NL177102C - Werkwijze voor het bereiden van synthesegas, waarbij de produktstroom wordt versneld, gedeeltelijk wordt afgebogen en wordt gekoeld. - Google Patents

Werkwijze voor het bereiden van synthesegas, waarbij de produktstroom wordt versneld, gedeeltelijk wordt afgebogen en wordt gekoeld.

Info

Publication number
NL177102C
NL177102C NLAANVRAGE7609992,A NL7609992A NL177102C NL 177102 C NL177102 C NL 177102C NL 7609992 A NL7609992 A NL 7609992A NL 177102 C NL177102 C NL 177102C
Authority
NL
Netherlands
Prior art keywords
accelerates
cools
synthesis gas
product flow
preparing synthesis
Prior art date
Application number
NLAANVRAGE7609992,A
Other languages
English (en)
Dutch (nl)
Other versions
NL7609992A (nl
NL177102B (nl
Original Assignee
Texaco Development Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Texaco Development Corp filed Critical Texaco Development Corp
Publication of NL7609992A publication Critical patent/NL7609992A/xx
Publication of NL177102B publication Critical patent/NL177102B/xx
Application granted granted Critical
Publication of NL177102C publication Critical patent/NL177102C/xx

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C10J3/466—Entrained flow processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/32—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
    • C01B3/34—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
    • C01B3/36—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using oxygen; using mixtures containing oxygen as gasifying agents
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/02—Fixed-bed gasification of lump fuel
    • C10J3/06—Continuous processes
    • C10J3/16—Continuous processes simultaneously reacting oxygen and water with the carbonaceous material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C10J3/48—Apparatus; Plants
    • C10J3/52—Ash-removing devices
    • C10J3/526—Ash-removing devices for entrained flow gasifiers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72—Other features
    • C10J3/74—Construction of shells or jackets
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72—Other features
    • C10J3/78—High-pressure apparatus
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72—Other features
    • C10J3/82—Gas withdrawal means
    • C10J3/84—Gas withdrawal means with means for removing dust or tar from the gas
    • C10J3/845—Quench rings
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72—Other features
    • C10J3/86—Other features combined with waste-heat boilers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/08—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
    • C10K1/10—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids
    • C10K1/101—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids with water only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/093—Coal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/0943—Coke
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/0946—Waste, e.g. MSW, tires, glass, tar sand, peat, paper, lignite, oil shale
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0956—Air or oxygen enriched air
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0959—Oxygen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0973—Water
    • C10J2300/0976—Water as steam
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1846—Partial oxidation, i.e. injection of air or oxygen only
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Industrial Gases (AREA)
  • Investigating Or Analysing Materials By Optical Means (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
NLAANVRAGE7609992,A 1975-10-01 1976-09-09 Werkwijze voor het bereiden van synthesegas, waarbij de produktstroom wordt versneld, gedeeltelijk wordt afgebogen en wordt gekoeld. NL177102C (nl)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US05/618,535 US3998609A (en) 1975-10-01 1975-10-01 Synthesis gas generation

Publications (3)

Publication Number Publication Date
NL7609992A NL7609992A (nl) 1977-04-05
NL177102B NL177102B (nl) 1985-03-01
NL177102C true NL177102C (nl) 1985-08-01

Family

ID=24478116

Family Applications (1)

Application Number Title Priority Date Filing Date
NLAANVRAGE7609992,A NL177102C (nl) 1975-10-01 1976-09-09 Werkwijze voor het bereiden van synthesegas, waarbij de produktstroom wordt versneld, gedeeltelijk wordt afgebogen en wordt gekoeld.

Country Status (22)

Country Link
US (1) US3998609A (fr)
JP (1) JPS5243804A (fr)
AU (1) AU499881B2 (fr)
BE (1) BE846676A (fr)
BR (1) BR7606378A (fr)
CA (1) CA1075905A (fr)
DE (1) DE2640165C2 (fr)
DK (1) DK434976A (fr)
ES (1) ES451284A1 (fr)
FR (1) FR2326465A1 (fr)
GB (1) GB1499709A (fr)
GR (1) GR61308B (fr)
IN (1) IN145255B (fr)
IT (1) IT1091951B (fr)
MX (1) MX3907E (fr)
NL (1) NL177102C (fr)
NO (1) NO150717C (fr)
PL (1) PL103562B1 (fr)
PT (1) PT65627B (fr)
SE (1) SE7610847L (fr)
YU (1) YU39974B (fr)
ZA (1) ZA765192B (fr)

Families Citing this family (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2705558B2 (de) * 1977-02-10 1980-10-23 Ruhrchemie Ag, 4200 Oberhausen Verfahren und Vorrichtung zum Vergasen von festen Brennstoffen, insbesondere Kohle durch partielle Oxidation
DD145025A3 (de) * 1978-09-28 1980-11-19 Klaus Egert Verfahren und vorrichtung zur glei hzeitigen gaskuehlung und schlackegranulierung
DD145860A3 (de) * 1978-09-28 1981-01-14 Helmut Peise Verfahren und vorrichtung zur beha dlung von druckvergasungsgasen
US4218423A (en) * 1978-11-06 1980-08-19 Texaco Inc. Quench ring and dip tube assembly for a reactor vessel
US4251228A (en) * 1979-05-30 1981-02-17 Texaco Development Corporation Production of cleaned and cooled synthesis gas
DE2933716C2 (de) * 1979-08-21 1985-06-13 Deutsche Babcock Ag, 4200 Oberhausen Mit einer Dampferzeugungsanlage versehener Gasgenerator
US4497638A (en) * 1979-10-05 1985-02-05 Stone & Webster Engineering Corp. Fuel gas generation for solids heating
US4367076A (en) * 1979-12-18 1983-01-04 Brennstoffinstitut Freiberg Method and apparatus for processing of dust-contaminated hot product gas
US4300913A (en) * 1979-12-18 1981-11-17 Brennstoffinstitut Freiberg Apparatus and method for the manufacture of product gas
US4411817A (en) * 1980-02-01 1983-10-25 Texaco Inc. Production of synthesis gas
US4343625A (en) * 1981-01-19 1982-08-10 Texaco Inc. High temperature solids gasification apparatus with slag reduction means
US4385906A (en) * 1982-02-25 1983-05-31 Texaco Development Corporation Start-up method for a gasification reactor
US4466808A (en) * 1982-04-12 1984-08-21 Texaco Development Corporation Method of cooling product gases of incomplete combustion containing ash and char which pass through a viscous, sticky phase
US4483690A (en) * 1982-06-07 1984-11-20 Texaco Development Corporation Apparatus for production of synthesis gas from heavy hydrocarbon fuels containing high metal concentrations
US4411671A (en) * 1982-06-07 1983-10-25 Texaco Development Corporation Production of synthesis gas from heavy hydrocarbon fuels containing high metal concentrations
US4411670A (en) * 1982-06-07 1983-10-25 Texaco Development Corporation Production of synthesis gas from heavy hydrocarbon fuels containing high metal concentrations
US4436530A (en) 1982-07-02 1984-03-13 Texaco Development Corporation Process for gasifying solid carbon containing materials
FR2530796A1 (fr) * 1982-07-21 1984-01-27 Creusot Loire Dispositif de conversion et de recuperation thermique
JPS5942981A (ja) * 1982-09-02 1984-03-09 Tokuzo Hirose 印字装置
US4444726A (en) * 1982-12-27 1984-04-24 Texaco Inc. Quench ring and dip tube assembly for a reactor vessel
US4494963A (en) * 1983-06-23 1985-01-22 Texaco Development Corporation Synthesis gas generation apparatus
EP0134858B1 (fr) * 1983-09-20 1986-09-17 Texaco Development Corporation Production du gaz de synthèse à partir d'hydrocarbures lourds ayant une concentration élevée en métal
US4547203A (en) * 1984-03-30 1985-10-15 Texaco Development Corporation Partial oxidation process
US4581899A (en) * 1984-07-09 1986-04-15 Texaco Inc. Synthesis gas generation with prevention of deposit formation in exit lines
CS253476B1 (en) * 1985-07-16 1987-11-12 Jaroslav Vitovec Method of phtalic anhydride vapours' continuous desublimation
US4946476A (en) * 1989-08-24 1990-08-07 Texaco Inc. Partial oxidation of bituminous coal
US5401282A (en) * 1993-06-17 1995-03-28 Texaco Inc. Partial oxidation process for producing a stream of hot purified gas
US6030493A (en) * 1994-11-04 2000-02-29 Kvaerner Pulping, Ab Process for recovering chemicals and energy from cellulose spent liquor using multiple gasifiers
US6550252B2 (en) 2000-10-12 2003-04-22 Texaco Inc. Nitrogen stripping of hydrotreater condensate
JP4827557B2 (ja) * 2006-02-28 2011-11-30 千代田化工建設株式会社 特殊形状耐火材を用いた反応器

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2813326A (en) * 1953-08-20 1957-11-19 Liebowitz Benjamin Transistors
GB769829A (en) * 1954-06-02 1957-03-13 Foster Wheeler Ltd Improvements in and relating to the production of synthesis gas
US2931715A (en) * 1956-10-24 1960-04-05 Texaco Inc Apparatus for the gasification of solid fuels
US3544291A (en) * 1968-04-22 1970-12-01 Texaco Inc Coal gasification process
US3676982A (en) * 1970-08-14 1972-07-18 Franklin Carr Price Method and apparatus for scrubbing gases
US3687646A (en) * 1970-12-21 1972-08-29 Texaco Development Corp Sewage disposal process
US3715195A (en) * 1971-06-30 1973-02-06 Texaco Inc Multihydrotorting of coal
FR2151471A5 (en) * 1971-08-30 1973-04-20 Texaco Development Corp Synthesis gas generation - by partial oxidn of hydrocarbon liquids
JPS4852067A (fr) * 1971-11-04 1973-07-21
ZA739012B (en) * 1973-05-18 1974-10-30 Otto & Co Gmbh Dr C A pressure reactor for producing a combustible gas
NL7402175A (nl) * 1974-02-18 1975-08-20 Shell Int Research Werkwijze voor de bereiding van een gas.
US3929429A (en) * 1974-09-26 1975-12-30 Texaco Inc Fuel gas from solid carbonaceous fuels

Also Published As

Publication number Publication date
US3998609A (en) 1976-12-21
AU1796876A (en) 1978-04-06
FR2326465A1 (fr) 1977-04-29
AU499881B2 (en) 1979-05-03
BE846676A (fr) 1977-03-28
CA1075905A (fr) 1980-04-22
IT1091951B (it) 1985-07-06
JPS5719044B2 (fr) 1982-04-20
ZA765192B (en) 1978-01-25
JPS5243804A (en) 1977-04-06
MX3907E (es) 1981-09-14
NO150717B (no) 1984-08-27
PT65627B (fr) 1978-04-05
BR7606378A (pt) 1977-06-21
DE2640165C2 (de) 1985-08-14
PL103562B1 (pl) 1979-06-30
NO763312L (fr) 1977-04-04
FR2326465B1 (fr) 1981-03-20
IN145255B (fr) 1978-09-16
YU238576A (en) 1982-05-31
NL7609992A (nl) 1977-04-05
GB1499709A (en) 1978-02-01
NO150717C (no) 1984-12-05
YU39974B (en) 1985-06-30
SE7610847L (sv) 1977-04-02
GR61308B (en) 1978-10-19
DE2640165A1 (de) 1977-04-14
NL177102B (nl) 1985-03-01
ES451284A1 (es) 1977-10-01
PT65627A (fr) 1976-10-01
DK434976A (da) 1977-04-02

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Legal Events

Date Code Title Description
BA A request for search or an international-type search has been filed
BB A search report has been drawn up
BC A request for examination has been filed
A85 Still pending on 85-01-01
V1 Lapsed because of non-payment of the annual fee