MY189261A - A metal modified y zeolite, its preparation and use - Google Patents

A metal modified y zeolite, its preparation and use

Info

Publication number
MY189261A
MY189261A MYPI2014003000A MYPI2014003000A MY189261A MY 189261 A MY189261 A MY 189261A MY PI2014003000 A MYPI2014003000 A MY PI2014003000A MY PI2014003000 A MYPI2014003000 A MY PI2014003000A MY 189261 A MY189261 A MY 189261A
Authority
MY
Malaysia
Prior art keywords
zeolite
preparation
metal modified
group metal
ivb group
Prior art date
Application number
MYPI2014003000A
Inventor
Jun Long
Huiping Tian
Shanqing Yu
Zhenbo Wang
Original Assignee
China Petroleum & Chem Corp
Sinopec Res Inst Petroleum
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by China Petroleum & Chem Corp, Sinopec Res Inst Petroleum filed Critical China Petroleum & Chem Corp
Publication of MY189261A publication Critical patent/MY189261A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • C10G11/04—Oxides
    • C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/085—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • B01J29/088—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/026—After-treatment
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/20—Faujasite type, e.g. type X or Y
    • C01B39/24—Type Y
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/37—Acid treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/40—Special temperature treatment, i.e. other than just for template removal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/05—Nuclear magnetic resonance [NMR]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/10—Infrared [IR]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/041—Mesoporous materials having base exchange properties, e.g. Si/Al-MCM-41
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/12—Surface area
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/16—Pore diameter

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Geology (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

The present invention relates to a metal modified Y zeolite, its preparation and use. Said zeolite contains 1-15wt% of IVB group metal as oxide and is characterized in that the ratio of the zeolite surface's IVB group metal content to the zeolite interior's IVB group metal content is not higher than 0.2; and/or the ratio of the distorted tetrahedral-coordinated framework aluminum to the tetrahedral-coordinated framework aluminum in the zeolite lattice structure is (0.1-0.8):1.
MYPI2014003000A 2013-10-22 2014-10-23 A metal modified y zeolite, its preparation and use MY189261A (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
CN201310499968 2013-10-22
CN201310499703 2013-10-22
CN201310499736 2013-10-22
CN201310501188 2013-10-22

Publications (1)

Publication Number Publication Date
MY189261A true MY189261A (en) 2022-01-31

Family

ID=52781869

Family Applications (1)

Application Number Title Priority Date Filing Date
MYPI2014003000A MY189261A (en) 2013-10-22 2014-10-23 A metal modified y zeolite, its preparation and use

Country Status (9)

Country Link
AU (1) AU2014253496B2 (en)
BR (1) BR102014026338B1 (en)
CA (1) CA2867947C (en)
FR (1) FR3012125A1 (en)
MX (1) MX356516B (en)
MY (1) MY189261A (en)
RU (1) RU2670744C9 (en)
SG (1) SG10201406881YA (en)
TW (1) TWI683699B (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110835114B (en) * 2018-08-17 2022-10-21 中国石油化工股份有限公司 Modified Y-type molecular sieve and preparation method thereof
CN110316741B (en) * 2019-05-09 2022-08-05 山东齐鲁华信高科有限公司 Preparation method of low-sodium high-silicon Y-type molecular sieve
CN112138709A (en) * 2019-06-28 2020-12-29 浙江恒澜科技有限公司 Catalyst, preparation method thereof and application of catalyst in cyclohexanone oxime gas-phase Beckmann rearrangement reaction
CN113683093A (en) * 2021-08-20 2021-11-23 中国高岭土有限公司 Preparation method of kaolin for cracking catalyst
CN118307008B (en) * 2024-04-01 2025-10-31 福州大学 Synthetic method of high-silicon ZSM-5 molecular sieve

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3671191A (en) 1970-09-16 1972-06-20 Grace W R & Co Preparation of high silica synthetic faujasite
CN1112248C (en) * 1999-12-02 2003-06-25 中国石油化工集团公司 Preparation of superstable Y-type molecular sieve
CN1111089C (en) 2000-10-26 2003-06-11 中国石油化工股份有限公司 Modified Y zeolite containing both notable metal and non-notable metal and its preparing process
ITMI20030347A1 (en) 2003-02-27 2004-08-28 Enitecnologie Spa CATALYST AND PROCESS FOR PREPARING LINEAR ALKANS.
CN100360221C (en) 2004-10-29 2008-01-09 中国石油化工股份有限公司 A kind of alumina carrier containing modified Y zeolite and its preparation method
CN100357399C (en) * 2005-03-31 2007-12-26 中国石油化工股份有限公司 Process for preparing cracking catalyst
EP1938898B1 (en) * 2005-09-12 2019-06-12 Petroleum Energy Center Catalyst composition for hydrogenation treatment of hydrocarbon and hydrogenation treatment method
CN101134576B (en) 2006-09-01 2010-09-08 中国石油大学(北京) Method for Improving Hydrothermal Stability of Y Molecular Sieve Using Skeleton Heteroatoms
RU2310509C1 (en) * 2006-09-18 2007-11-20 ООО "Компания Катахим" Method of preparing catalyst for hydrocracking of petroleum feedstock
RU2487756C1 (en) * 2009-04-29 2013-07-20 ПиКью КОРПОРЕЙШН Zeolite y
CN101898144B (en) 2009-05-27 2013-02-13 中国石油天然气股份有限公司 Catalytic cracking catalyst of Y-type molecular sieve containing skeleton heteroatom and preparation method thereof
US9221036B2 (en) * 2010-08-02 2015-12-29 Saudi Arabian Oil Company Hydrocracking catalyst for hydrocarbon oil, method for producing hydrocracking catalyst, and method for hydrocracking hydrocarbon oil with hydrocracking catalyst
RU2440190C1 (en) * 2010-09-24 2012-01-20 Государственное образовательное учреждение высшего профессионального образования "Уфимский государственный нефтяной технический университет" Method of producing catalyst for alkylation of paraffin hydrocarbons with olefins

Also Published As

Publication number Publication date
MX2014012902A (en) 2015-05-27
BR102014026338B1 (en) 2020-02-11
RU2670744C2 (en) 2018-10-25
TW201515702A (en) 2015-05-01
RU2014142572A3 (en) 2018-05-07
CA2867947A1 (en) 2015-04-22
RU2670744C9 (en) 2018-12-13
SG10201406881YA (en) 2015-05-28
AU2014253496A1 (en) 2015-05-07
TWI683699B (en) 2020-02-01
AU2014253496B2 (en) 2018-10-18
CA2867947C (en) 2021-11-09
BR102014026338A2 (en) 2015-09-22
FR3012125A1 (en) 2015-04-24
RU2014142572A (en) 2016-05-20
MX356516B (en) 2018-06-01

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