MA28050A1 - Nouveaux sulfonamides en tant que produits protecteurs de plantes - Google Patents
Nouveaux sulfonamides en tant que produits protecteurs de plantesInfo
- Publication number
- MA28050A1 MA28050A1 MA28905A MA28905A MA28050A1 MA 28050 A1 MA28050 A1 MA 28050A1 MA 28905 A MA28905 A MA 28905A MA 28905 A MA28905 A MA 28905A MA 28050 A1 MA28050 A1 MA 28050A1
- Authority
- MA
- Morocco
- Prior art keywords
- alkyl
- hydrogen
- alkoxy
- phenyl
- sulfonamides
- Prior art date
Links
- 229940124530 sulfonamide Drugs 0.000 title abstract 3
- 150000003456 sulfonamides Chemical class 0.000 title abstract 3
- 230000001681 protective effect Effects 0.000 title 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 5
- 239000001257 hydrogen Substances 0.000 abstract 5
- 125000000217 alkyl group Chemical group 0.000 abstract 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical class [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 3
- 125000003545 alkoxy group Chemical group 0.000 abstract 3
- 125000003342 alkenyl group Chemical group 0.000 abstract 2
- 125000000304 alkynyl group Chemical group 0.000 abstract 2
- 229910052736 halogen Inorganic materials 0.000 abstract 2
- 150000002367 halogens Chemical class 0.000 abstract 2
- 125000004970 halomethyl group Chemical group 0.000 abstract 2
- 150000002431 hydrogen Chemical class 0.000 abstract 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 2
- 229920006395 saturated elastomer Polymers 0.000 abstract 2
- 241000233866 Fungi Species 0.000 abstract 1
- CIUQDSCDWFSTQR-UHFFFAOYSA-N [C]1=CC=CC=C1 Chemical compound [C]1=CC=CC=C1 CIUQDSCDWFSTQR-UHFFFAOYSA-N 0.000 abstract 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 abstract 1
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 abstract 1
- 125000000262 haloalkenyl group Chemical group 0.000 abstract 1
- 125000001188 haloalkyl group Chemical group 0.000 abstract 1
- 125000000232 haloalkynyl group Chemical group 0.000 abstract 1
- 125000005842 heteroatom Chemical group 0.000 abstract 1
- 125000001624 naphthyl group Chemical group 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 230000003032 phytopathogenic effect Effects 0.000 abstract 1
- 239000004476 plant protection product Substances 0.000 abstract 1
- 125000001424 substituent group Chemical group 0.000 abstract 1
- 229910052717 sulfur Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/24—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D213/36—Radicals substituted by singly-bound nitrogen atoms
- C07D213/42—Radicals substituted by singly-bound nitrogen atoms having hetero atoms attached to the substituent nitrogen atom
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
- A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
- A01N41/04—Sulfonic acids; Derivatives thereof
- A01N41/06—Sulfonic acid amides
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
- C04B35/63—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
- C04B35/632—Organic additives
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D215/00—Heterocyclic compounds containing quinoline or hydrogenated quinoline ring systems
- C07D215/02—Heterocyclic compounds containing quinoline or hydrogenated quinoline ring systems having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen atoms or carbon atoms directly attached to the ring nitrogen atom
- C07D215/12—Heterocyclic compounds containing quinoline or hydrogenated quinoline ring systems having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen atoms or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
- C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
- C07D401/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D409/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms
- C07D409/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings
- C07D409/12—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings linked by a chain containing hetero atoms as chain links
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Ceramic Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Health & Medical Sciences (AREA)
- Zoology (AREA)
- Plant Pathology (AREA)
- Agronomy & Crop Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Pest Control & Pesticides (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Plural Heterocyclic Compounds (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
- Pyridine Compounds (AREA)
- Quinoline Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
Nouveaux sulfonamides en tant que produits protecteurs de plantes Résumé Sulfonamides de la formule I dans laquelle les substituants ont la signification suivante: R1 hydrogène, alkyle, alkoxy, alcényle ou alcynyle; et R2, R3, R4, R5 hydrogène, halogène, alkyle, alkoxy ou halogénométhyle; et R2 et R3 peuvent également former conjointement un cycle phényle, cyclopentyle ou cyclohexyle, ces cycles pouvant porter deux groupements R2' et R3', R2', R3' hydrogène, halogène, alkyle, alkoxy ou halogénométhyle; et dans le cas a), lorsque R2, R3, R4 et R5 signifient l'hydrogène: X veut dire un radical phényle, qui est substitué par un groupement -C(R6)=NOR7, avec R6 alkyle et R7 alkyle, benzyle, alcényle, halogénoalkyle, halogénoalcényle, alcynyle ou halogénoalcynyle; et dans le cas b), lorsqu'au moins l'un des groupements R2;, R3, R4 et R5 ne signifie pas l'hydrogène: X veut dire un radical phényle, naphtyle ou un hétérocycle saturé, partiellement saturé ou aromatique, à cinq ou six membres liés par l'intermédiaire d'un atome C, contenant un à quatre hétéroatomes du groupe O, N ou S, X pouvant être substitué conformément à la description; Procédé en vue de la préparation de ces composés, des agents les contenant ainsi qu'utilisation dans la lutte contre les champignons nuisibles phytopathogènes.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP03021098 | 2003-09-18 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MA28050A1 true MA28050A1 (fr) | 2006-07-03 |
Family
ID=34400459
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MA28905A MA28050A1 (fr) | 2003-09-18 | 2006-03-31 | Nouveaux sulfonamides en tant que produits protecteurs de plantes |
Country Status (23)
| Country | Link |
|---|---|
| US (2) | US7388018B2 (fr) |
| EP (1) | EP1663976B1 (fr) |
| JP (1) | JP4477006B2 (fr) |
| KR (1) | KR20060070563A (fr) |
| CN (1) | CN100406442C (fr) |
| AP (1) | AP2006003564A0 (fr) |
| AR (2) | AR045767A1 (fr) |
| AT (1) | ATE453625T1 (fr) |
| AU (1) | AU2004278095B2 (fr) |
| BR (1) | BRPI0414410A (fr) |
| CA (1) | CA2537486A1 (fr) |
| CO (1) | CO5660289A2 (fr) |
| CR (1) | CR8312A (fr) |
| DE (1) | DE502004010595D1 (fr) |
| EA (1) | EA008948B1 (fr) |
| EC (1) | ECSP066463A (fr) |
| IL (1) | IL173854A0 (fr) |
| MA (1) | MA28050A1 (fr) |
| MX (1) | MXPA06002500A (fr) |
| NZ (1) | NZ546218A (fr) |
| UA (1) | UA82124C2 (fr) |
| WO (1) | WO2005033081A1 (fr) |
| ZA (1) | ZA200602966B (fr) |
Families Citing this family (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4513808B2 (ja) * | 2004-07-02 | 2010-07-28 | 株式会社クレハ | ２，６−ジクロロ−４−ピリジルメチルアミン誘導体および農園芸用病害防除剤 |
| US20080161187A1 (en) * | 2005-03-16 | 2008-07-03 | Basf Aktiengesellschaft | Biphenyl-N-(4-Pyridyl) Methylsulfonamides |
| AU2006224567A1 (en) * | 2005-03-16 | 2006-09-21 | Basf Aktiengesellschaft | Use of N- (4-pyridyl) methylsulfonamides for combating arthropodal pests |
| KR20080104310A (ko) | 2006-02-14 | 2008-12-02 | 바스프 에스이 | 해충 방제를 위한 피리딘-4-일메틸아미드 |
| EP2007727A1 (fr) * | 2006-03-15 | 2008-12-31 | Basf Se | Dérivés de quinoline et leur emploi en tant que pesticides |
| US20100222219A1 (en) * | 2006-08-22 | 2010-09-02 | Basf Se | Thiophene-Sulphonic Acid Picolyl Amides |
| BRPI0716938A2 (pt) * | 2006-09-12 | 2013-09-17 | Basf Se | compostos, processo para a preparaÇço de compostos de quinolina, uso dos compostos, composiÇÕes, mÉtodos para o controle de pestes de artràpodes ou de nematàides, para a proteÇço de plantas em crescimento contra o ataque ou a infestaÇço por pestes de artràpodes ou de nematàides, para a proteÇço de sementes, e para o tratamento, o controle, a prevenÇço ou a proteÇço de animais contra a infestaÇço ou a infecÇço por parasitas, semente, e, misturas pesticidas sinergÍsticas |
| KR20090080565A (ko) | 2006-11-22 | 2009-07-24 | 바스프 에스이 | 살진균제로서 및 절지동물에 대해 유용한 피리미딜메틸-설폰아미드 화합물 |
| BRPI0719068A2 (pt) * | 2006-11-22 | 2013-11-26 | Basf Se | Compostos, processo para preparar compostos, composição agrícola, métodos para tratar fungos nocivos fitopatogênicos, e para combater pragar de artrópode, uso de compostos, e, semente |
| ES2545121T3 (es) * | 2007-08-21 | 2015-09-08 | Senomyx, Inc. | Compuestos que inhiben (bloquean) el sabor amargo en composiciones, y uso de los mismos |
| CA2705489A1 (fr) * | 2007-12-05 | 2009-06-11 | Basf Se | Composes pyridylmethyle sulfonamide |
| EP2252606A1 (fr) * | 2008-02-15 | 2010-11-24 | Basf Se | Composés de pyrimidylméthyl-sulfonamide |
| CN102007103A (zh) * | 2008-02-15 | 2011-04-06 | 巴斯夫欧洲公司 | 取代的磺酰胺化合物 |
| WO2009103650A1 (fr) * | 2008-02-22 | 2009-08-27 | Basf Se | Composés de sulfamide et leur utilisation en tant que fongicides |
| BRPI0909041A2 (pt) * | 2008-03-14 | 2015-07-28 | Basf Se | Compostos, uso de compostos, processo para preparar compostos, composições agroquímicas, método para combater fungos fitopatogênicos, e, semente. |
| WO2009124903A1 (fr) * | 2008-04-10 | 2009-10-15 | Basf Se | Pyridazinylméthylsulfonamides substitués |
| BRPI0912746A2 (pt) * | 2008-05-20 | 2015-07-28 | Basf Se | Compostos, processo para preparar compostos, composições agroquímicas, método para combater fungos fitopatogênicos, e, semente |
| US20110130283A1 (en) * | 2008-05-20 | 2011-06-02 | Basf Se | Substituted Pyridin-4-ylmethyl Sulfonamides |
| US20110065578A1 (en) | 2008-05-21 | 2011-03-17 | Basf Se | Substituted Pyridin-4-ylmethyl Sulfonamides |
| US8829026B2 (en) | 2010-10-01 | 2014-09-09 | Raqualia Pharma Inc. | Sulfamoyl benzoic acid heterobicyclic derivatives as TRPM8 antagonists |
| JP2014520151A (ja) * | 2011-06-20 | 2014-08-21 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | 蠕虫感染を処置するためのヘテロ環式化合物 |
| TW201326128A (zh) * | 2011-11-28 | 2013-07-01 | Du Pont | 磺醯胺驅蟲劑 |
| JPWO2014065411A1 (ja) * | 2012-10-26 | 2016-09-08 | 株式会社エス・ディー・エス バイオテック | 農園芸用の有害生物防除剤としてのスルホンアミド誘導体 |
| WO2014099837A1 (fr) | 2012-12-18 | 2014-06-26 | E. I. Du Pont De Nemours And Company | Sulfonamide anti-helminthique |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES8200663A1 (es) | 1980-06-23 | 1981-06-01 | Made Labor Sa | Un metodo para la produccion industrial de n-(4-piridilme- til)-benzamidas |
| US4874775A (en) * | 1985-06-11 | 1989-10-17 | Eli Lilly And Company | Agriculturally useful sulfonamides |
| US4699652A (en) | 1985-07-22 | 1987-10-13 | Hoffmann-La Roche Inc. | Fungicidal pyridine derivatives for use in agriculture |
| CA2338994A1 (fr) | 1998-07-31 | 2000-02-10 | Paul Leslie Ornstein | Derives de sulfonamide |
| US6586617B1 (en) * | 1999-04-28 | 2003-07-01 | Sumitomo Chemical Takeda Agro Company, Limited | Sulfonamide derivatives |
-
2004
- 2004-09-10 EA EA200600490A patent/EA008948B1/ru not_active IP Right Cessation
- 2004-09-10 CA CA002537486A patent/CA2537486A1/fr not_active Abandoned
- 2004-09-10 JP JP2006526566A patent/JP4477006B2/ja not_active Expired - Lifetime
- 2004-09-10 US US10/570,893 patent/US7388018B2/en not_active Expired - Fee Related
- 2004-09-10 DE DE502004010595T patent/DE502004010595D1/de not_active Expired - Lifetime
- 2004-09-10 NZ NZ546218A patent/NZ546218A/en unknown
- 2004-09-10 KR KR1020067005389A patent/KR20060070563A/ko not_active Ceased
- 2004-09-10 EP EP04765053A patent/EP1663976B1/fr not_active Expired - Lifetime
- 2004-09-10 AP AP2006003564A patent/AP2006003564A0/xx unknown
- 2004-09-10 AT AT04765053T patent/ATE453625T1/de not_active IP Right Cessation
- 2004-09-10 WO PCT/EP2004/010124 patent/WO2005033081A1/fr not_active Ceased
- 2004-09-10 AU AU2004278095A patent/AU2004278095B2/en not_active Ceased
- 2004-09-10 MX MXPA06002500A patent/MXPA06002500A/es active IP Right Grant
- 2004-09-10 CN CNB2004800270626A patent/CN100406442C/zh not_active Expired - Fee Related
- 2004-09-10 BR BRPI0414410-4A patent/BRPI0414410A/pt not_active Application Discontinuation
- 2004-09-17 AR ARP040103365A patent/AR045767A1/es active IP Right Grant
- 2004-09-21 AR ARP040103382A patent/AR045777A1/es unknown
- 2004-10-09 UA UAA200604147A patent/UA82124C2/uk unknown
-
2006
- 2006-02-21 IL IL173854A patent/IL173854A0/en unknown
- 2006-03-10 CO CO06024528A patent/CO5660289A2/es unknown
- 2006-03-22 CR CR8312A patent/CR8312A/es not_active Application Discontinuation
- 2006-03-30 EC EC2006006463A patent/ECSP066463A/es unknown
- 2006-03-31 MA MA28905A patent/MA28050A1/fr unknown
- 2006-04-12 ZA ZA200602966A patent/ZA200602966B/en unknown
-
2008
- 2008-04-11 US US12/101,175 patent/US20080221177A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| UA82124C2 (uk) | 2008-03-11 |
| WO2005033081A1 (fr) | 2005-04-14 |
| US20060293314A1 (en) | 2006-12-28 |
| AR045777A1 (es) | 2005-11-09 |
| AU2004278095A1 (en) | 2005-04-14 |
| ECSP066463A (es) | 2006-11-16 |
| BRPI0414410A (pt) | 2006-11-14 |
| EP1663976B1 (fr) | 2009-12-30 |
| NZ546218A (en) | 2008-07-31 |
| ZA200602966B (en) | 2007-07-25 |
| AU2004278095B2 (en) | 2010-06-24 |
| AR045767A1 (es) | 2005-11-09 |
| US20080221177A1 (en) | 2008-09-11 |
| ATE453625T1 (de) | 2010-01-15 |
| CA2537486A1 (fr) | 2005-04-14 |
| MXPA06002500A (es) | 2006-06-20 |
| US7388018B2 (en) | 2008-06-17 |
| CR8312A (es) | 2006-12-07 |
| CO5660289A2 (es) | 2006-07-31 |
| EA200600490A1 (ru) | 2006-08-25 |
| JP4477006B2 (ja) | 2010-06-09 |
| EA008948B1 (ru) | 2007-10-26 |
| EP1663976A1 (fr) | 2006-06-07 |
| IL173854A0 (en) | 2006-07-05 |
| CN100406442C (zh) | 2008-07-30 |
| KR20060070563A (ko) | 2006-06-23 |
| CN1852895A (zh) | 2006-10-25 |
| DE502004010595D1 (de) | 2010-02-11 |
| JP2007505849A (ja) | 2007-03-15 |
| AP2006003564A0 (en) | 2006-04-30 |
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