MX2009005106A - Proceso para la produccion de esteres de alquilo de acidos grasos y acroleina a partir de trigliceridos. - Google Patents

Proceso para la produccion de esteres de alquilo de acidos grasos y acroleina a partir de trigliceridos.

Info

Publication number
MX2009005106A
MX2009005106A MX2009005106A MX2009005106A MX2009005106A MX 2009005106 A MX2009005106 A MX 2009005106A MX 2009005106 A MX2009005106 A MX 2009005106A MX 2009005106 A MX2009005106 A MX 2009005106A MX 2009005106 A MX2009005106 A MX 2009005106A
Authority
MX
Mexico
Prior art keywords
triglycerides
acrolein
fatty acids
alkyl esters
preparing alkyl
Prior art date
Application number
MX2009005106A
Other languages
English (en)
Inventor
Klaus Huthmacher
Christoph Weckbecker
Hubert Redlingshoefer
Original Assignee
Evonik Degussa Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Evonik Degussa Gmbh filed Critical Evonik Degussa Gmbh
Publication of MX2009005106A publication Critical patent/MX2009005106A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/54—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition of compounds containing doubly bound oxygen atoms, e.g. esters
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/52—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition by dehydration and rearrangement involving two hydroxy groups in the same molecule
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/03—Preparation of carboxylic acid esters by reacting an ester group with a hydroxy group
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C1/00—Preparation of fatty acids from fats, fatty oils, or waxes; Refining the fatty acids
    • C11C1/08—Refining
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C1/00—Preparation of fatty acids from fats, fatty oils, or waxes; Refining the fatty acids
    • C11C1/08—Refining
    • C11C1/10—Refining by distillation
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
    • C11C3/003—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fatty acids with alcohols
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P7/00—Preparation of oxygen-containing organic compounds
    • C12P7/62—Carboxylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P7/00—Preparation of oxygen-containing organic compounds
    • C12P7/64—Fats; Fatty oils; Ester-type waxes; Higher fatty acids, i.e. having at least seven carbon atoms in an unbroken chain bound to a carboxyl group; Oxidised oils or fats
    • C12P7/6436—Fatty acid esters
    • C12P7/6445—Glycerides
    • C12P7/6458—Glycerides by transesterification, e.g. interesterification, ester interchange, alcoholysis or acidolysis
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P7/00—Preparation of oxygen-containing organic compounds
    • C12P7/64—Fats; Fatty oils; Ester-type waxes; Higher fatty acids, i.e. having at least seven carbon atoms in an unbroken chain bound to a carboxyl group; Oxidised oils or fats
    • C12P7/6436—Fatty acid esters
    • C12P7/649—Biodiesel, i.e. fatty acid alkyl esters
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Zoology (AREA)
  • Microbiology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • Biochemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Genetics & Genomics (AREA)
  • Biotechnology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

La invención se refiere a un procedimiento para preparar ésteres de alquilo de ácidos grasos que tiene la fórmula general (I) y acroleína por medio de la reacción de triglicéridos de la formula general (II), caracterizado porque a) los triglicéridos se hacen reaccionar con alcoholes R´-OH en la presencia de un catalizador adecuado para formar el éster alquilo de un ácido graso y glicerol y b) el glicerol formado se deshidrata catalíticamente para formar acroleína, b) en donde R representa R1, R2, y R3 y R1, R2, y R3 pueden ser completamente iguales o parcialmente iguales o completamente diferentes y representan un radical alquilo con 10 a 30 átomos de carbono de cadena recta o ramificada y eventualmente mono- o poli-insaturado, y R´ puede representar un radical alquilo con de 1 a 10 átomos de carbono o un radical cicloalquilo con de 3 a 6 átomos de carbono.
MX2009005106A 2006-11-20 2007-10-30 Proceso para la produccion de esteres de alquilo de acidos grasos y acroleina a partir de trigliceridos. MX2009005106A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102006054519A DE102006054519A1 (de) 2006-11-20 2006-11-20 Verfahren zur Herstellung von Fettsäurealkylestern und Acrolein aus Triglyceriden
PCT/EP2007/061669 WO2008061860A1 (de) 2006-11-20 2007-10-30 Verfahren zur herstellung von fettsäurealkylestern und acrolein aus triglyceriden

Publications (1)

Publication Number Publication Date
MX2009005106A true MX2009005106A (es) 2009-05-27

Family

ID=38988343

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2009005106A MX2009005106A (es) 2006-11-20 2007-10-30 Proceso para la produccion de esteres de alquilo de acidos grasos y acroleina a partir de trigliceridos.

Country Status (12)

Country Link
US (1) US7498454B2 (es)
EP (1) EP2097367B1 (es)
JP (1) JP5361731B2 (es)
CN (1) CN101535233A (es)
AT (1) ATE535509T1 (es)
BR (1) BRPI0718997B1 (es)
DE (1) DE102006054519A1 (es)
ES (1) ES2377218T3 (es)
MX (1) MX2009005106A (es)
MY (1) MY147480A (es)
RU (1) RU2009123233A (es)
WO (1) WO2008061860A1 (es)

Families Citing this family (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8445709B2 (en) * 2006-08-04 2013-05-21 Mcneff Research Consultants, Inc. Systems and methods for refining alkyl ester compositions
US7897798B2 (en) 2006-08-04 2011-03-01 Mcneff Research Consultants, Inc. Methods and apparatus for producing alkyl esters from lipid feed stocks and systems including same
US8585976B2 (en) * 2007-02-13 2013-11-19 Mcneff Research Consultants, Inc. Devices for selective removal of contaminants from a composition
US8017796B2 (en) * 2007-02-13 2011-09-13 Mcneff Research Consultants, Inc. Systems for selective removal of contaminants from a composition and methods of regenerating the same
US20110237828A1 (en) * 2007-08-29 2011-09-29 Showa Denko K.K. Acrolein production method and acrylic acid production method
US7943791B2 (en) * 2007-09-28 2011-05-17 Mcneff Research Consultants, Inc. Methods and compositions for refining lipid feed stocks
JP5134443B2 (ja) * 2008-06-05 2013-01-30 昭和電工株式会社 アクロレイン及びアクリル酸の製造方法
US20110224451A1 (en) * 2008-06-11 2011-09-15 Rajiv Kumar Chaturvedi Process for production of biodiesel
EP2145872A1 (de) * 2008-07-19 2010-01-20 Cognis IP Management GmbH Verfahren zur Dehydratisierung von Alkoholen
FR2935148B1 (fr) 2008-08-25 2010-08-27 Arkema France Procede de fabrication de fibres de carbone.
US8361174B2 (en) * 2008-10-07 2013-01-29 Sartec Corporation Catalysts, systems, and methods for producing fuels and fuel additives from polyols
US9102877B2 (en) * 2008-11-12 2015-08-11 Sartec Corporation Systems and methods for producing fuels from biomass
FR2938535B1 (fr) * 2008-11-20 2012-08-17 Arkema France Procede de fabrication de methylmercaptopropionaldehyde et de methionine a partir de matieres renouvelables
DE102008060888A1 (de) * 2008-12-09 2010-06-10 Evonik Stockhausen Gmbh Verfahren zur Herstellung von Acrolein umfassend die Aufarbeitung einer Rohglycerin-Phase
JP5478132B2 (ja) * 2009-07-01 2014-04-23 株式会社日立製作所 アクロレインの合成方法及び装置
FR2953829B1 (fr) * 2009-12-14 2011-12-09 Arkema France Procede de fabrication d'acroleine et/ou d'acide acrylique a partir de glycerol
CN102781577A (zh) * 2009-12-18 2012-11-14 巴特勒纪念研究院 多羟基化合物脱水系统、催化剂组合物、和方法
FR2954311B1 (fr) * 2009-12-22 2012-02-03 Arkema France Procede de synthese perfectionne d'acroleine a partir de glycerol
ES2373595B1 (es) * 2010-01-15 2012-12-21 Universidad De Extremadura Procedimiento de transesterificación mediante catálisis ácida heterogénea.
US20110218104A1 (en) * 2010-03-03 2011-09-08 Auburn University Biodiesel Solvents in Pesticide Compositions
DE102010002809A1 (de) * 2010-03-12 2011-11-17 Evonik Degussa Gmbh Verfahren zur Herstellung von linearen alpha,omega-Dicarbonsäurediestern
US9822051B2 (en) 2013-06-03 2017-11-21 Evonik Degussa Gmbh Method for producing acrolein
US9328054B1 (en) 2013-09-27 2016-05-03 Travis Danner Method of alcoholisis of fatty acids and fatty acid gyicerides
KR101629003B1 (ko) * 2013-11-18 2016-06-09 주식회사 엘지화학 글리세린 탈수반응용 촉매, 이의 제조 방법 및 아크롤레인의 제조 방법
US9796648B2 (en) 2014-05-02 2017-10-24 University Of Tennessee Research Foundation Glycerol dehydration methods and products thereof
CN105693519A (zh) * 2014-11-27 2016-06-22 上海华谊能源化工有限公司 一种对苯二甲酸二酯的低熔点混合物的制备方法
GB201505178D0 (en) 2015-03-26 2015-05-13 Stichting Dienst Landbouwkundi Production of fatty acid estolides
FR3059327B1 (fr) * 2016-11-25 2021-10-15 Arkema France Composition acide pour le traitement d'acides gras
US10239812B2 (en) 2017-04-27 2019-03-26 Sartec Corporation Systems and methods for synthesis of phenolics and ketones
CN109772439B (zh) * 2017-11-14 2022-02-08 中国石油化工股份有限公司 一种叔丁醇精制催化剂及其制备方法和应用
CN107915614B (zh) * 2017-12-06 2020-12-01 中国科学院山西煤炭化学研究所 一种制备丙烯醛的方法
US10544381B2 (en) 2018-02-07 2020-01-28 Sartec Corporation Methods and apparatus for producing alkyl esters from a reaction mixture containing acidified soap stock, alcohol feedstock, and acid
US10696923B2 (en) 2018-02-07 2020-06-30 Sartec Corporation Methods and apparatus for producing alkyl esters from lipid feed stocks, alcohol feedstocks, and acids
CN115350727B (zh) * 2022-10-21 2023-01-24 河北工业大学 一种改性磺酸树脂催化剂及其制备方法和应用

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DE4238492C2 (de) 1992-11-14 1995-06-14 Degussa Verfahren zur Herstellung von 1,2- und 1,3-Propandiol
DE4238493C1 (de) 1992-11-14 1994-04-21 Degussa Verfahren zur Herstellung von Acrolein und dessen Verwendung
WO2005021697A1 (en) 2003-08-29 2005-03-10 Nippon Shokubai Co., Ltd. Method of production of fatty acid alkyl esters and/or glycerine and fatty acid alkyl ester-containing composition
JP2005102533A (ja) * 2003-09-29 2005-04-21 Nippon Shokubai Co Ltd １，３−プロパンジオールの製造方法
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TWI522092B (zh) 2005-02-28 2016-02-21 贏創德固賽有限責任公司 丙烯酸和基於可再生原料之吸水聚合物結構及二者之製備方法
JP4909526B2 (ja) * 2005-04-12 2012-04-04 花王株式会社 アクロレインの製造方法

Also Published As

Publication number Publication date
JP5361731B2 (ja) 2013-12-04
RU2009123233A (ru) 2010-12-27
ATE535509T1 (de) 2011-12-15
CN101535233A (zh) 2009-09-16
BRPI0718997A2 (pt) 2014-02-18
EP2097367B1 (de) 2011-11-30
DE102006054519A1 (de) 2008-05-21
BRPI0718997B1 (pt) 2016-12-20
US20080119663A1 (en) 2008-05-22
WO2008061860A1 (de) 2008-05-29
US7498454B2 (en) 2009-03-03
MY147480A (en) 2012-12-14
JP2010510277A (ja) 2010-04-02
EP2097367A1 (de) 2009-09-09
ES2377218T3 (es) 2012-03-23

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