MY105409A - Production of 9-octadecene-1-01 using ruthenium/thin catalyst - Google Patents

Production of 9-octadecene-1-01 using ruthenium/thin catalyst

Info

Publication number
MY105409A
MY105409A MYPI90002305A MYPI19902305A MY105409A MY 105409 A MY105409 A MY 105409A MY PI90002305 A MYPI90002305 A MY PI90002305A MY PI19902305 A MYPI19902305 A MY PI19902305A MY 105409 A MY105409 A MY 105409A
Authority
MY
Malaysia
Prior art keywords
catalyst
octadecene
ruthenium
selectivity
tin
Prior art date
Application number
MYPI90002305A
Inventor
Kien Yoo Cheah
Niwa Shu-Ichi
Mizukami Fujio
Thin Sue Tang
Toba Makoto
Yuen May Choo
Original Assignee
Malaysian Palm Oil Board
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Malaysian Palm Oil Board filed Critical Malaysian Palm Oil Board
Priority to MYPI90002305A priority Critical patent/MY105409A/en
Publication of MY105409A publication Critical patent/MY105409A/en

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  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

A NEW CATALYST, RUTHENIUM- TIN SUPPORTED ON ALUMINA OR SILICA IS FOUND TO SELECTIVELY HYDROGENATE OLEIC ACID TO 9- OCTADECENE -1-01 AT LOW PRESSURE WITH HIGH YIELD. OUR STUDIES ALSO REVEAL THAT THE CATALYST PREPARED BY THE SOL- GEL METHOD SHOWED HIGHER ACTIVITY AND SELECTIVITY THAN THOSE PREPARED BY THE CONVENTIONAL IMPREGNATION AND COPRECIPITATION METHODS. IN THIS NEW METHOD THE RUTHENIUM AND TIN METALS ARE BETTER DISPERSED ON THE SUPPORT (ALUMINA OR SILICA) WHICH IS ALSO GENERATED FROM THEIR PRECURSORS DURING THE CATALYST PREPARATION PROCESS. THE PRESENCE OF TIN IMPARTS SELECTIVITY TO THE CATALYST. THE PERFORMANCE OF THE CATALYST DEPENDS ON THE RAW MATERIALS, ACTIVATION AS WELL AS REACTION CONDITIONS. UNDER OPTIMAL CONDITION OF 250?C AND 56KG/CM2 A CONVERSION (OF OLEIC ACID TO 9- OCTADECENE-1-01) OF 70- 83AND SELECTIVITY EXCEEDING 80AN BE ACHIEVED.
MYPI90002305A 1990-12-31 1990-12-31 Production of 9-octadecene-1-01 using ruthenium/thin catalyst MY105409A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
MYPI90002305A MY105409A (en) 1990-12-31 1990-12-31 Production of 9-octadecene-1-01 using ruthenium/thin catalyst

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
MYPI90002305A MY105409A (en) 1990-12-31 1990-12-31 Production of 9-octadecene-1-01 using ruthenium/thin catalyst

Publications (1)

Publication Number Publication Date
MY105409A true MY105409A (en) 1994-09-30

Family

ID=79553834

Family Applications (1)

Application Number Title Priority Date Filing Date
MYPI90002305A MY105409A (en) 1990-12-31 1990-12-31 Production of 9-octadecene-1-01 using ruthenium/thin catalyst

Country Status (1)

Country Link
MY (1) MY105409A (en)

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