MY123728A - Process for producing n- butyraldehyde and / or n- butanol - Google Patents

Process for producing n- butyraldehyde and / or n- butanol

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Publication number
MY123728A
MY123728A MYPI9600134A MY123728A MY 123728 A MY123728 A MY 123728A MY PI9600134 A MYPI9600134 A MY PI9600134A MY 123728 A MY123728 A MY 123728A
Authority
MY
Malaysia
Prior art keywords
formula
catalyst
transition metal
metal element
adduct
Prior art date
Application number
Inventor
Alfred THOME
Jurgen Kanand
Michael Roper
Rocco Paciello
Original Assignee
Basf Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Ag filed Critical Basf Ag
Priority to MYPI9600134 priority Critical patent/MY123728A/en
Publication of MY123728A publication Critical patent/MY123728A/en

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  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

A PROCESS FOR PREPARATION OF N-BUTYRALDEHYDE AND/OR N-BUTANOL, IN WHICH A) 1,3-BUTADIENE IS CAUSED TO REACT WITH AN AMINE OF THE FORMULA Ι, IN WHICH R¹ AND R² INDEPENDENTLY DENOTE HYDROGEN, OPTIONALLY SUBSTITUTED ALIPHATIC OR CYCLOALIPHATIC RADICALS, OR ARYL OR ARALKYL RADICALS OR ARE LINKED TO FORM A BRIDGING MEMBER CONTAINING THE HETERO ATOM, AT ELEVATED TEMPERATURE AND UNDER SUPERATMOSPHERIC PRESSURE IN THE PRESENCE OF A COMPOUND OF A GROUP VΙΙΙB ELEMENT AND IN THE PRESENCE OF AN ALKALI METAL AMIDE OR A BASIC METAL OXIDE TO FORM A MIXTURE OF THE ADDUCTS OF THE FORMULA ΙΙ (FORMULA ΙΙ, ΙΙΙ)B) THE ADDUCT ΙΙΙ IS ISOMERIZED TO THE ADDUCT ΙΙ,C) THE ADDUCT ΙΙ IS ISOMERIZED IN THE PRESENCE OF A HOMOGENEOUS OR HETEROGENEOUS TRANSITION METAL ELEMENT CATALYST IN THE LIQUID PHASE OR IN THE PRESENCE OF A HETEROGENEOUS CATALYST CONTAINING A TRANSITION METAL ELEMENT IN THE GASEOUS PHASE TO FORM THE ENAMINE OF THE FORMULA ΙV(FORMULA ΙV)AND D) N-BUTYRALDEHYDE AND/OR N-BUTANOL IS/ARE PRODUCED FROM THIS ENAMINE ΙV BY THE REACTION THEREOF WITH HYDROGEN AND WATER ONLY IN THE PRESENCE OF A HOMOGENEOUS OR HETEROGENEOUS TRANSITION METAL ELEMENT CATALYST IN THE LIQUID PHASE OR IN THE PRESENCE OF A HETEROGENOUS TRANSITION METAL ELEMENT CATALYST IN THE GASEOUS PHASE AND IN THE PRESENCE OF AN ACID OR IN PRESENCE OF ONE OF SAID CATALYST AND AN ACID, AND THE AMINE Ι IS LIBERATED, AND THE LIBERATED AMINE Ι IS RECYCLED TO THE STAGE DEFINED ABOVE AS PARTIAL REACTION A).
MYPI9600134 1996-01-13 1996-01-13 Process for producing n- butyraldehyde and / or n- butanol MY123728A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
MYPI9600134 MY123728A (en) 1996-01-13 1996-01-13 Process for producing n- butyraldehyde and / or n- butanol

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
MYPI9600134 MY123728A (en) 1996-01-13 1996-01-13 Process for producing n- butyraldehyde and / or n- butanol

Publications (1)

Publication Number Publication Date
MY123728A true MY123728A (en) 2006-05-31

Family

ID=47257317

Family Applications (1)

Application Number Title Priority Date Filing Date
MYPI9600134 MY123728A (en) 1996-01-13 1996-01-13 Process for producing n- butyraldehyde and / or n- butanol

Country Status (1)

Country Link
MY (1) MY123728A (en)

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