MY169045A - Adhesive composition, and laminate and method for manufacturing the same - Google Patents

Adhesive composition, and laminate and method for manufacturing the same

Info

Publication number
MY169045A
MY169045A MYPI2015001798A MYPI2015001798A MY169045A MY 169045 A MY169045 A MY 169045A MY PI2015001798 A MYPI2015001798 A MY PI2015001798A MY PI2015001798 A MYPI2015001798 A MY PI2015001798A MY 169045 A MY169045 A MY 169045A
Authority
MY
Malaysia
Prior art keywords
adhesive composition
polyol
molecular weight
component
average molecular
Prior art date
Application number
MYPI2015001798A
Inventor
Yuki Usa
Yusei Uchiyama
Yoshihiro Sato
Original Assignee
Toyo Ink Sc Holdings Co Ltd
Toyo Morton Ltd
Toyochem Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toyo Ink Sc Holdings Co Ltd, Toyo Morton Ltd, Toyochem Co Ltd filed Critical Toyo Ink Sc Holdings Co Ltd
Publication of MY169045A publication Critical patent/MY169045A/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04Polyurethanes
    • C09J175/08Polyurethanes from polyethers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/04Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/48Polyethers
    • C08G18/4825Polyethers containing two hydroxy groups
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2405/00Adhesive articles, e.g. adhesive tapes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2439/00Containers; Receptacles
    • B32B2439/70Food packaging
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2439/00Containers; Receptacles
    • B32B2439/80Medical packaging
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08Processes
    • C08G18/10Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30Low-molecular-weight compounds
    • C08G18/32Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3203Polyhydroxy compounds
    • C08G18/3206Polyhydroxy compounds aliphatic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/42Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4205Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups
    • C08G18/4208Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups
    • C08G18/4211Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups derived from aromatic dicarboxylic acids and dialcohols
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6666Compounds of group C08G18/48 or C08G18/52
    • C08G18/667Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/6674Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
    • C08G18/6677Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203 having at least three hydroxy groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/74Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/75Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
    • C08G18/751Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring
    • C08G18/752Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group
    • C08G18/753Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group
    • C08G18/755Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group and at least one isocyanate or isothiocyanate group linked to a secondary carbon atom of the cycloaliphatic ring, e.g. isophorone diisocyanate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/74Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • C08G18/7664Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
    • C08G18/7671Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups containing only one alkylene bisphenyl group
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04Polyurethanes
    • C09J175/06Polyurethanes from polyesters

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Laminated Bodies (AREA)
  • Wrappers (AREA)

Abstract

An adhesive composition that can exhibit equivalent or superior bonding performance with shorter-duration aging than before even when the environmental humidity is not tightly controlled to low humidity and that has a long pot life is provided. The adhesive composition according to the present invention includes a polyisocyanate component (A) and a polyol component (B); the polyisocyanate component (A) is a reaction product obtained by reacting 2,4'-diphenylmethane diisocyanate (a1) and 4,4'- diphenylmethane diisocyanate (a2) with a polyol essentially containing a polyether polyol (a3) under a condition of excessive isocyanate groups; and the polyol component (B) essentially contains a polyester diol (b1) with a number-average molecular weight of 500 or more and 3,000 or less and further contains at least either a diol (b2) or a triol (b3) with a number-average molecular weight of 50 or more and less than 500.
MYPI2015001798A 2013-01-22 2014-01-17 Adhesive composition, and laminate and method for manufacturing the same MY169045A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2013009142 2013-01-22
JP2013247979A JP5472525B1 (en) 2013-01-22 2013-11-29 Adhesive composition, laminate and method for producing the same

Publications (1)

Publication Number Publication Date
MY169045A true MY169045A (en) 2019-02-08

Family

ID=50749787

Family Applications (1)

Application Number Title Priority Date Filing Date
MYPI2015001798A MY169045A (en) 2013-01-22 2014-01-17 Adhesive composition, and laminate and method for manufacturing the same

Country Status (6)

Country Link
JP (1) JP5472525B1 (en)
CN (1) CN104955913B (en)
MY (1) MY169045A (en)
PH (1) PH12015501618A1 (en)
TW (1) TWI600737B (en)
WO (1) WO2014115521A1 (en)

Families Citing this family (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6361494B2 (en) * 2014-12-19 2018-07-25 東洋インキScホールディングス株式会社 Adhesive composition, laminate, and method for producing laminate
JP5812219B1 (en) * 2015-04-17 2015-11-11 東洋インキScホールディングス株式会社 Adhesive composition and laminate using the same
JP5975189B1 (en) * 2016-02-01 2016-08-23 東洋インキScホールディングス株式会社 Laminated body and manufacturing method thereof
JP6090522B1 (en) * 2016-03-29 2017-03-08 東洋インキScホールディングス株式会社 Laminated body and manufacturing method thereof
JP6747900B2 (en) * 2016-07-26 2020-08-26 Dicグラフィックス株式会社 High solid adhesive composition
JP6664845B2 (en) * 2016-08-09 2020-03-13 東洋インキScホールディングス株式会社 Laminate and manufacturing method thereof
JP6664846B2 (en) * 2016-08-19 2020-03-13 東洋インキScホールディングス株式会社 Laminate and manufacturing method thereof
WO2018101372A1 (en) * 2016-11-30 2018-06-07 日東電工株式会社 Adhesive composition, adhesive layer, and adhesive sheet
CN110088222B (en) * 2016-11-30 2021-11-23 日东电工株式会社 Adhesive composition, adhesive layer and adhesive sheet
JP6323580B1 (en) * 2017-02-14 2018-05-16 東洋インキScホールディングス株式会社 Adhesive and adhesive sheet
JP6911445B2 (en) * 2017-03-27 2021-07-28 東洋インキScホールディングス株式会社 Laminated body and its manufacturing method
JP6620963B2 (en) * 2017-12-13 2019-12-18 Dic株式会社 Reactive adhesive, laminated film and packaging
JP2020026105A (en) * 2018-08-14 2020-02-20 凸版印刷株式会社 Gas barrier laminate
US11072725B2 (en) 2018-12-19 2021-07-27 Crosslink Technology, Inc. Polyurethane compositions for coating
JP2021098825A (en) * 2019-12-23 2021-07-01 東洋インキScホールディングス株式会社 Solvent-free adhesive and laminate
JP7207617B1 (en) * 2021-04-13 2023-01-18 Dic株式会社 Two-component curable adhesive composition, anchor coating agent, adhesive, laminate, packaging material
JP7306597B1 (en) 2021-08-31 2023-07-11 Dic株式会社 Adhesive, laminate, method for producing laminate, packaging material
JP2023148008A (en) * 2022-03-30 2023-10-13 東洋インキScホールディングス株式会社 Solvent-free adhesives, laminates and packaging
JP7552962B1 (en) * 2022-12-21 2024-09-18 東ソー株式会社 Coating film, molded body, and coating agent containing polyurethane resin
JPWO2024225056A1 (en) 2023-04-27 2024-10-31
EP4725973A1 (en) 2023-06-08 2026-04-15 DIC Corporation Polyisocyanate composition, two-part curable composition, two-part curable adhesive, laminate, and packaging material
WO2025009458A1 (en) 2023-07-04 2025-01-09 Dic株式会社 Polyisocyanate composition, two-component curable composition, two-component curable coating agent, two-component curable adhesive, laminate, and packaging material
JPWO2025009399A1 (en) 2023-07-04 2025-01-09
JP7640005B1 (en) 2023-07-20 2025-03-05 Dic株式会社 Polyisocyanate compositions, two-component curing compositions, two-component curing coating agents, two-component curing adhesives, laminates, packaging materials
JP7832606B2 (en) 2023-07-20 2026-03-18 Dic株式会社 Polyisocyanate compositions, two-component curable compositions, two-component curable coatings, two-component curable adhesives, laminates, packaging materials

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63196678A (en) * 1987-02-09 1988-08-15 Dainippon Ink & Chem Inc Adhesive composition for laminating films
JP2619434B2 (en) * 1987-11-18 1997-06-11 サンスター技研株式会社 Thixotropic stable one-pack moisture-curable polyurethane resin composition
US6136136A (en) * 1992-11-25 2000-10-24 Henkel Corporation Moisture-curable polyurethane hotmelt adhesives with high green strength
MX9605802A (en) * 1994-05-25 1997-12-31 Henkel Kgaa Humidity-setting polyurethane hot-melt-type glue.
JPH10102031A (en) * 1996-09-30 1998-04-21 Dainippon Ink & Chem Inc Production of polyurethane resin for adhesive
US6884904B2 (en) * 2001-04-12 2005-04-26 Air Products And Chemicals, Inc. MDI-based polyurethane prepolymer with low monomeric MDI content
JP4074910B2 (en) * 2001-10-26 2008-04-16 大日本インキ化学工業株式会社 Floor construction method
US20030206775A1 (en) * 2002-05-03 2003-11-06 Markusch Peter H. Polyurethane/geotextile composite liner for canals and ditches based on liquefied monomeric MDI-derivatives
US6706776B2 (en) * 2002-06-18 2004-03-16 Bayer Corporation Syntactic foams with improved water resistance, long pot life and short demolding times
JP5604407B2 (en) * 2010-12-21 2014-10-08 ローム アンド ハース カンパニー Adhesive composition

Also Published As

Publication number Publication date
CN104955913A (en) 2015-09-30
TWI600737B (en) 2017-10-01
CN104955913B (en) 2017-05-17
WO2014115521A1 (en) 2014-07-31
PH12015501618B1 (en) 2015-09-28
JP5472525B1 (en) 2014-04-16
TW201430086A (en) 2014-08-01
JP2014159548A (en) 2014-09-04
PH12015501618A1 (en) 2015-09-28

Similar Documents

Publication Publication Date Title
MY169045A (en) Adhesive composition, and laminate and method for manufacturing the same
WO2014153046A3 (en) Polyurethanes, articles and coatings prepared therefrom and methods of making the same
WO2014186111A3 (en) Thermoplastic polyurethane from low free monomer prepolymer
MY167922A (en) Moisture-curable polyurethane hot-melt resin composition, adhesive, and article
MY167391A (en) Polyurethane resin composition for electrical insulation
MX2018007949A (en) One-part polyurethane adhesive composition, method of making a laminate, and laminate.
IN2015MN00432A (en)
WO2013037767A3 (en) Aqueous polyurethane dispersion for waterproof breathable coatings
MX2013012860A (en) Reactive roofing adhesive.
WO2010081127A3 (en) Adhesives and binders for electro-optic displays
RU2013132559A (en) LAYERS AND MEMBRANES BASED ON MDI FROM FORPOLIMERS CHARACTERIZED BY A VERY LOW LEVEL OF CONTENT OF FREE MONOMERIC ISOCIANATES
BR112017019210A2 (en) ultra-low monomer polyurethanes
WO2012097928A3 (en) Two-component polyurethane composition with delayed crosslinking
MX2015017969A (en) Hydrophobic polyurethane adhesive.
MX389257B (en) MOISTURE-CURING POLYURETHANE COMPOSITION COMPRISING SUSTAINABLY PRODUCED RAW MATERIALS.
AR051601A1 (en) WATERPROOF POLYURETHANE DISPERSIONS PREPARED FROM POLYESTER POLYOLES CONTAINING HYDROXIMETHYLS DERIVED FROM FATTY ACIDS
AR108882A1 (en) SOLVENT-BASED ADHESIVE COMPOSITIONS WITH A HIGH CONTENT OF SOLIDS AND METHODS TO MANUFACTURE THE SAME
WO2013072380A3 (en) Improved polyurethane foam composition
MX2017005020A (en) HYDROPHYL PREPOLIMERO FOR POLYURETHANE FOAMS.
BRPI1106997A2 (en) adhesive composition, method for bonding two or more substrates, and bonded assembly
MY163276A (en) Adhesive agent composition and laminated body
PH12020551156A1 (en) Two-component curable solventless adhesive and laminate film
WO2013029887A3 (en) Polyurethane systems having non-sag and paintability
MY186801A (en) Polyurethane elastomeric composition and method of preparing the same
MX2021005789A (en) Solventless adhesive composition and process for making and use in forming a laminate.