MY139735A - Preparation of acrolein by heterogeneously catalyzed partial gas phase oxidation of propene - Google Patents

Preparation of acrolein by heterogeneously catalyzed partial gas phase oxidation of propene

Info

Publication number
MY139735A
MY139735A MYPI20044514A MYPI20044514A MY139735A MY 139735 A MY139735 A MY 139735A MY PI20044514 A MYPI20044514 A MY PI20044514A MY PI20044514 A MYPI20044514 A MY PI20044514A MY 139735 A MY139735 A MY 139735A
Authority
MY
Malaysia
Prior art keywords
ranges
propene
acrolein
mol
formula
Prior art date
Application number
MYPI20044514A
Inventor
Jochen Dr Petzoldt
Klaus Joachim M Dr Mueller-Engel
Original Assignee
Basf Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE10353954A external-priority patent/DE10353954A1/en
Application filed by Basf Ag filed Critical Basf Ag
Publication of MY139735A publication Critical patent/MY139735A/en

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/888—Tungsten
    • B01J23/8885—Tungsten containing also molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/888—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/19—Catalysts containing parts with different compositions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/34—Mechanical properties
    • B01J35/36—Mechanical strength
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/55—Cylinders or rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

ACROLEIN IS PREPARED BY A PROCESS OF HETEROGENEOUS CATALYZED PARTIAL GAS PHASE OXIDATION, BY PASSING A STARTING REACTION GAS MIXTURE WHICH COMPRISES PROPENE, MOLECULAR OXYGEN AND AT LEAST ONE INERT GAS, IN WHICH THE MOLECULAR OXYGEN TO PROPENE (O2:C3H6) MOLE RATIO IS ≥1, AND CARBON DIOXIDE AND SATURATED HYDROCARBONS TOGETHER IN A TOTAL AMOUNT OF AT MOST 15 MOL %, AT ELEVATED TEMPERATURE AND AT AN HOURLY SPACE VELOCITY ON THE FIXED CATALYST BED OF PROPENE PRESENT IN THE STARTING REACTION GAS MIXTURE OF ≥120 I (STP)/LOH THROUGH A FIXED CATALYST BED WHOSE CATALYSTS ARE COMPRISED OF ANNULAR UNSUPPORTED CATALYSTS WHOSE ACTIVE COMPONENT IS AT LEAST ONE MULTIMETAL OXIDE OF FORMULA I, MO12WACOBFECBIDSIEKTON (I) WHEREIN A RANGES FROM ≥1 TO ≤3, B RANGES FROM ≥3 TO ≤8, C RANGES FROM ≥1 TO ≤4, D RANGES FROM ≥0.5 TO ≤1.5, E RANGES FROM ≥O TO ≤10, AND F RANGES FROM ≥0 TO ≤0.2 AND N IS A NUMBER WHICH IS DETERMINED BY THE VALENCY AND FREQUENCY OF THE ELEMENTS IN THE COMPOSITION OF FORMULA I OTHER THAN OXYGEN, IN SUCH A WAY THAT THE PROPENE CONVERSION IN SINGLE PASS IS ≥90 MOL % AND THE ASSOCIATED SELECTIVITY OF ACROLEIN FORMATION IS ≥80 MOL %, WHEREIN, IN THE MULTI METAL OXIDE COMPOSITION OF FORMULA I, THE FOLLOWING MOLE RATIOS ARE: CO/FE=FROM 2 TO 4 AND CO/MO=FROM 0.3 TO 0.7.
MYPI20044514A 2003-11-18 2004-11-01 Preparation of acrolein by heterogeneously catalyzed partial gas phase oxidation of propene MY139735A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US52066003P 2003-11-18 2003-11-18
DE10353954A DE10353954A1 (en) 2003-11-18 2003-11-18 Preparation of acrolein, for e.g. preparing acrylic acid, comprises heterogeneously catalyzed partial gas phase oxidation of gas mixture comprising propene, molecular oxygen and inert gas at elevated temperature on a fixed catalyst bed

Publications (1)

Publication Number Publication Date
MY139735A true MY139735A (en) 2009-10-30

Family

ID=34621298

Family Applications (1)

Application Number Title Priority Date Filing Date
MYPI20044514A MY139735A (en) 2003-11-18 2004-11-01 Preparation of acrolein by heterogeneously catalyzed partial gas phase oxidation of propene

Country Status (10)

Country Link
EP (1) EP1689524B1 (en)
JP (1) JP4751335B2 (en)
KR (1) KR101135780B1 (en)
AT (1) ATE500890T1 (en)
BR (1) BRPI0416633B1 (en)
DE (1) DE502004012292D1 (en)
MY (1) MY139735A (en)
RU (1) RU2373993C2 (en)
TW (1) TWI351313B (en)
WO (1) WO2005049200A1 (en)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102007028332A1 (en) * 2007-06-15 2008-12-18 Basf Se A method for feeding a reactor with a fixed catalyst bed comprising at least annular shaped catalyst bodies K.
DE102008042060A1 (en) 2008-09-12 2009-06-18 Basf Se Preparing catalyst molded body, useful e.g. in ammoxidation of propene to acrylonitrile, comprises mixing starting mass having fine particles of bismuth mixed oxide with another starting mass, and forming geometrical molded bodies
DE102008042064A1 (en) 2008-09-12 2010-03-18 Basf Se Process for the preparation of geometric shaped catalyst bodies
DE102008042061A1 (en) 2008-09-12 2010-03-18 Basf Se Process for the preparation of geometric shaped catalyst bodies
DE102008054586A1 (en) * 2008-12-12 2010-06-17 Basf Se Process for the continuous production of geometric shaped catalyst bodies K
JP5295815B2 (en) * 2009-02-18 2013-09-18 住友化学株式会社 Production catalyst for methacrolein and methacrylic acid
JP5908595B2 (en) 2012-09-28 2016-04-26 旭化成ケミカルズ株式会社 Oxide catalyst and method for producing the same, and method for producing unsaturated aldehyde, diolefin and unsaturated nitrile
JP5951121B2 (en) 2013-05-09 2016-07-13 日本化薬株式会社 Catalyst for producing unsaturated aldehyde and / or unsaturated carboxylic acid, method for producing the same, and method for producing unsaturated aldehyde and / or unsaturated carboxylic acid
RU2016104764A (en) 2013-07-18 2017-08-21 Ниппон Каяку Кабусики Кайся METHOD FOR PRODUCING UNSATURATED ALDEHYDE AND / OR UNSATURATED CARBONIC ACID
EP3263213B1 (en) 2015-02-27 2020-02-12 Nippon Kayaku Kabushiki Kaisha Catalyst for manufacturing unsaturated aldehyde and/or unsaturated carboxylic acid and manufacturing method of same, and manufacturing method of unsaturated aldehyde and/or unsaturated carboxylic acid
JP6447327B2 (en) * 2015-04-02 2019-01-09 三菱ケミカル株式会社 Composite oxide catalyst, method for producing acrolein and acrylic acid using the same
JP6694884B2 (en) 2015-07-10 2020-05-20 日本化薬株式会社 Process for producing unsaturated aldehyde and / or unsaturated carboxylic acid
EP3120926A1 (en) 2015-07-20 2017-01-25 Evonik Degussa GmbH Method for preparing mixed oxide catalysts
EP3770145A1 (en) 2019-07-24 2021-01-27 Basf Se A process for the continuous production of either acrolein or acrylic acid as the target product from propene
US20240351008A1 (en) * 2021-11-30 2024-10-24 Nippon Kayaku Kabushiki Kaisha Catalyst, and method for producing compound using same
KR20240116732A (en) * 2021-11-30 2024-07-30 닛뽄 가야쿠 가부시키가이샤 Catalyst and method for producing compounds using the same

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU1112618A1 (en) * 1982-07-30 1994-09-30 Институт катализа СО АН СССР Method of obtaining catalyst for propylene oxidation
DE4220859A1 (en) * 1992-06-25 1994-01-05 Basf Ag Multimetal oxide materials
FR2718061B1 (en) * 1994-04-01 1996-04-26 Rhone Poulenc Chimie Catalyst compositions of the coated type, comprising nickel, cobalt, molybdenum and their use for the preparation of unsaturated aldehydes.
MY121141A (en) * 1999-03-10 2005-12-30 Basf Ag Method for the catalytic gas-phase oxidation of propene into acrolein
DE10046957A1 (en) * 2000-09-21 2002-04-11 Basf Ag Process for producing a multimetal oxide catalyst, process for producing unsaturated aldehydes and / or carboxylic acids and band calciner

Also Published As

Publication number Publication date
WO2005049200A1 (en) 2005-06-02
EP1689524A1 (en) 2006-08-16
JP4751335B2 (en) 2011-08-17
EP1689524B1 (en) 2011-03-09
KR101135780B1 (en) 2012-04-16
KR20060132585A (en) 2006-12-21
DE502004012292D1 (en) 2011-04-21
JP2007511565A (en) 2007-05-10
ATE500890T1 (en) 2011-03-15
BRPI0416633B1 (en) 2014-04-08
RU2006121336A (en) 2008-01-10
RU2373993C2 (en) 2009-11-27
TWI351313B (en) 2011-11-01
TW200529923A (en) 2005-09-16
BRPI0416633A (en) 2007-01-16

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