MD4214B1 - Process for modifying the porous structure of activated coal impregnated with Cu(II) and its use for the treatment of underground waters from hydrogen sulfide and sulfides - Google Patents
Process for modifying the porous structure of activated coal impregnated with Cu(II) and its use for the treatment of underground waters from hydrogen sulfide and sulfides Download PDFInfo
- Publication number
- MD4214B1 MD4214B1 MDA20120054A MD20120054A MD4214B1 MD 4214 B1 MD4214 B1 MD 4214B1 MD A20120054 A MDA20120054 A MD A20120054A MD 20120054 A MD20120054 A MD 20120054A MD 4214 B1 MD4214 B1 MD 4214B1
- Authority
- MD
- Moldova
- Prior art keywords
- porous structure
- treatment
- sulfides
- modifying
- adsorbent
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 5
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 title abstract 4
- 239000003245 coal Substances 0.000 title abstract 4
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 title abstract 3
- 229910000037 hydrogen sulfide Inorganic materials 0.000 title abstract 3
- 150000003568 thioethers Chemical class 0.000 title abstract 3
- 239000003643 water by type Substances 0.000 title abstract 3
- 239000003463 adsorbent Substances 0.000 abstract 4
- 230000003197 catalytic effect Effects 0.000 abstract 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 2
- 230000003647 oxidation Effects 0.000 abstract 2
- 238000007254 oxidation reaction Methods 0.000 abstract 2
- 229910052760 oxygen Inorganic materials 0.000 abstract 2
- 239000001301 oxygen Substances 0.000 abstract 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- 238000013019 agitation Methods 0.000 abstract 1
- 239000007900 aqueous suspension Substances 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 229910052717 sulfur Inorganic materials 0.000 abstract 1
- 239000011593 sulfur Substances 0.000 abstract 1
- 239000000725 suspension Substances 0.000 abstract 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Landscapes
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
The invention relates to processes for modifying the porous structure of activated coals impregnated with Cu(II) and their use for the treatment by catalytic oxidation of underground waters from hydrogen sulfide and sulfides.The process for modifying the porous structure of activated coal impregnated with Cu(II) includes the mechanical agitation for one hour at room temperature of an adsorbent suspension in demineralized water with concomitant barbotage of oxygen. As a result is reduced the specific surface and volume of adsorbent micropores.The process for treatment of underground waters from hydrogen sulfide and sulfides by catalytic oxidation includes the addition in the underground water of activated coal impregnated with Cu(II), with a modified porous structure according to the above-mentioned process, the mechanical mixing of the coal-water suspension for an hour at room temperature with concomitant barbotage of oxygen, afterwards the activated coal is separated from the treated water for a possible reuse in a new cycle of treatment.Use of the adsorbent with the modified in that way porous structure excludes the formation of sulfur on its surface, which indicates an increase of the catalytic activity of such adsorbent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| MDA20120054A MD4214C1 (en) | 2012-06-18 | 2012-06-18 | Process for modifying the porous structure of activated coal impregnated with Cu(II) and its use for the treatment of underground waters from hydrogen sulfide and sulfides |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| MDA20120054A MD4214C1 (en) | 2012-06-18 | 2012-06-18 | Process for modifying the porous structure of activated coal impregnated with Cu(II) and its use for the treatment of underground waters from hydrogen sulfide and sulfides |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| MD4214B1 true MD4214B1 (en) | 2013-04-30 |
| MD4214C1 MD4214C1 (en) | 2013-11-30 |
Family
ID=48227599
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MDA20120054A MD4214C1 (en) | 2012-06-18 | 2012-06-18 | Process for modifying the porous structure of activated coal impregnated with Cu(II) and its use for the treatment of underground waters from hydrogen sulfide and sulfides |
Country Status (1)
| Country | Link |
|---|---|
| MD (1) | MD4214C1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| MD4435C1 (en) * | 2015-09-14 | 2017-04-30 | Институт Химии Академии Наук Молдовы | Process for purification of deep waters from ammonium, ammonia and hydrogen sulfide ions |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111099712A (en) * | 2020-01-15 | 2020-05-05 | 山东汇海医药化工有限公司 | Method for treating sodium sulfide wastewater generated in DCC synthesis process by using oxygen |
Family Cites Families (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3192156A (en) * | 1962-04-26 | 1965-06-29 | Pittsburgh Activated Carbon Co | Removal of hydrogen sulfide from water |
| JPS53113287A (en) * | 1977-03-15 | 1978-10-03 | Asahi Chem Ind Co Ltd | Regeneration method of active carbon |
| US4264451A (en) * | 1978-05-22 | 1981-04-28 | City Of Orlando | Water purification method |
| JPS61257238A (en) * | 1985-05-11 | 1986-11-14 | Chiyoda Chem Eng & Constr Co Ltd | Oxidation treatment method for sodium sulfide-containing aqueous solution and its catalyst |
| JPS61259754A (en) * | 1985-05-11 | 1986-11-18 | Mitsubishi Paper Mills Ltd | Process for treating aqueous solution containing sodium sulfide and its catalyst |
| RU2013379C1 (en) * | 1991-11-19 | 1994-05-30 | Научно-исследовательский институт кожи | Method of purifying sewage against sulfides |
| US5338463A (en) * | 1993-05-12 | 1994-08-16 | Mobil Oil Corporation | Wastewater treatment by catalytic oxidation |
| RU2042644C1 (en) * | 1994-01-05 | 1995-08-27 | Лев Николаевич Фесенко | Method of removing hydrogen sulfide from water |
| US5470486A (en) * | 1994-06-20 | 1995-11-28 | Uop | Conversion of water-soluble inorganic sulfide compounds in an aqueous stream |
| MD660G2 (en) * | 1996-05-16 | 1997-08-31 | Институт Химии Академии Наук Молдовы | Process for production of activated carbon |
| MD999G2 (en) * | 1998-02-23 | 1999-06-30 | Институт Химии Академии Наук Молдовы | Process for activated charcoal obtaining |
| MD1005G2 (en) * | 1998-02-23 | 1999-07-31 | Институт Химии Академии Наук Молдовы | Process for activated charcoal obtaining |
| WO2002043858A2 (en) * | 2000-11-29 | 2002-06-06 | Research Foundation Of The City University Of New York | Process to prepare adsorbents from organic fertilizer and their applications for removal of acidic gases from wet air streams |
| RU2224724C1 (en) * | 2002-06-21 | 2004-02-27 | Кочетков Алексей Юрьевич | Method of oxidizing sulfur and organic compounds in solutions (options) |
| MD2333G2 (en) * | 2003-02-20 | 2004-06-30 | Институт Химии Академии Наук Молдовы | Process for regeneration of the activated coal exhausted in the water treatment process |
| MD2480G2 (en) * | 2003-07-17 | 2005-01-31 | Институт Химии Академии Наук Молдовы | Process for water purification from sulphureted hydrogen and/or sulphides |
| MD2478G2 (en) * | 2003-07-17 | 2005-01-31 | Институт Химии Академии Наук Молдовы | Proces for regeneration of the used active coal |
| MD2523G2 (en) * | 2003-08-05 | 2005-03-31 | Институт Химии Академии Наук Молдовы | Process for regeneration of the used active coal (variants) |
| MD3097G2 (en) * | 2005-12-06 | 2007-02-28 | Институт Химии Академии Наук Молдовы | Process for underground water purification from sulphureted hydrogen and/or sulphides |
| MD3482G2 (en) * | 2007-04-25 | 2008-08-31 | Институт Химии Академии Наук Молдовы | Process for active coal modification |
| RU2361822C2 (en) * | 2007-08-03 | 2009-07-20 | Государственное образовательное учреждение высшего профессионального образования Новосибирский государственный архитектурно-строительный университет (Сибстрин) | Method of purifying water from hydrogen sulphide and sulphides |
| MD3776G2 (en) * | 2007-09-06 | 2009-07-31 | Государственный Университет Молд0 | Process for photocatalytic regeneration of waste active coal |
| RU2408544C1 (en) * | 2009-05-27 | 2011-01-10 | Сергей Анатольевич Ассаулюк | Method of purifying water from hydrogen sulphide |
| JP5655182B2 (en) * | 2009-08-06 | 2015-01-21 | 清水建設株式会社 | Method for removing dissolved sulfide and apparatus for removing dissolved sulfide |
| CN102139875B (en) * | 2011-04-27 | 2013-09-18 | 南京科孚纳米技术有限公司 | Method for preparing super activated carbon by utilizing modification supercritical oxidation technology |
-
2012
- 2012-06-18 MD MDA20120054A patent/MD4214C1/en not_active IP Right Cessation
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| MD4435C1 (en) * | 2015-09-14 | 2017-04-30 | Институт Химии Академии Наук Молдовы | Process for purification of deep waters from ammonium, ammonia and hydrogen sulfide ions |
Also Published As
| Publication number | Publication date |
|---|---|
| MD4214C1 (en) | 2013-11-30 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| TK4A | Erratum in official gazette in regard to patent for invention |
Free format text: RECTIFICATION IN INID 51 |
|
| FG4A | Patent for invention issued | ||
| KA4A | Patent for invention lapsed due to non-payment of fees (with right of restoration) | ||
| MM4A | Patent for invention definitely lapsed due to non-payment of fees |