NL8002004A - Werkwijze voor de bereiding van alkoxy alanaten van aardalkali metalen. - Google Patents

Werkwijze voor de bereiding van alkoxy alanaten van aardalkali metalen. Download PDF

Info

Publication number: NL8002004A
Authority: NL; Netherlands
Prior art keywords: alkaline earth; reaction; earth metal; process according; preparation
Prior art date: 1979-04-04

Application number

NL8002004A

Other languages

English (en)

Dutch (nl)

Original Assignee

Anic Spa

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1979-04-04

Filing date

1980-04-03

Publication date

1980-10-07

1980-04-03 Application filed by Anic Spa filed Critical Anic Spa

1980-10-07 Publication of NL8002004A publication Critical patent/NL8002004A/nl

Links

238000000034 method Methods 0.000 title claims description 11
229910052783 alkali metal Inorganic materials 0.000 title claims description 10
150000001340 alkali metals Chemical class 0.000 title claims description 10
238000002360 preparation method Methods 0.000 title description 13
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 27
238000006243 chemical reaction Methods 0.000 claims description 22
229910052784 alkaline earth metal Inorganic materials 0.000 claims description 17
150000001342 alkaline earth metals Chemical class 0.000 claims description 16
YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 14
239000002904 solvent Substances 0.000 claims description 11
239000002879 Lewis base Substances 0.000 claims description 6
229910052782 aluminium Inorganic materials 0.000 claims description 6
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 6
150000007527 lewis bases Chemical class 0.000 claims description 6
125000003545 alkoxy group Chemical group 0.000 claims description 4
229910001615 alkaline earth metal halide Inorganic materials 0.000 claims description 3
238000000354 decomposition reaction Methods 0.000 claims description 3
125000001931 aliphatic group Chemical group 0.000 claims description 2
125000003118 aryl group Chemical group 0.000 claims description 2
150000002170 ethers Chemical class 0.000 claims description 2
229930195733 hydrocarbon Natural products 0.000 claims description 2
150000002430 hydrocarbons Chemical class 0.000 claims description 2
239000002243 precursor Substances 0.000 claims description 2
125000000075 primary alcohol group Chemical group 0.000 claims description 2
150000003333 secondary alcohols Chemical class 0.000 claims description 2
150000003509 tertiary alcohols Chemical class 0.000 claims description 2
238000004519 manufacturing process Methods 0.000 claims 1
125000001424 substituent group Chemical group 0.000 claims 1
239000011575 calcium Substances 0.000 description 31
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 21
239000011541 reaction mixture Substances 0.000 description 15
239000011780 sodium chloride Substances 0.000 description 11
239000011521 glass Substances 0.000 description 7
239000000047 product Substances 0.000 description 7
239000000725 suspension Substances 0.000 description 7
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 6
229910052753 mercury Inorganic materials 0.000 description 6
239000012299 nitrogen atmosphere Substances 0.000 description 6
238000010992 reflux Methods 0.000 description 6
SPRIOUNJHPCKPV-UHFFFAOYSA-N hydridoaluminium Chemical compound [AlH] SPRIOUNJHPCKPV-UHFFFAOYSA-N 0.000 description 5
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
239000000203 mixture Substances 0.000 description 4
230000015572 biosynthetic process Effects 0.000 description 3
238000009835 boiling Methods 0.000 description 3
150000001875 compounds Chemical class 0.000 description 3
150000004820 halides Chemical class 0.000 description 3
150000004678 hydrides Chemical class 0.000 description 3
238000000746 purification Methods 0.000 description 3
238000003786 synthesis reaction Methods 0.000 description 3
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 2
VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
239000001110 calcium chloride Substances 0.000 description 2
229910001628 calcium chloride Inorganic materials 0.000 description 2
239000002002 slurry Substances 0.000 description 2
239000012312 sodium hydride Substances 0.000 description 2
229910000104 sodium hydride Inorganic materials 0.000 description 2
239000007787 solid Substances 0.000 description 2
UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
239000004215 Carbon black (E152) Substances 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
239000002253 acid Substances 0.000 description 1
230000001476 alcoholic effect Effects 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical compound [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
125000002481 alumanyl group Chemical group [H][Al]([H])[*] 0.000 description 1
150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
239000003153 chemical reaction reagent Substances 0.000 description 1
239000007810 chemical reaction solvent Substances 0.000 description 1
239000000470 constituent Substances 0.000 description 1
238000002425 crystallisation Methods 0.000 description 1
230000008025 crystallization Effects 0.000 description 1
238000001704 evaporation Methods 0.000 description 1
230000008020 evaporation Effects 0.000 description 1
238000001914 filtration Methods 0.000 description 1
125000000524 functional group Chemical group 0.000 description 1
125000005843 halogen group Chemical group 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
239000000543 intermediate Substances 0.000 description 1
238000002955 isolation Methods 0.000 description 1
229910001629 magnesium chloride Inorganic materials 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
229910001507 metal halide Inorganic materials 0.000 description 1
150000005309 metal halides Chemical class 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
239000012429 reaction media Substances 0.000 description 1
-1 sodium aluminum hydride Chemical compound 0.000 description 1
NTOCDDPMRUNYHP-UHFFFAOYSA-M sodium;2-(2,4,5-trichlorophenoxy)ethyl sulfate Chemical compound [Na+].[O-]S(=O)(=O)OCCOC1=CC(Cl)=C(Cl)C=C1Cl NTOCDDPMRUNYHP-UHFFFAOYSA-M 0.000 description 1
239000007858 starting material Substances 0.000 description 1
238000003756 stirring Methods 0.000 description 1
238000010257 thawing Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/68—Preparation of metal alcoholates
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/06—Aluminium compounds
- C07F5/069—Aluminium compounds without C-aluminium linkages

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Catalysts (AREA)

NL8002004A 1979-04-04 1980-04-03 Werkwijze voor de bereiding van alkoxy alanaten van aardalkali metalen. NL8002004A (nl)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
IT21566/79A IT1112971B (it)	1979-04-04	1979-04-04	Processo per la sintesi di alcossialanati di metalli alcalino-terrosi
IT2156679		1979-04-04

Publications (1)

Publication Number	Publication Date
NL8002004A true NL8002004A (nl)	1980-10-07

Family

ID=11183695

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NL8002004A NL8002004A (nl)	1979-04-04	1980-04-03	Werkwijze voor de bereiding van alkoxy alanaten van aardalkali metalen.

Country Status (15)

Country	Link
US (1)	US4288381A (de)
JP (1)	JPS55133386A (de)
AT (1)	AT376682B (de)
BE (1)	BE882626A (de)
CA (1)	CA1139774A (de)
CS (1)	CS210630B2 (de)
DE (1)	DE3013240C2 (de)
DK (1)	DK137080A (de)
EG (1)	EG14914A (de)
FR (1)	FR2453177A1 (de)
GB (1)	GB2047248B (de)
IT (1)	IT1112971B (de)
NL (1)	NL8002004A (de)
NO (1)	NO800933L (de)
SE (1)	SE8002500L (de)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB2548361B (en)	2016-03-15	2020-12-02	Dyson Technology Ltd	Method of fabricating an energy storage device
GB2566473B (en)	2017-09-14	2020-03-04	Dyson Technology Ltd	Magnesium salts
GB2566472B (en) *	2017-09-14	2020-03-04	Dyson Technology Ltd	Magnesium salts
GB2569387B (en)	2017-12-18	2022-02-02	Dyson Technology Ltd	Electrode
GB2569392B (en)	2017-12-18	2022-01-26	Dyson Technology Ltd	Use of aluminium in a cathode material
GB2569388B (en)	2017-12-18	2022-02-02	Dyson Technology Ltd	Compound
GB2569390A (en)	2017-12-18	2019-06-19	Dyson Technology Ltd	Compound

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US2720506A (en) *	1952-10-03	1955-10-11	Eastman Kodak Co	Organo-metallic aluminum catalysts for the preparation of polyesters
US3147272A (en) *	1959-08-18	1964-09-01	Herbert C Brown	Method of preparing partially reduced organic compounds
US3060216A (en) *	1959-12-08	1962-10-23	Basf Ag	Complex metal aluminum hydrides and their production
DE1157622B (de) *	1961-05-12	1963-11-21	Dr Karl Ziegler	Verfahren zur Herstellung sauerstoffhaltiger alkaliorganischer Komplexverbindungen des Aluminiums und/oder des Bors
US3184492A (en) *	1963-02-05	1965-05-18	Hoffmann La Roche	Process for the preparation of sodium aluminum methoxy hydride
GB1064654A (en) *	1963-10-02	1967-04-05	Snam Spa	Process for preparing complex aluminium hydrides partly substituted with alcoholate groups and compounds so obtained
US3652622A (en) *	1965-11-13	1972-03-28	Ceskoslovenska Akademie Ved	Organically substituted sodium aluminum hydrides and method of making and using the same
US3761500A (en) *	1970-05-26	1973-09-25	Owens Illinois Inc	Liquid double alkoxides
DE2049400C3 (de) *	1970-10-08	1982-03-11	Dynamit Nobel Ag, 5210 Troisdorf	Verfahren zur Herstellung von Alkalialuminiumalkoxiden
GB1525527A (en) *	1975-12-22	1978-09-20	Asahi Chemical Ind	Method for producing an organomagnesium complex

1979
- 1979-04-04 IT IT21566/79A patent/IT1112971B/it active
1980
- 1980-03-26 US US06/134,093 patent/US4288381A/en not_active Expired - Lifetime
- 1980-03-28 DK DK137080A patent/DK137080A/da not_active Application Discontinuation
- 1980-03-28 AT AT0169280A patent/AT376682B/de not_active IP Right Cessation
- 1980-03-31 NO NO800933A patent/NO800933L/no unknown
- 1980-04-01 SE SE8002500A patent/SE8002500L/xx not_active Application Discontinuation
- 1980-04-02 GB GB8010982A patent/GB2047248B/en not_active Expired
- 1980-04-02 EG EG202/80A patent/EG14914A/xx active
- 1980-04-02 CA CA000349044A patent/CA1139774A/en not_active Expired
- 1980-04-03 BE BE0/200111A patent/BE882626A/fr not_active IP Right Cessation
- 1980-04-03 CS CS802323A patent/CS210630B2/cs unknown
- 1980-04-03 NL NL8002004A patent/NL8002004A/nl not_active Application Discontinuation
- 1980-04-03 FR FR8007572A patent/FR2453177A1/fr active Granted
- 1980-04-03 DE DE3013240A patent/DE3013240C2/de not_active Expired
- 1980-04-04 JP JP4369880A patent/JPS55133386A/ja active Pending

Also Published As

Publication number	Publication date
DE3013240C2 (de)	1983-09-22
FR2453177A1 (fr)	1980-10-31
GB2047248A (en)	1980-11-26
SE8002500L (sv)	1980-10-05
CS210630B2 (en)	1982-01-29
BE882626A (fr)	1980-10-03
JPS55133386A (en)	1980-10-17
EG14914A (en)	1985-12-31
CA1139774A (en)	1983-01-18
NO800933L (no)	1980-10-06
DE3013240A1 (de)	1980-10-09
GB2047248B (en)	1983-03-09
FR2453177B1 (de)	1982-11-26
ATA169280A (de)	1984-05-15
IT1112971B (it)	1986-01-20
DK137080A (da)	1980-10-05
US4288381A (en)	1981-09-08
IT7921566A0 (it)	1979-04-04
AT376682B (de)	1984-12-27

Legal Events

Date	Code	Title
1980-10-27	A1A	A request for search or an international-type search has been filed
1981-10-01	BB	A search report has been drawn up
1985-01-01	A85	Still pending on 85-01-01
1987-06-01	BV	The patent application has lapsed

Publication	Publication Date	Title
KR20010102196A (ko)	2001-11-15	트리플로오아릴알루미늄 에테레이트 제조방법
US4370488A (en)	1983-01-25	Alkali metal complex compounds
NL8002004A (nl)	1980-10-07	Werkwijze voor de bereiding van alkoxy alanaten van aardalkali metalen.
US5730952A (en)	1998-03-24	Process for the preparation of lithium aluminum hydride in etheral solvents
Brown et al.	1983	Addition compounds of alkali-metal hydrides. 23. Preparation of potassium triisopropoxyborohydride in improved purity
USH429H (en)	1988-02-02	Low temperature synthesis of metal sulfides
CA1113679A (en)	1981-12-08	Synthesis of tetradecahydroundecaborate (-1) from borohydride ion
CS199593B2 (en)	1980-07-31	Process for preparing oligomere n-alkyliminoalanes
Bochkarev et al.	2002	Specific chemical behavior of NdII and DyII iodides in reactions with aromatic compounds
US3009964A (en)	1961-11-21	Process for preparation of calcium methylate
US4278611A (en)	1981-07-14	Process for synthesizing alkoxyalanates of alkaline earth metals
SU549087A3 (ru)	1977-02-28	Способ получени соединений алюмини полииминового типа
US4325885A (en)	1982-04-20	Method for preparation of oligomeric iminic derivatives of aluminum
US3639104A (en)	1972-02-01	Preparation of magnesium aluminum hydride
US2999889A (en)	1961-09-12	Divinylmagnesium and method of making
US3783054A (en)	1974-01-01	High energy beryllium rocket fuel compositions and processes therefor
WO1997006097A1 (en)	1997-02-20	Process for the preparation of lithium aliminum hydride in ethereal solvents
CS222657B2 (en)	1983-07-29	Method of preparation of oligomeric iminoalane
JP4416322B2 (ja)	2010-02-17	アルカリ金属アルコラートの製造
KR20040106317A (ko)	2004-12-17	불포화 유기 화합물의 그리냐르 제조방법
US3624117A (en)	1971-11-30	Compounds prepared from aluminium hydride-trialkyl amine and decaborane
NO303286B1 (no)	1998-06-22	FremgangsmÕte for fremstilling av vanadium-bis-arener
US3649223A (en)	1972-03-14	Process for recovery of soluble alkali metal hydrides from insoluble alkali metal aluminum hexahydrides
RU2160271C1 (ru)	2000-12-10	Способ получения 1-диалкиламин-2,3-фуллерен[60]алюмациклопропанов
SU1054292A1 (ru)	1983-11-15	Способ получени боргидридных комплексов редкоземельных элементов