MA33372B1 - Composés insecticides - Google Patents
Composés insecticidesInfo
- Publication number
- MA33372B1 MA33372B1 MA34469A MA34469A MA33372B1 MA 33372 B1 MA33372 B1 MA 33372B1 MA 34469 A MA34469 A MA 34469A MA 34469 A MA34469 A MA 34469A MA 33372 B1 MA33372 B1 MA 33372B1
- Authority
- MA
- Morocco
- Prior art keywords
- compounds
- formula
- pesticide compounds
- relates
- acarine
- Prior art date
Links
- 150000001875 compounds Chemical class 0.000 title abstract 5
- 239000000575 pesticide Substances 0.000 title 1
- 241000238631 Hexapoda Species 0.000 abstract 1
- 241000237852 Mollusca Species 0.000 abstract 1
- 241000244206 Nematoda Species 0.000 abstract 1
- 230000000895 acaricidal effect Effects 0.000 abstract 1
- 230000000749 insecticidal effect Effects 0.000 abstract 1
- 239000000543 intermediate Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 230000002013 molluscicidal effect Effects 0.000 abstract 1
- 230000001069 nematicidal effect Effects 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D409/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms
- C07D409/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings
- C07D409/12—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings linked by a chain containing hetero atoms as chain links
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
- C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D207/18—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member
- C07D207/20—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
- C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
- C07D401/04—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring-member bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D403/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00
- C07D403/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings
- C07D403/04—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings directly linked by a ring-member-to-ring-member bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D409/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms
- C07D409/14—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing three or more hetero rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/0803—Compounds with Si-C or Si-Si linkages
- C07F7/081—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te
- C07F7/0812—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te comprising a heterocyclic ring
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Agronomy & Crop Science (AREA)
- General Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Plural Heterocyclic Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catching Or Destruction (AREA)
- Pyrrole Compounds (AREA)
Abstract
CETTE INVENTION CONCERNE DES COMPOSÉS DE FORMULE (I), A1, A2, A3, A4, G, R1, R2, R3 AND R4 ARE AS DEFINED IN CLAIM 1; OR A SALT OR JV-OXIDE THEREOF. FURTHERMORE, THE PRESENT INVENTION RELATES TO PROCESSES AND INTERMEDIATES FOR PREPARING COMPOUNDS OF FORMULA (I), TO INSECTICIDAL, ACARICIDAL, NEMATICIDAL AND MOLLUSCICIDAL COMPOSITIONS COMPRISING THE COMPOUNDS OF FORMULA (I) AND TO METHODS OF USING THE COMPOUNDS OF FORMULA (I) TO CONTROL INSECT, ACARINE, NEMATODE AND MOLLUSC PESTS.
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB0910767A GB0910767D0 (en) | 2009-06-22 | 2009-06-22 | Insecticidal compounds |
| GB0910768A GB0910768D0 (en) | 2009-06-22 | 2009-06-22 | Insecticidal compounds |
| PCT/EP2009/059563 WO2010020522A1 (fr) | 2008-08-22 | 2009-07-24 | Composés insecticides |
| EP10153810 | 2010-02-17 | ||
| PCT/EP2010/058207 WO2010149506A1 (fr) | 2009-06-22 | 2010-06-11 | Composés insecticides |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MA33372B1 true MA33372B1 (fr) | 2012-06-01 |
Family
ID=43386046
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MA34469A MA33372B1 (fr) | 2009-06-22 | 2010-06-11 | Composés insecticides |
Country Status (21)
| Country | Link |
|---|---|
| US (4) | US8946447B2 (fr) |
| EP (1) | EP2445906B1 (fr) |
| JP (1) | JP5684802B2 (fr) |
| KR (1) | KR20120089626A (fr) |
| CN (1) | CN102803257B (fr) |
| AR (1) | AR077143A1 (fr) |
| AU (1) | AU2010264888B2 (fr) |
| BR (1) | BRPI1015931A2 (fr) |
| CA (1) | CA2764422A1 (fr) |
| CO (1) | CO6480914A2 (fr) |
| CU (1) | CU20110237A7 (fr) |
| DO (1) | DOP2011000400A (fr) |
| EA (1) | EA020755B1 (fr) |
| ES (1) | ES2502340T3 (fr) |
| MA (1) | MA33372B1 (fr) |
| MX (1) | MX2011013448A (fr) |
| NI (1) | NI201100220A (fr) |
| TW (1) | TW201100013A (fr) |
| UY (1) | UY32727A (fr) |
| WO (1) | WO2010149506A1 (fr) |
| ZA (1) | ZA201109217B (fr) |
Families Citing this family (34)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20110269804A1 (en) | 2008-08-22 | 2011-11-03 | Syngenta Crop Protection Llc | Insecticidal compounds |
| US8822502B2 (en) | 2008-08-22 | 2014-09-02 | Syngenta Crop Protection Llc | Insecticidal compounds |
| EP2331535B1 (fr) | 2008-09-04 | 2015-07-22 | Syngenta Participations AG | Composés insecticides |
| TWI487486B (zh) | 2009-12-01 | 2015-06-11 | Syngenta Participations Ag | 以異唑啉衍生物為主之殺蟲化合物 |
| JP2011219431A (ja) * | 2010-04-13 | 2011-11-04 | Bayer Cropscience Ag | 新規アリールニトロアルカン誘導体 |
| TW201211057A (en) * | 2010-06-11 | 2012-03-16 | Syngenta Participations Ag | Process for the preparation of dihydropyrrole derivatives |
| JP2012017289A (ja) * | 2010-07-08 | 2012-01-26 | Bayer Cropscience Ag | 殺虫性ピロリン誘導体 |
| JP2012062267A (ja) * | 2010-09-15 | 2012-03-29 | Bayer Cropscience Ag | 殺虫性ピロリンｎ−オキサイド誘導体 |
| JP2014028758A (ja) | 2010-11-19 | 2014-02-13 | Nissan Chem Ind Ltd | 寄生虫及び衛生害虫防除剤 |
| UY33887A (es) | 2011-02-03 | 2012-09-28 | Syngenta Ltd | Métodos de control de plagas en la soja |
| EP2688864A1 (fr) * | 2011-03-22 | 2014-01-29 | Syngenta Participations AG | Composés insecticides |
| UY34104A (es) | 2011-05-31 | 2013-01-03 | Syngenta Participations Ag | ?compuestos derivados benzamídicos heterocíclicos, procesos e intermedios para su preparación, composiciones y métodos para su uso?. |
| WO2013026929A1 (fr) | 2011-08-25 | 2013-02-28 | Syngenta Participations Ag | Dérivés de dihydropyrrole en tant que composés insecticides |
| WO2013026939A1 (fr) | 2011-08-25 | 2013-02-28 | Syngenta Participations Ag | Méthodes de lutte contre les termites et les fourmis |
| WO2013190050A1 (fr) * | 2012-06-21 | 2013-12-27 | Syngenta Participations Ag | Procédés de lutte contre des insectes |
| AR091513A1 (es) * | 2012-06-21 | 2015-02-11 | Syngenta Participations Ag | Metodos de control de plagas del suelo |
| WO2014019609A1 (fr) | 2012-07-31 | 2014-02-06 | Syngenta Participations Ag | Procédé de lutte contre des organismes nuisibles s'attaquant au soja |
| WO2014019950A1 (fr) | 2012-08-03 | 2014-02-06 | Syngenta Participations Ag | Procédé de lutte contre des organismes nuisibles s'attaquant au soja |
| WO2014019957A2 (fr) | 2012-08-03 | 2014-02-06 | Syngenta Participations Ag | Procédés de lutte antiparasitaire dans du soja |
| CN104520287A (zh) | 2012-08-03 | 2015-04-15 | 先正达参股股份有限公司 | 控制昆虫的方法 |
| WO2014029640A1 (fr) | 2012-08-24 | 2014-02-27 | Syngenta Participations Ag | Procédé de lutte contre les insectes |
| WO2014029709A1 (fr) | 2012-08-24 | 2014-02-27 | Syngenta Participations Ag | Procédés de contrôle des insectes |
| WO2014029639A1 (fr) | 2012-08-24 | 2014-02-27 | Syngenta Participations Ag | Procédés de lutte antiparasitaire pour les sols |
| WO2014114250A1 (fr) * | 2013-01-23 | 2014-07-31 | Syngenta Participations Ag | Dérivés de pyrazoline en tant que composés insecticides |
| PE20161068A1 (es) | 2014-02-26 | 2016-10-21 | Basf Se | Compuestos de azolina |
| CN107108596B (zh) | 2014-12-22 | 2021-01-12 | 巴斯夫欧洲公司 | 被稠合环体系取代的唑啉类化合物 |
| ES2733532T3 (es) | 2014-12-22 | 2019-11-29 | Basf Se | Compuestos de azolina sustituidos por un sistema de anillo carbocíclico condensado |
| WO2018172477A1 (fr) | 2017-03-23 | 2018-09-27 | Syngenta Participations Ag | Composés insecticides |
| EP3601280A1 (fr) | 2017-03-23 | 2020-02-05 | Syngenta Participations AG | Composés insecticides |
| WO2019243263A1 (fr) | 2018-06-19 | 2019-12-26 | Syngenta Participations Ag | Composés insecticides |
| US20220048876A1 (en) | 2018-09-26 | 2022-02-17 | Syngenta Participations Ag | Insecticidal compounds |
| MX2021006661A (es) | 2018-12-04 | 2021-07-07 | Basf Se | Proceso para la preparacion de 5-bromo-1,3-dicloro-2-fluoro-bencen o. |
| JP7519822B2 (ja) | 2020-06-19 | 2024-07-22 | 東京エレクトロン株式会社 | 収納モジュール、基板処理システムおよび消耗部材の搬送方法 |
| CN120774881A (zh) * | 2024-04-01 | 2025-10-14 | 山东康乔生物科技有限公司 | 一种含砜五元杂环基的异噁唑啉类化合物的制备方法 |
Family Cites Families (34)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6331640B1 (en) | 1998-10-13 | 2001-12-18 | Hoffmann-La Roche Inc. | Diaminopropionic acid derivatives |
| CN101768129B (zh) * | 2004-03-05 | 2012-05-23 | 日产化学工业株式会社 | 异*唑啉取代苯甲酰胺化合物的制备中间体 |
| JP5007788B2 (ja) | 2005-05-16 | 2012-08-22 | 日産化学工業株式会社 | ジヒドロアゾール置換ベンズアミド化合物及び有害生物防除剤 |
| TWI412322B (zh) | 2005-12-30 | 2013-10-21 | Du Pont | 控制無脊椎害蟲之異唑啉 |
| UY30090A1 (es) * | 2006-01-16 | 2007-08-31 | Syngenta Participations Ag | Insecticidas novedosos |
| CN101394742B (zh) * | 2006-01-16 | 2012-05-23 | 先正达参股股份有限公司 | 邻氨基苯甲酰胺衍生物及其防治昆虫和蜱螨目的用途 |
| US8658801B2 (en) * | 2006-02-16 | 2014-02-25 | Syngenta Crop Protection, Llc | Pesticides containing a bicyclic bisamide structure |
| WO2007125984A1 (fr) | 2006-04-28 | 2007-11-08 | Nihon Nohyaku Co., Ltd. | Derive isoxazoline, agent insecticide et utilisation de l'agent insecticide |
| JP5164525B2 (ja) * | 2006-11-01 | 2013-03-21 | 日本曹達株式会社 | 含窒素へテロ環化合物および有害生物防除剤 |
| WO2008154528A2 (fr) * | 2007-06-13 | 2008-12-18 | E. I. Du Pont De Nemours And Company | Insecticides à l'isoxazoline |
| WO2009011227A1 (fr) | 2007-07-18 | 2009-01-22 | Jsr Corporation | Composition anti-salissures, film protecteur de surface et procédé de protection de la surface d'une plaque polarisante |
| JPWO2009072621A1 (ja) * | 2007-12-07 | 2011-04-28 | 日産化学工業株式会社 | 置換ジヒドロアゾール化合物及び有害生物防除剤 |
| TWI411395B (zh) * | 2007-12-24 | 2013-10-11 | Syngenta Participations Ag | 殺蟲化合物 |
| MX2010007952A (es) * | 2008-02-07 | 2010-08-04 | Bayer Cropscience Ag | Arilpirrolinas insecticidas. |
| JP2009286773A (ja) | 2008-03-14 | 2009-12-10 | Bayer Cropscience Ag | 殺虫性縮環式アリール類 |
| US20110269804A1 (en) * | 2008-08-22 | 2011-11-03 | Syngenta Crop Protection Llc | Insecticidal compounds |
| EP2331535B1 (fr) | 2008-09-04 | 2015-07-22 | Syngenta Participations AG | Composés insecticides |
| CN102292331A (zh) | 2009-01-22 | 2011-12-21 | 先正达参股股份有限公司 | 杀虫化合物 |
| WO2010086225A1 (fr) | 2009-01-29 | 2010-08-05 | Syngenta Participations Ag | Composés insecticides |
| CN102365278B (zh) | 2009-03-26 | 2015-05-06 | 先正达参股股份有限公司 | 杀虫化合物 |
| JP2010254629A (ja) | 2009-04-27 | 2010-11-11 | Bayer Cropscience Ag | 光学活性アゾリン誘導体 |
| EP2432762B8 (fr) | 2009-05-19 | 2015-04-08 | Bayer Intellectual Property GmbH | Arylpyrrolines insecticidés |
| CN102725286A (zh) * | 2009-11-06 | 2012-10-10 | 拜耳作物科学公司 | 杀虫用芳基吡咯啉化合物 |
| ME02432B (fr) | 2009-12-17 | 2016-09-20 | Merial Inc | Dihydroazoles antiparasitaires et compositions les incluant |
| WO2011073444A2 (fr) | 2009-12-18 | 2011-06-23 | Basf Se | Azolines dans la lutte contre les nuisibles invertébrés |
| EP2531493B1 (fr) | 2010-02-01 | 2015-07-22 | Basf Se | Composés d'isoxazoline cétoniques substitués et leurs dérivés pour lutter contre des animaux nuisibles |
| US8754053B2 (en) | 2010-02-17 | 2014-06-17 | Syngenta Crop Protection Llc | Isoxazoline derivatives as insecticides |
| EA201201171A1 (ru) | 2010-02-22 | 2013-03-29 | Зингента Партисипейшнс Аг | Дигидрофурановые производные в качестве инсектицидных соединений |
| BR112012021238A2 (pt) | 2010-02-25 | 2016-06-21 | Syngenta Ltd | misturas pesticidas contendo derivados de isoxazolina e um fungicida |
| PH12012501599A1 (en) | 2010-02-25 | 2012-10-22 | Syngenta Ltd | Pesticidal mixtures containing isoxazoline derivatives and insecticide or nematoicidal biological agent |
| KR20120133401A (ko) | 2010-02-25 | 2012-12-10 | 신젠타 리미티드 | 이속사졸린 유도체의 제조 방법 |
| JP2011219431A (ja) * | 2010-04-13 | 2011-11-04 | Bayer Cropscience Ag | 新規アリールニトロアルカン誘導体 |
| AR081843A1 (es) | 2010-06-09 | 2012-10-24 | Syngenta Participations Ag | Mezclas pesticidas incluyendo derivados isoxazolina |
| BR112012031088A8 (pt) | 2010-06-09 | 2017-10-10 | Syngenta Participations Ag | Misturas pesticidas incluindo os derivados da isoxazolina |
-
2010
- 2010-06-11 JP JP2012515441A patent/JP5684802B2/ja not_active Expired - Fee Related
- 2010-06-11 CA CA2764422A patent/CA2764422A1/fr not_active Abandoned
- 2010-06-11 BR BRPI1015931-2A patent/BRPI1015931A2/pt not_active Application Discontinuation
- 2010-06-11 EP EP10726052.3A patent/EP2445906B1/fr not_active Not-in-force
- 2010-06-11 AU AU2010264888A patent/AU2010264888B2/en not_active Ceased
- 2010-06-11 US US13/379,812 patent/US8946447B2/en active Active
- 2010-06-11 MX MX2011013448A patent/MX2011013448A/es active IP Right Grant
- 2010-06-11 WO PCT/EP2010/058207 patent/WO2010149506A1/fr not_active Ceased
- 2010-06-11 EA EA201200031A patent/EA020755B1/ru not_active IP Right Cessation
- 2010-06-11 MA MA34469A patent/MA33372B1/fr unknown
- 2010-06-11 ES ES10726052.3T patent/ES2502340T3/es active Active
- 2010-06-11 KR KR1020127001855A patent/KR20120089626A/ko not_active Withdrawn
- 2010-06-11 CN CN201080027795.5A patent/CN102803257B/zh not_active Expired - Fee Related
- 2010-06-18 AR ARP100102164A patent/AR077143A1/es unknown
- 2010-06-21 TW TW099120079A patent/TW201100013A/zh unknown
- 2010-06-22 UY UY0001032727A patent/UY32727A/es not_active Application Discontinuation
-
2011
- 2011-12-14 ZA ZA2011/09217A patent/ZA201109217B/en unknown
- 2011-12-20 NI NI201100220A patent/NI201100220A/es unknown
- 2011-12-21 CO CO11176262A patent/CO6480914A2/es active IP Right Grant
- 2011-12-21 DO DO2011000400A patent/DOP2011000400A/es unknown
- 2011-12-22 CU CU20110237A patent/CU20110237A7/es unknown
-
2014
- 2014-12-18 US US14/574,877 patent/US9493445B2/en active Active
-
2016
- 2016-10-05 US US15/285,759 patent/US9834546B2/en active Active
-
2017
- 2017-11-13 US US15/810,438 patent/US10364235B2/en active Active
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