LU87429A1 - Produit a base de particules de polymere comportant des pigments melaniques,son procede de preparation et son utilisation,en particulier en cosmetique - Google Patents

Produit a base de particules de polymere comportant des pigments melaniques,son procede de preparation et son utilisation,en particulier en cosmetique Download PDF

Info

Publication number: LU87429A1
Authority: LU; Luxembourg
Prior art keywords: group; polymer; chosen; product according; keratin
Prior art date: 1989-01-17

Application number

LU87429A

Other languages

English (en)

French (fr)

Original Assignee

Oreal

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1989-01-17

Filing date

1989-01-17

Publication date

1990-07-24

1989-01-17 Application filed by Oreal filed Critical Oreal

1989-01-17 Priority to LU87429A priority Critical patent/LU87429A1/fr

1990-01-15 Priority to EP90400099A priority patent/EP0379409B1/de

1990-01-15 Priority to AT90400099T priority patent/ATE94377T1/de

1990-01-15 Priority to DE90400099T priority patent/DE69003258T2/de

1990-01-15 Priority to ES90400099T priority patent/ES2060077T3/es

1990-01-17 Priority to CA002007957A priority patent/CA2007957A1/fr

1990-01-17 Priority to JP2008070A priority patent/JPH02232264A/ja

1990-07-24 Publication of LU87429A1 publication Critical patent/LU87429A1/fr

Links

239000000049 pigment Substances 0.000 title claims abstract description 58
229920000642 polymer Polymers 0.000 title claims abstract description 57
239000002245 particle Substances 0.000 title claims abstract description 34
239000002537 cosmetic Substances 0.000 title claims description 13
238000002360 preparation method Methods 0.000 title description 8
XUMBMVFBXHLACL-UHFFFAOYSA-N Melanin Chemical compound O=C1C(=O)C(C2=CNC3=C(C(C(=O)C4=C32)=O)C)=C2C4=CNC2=C1C XUMBMVFBXHLACL-UHFFFAOYSA-N 0.000 claims abstract description 60
239000000843 powder Substances 0.000 claims abstract description 51
108010076876 Keratins Proteins 0.000 claims abstract description 33
102000011782 Keratins Human genes 0.000 claims abstract description 33
229920002101 Chitin Polymers 0.000 claims abstract description 19
238000007254 oxidation reaction Methods 0.000 claims abstract description 18
230000003647 oxidation Effects 0.000 claims abstract description 17
239000004005 microsphere Substances 0.000 claims abstract description 16
229920001577 copolymer Polymers 0.000 claims abstract description 9
UCMIRNVEIXFBKS-UHFFFAOYSA-N beta-alanine Chemical compound NCCC(O)=O UCMIRNVEIXFBKS-UHFFFAOYSA-N 0.000 claims abstract description 8
229920003229 poly(methyl methacrylate) Polymers 0.000 claims abstract description 7
239000004926 polymethyl methacrylate Substances 0.000 claims abstract description 7
229920001296 polysiloxane Polymers 0.000 claims abstract description 5
229920001059 synthetic polymer Polymers 0.000 claims abstract description 5
OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 claims abstract description 4
229920000299 Nylon 12 Polymers 0.000 claims abstract description 4
229920002292 Nylon 6 Polymers 0.000 claims abstract description 3
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 89
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 73
235000019441 ethanol Nutrition 0.000 claims description 58
239000000203 mixture Substances 0.000 claims description 40
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 27
210000004209 hair Anatomy 0.000 claims description 25
239000007800 oxidant agent Substances 0.000 claims description 20
238000000034 method Methods 0.000 claims description 18
-1 amino, carboxyl Chemical group 0.000 claims description 14
ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 13
210000003491 skin Anatomy 0.000 claims description 13
239000002904 solvent Substances 0.000 claims description 13
DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 claims description 12
239000002609 medium Substances 0.000 claims description 11
229920001661 Chitosan Polymers 0.000 claims description 9
229910001870 ammonium persulfate Inorganic materials 0.000 claims description 9
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 9
LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 claims description 9
239000003795 chemical substances by application Substances 0.000 claims description 8
239000000725 suspension Substances 0.000 claims description 8
229940000635 beta-alanine Drugs 0.000 claims description 7
210000002615 epidermis Anatomy 0.000 claims description 7
210000004709 eyebrow Anatomy 0.000 claims description 7
210000000720 eyelash Anatomy 0.000 claims description 7
239000012429 reaction media Substances 0.000 claims description 7
150000003839 salts Chemical class 0.000 claims description 7
SGNZYJXNUURYCH-UHFFFAOYSA-N 5,6-dihydroxyindole Chemical compound C1=C(O)C(O)=CC2=C1NC=C2 SGNZYJXNUURYCH-UHFFFAOYSA-N 0.000 claims description 6
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 6
GEHJBWKLJVFKPS-UHFFFAOYSA-N bromochloroacetic acid Chemical compound OC(=O)C(Cl)Br GEHJBWKLJVFKPS-UHFFFAOYSA-N 0.000 claims description 6
210000000003 hoof Anatomy 0.000 claims description 6
XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 claims description 6
230000005855 radiation Effects 0.000 claims description 6
235000010288 sodium nitrite Nutrition 0.000 claims description 6
125000004178 (C1-C4) alkyl group Chemical group 0.000 claims description 5
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 5
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 5
239000000839 emulsion Substances 0.000 claims description 5
239000001301 oxygen Substances 0.000 claims description 5
229910052760 oxygen Inorganic materials 0.000 claims description 5
KHIWWQKSHDUIBK-UHFFFAOYSA-N periodic acid Chemical compound OI(=O)(=O)=O KHIWWQKSHDUIBK-UHFFFAOYSA-N 0.000 claims description 5
239000012286 potassium permanganate Substances 0.000 claims description 5
239000007787 solid Substances 0.000 claims description 5
239000000126 substance Substances 0.000 claims description 5
MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 claims description 4
241001465754 Metazoa Species 0.000 claims description 4
239000004698 Polyethylene Substances 0.000 claims description 4
239000004793 Polystyrene Substances 0.000 claims description 4
239000000443 aerosol Substances 0.000 claims description 4
125000000217 alkyl group Chemical group 0.000 claims description 4
125000005102 carbonylalkoxy group Chemical group 0.000 claims description 4
210000003746 feather Anatomy 0.000 claims description 4
239000000499 gel Substances 0.000 claims description 4
239000006210 lotion Substances 0.000 claims description 4
239000002304 perfume Substances 0.000 claims description 4
229920000573 polyethylene Polymers 0.000 claims description 4
229920002223 polystyrene Polymers 0.000 claims description 4
NDVLTYZPCACLMA-UHFFFAOYSA-N silver oxide Chemical compound [O-2].[Ag+].[Ag+] NDVLTYZPCACLMA-UHFFFAOYSA-N 0.000 claims description 4
SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 claims description 4
125000000229 (C1-C4)alkoxy group Chemical group 0.000 claims description 3
ZUTZCXDHPIACCR-UHFFFAOYSA-N 3-methyl-1h-indole-5,6-diol Chemical compound OC1=C(O)C=C2C(C)=CNC2=C1 ZUTZCXDHPIACCR-UHFFFAOYSA-N 0.000 claims description 3
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 3
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 3
229920000168 Microcrystalline cellulose Polymers 0.000 claims description 3
239000004743 Polypropylene Substances 0.000 claims description 3
239000005708 Sodium hypochlorite Substances 0.000 claims description 3
239000003513 alkali Substances 0.000 claims description 3
229940107816 ammonium iodide Drugs 0.000 claims description 3
239000001913 cellulose Substances 0.000 claims description 3
235000010980 cellulose Nutrition 0.000 claims description 3
229920002678 cellulose Polymers 0.000 claims description 3
239000006071 cream Substances 0.000 claims description 3
229920006037 cross link polymer Polymers 0.000 claims description 3
239000006185 dispersion Substances 0.000 claims description 3
239000000945 filler Substances 0.000 claims description 3
239000006260 foam Substances 0.000 claims description 3
239000000463 material Substances 0.000 claims description 3
235000019813 microcrystalline cellulose Nutrition 0.000 claims description 3
235000013336 milk Nutrition 0.000 claims description 3
210000004080 milk Anatomy 0.000 claims description 3
238000006116 polymerization reaction Methods 0.000 claims description 3
229920001155 polypropylene Polymers 0.000 claims description 3
239000003755 preservative agent Substances 0.000 claims description 3
239000011541 reaction mixture Substances 0.000 claims description 3
CHRJZRDFSQHIFI-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;styrene Chemical compound C=CC1=CC=CC=C1.C=CC1=CC=CC=C1C=C CHRJZRDFSQHIFI-UHFFFAOYSA-N 0.000 claims description 2
XAWPKHNOFIWWNZ-UHFFFAOYSA-N 1h-indol-6-ol Chemical compound OC1=CC=C2C=CNC2=C1 XAWPKHNOFIWWNZ-UHFFFAOYSA-N 0.000 claims description 2
ORVPXPKEZLTMNW-UHFFFAOYSA-N 1h-indol-7-ol Chemical compound OC1=CC=CC2=C1NC=C2 ORVPXPKEZLTMNW-UHFFFAOYSA-N 0.000 claims description 2
HMTUVSJLXALWIU-UHFFFAOYSA-N 2,3-dimethyl-1h-indole-5,6-diol Chemical compound OC1=C(O)C=C2C(C)=C(C)NC2=C1 HMTUVSJLXALWIU-UHFFFAOYSA-N 0.000 claims description 2
DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 claims description 2
NLMQHXUGJIAKTH-UHFFFAOYSA-N 4-hydroxyindole Chemical compound OC1=CC=CC2=C1C=CN2 NLMQHXUGJIAKTH-UHFFFAOYSA-N 0.000 claims description 2
BIMHWDJKNOMNLD-UHFFFAOYSA-N 5-Hydroxyindole-2-carboxylic acid Chemical compound OC1=CC=C2NC(C(=O)O)=CC2=C1 BIMHWDJKNOMNLD-UHFFFAOYSA-N 0.000 claims description 2
LYZYLCBKDYUUES-UHFFFAOYSA-N 5-ethoxy-1h-indol-4-ol Chemical compound CCOC1=CC=C2NC=CC2=C1O LYZYLCBKDYUUES-UHFFFAOYSA-N 0.000 claims description 2
LMIQERWZRIFWNZ-UHFFFAOYSA-N 5-hydroxyindole Chemical compound OC1=CC=C2NC=CC2=C1 LMIQERWZRIFWNZ-UHFFFAOYSA-N 0.000 claims description 2
NUMLTQFTLCZMRX-UHFFFAOYSA-N 5-methoxy-1h-indol-4-ol Chemical compound COC1=CC=C2NC=CC2=C1O NUMLTQFTLCZMRX-UHFFFAOYSA-N 0.000 claims description 2
RWEBZZKCIMKUTO-UHFFFAOYSA-N 5-methoxy-1h-indol-6-ol Chemical compound C1=C(O)C(OC)=CC2=C1NC=C2 RWEBZZKCIMKUTO-UHFFFAOYSA-N 0.000 claims description 2
WZARGPVIAOAKMH-UHFFFAOYSA-N 6-methoxy-1h-indol-5-ol Chemical compound C1=C(O)C(OC)=CC2=C1C=CN2 WZARGPVIAOAKMH-UHFFFAOYSA-N 0.000 claims description 2
MVKYMRASKNZUGO-UHFFFAOYSA-N 7-methoxy-1h-indol-6-ol Chemical compound COC1=C(O)C=CC2=C1NC=C2 MVKYMRASKNZUGO-UHFFFAOYSA-N 0.000 claims description 2
241000272814 Anser sp. Species 0.000 claims description 2
241000287828 Gallus gallus Species 0.000 claims description 2
229910021578 Iron(III) chloride Inorganic materials 0.000 claims description 2
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 2
VXOSJAYSAUDUOR-UHFFFAOYSA-N N-methyl-5,6-dihydroxyindole Chemical compound OC1=C(O)C=C2N(C)C=CC2=C1 VXOSJAYSAUDUOR-UHFFFAOYSA-N 0.000 claims description 2
239000004952 Polyamide Substances 0.000 claims description 2
239000002535 acidifier Substances 0.000 claims description 2
125000002252 acyl group Chemical group 0.000 claims description 2
125000001931 aliphatic group Chemical group 0.000 claims description 2
229910052784 alkaline earth metal Inorganic materials 0.000 claims description 2
150000001342 alkaline earth metals Chemical class 0.000 claims description 2
150000001412 amines Chemical class 0.000 claims description 2
125000004103 aminoalkyl group Chemical group 0.000 claims description 2
239000002518 antifoaming agent Substances 0.000 claims description 2
239000003963 antioxidant agent Substances 0.000 claims description 2
239000012736 aqueous medium Substances 0.000 claims description 2
125000003710 aryl alkyl group Chemical group 0.000 claims description 2
125000003118 aryl group Chemical group 0.000 claims description 2
230000015572 biosynthetic process Effects 0.000 claims description 2
125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 claims description 2
125000004432 carbon atom Chemical group C* 0.000 claims description 2
125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 2
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 2
125000004181 carboxyalkyl group Chemical group 0.000 claims description 2
239000003054 catalyst Substances 0.000 claims description 2
AFSIMBWBBOJPJG-UHFFFAOYSA-N ethenyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC=C AFSIMBWBBOJPJG-UHFFFAOYSA-N 0.000 claims description 2
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 2
STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 claims description 2
125000002485 formyl group Chemical group [H]C(*)=O 0.000 claims description 2
229910052736 halogen Inorganic materials 0.000 claims description 2
150000002367 halogens Chemical class 0.000 claims description 2
229920001519 homopolymer Polymers 0.000 claims description 2
239000001257 hydrogen Substances 0.000 claims description 2
229910052739 hydrogen Inorganic materials 0.000 claims description 2
RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims description 2
229910000464 lead oxide Inorganic materials 0.000 claims description 2
229910052751 metal Inorganic materials 0.000 claims description 2
239000002184 metal Substances 0.000 claims description 2
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
239000008267 milk Substances 0.000 claims description 2
230000003020 moisturizing effect Effects 0.000 claims description 2
239000000178 monomer Substances 0.000 claims description 2
229920005615 natural polymer Polymers 0.000 claims description 2
239000002674 ointment Substances 0.000 claims description 2
239000003960 organic solvent Substances 0.000 claims description 2
235000011837 pasties Nutrition 0.000 claims description 2
229920002647 polyamide Polymers 0.000 claims description 2
239000003380 propellant Substances 0.000 claims description 2
239000003352 sequestering agent Substances 0.000 claims description 2
229910001923 silver oxide Inorganic materials 0.000 claims description 2
239000002562 thickening agent Substances 0.000 claims description 2
125000002813 thiocarbonyl group Chemical group *C(*)=S 0.000 claims description 2
210000002268 wool Anatomy 0.000 claims description 2
DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical class CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 claims 1
XZXYQEHISUMZAT-UHFFFAOYSA-N 2-[(2-hydroxy-5-methylphenyl)methyl]-4-methylphenol Chemical compound CC1=CC=C(O)C(CC=2C(=CC=C(C)C=2)O)=C1 XZXYQEHISUMZAT-UHFFFAOYSA-N 0.000 claims 1
HXDLWJWIAHWIKI-UHFFFAOYSA-N 2-hydroxyethyl acetate Chemical compound CC(=O)OCCO HXDLWJWIAHWIKI-UHFFFAOYSA-N 0.000 claims 1
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 1
230000003113 alkalizing effect Effects 0.000 claims 1
125000003277 amino group Chemical group 0.000 claims 1
125000005243 carbonyl alkyl group Chemical group 0.000 claims 1
239000003086 colorant Substances 0.000 claims 1
238000004043 dyeing Methods 0.000 claims 1
229940093476 ethylene glycol Drugs 0.000 claims 1
238000001033 granulometry Methods 0.000 claims 1
230000007062 hydrolysis Effects 0.000 claims 1
238000006460 hydrolysis reaction Methods 0.000 claims 1
HTUMBQDCCIXGCV-UHFFFAOYSA-N lead oxide Chemical compound [O-2].[Pb+2] HTUMBQDCCIXGCV-UHFFFAOYSA-N 0.000 claims 1
SIKJAQJRHWYJAI-UHFFFAOYSA-N Indole Chemical compound C1=CC=C2NC=CC2=C1 SIKJAQJRHWYJAI-UHFFFAOYSA-N 0.000 abstract 2
108010022355 Fibroins Proteins 0.000 abstract 1
229920001971 elastomer Polymers 0.000 abstract 1
239000000806 elastomer Substances 0.000 abstract 1
238000011065 in-situ storage Methods 0.000 abstract 1
PZOUSPYUWWUPPK-UHFFFAOYSA-N indole Natural products CC1=CC=CC2=C1C=CN2 PZOUSPYUWWUPPK-UHFFFAOYSA-N 0.000 abstract 1
RKJUIXBNRJVNHR-UHFFFAOYSA-N indolenine Natural products C1=CC=C2CC=NC2=C1 RKJUIXBNRJVNHR-UHFFFAOYSA-N 0.000 abstract 1
239000011347 resin Substances 0.000 abstract 1
229920005989 resin Polymers 0.000 abstract 1
239000000047 product Substances 0.000 description 32
238000001914 filtration Methods 0.000 description 30
238000005406 washing Methods 0.000 description 29
239000004615 ingredient Substances 0.000 description 28
238000003760 magnetic stirring Methods 0.000 description 27
150000001875 compounds Chemical class 0.000 description 22
HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 14
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 12
239000007864 aqueous solution Substances 0.000 description 11
230000001590 oxidative effect Effects 0.000 description 11
239000003921 oil Substances 0.000 description 8
NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Inorganic materials [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 description 8
239000000243 solution Substances 0.000 description 8
239000000975 dye Substances 0.000 description 7
235000019198 oils Nutrition 0.000 description 7
239000004166 Lanolin Substances 0.000 description 6
235000019388 lanolin Nutrition 0.000 description 6
229940039717 lanolin Drugs 0.000 description 6
238000003756 stirring Methods 0.000 description 6
HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 4
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 4
238000004040 coloring Methods 0.000 description 4
238000002156 mixing Methods 0.000 description 4
DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 4
JQWHASGSAFIOCM-UHFFFAOYSA-M sodium periodate Substances [Na+].[O-]I(=O)(=O)=O JQWHASGSAFIOCM-UHFFFAOYSA-M 0.000 description 4
239000001993 wax Substances 0.000 description 4
241000238424 Crustacea Species 0.000 description 3
241000238557 Decapoda Species 0.000 description 3
SXRSQZLOMIGNAQ-UHFFFAOYSA-N Glutaraldehyde Chemical compound O=CCCCC=O SXRSQZLOMIGNAQ-UHFFFAOYSA-N 0.000 description 3
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
125000002091 cationic group Chemical group 0.000 description 3
238000006243 chemical reaction Methods 0.000 description 3
235000010232 propyl p-hydroxybenzoate Nutrition 0.000 description 3
239000004405 propyl p-hydroxybenzoate Substances 0.000 description 3
235000015170 shellfish Nutrition 0.000 description 3
229910052708 sodium Inorganic materials 0.000 description 3
239000011734 sodium Substances 0.000 description 3
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
241000283690 Bos taurus Species 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
125000000129 anionic group Chemical group 0.000 description 2
235000013871 bee wax Nutrition 0.000 description 2
239000012166 beeswax Substances 0.000 description 2
239000008367 deionised water Substances 0.000 description 2
229910021641 deionized water Inorganic materials 0.000 description 2
238000004821 distillation Methods 0.000 description 2
239000010419 fine particle Substances 0.000 description 2
238000004108 freeze drying Methods 0.000 description 2
235000011187 glycerol Nutrition 0.000 description 2
230000037308 hair color Effects 0.000 description 2
229910052500 inorganic mineral Inorganic materials 0.000 description 2
XMBWDFGMSWQBCA-UHFFFAOYSA-M iodide Chemical compound [I-] XMBWDFGMSWQBCA-UHFFFAOYSA-M 0.000 description 2
BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
235000010270 methyl p-hydroxybenzoate Nutrition 0.000 description 2
239000004292 methyl p-hydroxybenzoate Substances 0.000 description 2
229960002216 methylparaben Drugs 0.000 description 2
239000011707 mineral Substances 0.000 description 2
229920000620 organic polymer Polymers 0.000 description 2
235000019271 petrolatum Nutrition 0.000 description 2
239000003505 polymerization initiator Substances 0.000 description 2
239000011148 porous material Substances 0.000 description 2
LPNYRYFBWFDTMA-UHFFFAOYSA-N potassium tert-butoxide Chemical compound [K+].CC(C)(C)[O-] LPNYRYFBWFDTMA-UHFFFAOYSA-N 0.000 description 2
ANBFRLKBEIFNQU-UHFFFAOYSA-M potassium;octadecanoate Chemical compound [K+].CCCCCCCCCCCCCCCCCC([O-])=O ANBFRLKBEIFNQU-UHFFFAOYSA-M 0.000 description 2
150000003254 radicals Chemical class 0.000 description 2
239000011877 solvent mixture Substances 0.000 description 2
239000004094 surface-active agent Substances 0.000 description 2
229960004418 trolamine Drugs 0.000 description 2
229940099259 vaseline Drugs 0.000 description 2
235000013311 vegetables Nutrition 0.000 description 2
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SVONRAPFKPVNKG-UHFFFAOYSA-N 2-ethoxyethyl acetate Chemical compound CCOCCOC(C)=O SVONRAPFKPVNKG-UHFFFAOYSA-N 0.000 description 1
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Classifications

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- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0241—Containing particulates characterized by their shape and/or structure
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- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/11—Encapsulated compositions
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- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/4906—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom
- A61K8/4913—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom having five membered rings, e.g. pyrrolidone carboxylic acid
- A61K8/492—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom having five membered rings, e.g. pyrrolidone carboxylic acid having condensed rings, e.g. indol
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- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
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- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/64—Proteins; Peptides; Derivatives or degradation products thereof
- A61K8/65—Collagen; Gelatin; Keratin; Derivatives or degradation products thereof
- A—HUMAN NECESSITIES
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- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
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- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
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- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/88—Polyamides
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- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
- A—HUMAN NECESSITIES
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- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
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- A61Q1/02—Preparations containing skin colorants, e.g. pigments
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- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/10—Preparations containing skin colorants, e.g. pigments for eyes, e.g. eyeliner, mascara
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
- A—HUMAN NECESSITIES
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- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/10—Preparations for permanently dyeing the hair
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
- C08K5/3415—Five-membered rings
- C08K5/3417—Five-membered rings condensed with carbocyclic rings
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- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/41—Particular ingredients further characterized by their size
- A61K2800/412—Microsized, i.e. having sizes between 0.1 and 100 microns
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/42—Colour properties
- A61K2800/43—Pigments; Dyes
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/56—Compounds, absorbed onto or entrapped into a solid carrier, e.g. encapsulated perfumes, inclusion compounds, sustained release forms

Landscapes

Health & Medical Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Veterinary Medicine (AREA)
Public Health (AREA)
General Health & Medical Sciences (AREA)
Animal Behavior & Ethology (AREA)
Epidemiology (AREA)
Birds (AREA)
Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Polymers & Plastics (AREA)
Medicinal Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Dermatology (AREA)
Cosmetics (AREA)
Pigments, Carbon Blacks, Or Wood Stains (AREA)
Processes Of Treating Macromolecular Substances (AREA)
Compositions Of Macromolecular Compounds (AREA)

LU87429A 1989-01-17 1989-01-17 Produit a base de particules de polymere comportant des pigments melaniques,son procede de preparation et son utilisation,en particulier en cosmetique LU87429A1 (fr)

Priority Applications (7)

Application Number	Priority Date	Filing Date	Title
LU87429A LU87429A1 (fr)	1989-01-17	1989-01-17	Produit a base de particules de polymere comportant des pigments melaniques,son procede de preparation et son utilisation,en particulier en cosmetique
EP90400099A EP0379409B1 (de)	1989-01-17	1990-01-15	Produkte auf der Basis von Melaninpigmente enthaltenden Polymerpartikeln, Verfahren zu ihrer Herstellung und ihre Verwendung, insbesondere in der Kosmetik
AT90400099T ATE94377T1 (de)	1989-01-17	1990-01-15	Produkte auf der basis von melaninpigmente enthaltenden polymerpartikeln, verfahren zu ihrer herstellung und ihre verwendung, insbesondere in der kosmetik.
DE90400099T DE69003258T2 (de)	1989-01-17	1990-01-15	Produkte auf der Basis von Melaninpigmente enthaltenden Polymerpartikeln, Verfahren zu ihrer Herstellung und ihre Verwendung, insbesondere in der Kosmetik.
ES90400099T ES2060077T3 (es)	1989-01-17	1990-01-15	Productos a base de particulas de polimero que comprenden pigmentos melanicos, su procedimiento de preparacion y su utilizacion, en particular en cosmetica.
CA002007957A CA2007957A1 (fr)	1989-01-17	1990-01-17	Produit a base de particules de polymere comportant des pigments melaniques, son procede de preparation et son utilisation, en particulier en cosmetique
JP2008070A JPH02232264A (ja)	1989-01-17	1990-01-17	ポリマー粒子からなる製品、その製造方法および化粧品組成物

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
LU87429A LU87429A1 (fr)	1989-01-17	1989-01-17	Produit a base de particules de polymere comportant des pigments melaniques,son procede de preparation et son utilisation,en particulier en cosmetique

Publications (1)

Publication Number	Publication Date
LU87429A1 true LU87429A1 (fr)	1990-07-24

Family

ID=19731136

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
LU87429A LU87429A1 (fr)	1989-01-17	1989-01-17	Produit a base de particules de polymere comportant des pigments melaniques,son procede de preparation et son utilisation,en particulier en cosmetique

Country Status (7)

Country	Link
EP (1)	EP0379409B1 (de)
JP (1)	JPH02232264A (de)
AT (1)	ATE94377T1 (de)
CA (1)	CA2007957A1 (de)
DE (1)	DE69003258T2 (de)
ES (1)	ES2060077T3 (de)
LU (1)	LU87429A1 (de)

Families Citing this family (43)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR2658720B1 (fr) *	1990-02-28	1994-09-09	Oreal	Composition cosmetique sous forme de poudre compactee contenant des microspheres creuses en materiau synthetique thermoplastique.
JP2879947B2 (ja) *	1990-06-04	1999-04-05	鐘紡株式会社	毛髪改質剤
JPH0441410A (ja) *	1990-06-05	1992-02-12	Kao Corp	化粧料組成物
LU87814A1 (fr) *	1990-09-27	1992-05-25	Oreal	Composition cosmetique comportant une dispersion de vesicules lipidiques ainsi que des pigments melaniques,et son utilisation
US5874091A (en) *	1990-09-27	1999-02-23	L'oreal	Cosmetic composition comprising a dispersion of lipid vesicles as well as melanin pigments
FR2675377B1 (fr) *	1991-04-22	1995-02-03	Oreal	Microspheres poreuses enrobees a l'aide d'une huile perfluoree, d'une huile de silicone fluoree ou d'une gomme de silicone et leur utilisation en cosmetique.
FR2677544B1 (fr) *	1991-06-14	1993-09-24	Oreal	Composition cosmetique contenant un melange de nanopigments d'oxydes metalliques et de pigments melaniques.
US5645609A (en) *	1991-08-01	1997-07-08	L'oreal	Compositions which contain and processes which use an insoluble pigment obtained by the oxidative polymerization of indole derivatives for the temporary dyeing of keratinous fibers
FR2679771A1 (fr) *	1991-08-01	1993-02-05	Oreal	Utilisation pour la teinture temporaire des fibres keratiniques d'un pigment insoluble obtenu par polymerisation oxydante de derives indoliques.
US5246780A (en) *	1991-08-29	1993-09-21	L'oreal	Coated particle for use in cosmetic preparations and method
FR2686248B1 (fr) *	1992-01-16	1994-04-15	Oreal	Produit a base de particules minerales ou organiques portant un produit indolinique, son procede de preparation et son utilisation en cosmetique.
FR2686344B1 (fr) *	1992-01-16	1994-04-15	Oreal	Produits indoliniques, leurs procedes de preparation et leur utilisation en cosmetique.
FR2686345A1 (fr) *	1992-01-16	1993-07-23	Oreal	Produit a base de particules minerales colorees comportant un pigment melanique, son procede de preparation et son utilisation en cosmetique.
AU2771792A (en) *	1992-03-31	1993-11-08	Kyowa Hakko Kogyo Co. Ltd.	Novel cosmetic
WO1993019721A1 (fr) *	1992-03-31	1993-10-14	Kyowa Hakko Kogyo Co., Ltd.	Produit cosmetique nouveau
GB9211708D0 (en) †	1992-06-03	1992-07-15	Unilever Plc	Cosmetic composition
FR2695033B1 (fr) *	1992-08-25	1994-11-25	Oreal	Polymère colorant mélanique hydrosoluble, son procédé d'abtention et son utilisation dans des compositions cosmétiques de coloration.
FR2722092B1 (fr) *	1994-07-11	1996-08-14	Oreal	Composition capillaire solide contenant un agent structurant particulaire
CN1092513C (zh) †	1994-09-19	2002-10-16	科洛尔迪雷克特公司	染发制品
FR2741530B1 (fr) *	1995-11-23	1998-01-02	Oreal	Utilisation pour la coloration temporaire des cheveux ou poils d'animaux d'une composition a base d'une dispersion de polymere filmogene et d'un pigment non-melanique
FR2744632B1 (fr) *	1996-02-13	1998-03-27	Oreal	Utilisation d'une suspension aqueuse de microfibrilles d'origine naturelle pour la preparation de compositions cosmetiques ou dermatologiques, compositions cosmetiques ou dermatologiques et applications
CN1188102C (zh) *	1998-06-05	2005-02-09	荷兰联合利华有限公司	头发护理组合物和在头发上沉积溶胀聚合物颗粒的方法
KR100330703B1 (ko) *	1998-10-17	2002-06-20	서경배	화장료용 복합안료 및 이의 제조방법
BR9804597A (pt)	1998-11-10	2000-05-30	Cosmeticos Natural Ind Com	Composição cosmética sob a forma de pó.
FR2788688B1 (fr) *	1999-01-25	2002-12-06	Merck Sa	Composition cosmetique anhydre essentiellement exempte de liant gras et procede de preparation d'une telle composition
US6814959B1 (en)	1999-07-13	2004-11-09	Pharmasol Gmbh	UV radiation reflecting or absorbing agents, protecting against harmful UV radiation and reinforcing the natural skin barrier
EP1103246A1 (de) *	1999-11-15	2001-05-30	Cognis Corporation	Wasserfreie PulverZusammensetzungen
IL150024A0 (en)	1999-12-08	2002-12-01	Allmighty Co Ltd	Radioprotective materials and utilization thereof
WO2001074310A2 (en) *	2000-03-31	2001-10-11	The Procter & Gamble Company	Leave-in hair cosmetic compositions for enhancing volume containing microspheres
JPWO2003063179A1 (ja)	2002-01-23	2005-05-26	株式会社オールマイティー	放射線防護物質及びその利用
FR2856594B1 (fr) *	2003-06-26	2006-03-03	Oreal	Particules poreuses chargees en compose(s) actif(s) cosmetique(s) ou pharmaceutique(s)
US20050031699A1 (en)	2003-06-26	2005-02-10	L'oreal	Porous particles loaded with cosmetically or pharmaceutically active compounds
FR2876025B1 (fr) *	2004-10-04	2007-02-09	Oreal	Composition cosmetique capillaire a base de particules creuses et de polyurethane fixant silicone
FR2876026B1 (fr) *	2004-10-04	2007-02-09	Oreal	Composition cosmetique capillaire a base de particules creuses et de polymere fixant non silicone
US7455850B2 (en)	2004-12-23	2008-11-25	Avon Products. Inc.	Two-part cosmetic product
FR2962032B1 (fr) *	2009-12-23	2019-11-15	L'oreal	Composition pour colorer les fibres keratiniques comprenant au moins un derive d'orthodiphenol, un agent oxydant, une argile et un agent alcalinisant
GB201615047D0 (en) *	2016-09-05	2016-10-19	Spheritech Ltd	Microparticle composition and use thereof
AU2019312917A1 (en) *	2018-07-31	2021-02-18	Wool Research Organisation Of New Zealand Incorporated	Keratin compositions
JP7236296B2 (ja) *	2019-03-22	2023-03-09	株式会社ミルボン	染毛用組成物及び染毛方法
FR3102363B1 (fr) *	2019-10-28	2021-12-03	Oreal	Procédé de traitement des fibres kératiniques au moyen d’une composition contenant de l’arginine et d’une composition oxydante
JP7379110B2 (ja) *	2019-11-21	2023-11-14	花王株式会社	構造発色に用いられるメラニン被覆粒子
JP2023124673A (ja) *	2022-02-25	2023-09-06	北海道曹達株式会社	組成物及び複合体の製造方法
CN115197118B (zh) *	2022-06-21	2024-01-23	贵州医科大学	一种3,3双取代硫化氧化吲哚衍生物的合成方法

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IT1143699B (it) *	1976-11-29	1986-10-22	Hoffmann La Roche	Preparato cosmetico per shampoo secco contenente cellulosa sotto forma di polvere
LU86668A1 (fr) *	1986-11-17	1988-06-13	Oreal	Procede de teinture des fibres keratiniques avec des derives d'indole associes avec un iodure
LU86946A1 (fr) *	1987-07-17	1989-03-08	Oreal	Poudre ultrafine comportant des pigments melaniques,son procede de preparation et son utilisation en cosmetique
US4855144A (en) *	1987-10-23	1989-08-08	Advanced Polymer Systems	Synthetic melanin aggregates

1989
- 1989-01-17 LU LU87429A patent/LU87429A1/fr unknown
1990
- 1990-01-15 AT AT90400099T patent/ATE94377T1/de not_active IP Right Cessation
- 1990-01-15 DE DE90400099T patent/DE69003258T2/de not_active Expired - Fee Related
- 1990-01-15 ES ES90400099T patent/ES2060077T3/es not_active Expired - Lifetime
- 1990-01-15 EP EP90400099A patent/EP0379409B1/de not_active Expired - Lifetime
- 1990-01-17 CA CA002007957A patent/CA2007957A1/fr not_active Abandoned
- 1990-01-17 JP JP2008070A patent/JPH02232264A/ja active Pending

Also Published As

Publication number	Publication date
EP0379409B1 (de)	1993-09-15
CA2007957A1 (fr)	1990-07-17
ES2060077T3 (es)	1994-11-16
ATE94377T1 (de)	1993-10-15
DE69003258T2 (de)	1994-01-13
JPH02232264A (ja)	1990-09-14
DE69003258D1 (de)	1993-10-21
EP0379409A1 (de)	1990-07-25

Publication	Publication Date	Title
EP0379409B1 (de)	1993-09-15	Produkte auf der Basis von Melaninpigmente enthaltenden Polymerpartikeln, Verfahren zu ihrer Herstellung und ihre Verwendung, insbesondere in der Kosmetik
CA2071276C (fr)	2006-05-23	Composition cosmetique contenant un melange de nanopigments d'oxydes metalliques et de pigments melaniques
EP0575605B1 (de)	1996-11-27	Mittel auf basis von anorganischen oder organischen partikeln mit einer indolinverbindung
EP0467767B1 (de)	1994-09-21	Produkte auf Basis von Melaninpigment enthaltenden plättchenförmigen Partikeln und Verfahren zu ihrer Herstellung
CA2102095C (fr)	2008-08-19	Composition cosmetique contenant des pigments melaniques en association avec certains tocopherols, et procede de protection de la peau, des cheveux, des muqueuses et des compositions cosmetiques
CA2105280C (fr)	2004-04-13	Produit a base de particules minerales colorees comportant un pigment melanique, son procede de preparation et son utilisation en cosmetique
CA2119360C (fr)	2002-03-26	Dispersion fine de pigments melaniques, sa preparation et son utilisation en cosmetique
CH676243A5 (de)	1990-12-28
EP0575604B1 (de)	1995-12-06	Indolin-produkte, ihren verfahren zu deren herstellung sowie ihren verwendung in der kosmetik
EP0504347B1 (de)	1994-12-28	Eine lipidvesikeldispersion und melaninpigmente enthaltendes kosmetikum
EP0647255B1 (de)	1999-12-15	Herstellungsverfahren eines melaninpigments von geringer korngrösse sowie seine anwendung in der kosmetik
FR2695033A1 (fr)	1994-03-04	Polymère colorant mélanique hydrosoluble, son procédé d'abtention et son utilisation dans des compositions cosmétiques de coloration.