MX363101B - Catalizador de metaloceno soportado por medios de soporte hibridos, procesos para producir el mismo, procesos de polimerizacion para producir un homopolimero o copolimero de etileno con distribucion de masa molar amplia o bimodal, uso del catalizador de metaloceno soportado y polimero de etileno con distribucion de masa molar amplia o bimodal. - Google Patents

Catalizador de metaloceno soportado por medios de soporte hibridos, procesos para producir el mismo, procesos de polimerizacion para producir un homopolimero o copolimero de etileno con distribucion de masa molar amplia o bimodal, uso del catalizador de metaloceno soportado y polimero de etileno con distribucion de masa molar amplia o bimodal.

Info

Publication number
MX363101B
MX363101B MX2015006615A MX2015006615A MX363101B MX 363101 B MX363101 B MX 363101B MX 2015006615 A MX2015006615 A MX 2015006615A MX 2015006615 A MX2015006615 A MX 2015006615A MX 363101 B MX363101 B MX 363101B
Authority
MX
Mexico
Prior art keywords
supporting means
metallocene catalyst
metallocene
supported
catalyst supported
Prior art date
Application number
MX2015006615A
Other languages
English (en)
Other versions
MX2015006615A (es
Inventor
Brambilla Rodrigo
Silva Lacerda Miranda Marcia
Henrique Zimnoch Dos Santos João
Silveira Fernando
Original Assignee
Braskem Sa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Braskem Sa filed Critical Braskem Sa
Publication of MX2015006615A publication Critical patent/MX2015006615A/es
Publication of MX363101B publication Critical patent/MX363101B/es

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/72—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44
    • C08F4/74—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from refractory metals
    • C08F4/76—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from refractory metals selected from titanium, zirconium, hafnium, vanadium, niobium or tantalum
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/02—Carriers therefor
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/01—Additive used together with the catalyst, excluding compounds containing Al or B
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

La presente invención se refiere a un catalizador de metaloceno que contiene un metal de transición del grupo 4 o 5 de la tabla periódica, el cual es soportado por medios de soporte catalítico híbrido con grupos orgánicos alifáticos. Un proceso para soportar metaloceno en estos medios de soporte catalítico híbrido con grupos orgánicos alifáticos también se describe. La principal ventaja del catalizador metaloceno soportado de la presente invención es que un polímero de etileno con distribución de masa molar amplia o bimodal se produce usando solamente un tipo del complejo de metaloceno en los medios de soporte. Como un resultado, la resma producida puede ser procesada de una manera mejorada, lo cual consecuentemente costos de procesamiento potencialmente disminuidos.
MX2015006615A 2012-11-26 2012-11-26 Catalizador de metaloceno soportado por medios de soporte hibridos, procesos para producir el mismo, procesos de polimerizacion para producir un homopolimero o copolimero de etileno con distribucion de masa molar amplia o bimodal, uso del catalizador de metaloceno soportado y polimero de etileno con distribucion de masa molar amplia o bimodal. MX363101B (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/BR2012/000475 WO2014078919A1 (pt) 2012-11-26 2012-11-26 Catalisador metaloceno suportado em suporte híbrido, processo de obtenção do mesmo, processo de polimerização para obtenção de um homopolímero ou copolímero de etileno com distribuição de massa molar ampla ou bimodal, uso do catalisador de metaloceno suportado e polímero de etileno com distribuição de massa molar ampla ou bimodal

Publications (2)

Publication Number Publication Date
MX2015006615A MX2015006615A (es) 2015-11-16
MX363101B true MX363101B (es) 2019-03-08

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
MX2015006615A MX363101B (es) 2012-11-26 2012-11-26 Catalizador de metaloceno soportado por medios de soporte hibridos, procesos para producir el mismo, procesos de polimerizacion para producir un homopolimero o copolimero de etileno con distribucion de masa molar amplia o bimodal, uso del catalizador de metaloceno soportado y polimero de etileno con distribucion de masa molar amplia o bimodal.

Country Status (6)

Country Link
US (1) US9695254B2 (es)
EP (1) EP2923756B1 (es)
AR (1) AR093428A1 (es)
BR (1) BR112015011215B1 (es)
MX (1) MX363101B (es)
WO (1) WO2014078919A1 (es)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015081409A1 (pt) * 2013-12-05 2015-06-11 Braskem S.A. Catalisador metaloceno a base de metal de transição dos grupos 4 ou 5 da tabela periódica imobilizado sobre um suporte modificado com sílica híbrida solúvel, processo de obtenção do mesmo e seu uso
CN110520492A (zh) * 2017-06-29 2019-11-29 住友化学株式会社 组合物
KR20220123415A (ko) * 2019-12-26 2022-09-06 다우 글로벌 테크놀로지스 엘엘씨 탁월한 가공성을 갖는 중합체 조성물의 제조 공정
WO2023114773A1 (en) 2021-12-16 2023-06-22 Chevron Phillips Chemical Company Lp Modifications of sulfated bentonites and uses thereof in metallocene catalyst systems for olefin polymerization

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EP2923756A4 (en) 2016-09-07
BR112015011215A2 (pt) 2016-04-05
US20150274852A1 (en) 2015-10-01
EP2923756B1 (en) 2018-05-30
MX2015006615A (es) 2015-11-16
US9695254B2 (en) 2017-07-04

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