Substances 0.000 claims description 6
-1 fluorine ions Chemical class 0.000 claims description 4
150000001875 compounds Chemical class 0.000 claims description 2
230000001590 oxidative effect Effects 0.000 claims description 2
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims 1
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims 1
239000011575 calcium Substances 0.000 claims 1
229910052791 calcium Inorganic materials 0.000 claims 1
HUAUNKAZQWMVFY-UHFFFAOYSA-M sodium;oxocalcium;hydroxide Chemical compound [OH-].[Na+].[Ca]=O HUAUNKAZQWMVFY-UHFFFAOYSA-M 0.000 claims 1
239000007789 gas Substances 0.000 description 26
239000011734 sodium Substances 0.000 description 26
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 24
229910052708 sodium Inorganic materials 0.000 description 24
229910001413 alkali metal ion Inorganic materials 0.000 description 22
239000002344 surface layer Substances 0.000 description 21
238000012360 testing method Methods 0.000 description 21
239000000203 mixture Substances 0.000 description 17
239000005361 soda-lime glass Substances 0.000 description 16
150000002500 ions Chemical class 0.000 description 14
230000008901 benefit Effects 0.000 description 13
230000005012 migration Effects 0.000 description 12
238000013508 migration Methods 0.000 description 12
239000003513 alkali Substances 0.000 description 9
238000002386 leaching Methods 0.000 description 9
238000006243 chemical reaction Methods 0.000 description 8
238000009826 distribution Methods 0.000 description 8
230000000052 comparative effect Effects 0.000 description 6
239000005357 flat glass Substances 0.000 description 6
KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 5
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 5
238000001816 cooling Methods 0.000 description 5
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
238000000137 annealing Methods 0.000 description 4
230000006866 deterioration Effects 0.000 description 4
239000010410 layer Substances 0.000 description 4
229910001948 sodium oxide Inorganic materials 0.000 description 4
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
230000002378 acidificating effect Effects 0.000 description 3
229910052783 alkali metal Inorganic materials 0.000 description 3
150000001340 alkali metals Chemical class 0.000 description 3
230000015572 biosynthetic process Effects 0.000 description 3
210000000078 claw Anatomy 0.000 description 3
230000002349 favourable effect Effects 0.000 description 3
230000006870 function Effects 0.000 description 3
238000010438 heat treatment Methods 0.000 description 3
239000000463 material Substances 0.000 description 3
XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 3
229910001887 tin oxide Inorganic materials 0.000 description 3
NPNPZTNLOVBDOC-UHFFFAOYSA-N 1,1-difluoroethane Chemical compound CC(F)F NPNPZTNLOVBDOC-UHFFFAOYSA-N 0.000 description 2
YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 2
206010021036 Hyponatraemia Diseases 0.000 description 2
230000032683 aging Effects 0.000 description 2
230000003679 aging effect Effects 0.000 description 2
238000010924 continuous production Methods 0.000 description 2
125000004122 cyclic group Chemical group 0.000 description 2
230000000694 effects Effects 0.000 description 2
238000006253 efflorescence Methods 0.000 description 2
238000009791 electrochemical migration reaction Methods 0.000 description 2
238000011065 in-situ storage Methods 0.000 description 2
230000003287 optical effect Effects 0.000 description 2
239000002245 particle Substances 0.000 description 2
238000012545 processing Methods 0.000 description 2
206010037844 rash Diseases 0.000 description 2
150000003839 salts Chemical class 0.000 description 2
239000000377 silicon dioxide Substances 0.000 description 2
159000000000 sodium salts Chemical class 0.000 description 2
TXEYQDLBPFQVAA-UHFFFAOYSA-N tetrafluoromethane Chemical compound FC(F)(F)F TXEYQDLBPFQVAA-UHFFFAOYSA-N 0.000 description 2
238000001771 vacuum deposition Methods 0.000 description 2
125000002066 L-histidyl group Chemical group [H]N1C([H])=NC(C([H])([H])[C@](C(=O)[*])([H])N([H])[H])=C1[H] 0.000 description 1
238000006124 Pilkington process Methods 0.000 description 1
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
230000009471 action Effects 0.000 description 1
230000001154 acute effect Effects 0.000 description 1
230000001464 adherent effect Effects 0.000 description 1
230000002411 adverse Effects 0.000 description 1
230000004075 alteration Effects 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
238000013475 authorization Methods 0.000 description 1
230000004888 barrier function Effects 0.000 description 1
239000012159 carrier gas Substances 0.000 description 1
238000005520 cutting process Methods 0.000 description 1
230000007423 decrease Effects 0.000 description 1
230000007547 defect Effects 0.000 description 1
238000000151 deposition Methods 0.000 description 1
230000008021 deposition Effects 0.000 description 1
230000003628 erosive effect Effects 0.000 description 1
238000000605 extraction Methods 0.000 description 1
238000007496 glass forming Methods 0.000 description 1
230000003301 hydrolyzing effect Effects 0.000 description 1
230000006872 improvement Effects 0.000 description 1
238000009434 installation Methods 0.000 description 1
230000001788 irregular Effects 0.000 description 1
238000005304 joining Methods 0.000 description 1
239000004973 liquid crystal related substance Substances 0.000 description 1
239000006060 molten glass Substances 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
238000007747 plating Methods 0.000 description 1
231100000572 poisoning Toxicity 0.000 description 1
230000000607 poisoning effect Effects 0.000 description 1
230000002028 premature Effects 0.000 description 1
238000011084 recovery Methods 0.000 description 1
230000009467 reduction Effects 0.000 description 1
238000011160 research Methods 0.000 description 1
230000000717 retained effect Effects 0.000 description 1
230000035939 shock Effects 0.000 description 1
229910052709 silver Inorganic materials 0.000 description 1
239000004332 silver Substances 0.000 description 1
239000002356 single layer Substances 0.000 description 1
229910052938 sodium sulfate Inorganic materials 0.000 description 1
235000011152 sodium sulphate Nutrition 0.000 description 1
238000003860 storage Methods 0.000 description 1
230000035882 stress Effects 0.000 description 1
229910052717 sulfur Inorganic materials 0.000 description 1
239000011593 sulfur Substances 0.000 description 1
239000000725 suspension Substances 0.000 description 1
239000010409 thin film Substances 0.000 description 1
238000009827 uniform distribution Methods 0.000 description 1
238000010792 warming Methods 0.000 description 1
238000004876 x-ray fluorescence Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C21/00—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31—Surface property or characteristic of web, sheet or block
- Y10T428/315—Surface modified glass [e.g., tempered, strengthened, etc.]

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
General Chemical & Material Sciences (AREA)
Geochemistry & Mineralogy (AREA)
Materials Engineering (AREA)
Organic Chemistry (AREA)
Surface Treatment Of Glass (AREA)
Re-Forming, After-Treatment, Cutting And Transporting Of Glass Products (AREA)
Glass Compositions (AREA)

LU87055A 1986-12-04 1987-11-30 Verre desalcalinise en feuilles et procede de fabrication d'un tel verre LU87055A1 (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
GB8629042A GB2199318B (en)	1986-12-04	1986-12-04	Dealkalised sheet glass and method of producing same
GB8629042		1986-12-04

Publications (1)

Publication Number	Publication Date
LU87055A1 true LU87055A1 (fr)	1988-06-13

Family

ID=10608469

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
LU87055A LU87055A1 (fr)	1986-12-04	1987-11-30	Verre desalcalinise en feuilles et procede de fabrication d'un tel verre

Country Status (10)

Country	Link
US (1)	US5093196A (it)
JP (1)	JP2607898B2 (it)
BE (1)	BE1001670A3 (it)
DE (1)	DE3741031A1 (it)
ES (1)	ES2005499A6 (it)
FR (1)	FR2609284B1 (it)
GB (1)	GB2199318B (it)
IT (1)	IT1211552B (it)
LU (1)	LU87055A1 (it)
NL (1)	NL194886C (it)

Families Citing this family (31)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB2206878B (en) *	1987-07-11	1991-07-17	Glaverbel	Pyrolytically coated sheet glass and process of manufacturing same
US5250098A (en) *	1992-07-27	1993-10-05	Ford Motor Company	Thermally durable anti-reflective glass
FR2696441B1 (fr) *	1992-10-02	1994-12-16	Saint Gobain Vitrage Int	Désalcalinisation de feuilles de verre à faible teneur en alcalins.
DE4243838A1 (de) *	1992-12-23	1994-02-24	Schott Glaswerke	Verfahren zur Oberflächenmodifikation von Glas und Glaskeramik
CA2163856C (en) *	1993-08-19	2002-02-05	Mark Piper	Stain-resistant glass and method of making same
IT1262463B (it) *	1993-11-30	1996-06-19	Siv Soc Italiana Vetro	Procedimento e dispositivo per la fabbricazione di vetro piano con caratteristiche migliorate.
US5985700A (en) *	1996-11-26	1999-11-16	Corning Incorporated	TFT fabrication on leached glass surface
ATE369829T1 (de) *	2003-12-22	2007-09-15	3M Espe Ag	Glasfüllmaterial und verfahren zur herstellung
US20070111042A1 (en) *	2005-11-16	2007-05-17	Seagate Technology Llc	Alkali-depleted glass & glass-based substrates for magnetic & magneto-optical recording media
FI20060288A0 (fi) *	2006-03-27	2006-03-27	Abr Innova Oy	Pinnoitusmenetelmä
DE102007025687B3 (de) *	2007-06-01	2009-01-08	Schott Ag	Verwendung einer Glasscheibe aus Borosilikatglas in einer Flachanzeigevorrichtung und Flachanzeigevorrichtung mit dieser Glasscheibe
FI20090057A0 (fi) *	2009-02-17	2009-02-17	Beneq Oy	Antibakteerinen lasi
WO2010110011A1 (ja)	2009-03-26	2010-09-30	日本碍子株式会社	ハニカムフィルタ及びハニカムフィルタの製造方法
JP5456353B2 (ja)	2009-03-31	2014-03-26	日本碍子株式会社	ハニカムフィルタ
KR20120104972A (ko) *	2009-12-04	2012-09-24	아사히 가라스 가부시키가이샤	유리판 및 그 제조 방법
JP5369029B2 (ja)	2010-03-12	2013-12-18	日本碍子株式会社	ハニカムフィルタ
JP5757473B2 (ja)	2010-07-26	2015-07-29	旭硝子株式会社	Ｃｕ−Ｉｎ−Ｇａ−Ｓｅ太陽電池用ガラス基板及びそれを用いた太陽電池
CN103079678B (zh) *	2010-08-27	2015-08-26	英派尔科技开发有限公司	氢氟烷消除装置
EP2679552B1 (en) *	2011-02-21	2018-08-01	LG Chem, Ltd.	Use of a device for forming glass surface lubricating layer
WO2012115415A2 (ko) *	2011-02-21	2012-08-30	주식회사 엘지화학	유리 표면 윤활층 형성 방법 및 이를 이용하는 유리 제조 방법
JP6410108B2 (ja) *	2011-07-19	2018-10-24	日本電気硝子株式会社	ガラス基材
JP5983100B2 (ja) *	2011-07-19	2016-08-31	日本電気硝子株式会社	ガラス基材
CN104812713A (zh) *	2012-11-16	2015-07-29	旭硝子株式会社	玻璃制造方法及玻璃制造装置
WO2014104303A1 (ja) *	2012-12-27	2014-07-03	旭硝子株式会社	化学強化時の反りを低減できるガラス板の製造方法及びガラス板
CN104884398B (zh) *	2012-12-27	2017-05-31	旭硝子株式会社	化学强化用浮法玻璃
CN105189396B (zh) *	2013-03-19	2019-10-22	日本板硝子株式会社	玻璃板及玻璃板的制造方法
JP6395723B2 (ja)	2013-04-09	2018-09-26	日本板硝子株式会社	ガラス板の製造方法及びガラス板
WO2014179163A1 (en)	2013-04-30	2014-11-06	Corning Incorporated	Glass with depleted layer and polycrystalline-silicon tft built thereon
JPWO2014189003A1 (ja) *	2013-05-20	2017-02-23	旭硝子株式会社	ガラス基板及びｃｉｇｓ太陽電池
FR3017613B1 (fr) *	2014-02-18	2020-03-13	Glass Surface Technology	Procede et dispositif de passivation de la surface interne d'un flacon en verre et flacon obtenu avec un tel procede.
DE102019100261B4 (de) *	2019-01-08	2020-10-01	Schott Ag	Element aus Glas mit verminderter elektrostatischer Aufladung

Family Cites Families (14)

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Publication number	Priority date	Publication date	Assignee	Title
GB294391A (en) *	1927-08-25	1928-07-26	Kiyoshi Kamita	A process for preventing the weathering (especially clouding, tarnishing and lustering) of the surface of glass
DE1040198B (de) *	1957-10-11	1958-10-02	Kurz Fredrik W A	Verfahren zur Erhoehung der chemischen Widerstandsfaehigkeit von Glasgegenstaenden
US3451796A (en) *	1966-05-16	1969-06-24	Corning Glass Works	Method of treating strengthened glass surface to increase acid durability
US3653864A (en) *	1969-03-17	1972-04-04	Corning Glass Works	Dealkalization of glass surfaces
US4022947A (en) *	1975-11-06	1977-05-10	Airco, Inc.	Transparent panel having high reflectivity for solar radiation and a method for preparing same
US4026692A (en) *	1975-12-15	1977-05-31	Corning Glass Works	Press molding optical articles from acid hydrated glasses
JPS5440816A (en) *	1977-09-08	1979-03-31	Daiichi Garasu Kk	Antiichemical treatment of glass container
JPS57129845A (en) *	1981-01-29	1982-08-12	Nippon Taisanbin Kogyo Kk	Glass bottle provided with both mechanical strength and chemical durability and its manufacture
GB2102786B (en) *	1981-07-10	1985-01-09	Glaverbel	Method of modifying the light-reflecting properties of glass
LU83731A1 (fr) *	1981-11-04	1983-09-01	Inst Nat Du Verre	Procede de desalcalinisation de la surface interne d'objets en verre creux
JPS59189320A (ja) *	1983-04-13	1984-10-26	Nippon Taisanbin Kogyo Kk	液晶表示体の電極板
US4518222A (en) *	1983-12-08	1985-05-21	Corning Glass Works	Optical device and method
IT1177081B (it) *	1984-10-30	1987-08-26	Vitreal Specchi Spa	Apparecchiatura per l'incisione in continuo all'acido su una faccia di lastre di vetro
US4578100A (en) *	1985-04-01	1986-03-25	Ppg Industries, Inc.	Method of making non-glare coated glass

1986
- 1986-12-04 GB GB8629042A patent/GB2199318B/en not_active Expired - Lifetime
1987
- 1987-11-17 BE BE8701301A patent/BE1001670A3/fr not_active IP Right Cessation
- 1987-11-18 FR FR878716055A patent/FR2609284B1/fr not_active Expired - Lifetime
- 1987-11-23 IT IT8768001A patent/IT1211552B/it active
- 1987-11-26 NL NL8702840A patent/NL194886C/nl not_active IP Right Cessation
- 1987-11-27 JP JP62299620A patent/JP2607898B2/ja not_active Expired - Fee Related
- 1987-11-30 LU LU87055A patent/LU87055A1/fr unknown
- 1987-12-01 ES ES8703792A patent/ES2005499A6/es not_active Expired
- 1987-12-03 DE DE19873741031 patent/DE3741031A1/de not_active Withdrawn
1991
- 1991-01-25 US US07/646,520 patent/US5093196A/en not_active Expired - Lifetime

Also Published As

Publication number	Publication date
NL194886C (nl)	2003-06-04
ES2005499A6 (es)	1989-03-01
IT1211552B (it)	1989-11-03
FR2609284A1 (fr)	1988-07-08
IT8768001A0 (it)	1987-11-23
GB2199318A (en)	1988-07-06
JP2607898B2 (ja)	1997-05-07
NL8702840A (nl)	1988-07-01
DE3741031A1 (de)	1988-06-09
GB2199318B (en)	1990-11-14
BE1001670A3 (fr)	1990-02-06
GB8629042D0 (en)	1987-01-14
JPS63159238A (ja)	1988-07-02
US5093196A (en)	1992-03-03
NL194886B (nl)	2003-02-03
FR2609284B1 (fr)	1992-05-22

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