MA34789B1 - Nanoferrites (nanoparticules et nanotiges) à base de nd1-xmxfe204 (n=co,ni,mn et sn) - Google Patents
Nanoferrites (nanoparticules et nanotiges) à base de nd1-xmxfe204 (n=co,ni,mn et sn)Info
- Publication number
- MA34789B1 MA34789B1 MA35010A MA35010A MA34789B1 MA 34789 B1 MA34789 B1 MA 34789B1 MA 35010 A MA35010 A MA 35010A MA 35010 A MA35010 A MA 35010A MA 34789 B1 MA34789 B1 MA 34789B1
- Authority
- MA
- Morocco
- Prior art keywords
- nanoparticles
- transition metals
- magnetic properties
- ndfe2o4
- nanoferrite
- Prior art date
Links
- 239000002105 nanoparticle Substances 0.000 title abstract 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title 2
- 229910052742 iron Inorganic materials 0.000 title 1
- 230000005291 magnetic effect Effects 0.000 abstract 5
- 229910052723 transition metal Inorganic materials 0.000 abstract 3
- 230000005415 magnetization Effects 0.000 abstract 2
- 239000000463 material Substances 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 150000003624 transition metals Chemical class 0.000 abstract 2
- 229910000859 α-Fe Inorganic materials 0.000 abstract 2
- 241000238366 Cephalopoda Species 0.000 abstract 1
- 230000000903 blocking effect Effects 0.000 abstract 1
- 125000002091 cationic group Chemical group 0.000 abstract 1
- 238000000975 co-precipitation Methods 0.000 abstract 1
- 230000008878 coupling Effects 0.000 abstract 1
- 238000010168 coupling process Methods 0.000 abstract 1
- 238000005859 coupling reaction Methods 0.000 abstract 1
- 238000002425 crystallisation Methods 0.000 abstract 1
- 230000008025 crystallization Effects 0.000 abstract 1
- 238000003384 imaging method Methods 0.000 abstract 1
- 150000002500 ions Chemical class 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000007777 multifunctional material Substances 0.000 abstract 1
- 239000002073 nanorod Substances 0.000 abstract 1
- 230000005298 paramagnetic effect Effects 0.000 abstract 1
- 239000000843 powder Substances 0.000 abstract 1
- 229910052761 rare earth metal Inorganic materials 0.000 abstract 1
- -1 rare earth transition metals Chemical class 0.000 abstract 1
- 229910052596 spinel Inorganic materials 0.000 abstract 1
- 239000011029 spinel Substances 0.000 abstract 1
- 229910052566 spinel group Inorganic materials 0.000 abstract 1
- 230000007704 transition Effects 0.000 abstract 1
Classifications
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- H01F1/00—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
- H01F1/0036—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties showing low dimensional magnetism, i.e. spin rearrangements due to a restriction of dimensions, e.g. showing giant magnetoresistivity
- H01F1/0045—Zero dimensional, e.g. nanoparticles, soft nanoparticles for medical/biological use
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
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- C01G19/00—Compounds of tin
- C01G19/006—Compounds containing tin, with or without oxygen or hydrogen, and containing two or more other elements
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- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G45/00—Compounds of manganese
- C01G45/12—Complex oxides containing manganese and at least one other metal element
- C01G45/1221—Manganates or manganites with trivalent manganese, tetravalent manganese or mixtures thereof
- C01G45/1235—Manganates or manganites with trivalent manganese, tetravalent manganese or mixtures thereof of the type (Mn2O4)2-, e.g. Li2Mn2O4 or Li2(MxMn2-x)O4
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- C01G49/00—Compounds of iron
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- C01G49/0054—Mixed oxides or hydroxides containing one rare earth metal, yttrium or scandium
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- C01G51/00—Compounds of cobalt
- C01G51/40—Complex oxides containing cobalt and at least one other metal element
- C01G51/70—Complex oxides containing cobalt and at least one other metal element containing rare earths, e.g. LaCoO3
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- C01G53/00—Compounds of nickel
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- C01G53/70—Complex oxides containing nickel and at least one other metal element containing rare earths, e.g. LaNiO3
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- C04B35/2608—Compositions containing one or more ferrites of the group comprising manganese, zinc, nickel, copper or cobalt and one or more ferrites of the group comprising rare earth metals, alkali metals, alkaline earth metals or lead
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Abstract
Cette invention fournit des matériaux de nanoferrite (en poudre) à base d'un mélange de terre rare, métaux de transition. Les nano-ferrites (nanoparticules et nanorodes) de nd1-xmxfe2o4 (m=co,ni,mn,sn....) spinelles ferrites ont été préparés par la méthode de co-précipitation. La diffraction des rayons drx et l'imagerie par tem confirment une bonne cristallisation des nanorodes pour le cas de ndfe2o4 dopé par des métaux de transition et nanoparticles pour le cas de ndfe2o4 dopé par des terres rares. Les résultats montrent que la distribution cationique sur les sites tétraédriques et octaédriques dans le réseau spinelle est partiellement inverse. Les propriétés magnétiques des échantillons ont été caractérisées en utilisant un dispositif d'interférence supraconducteur quantique (squid). Les propriétés magnétiques monrent que le système a un fort moment de saturation et un champ coercitif modéré à la température ambiante. L'aimantation résiduelle, l'aimantation à saturation, le champ coercitif, la température de blocage, et la température de transition du matériau nanoferrite sont optimisés par la concentration des ions magnétiques la taille et la forme des nanoparticules, afin d'atteindre les caractéristiques requises pour des applications bien définies. Les nanoparticules super paramagnétiques fabriquées sont des matériaux multifonctionnels où la taille et la forme présentent un intérêt pour le couplage magnétique et pour les applications. Ces nanoparticules d'oxyde avec un mélange de métaux de transition et de terre rares sont simples et peu coûteux à fabriquer en grandes quantités avec des propriétés magnétiques uniformes et sous différentes formes; encapsulé, fonctionnalisé ou laissé nu comme un oxyde stable à la température ambiante.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| MA35010A MA34789B1 (fr) | 2012-06-28 | 2012-06-28 | Nanoferrites (nanoparticules et nanotiges) à base de nd1-xmxfe204 (n=co,ni,mn et sn) |
| PCT/MA2013/000004 WO2014003527A1 (fr) | 2012-06-28 | 2013-04-05 | Nano-ferrites (nanoparticules et nanorodes) a base de nd1-xmexfe2o4 (m =co, ni, mn,sn) |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| MA35010A MA34789B1 (fr) | 2012-06-28 | 2012-06-28 | Nanoferrites (nanoparticules et nanotiges) à base de nd1-xmxfe204 (n=co,ni,mn et sn) |
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| CN116282188B (zh) * | 2023-03-23 | 2024-09-06 | 中国科学院赣江创新研究院 | 一种钕掺杂锶铁氧体吸波材料及其制备方法 |
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