MY192057A - Catalyst for production of methacrylic acid, catalyst precursor for production of methacrylic acid, method for producing said catalyst and catalyst precursor, method for producing methacrylic acid, and method for producing methacrylate ester - Google Patents
Catalyst for production of methacrylic acid, catalyst precursor for production of methacrylic acid, method for producing said catalyst and catalyst precursor, method for producing methacrylic acid, and method for producing methacrylate esterInfo
- Publication number
- MY192057A MY192057A MYPI2019003714A MYPI2019003714A MY192057A MY 192057 A MY192057 A MY 192057A MY PI2019003714 A MYPI2019003714 A MY PI2019003714A MY PI2019003714 A MYPI2019003714 A MY PI2019003714A MY 192057 A MY192057 A MY 192057A
- Authority
- MY
- Malaysia
- Prior art keywords
- methacrylic acid
- catalyst
- producing
- production
- catalyst precursor
- Prior art date
Links
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 title abstract 6
- 238000004519 manufacturing process Methods 0.000 title abstract 6
- 239000003054 catalyst Substances 0.000 title abstract 4
- 239000012018 catalyst precursor Substances 0.000 title 2
- -1 methacrylate ester Chemical class 0.000 title 1
- STNJBCKSHOAVAJ-UHFFFAOYSA-N Methacrolein Chemical compound CC(=C)C=O STNJBCKSHOAVAJ-UHFFFAOYSA-N 0.000 abstract 2
- 230000003197 catalytic effect Effects 0.000 abstract 2
- 230000003647 oxidation Effects 0.000 abstract 2
- 238000007254 oxidation reaction Methods 0.000 abstract 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 abstract 1
- 229910052787 antimony Inorganic materials 0.000 abstract 1
- 229910052785 arsenic Inorganic materials 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 229910052788 barium Inorganic materials 0.000 abstract 1
- 229910052797 bismuth Inorganic materials 0.000 abstract 1
- 229910052796 boron Inorganic materials 0.000 abstract 1
- 229910052792 caesium Inorganic materials 0.000 abstract 1
- 229910052791 calcium Inorganic materials 0.000 abstract 1
- 229910052804 chromium Inorganic materials 0.000 abstract 1
- 229910001882 dioxygen Inorganic materials 0.000 abstract 1
- 229910052732 germanium Inorganic materials 0.000 abstract 1
- 229910052738 indium Inorganic materials 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 229910052746 lanthanum Inorganic materials 0.000 abstract 1
- 229910052745 lead Inorganic materials 0.000 abstract 1
- 229910052744 lithium Inorganic materials 0.000 abstract 1
- 229910052749 magnesium Inorganic materials 0.000 abstract 1
- 229910052748 manganese Inorganic materials 0.000 abstract 1
- 229910052759 nickel Inorganic materials 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 229910052763 palladium Inorganic materials 0.000 abstract 1
- 229910052700 potassium Inorganic materials 0.000 abstract 1
- 229910052701 rubidium Inorganic materials 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 229910052712 strontium Inorganic materials 0.000 abstract 1
- 229910052717 sulfur Inorganic materials 0.000 abstract 1
- 229910052715 tantalum Inorganic materials 0.000 abstract 1
- 229910052716 thallium Inorganic materials 0.000 abstract 1
- 229910052718 tin Inorganic materials 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
- 229910052726 zirconium Inorganic materials 0.000 abstract 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/24—Nitrogen compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
- B01J27/198—Vanadium
- B01J27/199—Vanadium with chromium, molybdenum, tungsten or polonium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
- C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
- C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
- C07C57/03—Monocarboxylic acids
- C07C57/04—Acrylic acid; Methacrylic acid
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
- C07C69/533—Monocarboxylic acid esters having only one carbon-to-carbon double bond
- C07C69/54—Acrylic acid esters; Methacrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B61/00—Other general methods
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Provided is a catalyst that makes it possible to produce methacrylic acid at a high selectivity by a gas-phase catalytic oxidation of methacrolein. A methacrylic acid production catalyst is used when methacrylic acid is produced by a gas-phase catalytic oxidation of methacrolein with molecular oxygen, and has a composition in the following formula: PaMObVcNbdCueAfEgGh(NH4)iOj ('A' represents at least one of Si, Ge, As and Sb, 'E' represents at least one of Bi, Zr, Te, Ag, Se, W, B, Fe, Zn, Cr, Mg, Ca, Sr, Ta, Co, Ni, Mn, Ba, Ti, Sn, Pb, In, S, Pd, Ga, Ce and La, and 'G' represents at least one of Li, Na, K, Rb, Cs and Tl. When b = 12, 0.5 ? a+ f ? 2.1, 0.01 ? c + d ? 3, 0.5 ? a, 0 ? c, 0.01 ? d ? 3, 0.005 ? e ? 3, 0 ? f, 0 ? g ? 3, 0.01 ? h ? 3 and O ? i ? 5 are satisfied, and j is a mole ratio of oxygen that satisfies valences of the components).
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2017028174 | 2017-02-17 | ||
| PCT/JP2018/001397 WO2018150797A1 (en) | 2017-02-17 | 2018-01-18 | Catalyst for production of methacrylic acid, catalyst precursor for production of methacrylic acid, method for producing said catalyst and catalyst precursor, method for producing methacrylic acid, and method for producing methacrylate ester |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MY192057A true MY192057A (en) | 2022-07-25 |
Family
ID=63170598
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MYPI2019003714A MY192057A (en) | 2017-02-17 | 2018-01-18 | Catalyst for production of methacrylic acid, catalyst precursor for production of methacrylic acid, method for producing said catalyst and catalyst precursor, method for producing methacrylic acid, and method for producing methacrylate ester |
Country Status (6)
| Country | Link |
|---|---|
| JP (1) | JP6819699B2 (en) |
| KR (1) | KR102310395B1 (en) |
| CN (1) | CN110300622B (en) |
| MY (1) | MY192057A (en) |
| SA (1) | SA519402151B1 (en) |
| WO (1) | WO2018150797A1 (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP7188707B2 (en) * | 2018-09-18 | 2022-12-13 | 三菱ケミカル株式会社 | Catalyst for producing methacrylic acid, method for producing the same, and method for producing methacrylic acid and methacrylic acid ester |
| JP7441474B2 (en) * | 2020-03-31 | 2024-03-01 | 三菱ケミカル株式会社 | Catalyst, method for producing isobutyraldehyde and methacrolein, method for producing methacrylic acid, and method for producing methacrylic acid ester |
| JP2023524594A (en) * | 2020-05-08 | 2023-06-12 | エアー カンパニー ホールディングス インコーポレイテッド | Molybdenum-based catalyst for carbon dioxide conversion |
| CN117396457A (en) * | 2021-05-25 | 2024-01-12 | 三菱化学株式会社 | Method for producing one or both of (meth)acrolein and (meth)acrylic acid |
| CN113976179B (en) * | 2021-11-04 | 2024-02-09 | 淄博市翔力致高新材料有限责任公司 | Hollow structure catalyst and preparation method and application thereof |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4252682A (en) * | 1978-12-26 | 1981-02-24 | Halcon Research And Development Corp. | Catalyst for producing methacrylic acid |
| JPH0832644B2 (en) * | 1988-04-05 | 1996-03-29 | 旭化成工業株式会社 | Method for producing methacrylic acid and / or methacrolein |
| JP3370589B2 (en) * | 1997-12-25 | 2003-01-27 | 三菱レイヨン株式会社 | Catalyst for producing methacrylic acid and method for producing methacrylic acid using the same |
| JPH11228487A (en) | 1998-02-18 | 1999-08-24 | Mitsubishi Rayon Co Ltd | Method for producing methacrylic acid |
| JP4045693B2 (en) * | 1999-04-27 | 2008-02-13 | 住友化学株式会社 | Method for producing methacrylic acid |
| JP4222721B2 (en) * | 2000-12-25 | 2009-02-12 | 三菱レイヨン株式会社 | Method for producing methacrylic acid |
| SG156608A1 (en) * | 2003-10-27 | 2009-11-26 | Mitsubishi Rayon Co | Method for producing catalyst for methacrylic acid production, catalyst for methacrylic acid production, and method for producing methacrylic acid |
| JP2006314923A (en) * | 2005-05-12 | 2006-11-24 | Nippon Kayaku Co Ltd | Manufacturing method of catalyst for producing methacrylic acid |
| JP2012102129A (en) * | 2012-01-05 | 2012-05-31 | Mitsubishi Rayon Co Ltd | Methacrylic acid purification method |
| JP5915895B2 (en) * | 2012-03-16 | 2016-05-11 | 三菱レイヨン株式会社 | Method for producing a catalyst for methacrylic acid production |
| JP5892826B2 (en) * | 2012-03-27 | 2016-03-23 | 住友化学株式会社 | Method for producing methacrylic acid |
| JP6180754B2 (en) * | 2013-02-22 | 2017-08-16 | 旭化成株式会社 | Oxide catalyst, method for producing the same, and method for producing unsaturated aldehyde |
| JP2014226614A (en) * | 2013-05-23 | 2014-12-08 | 住友化学株式会社 | Method for producing catalyst for producing methacrylic acid, and method for producing methacrylic acid |
| KR101903267B1 (en) * | 2014-07-02 | 2018-10-01 | 미쯔비시 케미컬 주식회사 | Method for producing isobutylene, method for producing methacrylic acid, and method for producing methyl methacrylate |
-
2018
- 2018-01-18 MY MYPI2019003714A patent/MY192057A/en unknown
- 2018-01-18 WO PCT/JP2018/001397 patent/WO2018150797A1/en not_active Ceased
- 2018-01-18 CN CN201880012149.8A patent/CN110300622B/en active Active
- 2018-01-18 KR KR1020197021407A patent/KR102310395B1/en active Active
- 2018-01-18 JP JP2018568053A patent/JP6819699B2/en active Active
-
2019
- 2019-06-13 SA SA519402151A patent/SA519402151B1/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CN110300622A (en) | 2019-10-01 |
| KR20190095448A (en) | 2019-08-14 |
| CN110300622B (en) | 2022-08-26 |
| KR102310395B1 (en) | 2021-10-07 |
| WO2018150797A1 (en) | 2018-08-23 |
| JPWO2018150797A1 (en) | 2019-12-26 |
| JP6819699B2 (en) | 2021-01-27 |
| SA519402151B1 (en) | 2023-02-15 |
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