MX2009005397A - Proceso para la conversion de compuestos nitrilo en acidos carboxilicos y esteres correspondientes. - Google Patents
Proceso para la conversion de compuestos nitrilo en acidos carboxilicos y esteres correspondientes.Info
- Publication number
- MX2009005397A MX2009005397A MX2009005397A MX2009005397A MX2009005397A MX 2009005397 A MX2009005397 A MX 2009005397A MX 2009005397 A MX2009005397 A MX 2009005397A MX 2009005397 A MX2009005397 A MX 2009005397A MX 2009005397 A MX2009005397 A MX 2009005397A
- Authority
- MX
- Mexico
- Prior art keywords
- compounds
- carboxylic
- function
- esters
- carboxylic acids
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 4
- -1 nitrile compounds Chemical class 0.000 title abstract 2
- 150000001735 carboxylic acids Chemical class 0.000 title 1
- 150000002148 esters Chemical class 0.000 title 1
- 150000001875 compounds Chemical class 0.000 abstract 5
- 150000002825 nitriles Chemical group 0.000 abstract 3
- 150000001408 amides Chemical group 0.000 abstract 2
- 150000007522 mineralic acids Chemical class 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- 150000005690 diesters Chemical class 0.000 abstract 1
- 230000000887 hydrating effect Effects 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 230000003301 hydrolyzing effect Effects 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/08—Preparation of carboxylic acids or their salts, halides or anhydrides from nitriles
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C53/00—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
- C07C53/126—Acids containing more than four carbon atoms
- C07C53/128—Acids containing more than four carbon atoms the carboxylic group being bound to a carbon atom bound to at least two other carbon atoms, e.g. neo-acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/48—Separation; Purification; Stabilisation; Use of additives
- C07C67/52—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
- C07C67/54—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Crystallography & Structural Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
La presente invención está relacionada con un método para convertir los compuestos de hidrocarburo que tienen al menos una función de nitrilo en compuestos que tienen al menos una función carboxílica, y con un método para obtener compuestos de éster a partir de compuestos carboxílicos obtenidos así. La invención proporciona un método para convertir compuestos que tienen al menos una función de nitrilo en compuestos que tienen al menos una función carboxílica, que comprende hidratar las funciones de nitrilo con la función de amida mediante la reacción con agua en presencia de un ácido inorgánico concentrado, e hidrolizar las funciones de amida en funciones carboxílicas y haciendo reaccionar con agua y un ácido inorgánico concentrado. Los compuestos carboxílicos obtenidos así pueden luego eterificarse en diésteres. Éste último puede usarse ventajosamente como solvente.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0610302A FR2909088B1 (fr) | 2006-11-24 | 2006-11-24 | Procede de transformation de composes nitriles en acides carboxyliques et esters correspondants |
| PCT/EP2007/062748 WO2008062058A1 (fr) | 2006-11-24 | 2007-11-23 | Procede de transformation de composes nitriles en acides carboxyliques et esters correspondants |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX2009005397A true MX2009005397A (es) | 2009-06-02 |
Family
ID=38234316
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2009005397A MX2009005397A (es) | 2006-11-24 | 2007-11-23 | Proceso para la conversion de compuestos nitrilo en acidos carboxilicos y esteres correspondientes. |
Country Status (17)
| Country | Link |
|---|---|
| US (1) | US8263804B2 (es) |
| EP (1) | EP2091905B1 (es) |
| JP (1) | JP5548455B2 (es) |
| KR (1) | KR101162519B1 (es) |
| CN (1) | CN101641318B (es) |
| AR (1) | AR063897A1 (es) |
| AU (1) | AU2007324504B2 (es) |
| BR (1) | BRPI0719378A2 (es) |
| CA (1) | CA2670212C (es) |
| EA (1) | EA017506B1 (es) |
| ES (1) | ES2544333T3 (es) |
| FR (1) | FR2909088B1 (es) |
| MX (1) | MX2009005397A (es) |
| PL (1) | PL2091905T3 (es) |
| TW (1) | TWI415832B (es) |
| WO (1) | WO2008062058A1 (es) |
| ZA (1) | ZA200903597B (es) |
Families Citing this family (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2850966B1 (fr) | 2003-02-10 | 2005-03-18 | Rhodia Polyamide Intermediates | Procede de fabrication de composes dinitriles |
| FR2854891B1 (fr) | 2003-05-12 | 2006-07-07 | Rhodia Polyamide Intermediates | Procede de preparation de dinitriles |
| US7973174B2 (en) | 2005-10-18 | 2011-07-05 | Invista North America S.A.R.L. | Process of making 3-aminopentanenitrile |
| WO2007109005A2 (en) | 2006-03-17 | 2007-09-27 | Invista Technologies S.A R.L. | Method for the purification of triorganophosphites by treatment with a basic additive |
| US7880028B2 (en) | 2006-07-14 | 2011-02-01 | Invista North America S.A R.L. | Process for making 3-pentenenitrile by hydrocyanation of butadiene |
| US7919646B2 (en) | 2006-07-14 | 2011-04-05 | Invista North America S.A R.L. | Hydrocyanation of 2-pentenenitrile |
| CN101687658B (zh) | 2007-05-14 | 2013-07-24 | 因温斯特技术公司 | 高效反应器和方法 |
| WO2008157218A1 (en) | 2007-06-13 | 2008-12-24 | Invista Technologies S.A.R.L. | Process for improving adiponitrile quality |
| FR2922548B1 (fr) | 2007-10-22 | 2012-11-30 | Rhodia Operations | Diesters d'acides dicarboxyliques,procedes de preparation et utilisations |
| US7977502B2 (en) | 2008-01-15 | 2011-07-12 | Invista North America S.A R.L. | Process for making and refining 3-pentenenitrile, and for refining 2-methyl-3-butenenitrile |
| WO2009091790A1 (en) | 2008-01-15 | 2009-07-23 | Invista Technologies S.A.R.L. | Hydrocyanation of pentenenitriles |
| CA2712318C (fr) | 2008-01-25 | 2015-12-08 | Rhodia Operations | Utilisation d'esteramides a titre de solvants, esteramides en tant que tels et procede de preparation d'esteramides |
| FR2927081B1 (fr) * | 2008-02-01 | 2012-09-14 | Rhodia Operations | Mousses de polyurethanne |
| EP2334624B1 (en) | 2008-10-14 | 2014-10-01 | Invista Technologies S.à.r.l. | Process for making 2-secondary-alkyl-4,5-di-(normal-alkyl)phenols |
| FR2941462B1 (fr) | 2009-01-23 | 2013-07-05 | Rhodia Operations | Composition decapante |
| CN102471218B (zh) | 2009-08-07 | 2014-11-05 | 因温斯特技术公司 | 用于形成二酯的氢化并酯化 |
| FR2949116B1 (fr) | 2009-08-13 | 2012-08-31 | Rhodia Operations | Composition de nettoyage de graffiti |
| EP2789652A1 (fr) * | 2013-04-10 | 2014-10-15 | Rhodia Opérations | Composition plastifiante |
| CN103274924B (zh) * | 2013-05-24 | 2014-10-15 | 武汉工程大学 | 一种化合物1,3-二羧基-2,2-二(乙酸基)丙烷及其合成方法 |
| WO2015009847A1 (en) * | 2013-07-17 | 2015-01-22 | Invista Technologies S.À R.L. | Separating a solvent from a nickel catalyst by distillation |
| WO2015096022A1 (en) * | 2013-12-24 | 2015-07-02 | Rhodia Operations | Production of a compound comprising at least one carboxylic acid functional group |
| CA2971549A1 (en) * | 2014-12-24 | 2016-06-30 | Kuraray Co., Ltd. | Method for producing aldehyde compound, and acetal compound |
| FR3041357B1 (fr) | 2015-09-17 | 2017-09-01 | Rhodia Operations | Solvants de decapage des resines photosensibles |
| CN109790389A (zh) | 2016-07-26 | 2019-05-21 | 罗地亚经营管理公司 | 用于烃粘结剂的助熔剂 |
| FR3065732B1 (fr) | 2017-04-27 | 2019-07-19 | Rhodia Operations | Agents d'interfaces pour la preparation de revetements routiers a froid |
| CN109824514A (zh) * | 2019-03-06 | 2019-05-31 | 重庆中平紫光科技发展有限公司 | 一种合成2-甲基戊二酸二甲酯的方法 |
| CN111100022A (zh) * | 2019-10-30 | 2020-05-05 | 石家庄市栾城区华英工贸有限责任公司 | 一种路易斯酸催化腈类化合物水解制备羧酸类化合物的方法 |
| CN113149823B (zh) * | 2021-03-29 | 2023-12-08 | 上海青平药业有限公司 | 一种2-r1戊酸的制备方法 |
| CN113788755A (zh) * | 2021-09-26 | 2021-12-14 | 四川玖源高新材料有限公司 | 2-甲基戊二酸二甲酯的制备方法 |
| CN113773197A (zh) * | 2021-09-26 | 2021-12-10 | 四川玖源高新材料有限公司 | 戊烯酸甲酯的制备方法 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB339235A (en) * | 1929-12-18 | 1930-12-04 | Ig Farbenindustrie Ag | Improvements in the manufacture and production of carboxylic acids from nitriles |
| GB970953A (en) * | 1962-02-21 | 1964-09-23 | Angeli Inst Spa | ª‡,ª‡-disubstituted 1-naphthylacetic acids |
| US3377378A (en) * | 1965-05-10 | 1968-04-09 | Standard Oil Co | Manufacture of esters from carboxylic acid nitriles |
| US3492345A (en) * | 1965-06-04 | 1970-01-27 | Degussa | Process for hydrolysis of nitriles with recovery of nitrogen values derived from the nitrile group |
| DE1281446B (de) * | 1965-08-11 | 1968-10-31 | Degussa | Verfahren zur Herstellung von Carbonsaeureestern aus Nitrilen unter Wiedergewinnung von Ammoniak |
| GB1122448A (en) * | 1965-09-22 | 1968-08-07 | Nat Distillers Chem Corp | Process for preparing unsaturated dicarboxylic acids |
| DE1768282B2 (de) * | 1968-04-25 | 1975-12-11 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Herstellung von beta-Alanin und 2-Methyl-beta-alanin |
| US4028406A (en) * | 1970-07-03 | 1977-06-07 | Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler | Process of preparing penicillamine |
| AU4839279A (en) * | 1978-07-18 | 1980-01-24 | Imperial Chemical Industries Ltd. | Cyclopropane carboxylic acids |
| US6413918B1 (en) * | 1998-04-27 | 2002-07-02 | E. I. Du Pont De Nemours And Company | Non-symmetric, partially fluorinated lubricant additives |
| DE102004004683A1 (de) * | 2004-01-29 | 2005-08-18 | Basf Ag | Verfahren zur Herstellung von Dinitrilen |
-
2006
- 2006-11-24 FR FR0610302A patent/FR2909088B1/fr not_active Expired - Fee Related
-
2007
- 2007-11-22 AR ARP070105185A patent/AR063897A1/es not_active Application Discontinuation
- 2007-11-23 MX MX2009005397A patent/MX2009005397A/es active IP Right Grant
- 2007-11-23 EP EP07822844.2A patent/EP2091905B1/fr active Active
- 2007-11-23 CA CA2670212A patent/CA2670212C/fr not_active Expired - Fee Related
- 2007-11-23 CN CN2007800433190A patent/CN101641318B/zh active Active
- 2007-11-23 AU AU2007324504A patent/AU2007324504B2/en not_active Ceased
- 2007-11-23 KR KR1020097010552A patent/KR101162519B1/ko active Active
- 2007-11-23 US US12/516,042 patent/US8263804B2/en active Active
- 2007-11-23 WO PCT/EP2007/062748 patent/WO2008062058A1/fr not_active Ceased
- 2007-11-23 TW TW096144596A patent/TWI415832B/zh not_active IP Right Cessation
- 2007-11-23 ES ES07822844.2T patent/ES2544333T3/es active Active
- 2007-11-23 JP JP2009537650A patent/JP5548455B2/ja not_active Expired - Fee Related
- 2007-11-23 BR BRPI0719378-5A patent/BRPI0719378A2/pt active Search and Examination
- 2007-11-23 PL PL07822844T patent/PL2091905T3/pl unknown
- 2007-11-23 EA EA200970508A patent/EA017506B1/ru not_active IP Right Cessation
-
2009
- 2009-05-25 ZA ZA200903597A patent/ZA200903597B/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| JP2010510295A (ja) | 2010-04-02 |
| JP5548455B2 (ja) | 2014-07-16 |
| FR2909088B1 (fr) | 2009-02-13 |
| AR063897A1 (es) | 2009-02-25 |
| CA2670212C (fr) | 2012-07-03 |
| AU2007324504B2 (en) | 2011-04-21 |
| KR101162519B1 (ko) | 2012-07-09 |
| CN101641318A (zh) | 2010-02-03 |
| TW200835679A (en) | 2008-09-01 |
| BRPI0719378A2 (pt) | 2014-02-11 |
| EP2091905B1 (fr) | 2015-05-13 |
| AU2007324504A1 (en) | 2008-05-29 |
| CA2670212A1 (fr) | 2008-05-29 |
| KR20090082426A (ko) | 2009-07-30 |
| US8263804B2 (en) | 2012-09-11 |
| WO2008062058A1 (fr) | 2008-05-29 |
| ES2544333T3 (es) | 2015-08-28 |
| ZA200903597B (en) | 2010-07-28 |
| EA017506B1 (ru) | 2013-01-30 |
| PL2091905T3 (pl) | 2015-10-30 |
| EP2091905A1 (fr) | 2009-08-26 |
| TWI415832B (zh) | 2013-11-21 |
| US20100145091A1 (en) | 2010-06-10 |
| FR2909088A1 (fr) | 2008-05-30 |
| CN101641318B (zh) | 2013-04-24 |
| EA200970508A1 (ru) | 2009-12-30 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG | Grant or registration |