MY147009A - Hydroformylation process and product separation with improved recovery of rhodium - Google Patents

Hydroformylation process and product separation with improved recovery of rhodium

Info

Publication number
MY147009A
MY147009A MYPI20084582A MYPI20084582A MY147009A MY 147009 A MY147009 A MY 147009A MY PI20084582 A MYPI20084582 A MY PI20084582A MY PI20084582 A MYPI20084582 A MY PI20084582A MY 147009 A MY147009 A MY 147009A
Authority
MY
Malaysia
Prior art keywords
hydroformylation
total pressure
rhodium
stages
separation
Prior art date
Application number
MYPI20084582A
Inventor
Peng Jun Wei
Kurt D Olson
Donald L Morrison
Brian M Roesch
Donald L Bunning
Jeffrey G Hippler
Vincent J Stricker
Original Assignee
Dow Global Technologies Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Inc filed Critical Dow Global Technologies Inc
Publication of MY147009A publication Critical patent/MY147009A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C07C45/80—Separation; Purification; Stabilisation; Use of additives by liquid-liquid treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • C07C67/343—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C67/347—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by addition to unsaturated carbon-to-carbon bonds
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

A NON-AQUEOUS HYDROFORMYLATION PROCESS WITH LIQUID CATALYST RECYCLE INVOLVING A HYDROFORMYLATION STEP AND ONE OR MORE STAGES OF PHASE SEPARATION TO RECOVER A HIGH MOLECULAR WEIGHT ALDEHYDE PRODUCT WITH EFFICIENT RECOVERY OF RHODIUM CATALYST. THE PROCESS INCLUDES A HYDROFORMYLATION STEP TO PREPARE A NON-AQUEOUS HYDROFORMYLATION REACTION PRODUCT COMPOSITION COMPRISING ONE OR MORE ALDEHYDE PRODUCTS, ONE OR MORE CONJUGATED POLYOLEFINS, A RHODIUM-ORGANOPHOSPHORUS LIGAND COMPLEX, FREE ORGANOPHOSPHORUS LIGAND, AND AN ORGANIC SOLUBILIZING AGENT FOR SAID COMPLEX AND SAID FREE LIGAND, AND THEREAFTER ONE ORE MORE STAGES OF PHASE SEPARATION USING ADDED WATER UNDER A CARBON MONOXIDE GAS, HYDROGEN GAS, OR A MIXTURE THEREOF. THE PROCESS REQUIRES A SPECIFIC RANGE OF TOTAL PRESSURE FOR THE HYDROFORMYLATION, A SPECIFIC RANGE OF TOTAL PRESSURE FOR AT LEAST ONE OF THE SEPARATION STAGES, AND A MINIMUM SUM OF THE TOTAL PRESSURE OF THE HYDROFORMYLATION STEP AND THE TOTAL PRESSURE OF THE SEPARATION STAGE CONTAINING SAID GAS.
MYPI20084582A 2006-05-15 2007-04-17 Hydroformylation process and product separation with improved recovery of rhodium MY147009A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US80055506P 2006-05-15 2006-05-15

Publications (1)

Publication Number Publication Date
MY147009A true MY147009A (en) 2012-10-15

Family

ID=38453227

Family Applications (1)

Application Number Title Priority Date Filing Date
MYPI20084582A MY147009A (en) 2006-05-15 2007-04-17 Hydroformylation process and product separation with improved recovery of rhodium

Country Status (8)

Country Link
US (1) US7663002B2 (en)
EP (1) EP2021312B1 (en)
CN (1) CN101443302B (en)
AR (1) AR060911A1 (en)
BR (1) BRPI0710853A2 (en)
CA (1) CA2652016C (en)
MY (1) MY147009A (en)
WO (1) WO2007133379A1 (en)

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BRPI0714266A2 (en) 2006-08-17 2013-04-24 Dow Global Technologies Inc Method for Liquid / Liquid Separation and Method for Using a Swing Plate Extraction Column for Liquid / Liquid Separation
EP2167454A2 (en) 2007-06-13 2010-03-31 Dow Global Technologies Inc. Extraction process for aldehyde product separation and catalyst recovery
CA2692591A1 (en) * 2007-07-06 2009-01-15 Dow Global Technologies Inc. Purification of hydroformylated and hydrogenated fatty alkyl ester compositions
WO2009091670A1 (en) * 2008-01-15 2009-07-23 Dow Global Technologies Inc. Sulfonated organophosphine compounds and use thereof in hydroformylation processes
BRPI0905699A2 (en) * 2008-01-15 2015-07-14 Dow Global Technologies Inc Complex catalyst composition, complex catalyst or precursor composition, complex catalyst solution or complex catalyst precursor solution and hydroformylation process
EP2942343B1 (en) 2009-12-22 2019-09-04 Dow Technology Investments LLC Controlling the normal : iso aldehyde ratio in a mixed ligand hydroformylation process
EP3710161B1 (en) * 2017-11-13 2024-10-16 Dow Technology Investments LLC Processes for recovery of rhodium from a hydroformylation process
TWI793216B (en) * 2017-12-07 2023-02-21 美商陶氏科技投資公司 Hydroformylation process
EP4223737A1 (en) 2022-02-08 2023-08-09 Evonik Operations GmbH Optimized thermal separation by prior gas exchange
CN115646377A (en) * 2022-11-16 2023-01-31 陕西延长石油（集团）有限责任公司 Reaction system and method for continuously producing alpha-alkyl ester
CN119591482B (en) * 2024-11-19 2026-01-23 成都欣华源科技有限责任公司 Continuous circulation process and system for hydroformylation of high-carbon olefin

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Also Published As

Publication number Publication date
US7663002B2 (en) 2010-02-16
CN101443302B (en) 2013-04-10
CA2652016A1 (en) 2007-11-22
WO2007133379A1 (en) 2007-11-22
EP2021312A1 (en) 2009-02-11
US20090118548A1 (en) 2009-05-07
CA2652016C (en) 2015-02-03
BRPI0710853A2 (en) 2011-05-17
AR060911A1 (en) 2008-07-23
EP2021312B1 (en) 2014-10-15
CN101443302A (en) 2009-05-27

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