MA20150423A1 - Production de phosphates d'ammonium - Google Patents
Production de phosphates d'ammoniumInfo
- Publication number
- MA20150423A1 MA20150423A1 MA37787A MA37787A MA20150423A1 MA 20150423 A1 MA20150423 A1 MA 20150423A1 MA 37787 A MA37787 A MA 37787A MA 37787 A MA37787 A MA 37787A MA 20150423 A1 MA20150423 A1 MA 20150423A1
- Authority
- MA
- Morocco
- Prior art keywords
- phosphate
- liquid
- solvent
- extraction
- washing
- Prior art date
Links
- 239000004254 Ammonium phosphate Substances 0.000 title abstract 3
- 235000019289 ammonium phosphates Nutrition 0.000 title abstract 3
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- ZRIUUUJAJJNDSS-UHFFFAOYSA-N ammonium phosphates Chemical class [NH4+].[NH4+].[NH4+].[O-]P([O-])([O-])=O ZRIUUUJAJJNDSS-UHFFFAOYSA-N 0.000 title 1
- 229910019142 PO4 Inorganic materials 0.000 abstract 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract 5
- 239000010452 phosphate Substances 0.000 abstract 5
- 235000021317 phosphate Nutrition 0.000 abstract 5
- 239000002904 solvent Substances 0.000 abstract 4
- 238000005406 washing Methods 0.000 abstract 4
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical class [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 abstract 3
- 238000000605 extraction Methods 0.000 abstract 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 abstract 2
- 229910000148 ammonium phosphate Inorganic materials 0.000 abstract 2
- 238000000622 liquid--liquid extraction Methods 0.000 abstract 2
- 239000000243 solution Substances 0.000 abstract 2
- 238000000638 solvent extraction Methods 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- 229910002651 NO3 Inorganic materials 0.000 abstract 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 abstract 1
- 229910021529 ammonia Inorganic materials 0.000 abstract 1
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 abstract 1
- 229910000387 ammonium dihydrogen phosphate Inorganic materials 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 238000001816 cooling Methods 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 235000019837 monoammonium phosphate Nutrition 0.000 abstract 1
- 239000006012 monoammonium phosphate Substances 0.000 abstract 1
- -1 nitrate ions Chemical class 0.000 abstract 1
- 239000002244 precipitate Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/16—Oxyacids of phosphorus; Salts thereof
- C01B25/46—Preparation involving solvent-solvent extraction
- C01B25/461—Preparation involving solvent-solvent extraction the phosphoric acid present in the medium obtained after reaction being first extracted from the liquid phase formed or separated then re-extracted as free acid by using water or as a phosphate by using a basic compound
- C01B25/462—Preparation involving solvent-solvent extraction the phosphoric acid present in the medium obtained after reaction being first extracted from the liquid phase formed or separated then re-extracted as free acid by using water or as a phosphate by using a basic compound the extracting agent being alcohol or a mixture of alcohols
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D11/00—Solvent extraction
- B01D11/04—Solvent extraction of solutions which are liquid
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D9/00—Crystallisation
- B01D9/0004—Crystallisation cooling by heat exchange
- B01D9/0013—Crystallisation cooling by heat exchange by indirect heat exchange
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/16—Oxyacids of phosphorus; Salts thereof
- C01B25/26—Phosphates
- C01B25/28—Ammonium phosphates
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/16—Oxyacids of phosphorus; Salts thereof
- C01B25/46—Preparation involving solvent-solvent extraction
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/16—Oxyacids of phosphorus; Salts thereof
- C01B25/46—Preparation involving solvent-solvent extraction
- C01B25/461—Preparation involving solvent-solvent extraction the phosphoric acid present in the medium obtained after reaction being first extracted from the liquid phase formed or separated then re-extracted as free acid by using water or as a phosphate by using a basic compound
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B11/00—Fertilisers produced by wet-treating or leaching raw materials either with acids in such amounts and concentrations as to yield solutions followed by neutralisation, or with alkaline lyes
- C05B11/04—Fertilisers produced by wet-treating or leaching raw materials either with acids in such amounts and concentrations as to yield solutions followed by neutralisation, or with alkaline lyes using mineral acid
- C05B11/08—Fertilisers produced by wet-treating or leaching raw materials either with acids in such amounts and concentrations as to yield solutions followed by neutralisation, or with alkaline lyes using mineral acid using sulfuric acid
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B11/00—Fertilisers produced by wet-treating or leaching raw materials either with acids in such amounts and concentrations as to yield solutions followed by neutralisation, or with alkaline lyes
- C05B11/04—Fertilisers produced by wet-treating or leaching raw materials either with acids in such amounts and concentrations as to yield solutions followed by neutralisation, or with alkaline lyes using mineral acid
- C05B11/10—Fertilisers produced by wet-treating or leaching raw materials either with acids in such amounts and concentrations as to yield solutions followed by neutralisation, or with alkaline lyes using mineral acid using orthophosphoric acid
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B7/00—Fertilisers based essentially on alkali or ammonium orthophosphates
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05C—NITROGENOUS FERTILISERS
- C05C3/00—Fertilisers containing other salts of ammonia or ammonia itself, e.g. gas liquor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/24—Stationary reactors without moving elements inside
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Analytical Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Extraction Or Liquid Replacement (AREA)
- Fertilizers (AREA)
- Physical Water Treatments (AREA)
- Manufacture And Refinement Of Metals (AREA)
Abstract
La présente invention concerne un système (100) servant à la production de phosphates de mono- ou de di-ammonium complètement solubles, purs et bien définis, ledit système comprenant une section d'extraction (10), une section de lavage (20) et des systèmes de traitement final (90). La section d'extraction effectue une extraction liquide-liquide du phosphate entre un liquide de charge (1) comprenant de l'acide phosphorique et essentiellement exempt d'ions nitrate, et un solvant (5) ayant une solubilité inférieure à 2 % dans l'eau. La section de lavage effectue une extraction liquide-liquide du phosphate entre le solvant chargé en phosphate et une solution de lavage (4). Le solvant appauvri en phosphate est remis en circulation vers la section d'extraction afin d'extraire de nouveau le phosphate. La solution de lavage est une solution aqueuse de phosphate d'ammonium, au moins 80 % du phosphate d'ammonium étant du phosphate de monoammonium et/ou le solvant étant un alcool non miscible à l'eau. Les systèmes de traitement final comprennent une source d'ammoniac (60), un système d'addition (70), un système de refroidissement (50), un dispositif d'élimination de précipité (40) et un système de recirculation (80).
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SE1250666A SE536607C2 (sv) | 2012-06-21 | 2012-06-21 | Framställning av ammoniumfosfater |
| PCT/SE2013/050736 WO2013191639A1 (fr) | 2012-06-21 | 2013-06-19 | Production de phosphates d'ammonium |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| MA20150423A1 true MA20150423A1 (fr) | 2015-11-30 |
| MA37787B1 MA37787B1 (fr) | 2016-06-30 |
Family
ID=49769961
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MA37787A MA37787B1 (fr) | 2012-06-21 | 2013-06-19 | Production de phosphates d'ammonium |
Country Status (22)
| Country | Link |
|---|---|
| US (1) | US9738522B2 (fr) |
| EP (1) | EP2864249B1 (fr) |
| JP (1) | JP6301325B2 (fr) |
| CN (1) | CN104411626B (fr) |
| AU (1) | AU2013277841B2 (fr) |
| BR (1) | BR112014032059B1 (fr) |
| CA (1) | CA2877271C (fr) |
| DK (1) | DK2864249T3 (fr) |
| ES (1) | ES2776028T3 (fr) |
| HR (1) | HRP20200318T1 (fr) |
| HU (1) | HUE048440T2 (fr) |
| IL (1) | IL235922B (fr) |
| LT (1) | LT2864249T (fr) |
| MA (1) | MA37787B1 (fr) |
| PL (1) | PL2864249T3 (fr) |
| PT (1) | PT2864249T (fr) |
| RS (1) | RS60047B1 (fr) |
| RU (1) | RU2632009C2 (fr) |
| SE (1) | SE536607C2 (fr) |
| SI (1) | SI2864249T1 (fr) |
| TN (1) | TN2014000482A1 (fr) |
| WO (1) | WO2013191639A1 (fr) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105329868A (zh) * | 2015-10-30 | 2016-02-17 | 东华工程科技股份有限公司 | 一种从合成氨尾气中回收氨和氢气的方法 |
| SE541387C2 (en) * | 2017-12-19 | 2019-09-10 | Easymining Sweden Ab | Chemical processing of struvite |
| CN109675340B (zh) * | 2019-03-07 | 2021-12-14 | 黄河三角洲京博化工研究院有限公司 | 一种清洗废轧制油油泥的脱油剂及其使用方法 |
| CN110877901B (zh) * | 2019-12-16 | 2023-02-28 | 瓮福达州化工有限责任公司 | 湿法磷酸生产工业级磷酸一铵和工业级磷酸二铵的方法及系统 |
| CN115916730B (zh) * | 2020-06-12 | 2025-11-04 | 易开采瑞典有限公司 | 磷酸钾的生产 |
| SE2051374A1 (en) | 2020-11-25 | 2022-04-26 | Easymining Sweden Ab | Recovery of commercial substances from apatite mineral |
| DE102021205595A1 (de) * | 2021-06-01 | 2022-12-01 | Glatt Ingenieurtechnik Gesellschaft mit beschränkter Haftung | Verfahren und Vorrichtung zur Herstellung von Düngemittelgranulat |
| CN113648958B (zh) * | 2021-08-24 | 2022-08-30 | 天门安安化工科技有限公司 | 以氨气或可溶性碱为原料的可溶性次磷酸盐的连续生产系统及方法 |
| WO2023246540A1 (fr) * | 2022-06-20 | 2023-12-28 | 贵州芭田生态工程有限公司 | Procédé de co-production de phosphate de fer au moyen d'un appareil d'engrais nitrophosphaté, produit et système |
| SE546748C2 (en) * | 2022-07-01 | 2025-02-18 | Plagazi Ab | A method for extraction of phosphorous and a system as such |
| SE546282C2 (en) * | 2023-01-27 | 2024-09-24 | Easymining Sweden Ab | Processing of phosphate solutions |
| BE1032303B1 (fr) * | 2023-12-28 | 2025-08-12 | Prayon | Procédé de production d’orthophosphate d’ammonium cristallin |
| BE1031854B1 (fr) * | 2023-12-28 | 2025-02-25 | Prayon | Procédé de production d’orthophosphate d’ammonium cristallin |
Family Cites Families (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB636035A (en) | 1946-04-26 | 1950-04-19 | Monsanto Chemicals | Improvements in or relating to process of producing diammonium phosphate and the product resulting therefrom |
| US3072461A (en) | 1960-07-29 | 1963-01-08 | Dow Chemical Co | Preparation of phosphoric acid |
| GB1128104A (en) | 1965-05-25 | 1968-09-25 | Chem & Phosphates Ltd | A process for the production of concentrated phosphoric acid |
| US3415619A (en) * | 1966-06-30 | 1968-12-10 | Dow Chemical Co | Process for making ammonium phosphate |
| US3518071A (en) | 1967-01-23 | 1970-06-30 | Chemical Construction Corp | Production of nitrophosphate fertilizer and ammonium nitrate-calcium carbonate fertilizers |
| FR1540488A (fr) | 1967-08-17 | 1968-09-27 | Azote Office Nat Ind | Fabrication de phosphates et de nitrate d'ammonium à partir des phosphates naturels |
| DE2204779B2 (de) | 1972-02-02 | 1976-06-16 | Friedrich Uhde Gmbh, 4600 Dortmund | Verfahren zur herstellung von ammonphosphaten |
| SU424849A1 (ru) * | 1972-05-12 | 1974-04-25 | Б. Н. Ласкорин, Ш. Голынко , Г. К. Целпщев | СПОСОБ ПОЛУЧЕНИЯ ФОСФАТОВ АММОПИЯ1 ,*f :'й г- '••^'•, • ,. Г^-:'' • |Ф1>&1Д ;. .'.Mi.; i•:^J |
| US3975178A (en) | 1973-10-12 | 1976-08-17 | Tennessee Valley Authority | Purification of wet-process phosphoric acid with methanol and ammonia |
| US4024225A (en) * | 1973-11-02 | 1977-05-17 | United States Steel Corporation | Method of making high purity alkali metal phosphates from wet-process phosphoric acid |
| US4082836A (en) * | 1975-07-02 | 1978-04-04 | Occidental Petroleum Corporation | Process for the purification of phosphoric acid by extraction |
| GB1560984A (en) | 1975-08-05 | 1980-02-13 | Albright & Wilson | Process for preparing phosphate salts |
| UST952002I4 (fr) * | 1975-08-29 | 1976-11-02 | ||
| US4053564A (en) * | 1976-05-20 | 1977-10-11 | Occidental Petroleum Company | Extraction process for purification of phosphoric acid |
| ZA774159B (en) * | 1977-10-27 | 1978-07-26 | Albright & Wilson | Process for preparing phosphate salts |
| US4236911A (en) * | 1979-11-08 | 1980-12-02 | Tennessee Valley Authority | Purification and conversion of phosphoric acid to ammonium phosphates |
| US4325927A (en) * | 1979-12-14 | 1982-04-20 | Agrico Chemical Company | Purified monoammonium phosphate process |
| US4311681A (en) | 1980-05-19 | 1982-01-19 | Fmc Corporation | Method of regenerating phosphoric acid extraction solvent |
| DE3246416A1 (de) * | 1982-12-15 | 1984-06-20 | Hoechst Ag, 6230 Frankfurt | Verfahren zur reinigung von nassverfahrensphosphorsaeure |
| DE3246415A1 (de) * | 1982-12-15 | 1984-06-20 | Hoechst Ag, 6230 Frankfurt | Verfahren zur reinigung von nassverfahrenphosphorsaeure |
| DE3413020A1 (de) | 1984-04-06 | 1985-10-17 | Hoechst Ag, 6230 Frankfurt | Verfahren zur herstellung einer alkaliphosphatloesung |
| US4751066A (en) | 1986-05-08 | 1988-06-14 | Fmc Corporation | Process for preparing alkali metal phosphate |
| US4781905A (en) * | 1986-05-30 | 1988-11-01 | Yu Ming Jiang | Process for producing phosphoric acid and/or phosphates from wet-process phosphoric acid and an extractant therein |
| GR862922B (en) * | 1986-12-18 | 1987-01-12 | Himikes Viomihanies Voreiou El | Tubular reactor |
| RU2022919C1 (ru) * | 1991-04-12 | 1994-11-15 | Воскресенский филиал Научно-исследовательского института по удобрениям и инсектофунгицидам им.проф.Я.В.Самойлова | Установка для получения растворов аммонийфосфатов |
| RU2205789C1 (ru) * | 2002-06-07 | 2003-06-10 | Открытое акционерное общество "Воскресенский научно-исследовательский институт по удобрениям и фосфорной кислоте" | Способ очистки экстракционной фосфорной кислоты |
| CN100396600C (zh) * | 2006-06-01 | 2008-06-25 | 武汉工程大学 | 固液反萃法制取磷铵的工艺 |
| CN101679038B (zh) | 2007-03-19 | 2012-10-10 | 易开采瑞典有限公司 | 磷的回收 |
| SE535871C2 (sv) * | 2009-05-27 | 2013-01-22 | Easymining Sweden Ab | Produktion av ammoniumfosfater |
-
2012
- 2012-06-21 SE SE1250666A patent/SE536607C2/sv unknown
-
2013
- 2013-06-19 LT LTEP13806613.9T patent/LT2864249T/lt unknown
- 2013-06-19 BR BR112014032059-4A patent/BR112014032059B1/pt active IP Right Grant
- 2013-06-19 RS RS20200257A patent/RS60047B1/sr unknown
- 2013-06-19 CA CA2877271A patent/CA2877271C/fr active Active
- 2013-06-19 DK DK13806613.9T patent/DK2864249T3/da active
- 2013-06-19 RU RU2014150476A patent/RU2632009C2/ru active
- 2013-06-19 HU HUE13806613A patent/HUE048440T2/hu unknown
- 2013-06-19 WO PCT/SE2013/050736 patent/WO2013191639A1/fr not_active Ceased
- 2013-06-19 CN CN201380032865.XA patent/CN104411626B/zh active Active
- 2013-06-19 JP JP2015518378A patent/JP6301325B2/ja active Active
- 2013-06-19 PL PL13806613T patent/PL2864249T3/pl unknown
- 2013-06-19 US US14/409,131 patent/US9738522B2/en active Active
- 2013-06-19 MA MA37787A patent/MA37787B1/fr unknown
- 2013-06-19 PT PT138066139T patent/PT2864249T/pt unknown
- 2013-06-19 HR HRP20200318TT patent/HRP20200318T1/hr unknown
- 2013-06-19 SI SI201331679T patent/SI2864249T1/sl unknown
- 2013-06-19 EP EP13806613.9A patent/EP2864249B1/fr active Active
- 2013-06-19 ES ES13806613T patent/ES2776028T3/es active Active
- 2013-06-19 AU AU2013277841A patent/AU2013277841B2/en active Active
-
2014
- 2014-11-20 TN TN2014000482A patent/TN2014000482A1/fr unknown
- 2014-11-26 IL IL235922A patent/IL235922B/en active IP Right Grant
Also Published As
| Publication number | Publication date |
|---|---|
| US20150360946A1 (en) | 2015-12-17 |
| PT2864249T (pt) | 2020-03-10 |
| JP2015527960A (ja) | 2015-09-24 |
| AU2013277841B2 (en) | 2015-12-24 |
| SE1250666A1 (sv) | 2013-12-22 |
| RU2632009C2 (ru) | 2017-10-02 |
| RS60047B1 (sr) | 2020-04-30 |
| RU2014150476A (ru) | 2016-08-10 |
| TN2014000482A1 (en) | 2016-03-30 |
| CA2877271C (fr) | 2020-07-07 |
| CN104411626A (zh) | 2015-03-11 |
| CA2877271A1 (fr) | 2013-12-27 |
| MA37787B1 (fr) | 2016-06-30 |
| IL235922B (en) | 2018-07-31 |
| EP2864249A1 (fr) | 2015-04-29 |
| EP2864249B1 (fr) | 2019-12-11 |
| JP6301325B2 (ja) | 2018-03-28 |
| BR112014032059A2 (pt) | 2017-06-27 |
| HRP20200318T1 (hr) | 2020-09-04 |
| PL2864249T3 (pl) | 2020-06-29 |
| ES2776028T3 (es) | 2020-07-28 |
| DK2864249T3 (da) | 2020-03-16 |
| SI2864249T1 (sl) | 2020-07-31 |
| LT2864249T (lt) | 2020-03-25 |
| SE536607C2 (sv) | 2014-03-25 |
| AU2013277841A1 (en) | 2015-01-22 |
| HUE048440T2 (hu) | 2020-07-28 |
| WO2013191639A1 (fr) | 2013-12-27 |
| CN104411626B (zh) | 2017-08-08 |
| BR112014032059B1 (pt) | 2021-12-21 |
| EP2864249A4 (fr) | 2016-04-06 |
| US9738522B2 (en) | 2017-08-22 |
| IL235922A0 (en) | 2015-01-29 |
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