MD3685C2 - Process for obtaining hexa-m-acetato-m3-oxo-tris(aqua)triferrum(III) nitrate in solid form and in the form of aqueous solution - Google Patents
Process for obtaining hexa-m-acetato-m3-oxo-tris(aqua)triferrum(III) nitrate in solid form and in the form of aqueous solution Download PDFInfo
- Publication number
- MD3685C2 MD3685C2 MDA20080024A MD20080024A MD3685C2 MD 3685 C2 MD3685 C2 MD 3685C2 MD A20080024 A MDA20080024 A MD A20080024A MD 20080024 A MD20080024 A MD 20080024A MD 3685 C2 MD3685 C2 MD 3685C2
- Authority
- MD
- Moldova
- Prior art keywords
- iii
- obtaining
- triferrum
- acetato
- aqua
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 3
- 239000007787 solid Substances 0.000 title abstract 3
- 239000007983 Tris buffer Substances 0.000 title abstract 2
- 229910002651 NO3 Inorganic materials 0.000 title 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 title 1
- 239000007864 aqueous solution Substances 0.000 title 1
- 239000000243 solution Substances 0.000 abstract 2
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical class [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 abstract 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical class O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 abstract 1
- MSNWSDPPULHLDL-UHFFFAOYSA-K ferric hydroxide Chemical compound [OH-].[OH-].[OH-].[Fe+3] MSNWSDPPULHLDL-UHFFFAOYSA-K 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 238000004062 sedimentation Methods 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
Abstract
The invention relates to chemistry, in particular to a process for obtaining hexa-µ-acetato-µ3-oxo-tris(aqua)triferrum(III) in solid and liquid form that can be used in different fields, especially in agriculture as antichlorosic complex.The process, according to the invention, provides for the sedimentation of iron(III) hydroxide from any water-soluble iron(III) salt, washing and treatment thereof with acetic and nitric acids in the molar ratio of 3:6:1, correspondingly, afterwards the obtained solution is optionally filtered. For complex obtaining in solid form the earlier obtained solution is concentrated, and then the crystallized product is separated and dried.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| MDA20080024A MD3685C2 (en) | 2008-01-29 | 2008-01-29 | Process for obtaining hexa-m-acetato-m3-oxo-tris(aqua)triferrum(III) nitrate in solid form and in the form of aqueous solution |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| MDA20080024A MD3685C2 (en) | 2008-01-29 | 2008-01-29 | Process for obtaining hexa-m-acetato-m3-oxo-tris(aqua)triferrum(III) nitrate in solid form and in the form of aqueous solution |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| MD3685B1 MD3685B1 (en) | 2008-08-31 |
| MD3685C2 true MD3685C2 (en) | 2009-03-31 |
Family
ID=39740085
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MDA20080024A MD3685C2 (en) | 2008-01-29 | 2008-01-29 | Process for obtaining hexa-m-acetato-m3-oxo-tris(aqua)triferrum(III) nitrate in solid form and in the form of aqueous solution |
Country Status (1)
| Country | Link |
|---|---|
| MD (1) | MD3685C2 (en) |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB785025A (en) * | 1953-04-20 | 1957-10-23 | Ciba Ltd | Manufacture and use of complex iron salts |
| JPS6471842A (en) * | 1987-09-11 | 1989-03-16 | Nitto Chemical Industry Co Ltd | Production of aminopolycarboxylic acid iron (ii) complex ammonium salt |
| JPH06145120A (en) * | 1992-06-29 | 1994-05-24 | Nitto Chem Ind Co Ltd | Method for producing ferric aminopolycarboxylic acid ammonium salt |
| RU2100365C1 (en) * | 1995-06-20 | 1997-12-27 | Архангельский государственный технический университет | Method for production of antichlorose preparation |
| MD955G2 (en) * | 1997-07-29 | 1999-03-31 | Институт Химии Академии Наук Молдовы | Hexa-ÕmuÚ-acetato(O,O')-ÕmuÚsubÕ3Ú-oxo-tris (N,N'-diethylnicotinamide)-diiron(III)cobalt(II) monohydrate having plant growing,vegetation and productivity regulation activity |
| MD2361G2 (en) * | 2002-05-23 | 2004-09-30 | Институт Физиологии Растений Академии Наук Республики Молдова | Hexa-µ-acetato(O,O')-µ3-oxo-tris(N,N'-diethylnicotinamide)-differum(III)manganese(II)dihydrate - ground nut growth regulator and process for ground nut treatment |
| EP1667946A1 (en) * | 2003-09-12 | 2006-06-14 | Norman Klaunzer | Fe(iii)-complexes for use as micronutrients for fertilizers |
| WO2007013219A1 (en) * | 2005-07-29 | 2007-02-01 | Aichi Steel Corporation | Iron supplying agent for plant for use in alkaline soil, and process for production of the same |
-
2008
- 2008-01-29 MD MDA20080024A patent/MD3685C2/en not_active IP Right Cessation
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB785025A (en) * | 1953-04-20 | 1957-10-23 | Ciba Ltd | Manufacture and use of complex iron salts |
| JPS6471842A (en) * | 1987-09-11 | 1989-03-16 | Nitto Chemical Industry Co Ltd | Production of aminopolycarboxylic acid iron (ii) complex ammonium salt |
| JPH06145120A (en) * | 1992-06-29 | 1994-05-24 | Nitto Chem Ind Co Ltd | Method for producing ferric aminopolycarboxylic acid ammonium salt |
| RU2100365C1 (en) * | 1995-06-20 | 1997-12-27 | Архангельский государственный технический университет | Method for production of antichlorose preparation |
| MD955G2 (en) * | 1997-07-29 | 1999-03-31 | Институт Химии Академии Наук Молдовы | Hexa-ÕmuÚ-acetato(O,O')-ÕmuÚsubÕ3Ú-oxo-tris (N,N'-diethylnicotinamide)-diiron(III)cobalt(II) monohydrate having plant growing,vegetation and productivity regulation activity |
| MD2361G2 (en) * | 2002-05-23 | 2004-09-30 | Институт Физиологии Растений Академии Наук Республики Молдова | Hexa-µ-acetato(O,O')-µ3-oxo-tris(N,N'-diethylnicotinamide)-differum(III)manganese(II)dihydrate - ground nut growth regulator and process for ground nut treatment |
| EP1667946A1 (en) * | 2003-09-12 | 2006-06-14 | Norman Klaunzer | Fe(iii)-complexes for use as micronutrients for fertilizers |
| WO2007013219A1 (en) * | 2005-07-29 | 2007-02-01 | Aichi Steel Corporation | Iron supplying agent for plant for use in alkaline soil, and process for production of the same |
Non-Patent Citations (4)
| Title |
|---|
| Weinland R.F., Kessler K, Bayerl A. Z. anorg. chem. 1924, 132, s.222 * |
| Weinland R.F., Kessler K., Bayerl A. Z.anorg. Chem. 1924, 132, s. 222 * |
| Тома С.И., Великсар С.Г., Шандру И.А., Туртэ К.И, Воронцов В.А. Садоводство и виноградарство Молдавии. 1987, № 7, с. 41-43 * |
| Тома С.И., Великсар С.Г., Шандру И.А., Туртэ К.И., Воронцов В.А. Садоводство и виноградарство Молдавии. 1987, № 7, с. 41-43 * |
Also Published As
| Publication number | Publication date |
|---|---|
| MD3685B1 (en) | 2008-08-31 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG4A | Patent for invention issued | ||
| KA4A | Patent for invention lapsed due to non-payment of fees (with right of restoration) | ||
| MM4A | Patent for invention definitely lapsed due to non-payment of fees |