MX3152E - PROCEDURE FOR THE PREPARATION OF DERIVATIVES OF 8 - AN IMPROVED PROCEDURE FOR OBTAINING SELECTAMINO - TEO FILINA IVA OF A POLICE RENT POLYAMINE PREDOMINANTLY NON-CYCLICAL - Google Patents

PROCEDURE FOR THE PREPARATION OF DERIVATIVES OF 8 - AN IMPROVED PROCEDURE FOR OBTAINING SELECTAMINO - TEO FILINA IVA OF A POLICE RENT POLYAMINE PREDOMINANTLY NON-CYCLICAL

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Publication number
MX3152E
MX3152E MX6776U MX6776U MX3152E MX 3152 E MX3152 E MX 3152E MX 6776 U MX6776 U MX 6776U MX 6776 U MX6776 U MX 6776U MX 3152 E MX3152 E MX 3152E
Authority
MX
Mexico
Prior art keywords
formula
see
procedure
derivatives
selectamino
Prior art date
Application number
MX6776U
Other languages
Spanish (es)
Inventor
Jean Raymond Quelet
Michael Edward Brennan
Ernest Leon Yeakey
Original Assignee
Texaco Dev Corp Laboratoire Le
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from FR7507675A external-priority patent/FR2303551A1/en
Priority claimed from US05/583,017 external-priority patent/US4036881A/en
Application filed by Texaco Dev Corp Laboratoire Le filed Critical Texaco Dev Corp Laboratoire Le
Publication of MX3152E publication Critical patent/MX3152E/en

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  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

La presente invención se refiere a un procedimientde preparación de derivados de 8-amino-teofilina de fórmula (VER FIGURA) en la cual A es un radical alcohileno lineal o ramificado que tiene de 2 a 4 la fórmula general (VER FIGURA) en donde R es un dical alcohileno lineal o ramificado que tiene de X es un número de 2 a 6, e y es un número de 2 a 6, con un compuesto alcanolamina de la fórmula (VER FIGURA) en donde R es un hidrógeno o un radical alquilo de bajo contenido; X es un número de 2 a 6; e y es un número de 0 a 3, en la presencia de una cantidad catalíticamente efectiva, de una substancia que contiene fósforo a temperaturas comprendidas entre 250°C y 350°C bajo una presión suficiente para mantener la mezcla esencialmente en la fase líquida y la recuperación del compuesto poliamina polialquileno, de una mezcla de reacción resultante, caracterizado porque la substancia que comprende fósforo es escogida de los fosfatos de metales acídicos compuestos de ácido fósforico y sus compuendensa una piperazina sustituída de fórmula (VER Fe fosfato, alquilo o arilo, ésteres de fosfato alqinen anteriormente, con un derivado de fórmula (VEo o arilo, y ácido fosfóricos, monosales de metal alcalino, de ácido fosfórico, los tioanálogos de lndose la reacción de condensación mediante fusión de los reactivos juntos, a una temperatura aproximadamente 180 a 190°C.The present invention relates to a process for preparing 8-amino-theophylline derivatives of the formula (SEE FIGURE) in which A is a linear or branched alcoholic radical having from 2 to 4 the general formula (SEE FIGURE) where R is a linear or branched alcoholic dical having X is a number from 2 to 6, and y is a number from 2 to 6, with an alkanolamine compound of the formula (SEE FIGURE) where R is a hydrogen or an alkyl radical of low content; X is a number from 2 to 6; ey is a number from 0 to 3, in the presence of a catalytically effective amount, of a phosphorous-containing substance at temperatures between 250 ° C and 350 ° C under a pressure sufficient to keep the mixture essentially in the liquid phase and the recovery of the polyalkylene polyamine compound, from a resulting reaction mixture, characterized in that the phosphorus-containing substance is chosen from the acidic metal phosphates composed of phosphoric acid and its compounds is a substituted piperazine of the formula (SEE Fe phosphate, alkyl or aryl, esters of phosphate alqinen above, with a derivative of the formula (VEo or aryl, and phosphoric acids, monosalts of alkali metal, of phosphoric acid, the thio analogues of the condensation reaction by melting the reagents together, at a temperature of approximately 180 to 190 ° C.

MX6776U 1975-03-12 1976-03-11 PROCEDURE FOR THE PREPARATION OF DERIVATIVES OF 8 - AN IMPROVED PROCEDURE FOR OBTAINING SELECTAMINO - TEO FILINA IVA OF A POLICE RENT POLYAMINE PREDOMINANTLY NON-CYCLICAL MX3152E (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR7507675A FR2303551A1 (en) 1975-03-12 1975-03-12 8-AMINO THEOPHYLLINE DERIVATIVES, THEIR PREPARATION PROCESS AND THEIR APPLICATIONS
US05/583,017 US4036881A (en) 1975-06-02 1975-06-02 Preparation of polyalkylene polyamines

Publications (1)

Publication Number Publication Date
MX3152E true MX3152E (en) 1980-05-09

Family

ID=26218777

Family Applications (1)

Application Number Title Priority Date Filing Date
MX6776U MX3152E (en) 1975-03-12 1976-03-11 PROCEDURE FOR THE PREPARATION OF DERIVATIVES OF 8 - AN IMPROVED PROCEDURE FOR OBTAINING SELECTAMINO - TEO FILINA IVA OF A POLICE RENT POLYAMINE PREDOMINANTLY NON-CYCLICAL

Country Status (1)

Country Link
MX (1) MX3152E (en)

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