MY179699A - Method for preparing glycol ester using reactive distillation - Google Patents

Method for preparing glycol ester using reactive distillation

Info

Publication number
MY179699A
MY179699A MYPI2016000302A MYPI2016000302A MY179699A MY 179699 A MY179699 A MY 179699A MY PI2016000302 A MYPI2016000302 A MY PI2016000302A MY PI2016000302 A MYPI2016000302 A MY PI2016000302A MY 179699 A MY179699 A MY 179699A
Authority
MY
Malaysia
Prior art keywords
glycol ester
preparing
reactive distillation
carboxylic acid
glycol
Prior art date
Application number
MYPI2016000302A
Inventor
Min Gyoo Park
Dong Wook Kim
Jin Su Ham
Seol A Kim
Jeong Eop Choi
Suk Joon Kim
Hyun Chul Choi
Ki Nam Chung
Byung Pyo Park
Jae Ho Lee
Original Assignee
Sk Mat Performance Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sk Mat Performance Co Ltd filed Critical Sk Mat Performance Co Ltd
Publication of MY179699A publication Critical patent/MY179699A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/48—Separation; Purification; Stabilisation; Use of additives
    • C07C67/52—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
    • C07C67/54—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/009—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping in combination with chemical reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/14—Fractional distillation or use of a fractionation or rectification column
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/245—Stationary reactors without moving elements inside placed in series
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/66—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety
    • C07C69/67—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of saturated acids
    • C07C69/708—Ethers
    • C07C69/712—Ethers the hydroxy group of the ester being etherified with a hydroxy compound having the hydroxy group bound to a carbon atom of a six-membered aromatic ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002—Chemical plants
    • B01J2219/00027—Process aspects
    • B01J2219/0004—Processes in series
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00274—Sequential or parallel reactions; Apparatus and devices for combinatorial chemistry or for making arrays; Chemical library technology
    • B01J2219/00718—Type of compounds synthesised
    • B01J2219/0072—Organic compounds
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Provided is a method for preparing a glycol ester capable of increasing a conversion rate of a glycol ether under low temperature and pressure conditions, minimizing a reflux amount using a reactive distillation column, and decreasing a production amount of impurities, in preparing the glycol ester using the glycol ether and a carboxylic acid. In addition, provided is a method for preparing a glycol ester for electronics capable of decreasing a loss of the glycol ester toward an upper portion of a reactive distillation column by injecting an excess amount of a carboxylic acid as compared to a molar number of a glycol ether and easily separating the glycol ester and the carboxylic acid from each other under a pressurized condition, and simplifying a subsequent separation column process without a separate azeotropic distillation apparatus. Figure 1
MYPI2016000302A 2013-08-20 2014-07-29 Method for preparing glycol ester using reactive distillation MY179699A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR1020130098551A KR101349106B1 (en) 2013-08-20 2013-08-20 Method for preparing glycol ester using reactive distillation
PCT/KR2014/006912 WO2015026073A1 (en) 2013-08-20 2014-07-29 Method for preparing glycol ester using reactive distillation

Publications (1)

Publication Number Publication Date
MY179699A true MY179699A (en) 2020-11-11

Family

ID=50144953

Family Applications (1)

Application Number Title Priority Date Filing Date
MYPI2016000302A MY179699A (en) 2013-08-20 2014-07-29 Method for preparing glycol ester using reactive distillation

Country Status (5)

Country Link
KR (1) KR101349106B1 (en)
CN (1) CN104640836B (en)
MY (1) MY179699A (en)
TW (1) TWI579266B (en)
WO (1) WO2015026073A1 (en)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105693514B (en) * 2016-03-18 2018-05-15 江苏雷蒙化工科技有限公司 The continuous production system and its production method of a kind of low-carbon carboxylate of polyalcohol
CN109456190A (en) * 2018-10-18 2019-03-12 天津大学 A kind of method of the continuous synthesizing propylene glycol monomethyl ether acetate of the highly selective catalytic distillation of low temperature
CN110305012A (en) * 2019-08-16 2019-10-08 南通百川新材料有限公司 Synthesis process of semiconductor-grade propylene glycol methyl ether acetate
CN110423197B (en) * 2019-09-17 2023-11-14 凯瑞环保科技股份有限公司 Device and method for producing ethylene glycol diacetate by using low-concentration ethylene glycol
WO2021126140A1 (en) * 2019-12-16 2021-06-24 Eastman Chemical Company Esterification of acetic acid recovered from wood acetylation with ether-alcohols
WO2021172898A1 (en) * 2020-02-26 2021-09-02 영남대학교 산학협력단 Apparatus and method for manufacturing propylene glycol methyl ether acetate
WO2021214144A1 (en) * 2020-04-22 2021-10-28 Dsm Ip Assets B.V. Process for the preparation of alpha,omega-alkanediol mononitrate
CN112194580B (en) * 2020-11-04 2021-09-14 中建安装集团有限公司 Device and process for producing propylene glycol monomethyl ether acetate by reactive distillation coupled pervaporation
KR102399263B1 (en) * 2021-08-09 2022-05-17 에스케이머티리얼즈퍼포먼스 주식회사 Process for the preparation of propylene glycol monomethyl ether acetate
KR102498772B1 (en) * 2021-11-29 2023-02-10 주식회사 켐트로닉스 Manufacturing method of ultra-high purity PGMEA
CN115745797A (en) * 2022-12-03 2023-03-07 福州大学 Process for synthesizing propylene glycol monomethyl ether acetate and byproduct 1, 2-diacetoxy propane through continuous reaction, rectification and esterification
WO2025143078A1 (en) * 2023-12-27 2025-07-03 Ｋｈネオケム株式会社 Propylene glycol monomethyl ether acetate composition
CN120569362B (en) * 2023-12-27 2026-02-03 Kh新化株式会社 Propylene glycol monomethyl ether acetate composition

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2466448A1 (en) 1979-10-01 1981-04-10 Propylox Sa PROCESS FOR THE RECOVERY OF CARBOXYLIC ACIDS FROM MIXTURES CONTAINING ESTERS OF GLYCOLS DERIVED FROM THESE ACIDS
US5202463A (en) 1991-09-10 1993-04-13 Arco Chemical Technology, L.P. Process for the preparation of a glycol ether ester
FR2757156B1 (en) * 1996-12-17 1999-01-22 Bp Chemicals Snc CONTINUOUS MANUFACTURING PROCESS OF ESTERS
KR100286571B1 (en) * 1999-03-11 2001-03-15 남창우 Method for preparing glycol ester using reactive distillation
JP3763076B2 (en) * 2002-12-03 2006-04-05 株式会社日本触媒 Method for producing α-hydroxycarboxylic acid ester
US7122698B2 (en) * 2002-10-09 2006-10-17 Nippon Shokubai Co., Ltd. Method for producing α-hydroxycarboxylate
KR100779521B1 (en) 2005-07-15 2007-11-28 주식회사 엘지화학 Combined method of carboxylic acid and ester compound

Also Published As

Publication number Publication date
CN104640836B (en) 2016-11-23
TWI579266B (en) 2017-04-21
KR101349106B1 (en) 2014-01-08
CN104640836A (en) 2015-05-20
TW201507997A (en) 2015-03-01
WO2015026073A1 (en) 2015-02-26

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