MY147009A - Hydroformylation process and product separation with improved recovery of rhodium - Google Patents

Hydroformylation process and product separation with improved recovery of rhodium

Info

Publication number
MY147009A
MY147009A MYPI20084582A MYPI20084582A MY147009A MY 147009 A MY147009 A MY 147009A MY PI20084582 A MYPI20084582 A MY PI20084582A MY PI20084582 A MYPI20084582 A MY PI20084582A MY 147009 A MY147009 A MY 147009A
Authority
MY
Malaysia
Prior art keywords
hydroformylation
total pressure
rhodium
stages
separation
Prior art date
Application number
MYPI20084582A
Inventor
Peng Jun Wei
Kurt D Olson
Donald L Morrison
Brian M Roesch
Donald L Bunning
Jeffrey G Hippler
Vincent J Stricker
Original Assignee
Dow Global Technologies Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Inc filed Critical Dow Global Technologies Inc
Publication of MY147009A publication Critical patent/MY147009A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C07C45/80—Separation; Purification; Stabilisation; Use of additives by liquid-liquid treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • C07C67/343—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C67/347—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by addition to unsaturated carbon-to-carbon bonds
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

A NON-AQUEOUS HYDROFORMYLATION PROCESS WITH LIQUID CATALYST RECYCLE INVOLVING A HYDROFORMYLATION STEP AND ONE OR MORE STAGES OF PHASE SEPARATION TO RECOVER A HIGH MOLECULAR WEIGHT ALDEHYDE PRODUCT WITH EFFICIENT RECOVERY OF RHODIUM CATALYST. THE PROCESS INCLUDES A HYDROFORMYLATION STEP TO PREPARE A NON-AQUEOUS HYDROFORMYLATION REACTION PRODUCT COMPOSITION COMPRISING ONE OR MORE ALDEHYDE PRODUCTS, ONE OR MORE CONJUGATED POLYOLEFINS, A RHODIUM-ORGANOPHOSPHORUS LIGAND COMPLEX, FREE ORGANOPHOSPHORUS LIGAND, AND AN ORGANIC SOLUBILIZING AGENT FOR SAID COMPLEX AND SAID FREE LIGAND, AND THEREAFTER ONE ORE MORE STAGES OF PHASE SEPARATION USING ADDED WATER UNDER A CARBON MONOXIDE GAS, HYDROGEN GAS, OR A MIXTURE THEREOF. THE PROCESS REQUIRES A SPECIFIC RANGE OF TOTAL PRESSURE FOR THE HYDROFORMYLATION, A SPECIFIC RANGE OF TOTAL PRESSURE FOR AT LEAST ONE OF THE SEPARATION STAGES, AND A MINIMUM SUM OF THE TOTAL PRESSURE OF THE HYDROFORMYLATION STEP AND THE TOTAL PRESSURE OF THE SEPARATION STAGE CONTAINING SAID GAS.
MYPI20084582A 2006-05-15 2007-04-17 Hydroformylation process and product separation with improved recovery of rhodium MY147009A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US80055506P 2006-05-15 2006-05-15

Publications (1)

Publication Number Publication Date
MY147009A true MY147009A (en) 2012-10-15

Family

ID=38453227

Family Applications (1)

Application Number Title Priority Date Filing Date
MYPI20084582A MY147009A (en) 2006-05-15 2007-04-17 Hydroformylation process and product separation with improved recovery of rhodium

Country Status (8)

Country Link
US (1) US7663002B2 (en)
EP (1) EP2021312B1 (en)
CN (1) CN101443302B (en)
AR (1) AR060911A1 (en)
BR (1) BRPI0710853A2 (en)
CA (1) CA2652016C (en)
MY (1) MY147009A (en)
WO (1) WO2007133379A1 (en)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7351868B2 (en) 2003-07-03 2008-04-01 Union Carbide Chemicals & Plastics Technology Corporation Minimization of ligand degradation products, of reversion of same to useful phosphine ligands
AR058048A1 (en) 2005-09-15 2008-01-23 Dow Global Technologies Inc PROCEDURE FOR MONOSULFONATION OF AROMATIC PHOSPHINES AND ZWITTERIONIC PRODUCT DERIVED FROM THE SAME
EP2054130B1 (en) 2006-08-17 2012-10-17 Dow Global Technologies LLC Liquid-liquid extraction
CN101778812B (en) * 2007-06-13 2015-02-18 陶氏环球技术有限责任公司 Extraction process for aldehyde product separation and catalyst recovery
MY149004A (en) * 2007-07-06 2013-06-28 Dow Global Technologies Inc Purification of hydroformylated and hydrogenated fatty alkyl ester compositions
EP2231683B1 (en) * 2008-01-15 2016-03-23 Dow Global Technologies LLC Sulfonated organophosphine compounds and use thereof in hydroformylation processes
EP2231682B1 (en) * 2008-01-15 2016-01-06 Dow Global Technologies LLC Sulfonated organophosphine compounds and use thereof in hydroformylation processes
CN102741210B (en) * 2009-12-22 2016-02-24 陶氏技术投资有限责任公司 Controlling the Normal:Isomer Aldehyde Ratio in a Mixed Ligand Hydroformylation Process
JP7269238B2 (en) * 2017-11-13 2023-05-08 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー Process for recovering rhodium from hydroformylation processes
TWI793216B (en) * 2017-12-07 2023-02-21 美商陶氏科技投資公司 Hydroformylation process
EP4223737A1 (en) * 2022-02-08 2023-08-09 Evonik Operations GmbH Optimized thermal separation by prior gas exchange
CN115646377A (en) * 2022-11-16 2023-01-31 陕西延长石油（集团）有限责任公司 Reaction system and method for continuously producing alpha-alkyl ester
CN119591482B (en) * 2024-11-19 2026-01-23 成都欣华源科技有限责任公司 Continuous circulation process and system for hydroformylation of high-carbon olefin

Family Cites Families (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3235030A1 (en) 1982-09-22 1984-03-22 Ruhrchemie Ag, 4200 Oberhausen METHOD FOR PRODUCING SULFONATED ARYLPHOSPHINES
US4633021A (en) * 1985-11-29 1986-12-30 National Distillers And Chemical Corporation Olefin hydroformylation
US4731486A (en) 1986-11-18 1988-03-15 Union Carbide Corporation Hydroformylation using low volatile phosphine ligands
US5294415A (en) * 1988-06-30 1994-03-15 Hoechst Aktiengesellschaft Process for the separation and recovery of rhodium from the products of the oxo synthesis
EP0350922B1 (en) * 1988-07-14 1994-09-21 UNION CARBIDE CHEMICALS AND PLASTICS COMPANY INC. (a New York corporation) Process for catalyst-aldehyde product separation
US5180854A (en) * 1988-07-14 1993-01-19 Union Carbide Chemicals & Plastics Technology Corporation Process for catalyst aldehyde product separation
KR950000633B1 (en) 1988-07-14 1995-01-26 유니온 카바이드 케미칼즈 앤드 플라스틱스 캄파니 인코포레이티드 Process for producing alcohols and aldehydes
US4935550A (en) * 1988-08-12 1990-06-19 Union Carbide Chemicals And Plastics Company Inc. Catalytic metal recovery from non-polar organic solutions
US5138101A (en) * 1991-07-19 1992-08-11 Eastman Kodak Company Recovery of high-boiling aldehydes from rhodium-catalyzed hydroformylation processes
DE4135049A1 (en) * 1991-10-24 1993-05-06 Hoechst Ag, 6230 Frankfurt, De METHOD FOR THE RECOVERY OF RHODIUM FROM THE REACTION PRODUCTS OF THE OXOSYNTHESIS
DE4408950A1 (en) * 1994-03-16 1995-09-21 Basf Ag Process for the preparation of alcohols and / or aldehydes
DE4427428A1 (en) 1994-08-03 1996-02-29 Basf Ag Process for the preparation of aldehydes
US5648554A (en) * 1995-04-12 1997-07-15 Mitsubishi Chemical Corporation Method for producing aldehydes
BR9503081A (en) 1995-06-29 1996-08-06 Craveiro Afranio Aragao Process of obtaining methyl esters and glycerin at room temperature from triglycerides
DE19532393A1 (en) * 1995-09-02 1997-03-06 Hoechst Ag Process for the hydroformylation of olefinically unsaturated compounds
US5932772A (en) * 1998-02-02 1999-08-03 Union Carbide Chemicals & Plastics Technology Corporation Separation processes
DE19908978B4 (en) 1999-03-02 2005-12-29 L.U.T. Labor- Und Umwelttechnik Jena Gmbh Process for the preparation of fatty acid methyl esters from triglycerides and fatty acids
ES2252040T3 (en) 1999-08-18 2006-05-16 Biox Corporation SIMPLE PHASE PROCESS FOR THE PRODUCTION OF METHYL ESTERS OF FATTY ACIDS FROM TRIGLICERID BLENDS AND FATTY ACIDS.
DE10005084C1 (en) * 2000-02-04 2001-09-13 Celanese Chem Europe Gmbh Process for the recovery of rhodium from reaction products of oxosynthesis
US6469169B1 (en) * 2001-03-20 2002-10-22 Council Of Scientific And Industrial Research Water soluble palladium complexes and process for the preparation thereof
DE10160368B4 (en) * 2001-12-08 2004-04-08 Celanese Chemicals Europe Gmbh Process for the preparation of aldehydes
DE60304034T2 (en) * 2002-03-11 2006-10-12 Union Carbide Chemicals & Plastics Technology Corp., Danbury BISPHOSPHITE LIGANDS FOR CARBONYLATION PROCESSES
WO2004035595A1 (en) * 2002-10-15 2004-04-29 Union Carbide Chemicals & Plastics Technology Corporation Bis-chelating ligand and use thereof in carbonylation processes
WO2004096744A2 (en) * 2003-04-25 2004-11-11 Dow Global Technolgies Inc. Aldehyde and alcohol compositions derived from seed oils
JP2006524744A (en) 2003-04-25 2006-11-02 ダウ グローバル テクノロジーズ インコーポレイティド Vegetable oil-based polyol and polyurethane produced therefrom
US7351868B2 (en) * 2003-07-03 2008-04-01 Union Carbide Chemicals & Plastics Technology Corporation Minimization of ligand degradation products, of reversion of same to useful phosphine ligands
WO2006020287A1 (en) * 2004-08-02 2006-02-23 Union Carbide Chemicals & Plastics Technology Corporation Stabilization of a hydroformylation process
US7799055B2 (en) 2006-07-07 2010-09-21 Warsaw Orthopedic, Inc. Minimal spacing spinal stabilization device and method
WO2008024468A2 (en) 2006-08-24 2008-02-28 Eklin Medical Systems, Inc. Computerized medical information system
WO2008056993A2 (en) 2006-11-06 2008-05-15 Fisher & Paykel Healthcare Limited Integrated humidifier chamber & lid
MY146479A (en) 2006-12-11 2012-08-15 Dow Global Technologies Inc Aldehyde and alcohol compositions derived from seed oils

Also Published As

Publication number Publication date
US20090118548A1 (en) 2009-05-07
WO2007133379A1 (en) 2007-11-22
EP2021312B1 (en) 2014-10-15
US7663002B2 (en) 2010-02-16
CN101443302A (en) 2009-05-27
AR060911A1 (en) 2008-07-23
CN101443302B (en) 2013-04-10
EP2021312A1 (en) 2009-02-11
BRPI0710853A2 (en) 2011-05-17
CA2652016A1 (en) 2007-11-22
CA2652016C (en) 2015-02-03

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