NL8006571A - Werkwijze voor het winnen van een uraniumbevattend concentraat en fosforzuur, alsmede uraniumbevattend concentraat en fosforzuur verkregen volgens deze werkwijze. - Google Patents
Werkwijze voor het winnen van een uraniumbevattend concentraat en fosforzuur, alsmede uraniumbevattend concentraat en fosforzuur verkregen volgens deze werkwijze. Download PDFInfo
- Publication number
- NL8006571A NL8006571A NL8006571A NL8006571A NL8006571A NL 8006571 A NL8006571 A NL 8006571A NL 8006571 A NL8006571 A NL 8006571A NL 8006571 A NL8006571 A NL 8006571A NL 8006571 A NL8006571 A NL 8006571A
- Authority
- NL
- Netherlands
- Prior art keywords
- phosphoric acid
- uranium
- solution
- water
- vessel
- Prior art date
Links
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 title claims description 99
- 229910000147 aluminium phosphate Inorganic materials 0.000 title claims description 49
- 238000000034 method Methods 0.000 title claims description 28
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 33
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 27
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims description 20
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 19
- 229910052770 Uranium Inorganic materials 0.000 claims description 18
- JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 claims description 18
- 239000000377 silicon dioxide Substances 0.000 claims description 17
- 239000007789 gas Substances 0.000 claims description 16
- 238000001556 precipitation Methods 0.000 claims description 16
- 239000012141 concentrate Substances 0.000 claims description 12
- DDFHBQSCUXNBSA-UHFFFAOYSA-N 5-(5-carboxythiophen-2-yl)thiophene-2-carboxylic acid Chemical compound S1C(C(=O)O)=CC=C1C1=CC=C(C(O)=O)S1 DDFHBQSCUXNBSA-UHFFFAOYSA-N 0.000 claims description 11
- 235000012239 silicon dioxide Nutrition 0.000 claims description 11
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 10
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 10
- 230000029087 digestion Effects 0.000 claims description 10
- 239000011737 fluorine Substances 0.000 claims description 10
- 229910052731 fluorine Inorganic materials 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 10
- 229910021529 ammonia Inorganic materials 0.000 claims description 8
- 239000002367 phosphate rock Substances 0.000 claims description 8
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 7
- 239000002270 dispersing agent Substances 0.000 claims description 7
- 239000002244 precipitate Substances 0.000 claims description 7
- 229910052710 silicon Inorganic materials 0.000 claims description 7
- 239000010703 silicon Substances 0.000 claims description 7
- 238000001704 evaporation Methods 0.000 claims description 5
- 230000008020 evaporation Effects 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims description 3
- 239000001257 hydrogen Substances 0.000 claims 2
- -1 hydrogen hexafluorosilicate Chemical class 0.000 claims 2
- 238000011084 recovery Methods 0.000 claims 1
- 235000011007 phosphoric acid Nutrition 0.000 description 40
- 238000006243 chemical reaction Methods 0.000 description 13
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 10
- 229910019142 PO4 Inorganic materials 0.000 description 9
- 235000011132 calcium sulphate Nutrition 0.000 description 9
- 235000021317 phosphate Nutrition 0.000 description 9
- 238000002156 mixing Methods 0.000 description 8
- 239000006096 absorbing agent Substances 0.000 description 7
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 7
- 239000010452 phosphate Substances 0.000 description 7
- 229910004014 SiF4 Inorganic materials 0.000 description 6
- 239000001175 calcium sulphate Substances 0.000 description 6
- ABTOQLMXBSRXSM-UHFFFAOYSA-N silicon tetrafluoride Chemical compound F[Si](F)(F)F ABTOQLMXBSRXSM-UHFFFAOYSA-N 0.000 description 6
- 239000012295 chemical reaction liquid Substances 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 238000004821 distillation Methods 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 238000005119 centrifugation Methods 0.000 description 2
- 239000003638 chemical reducing agent Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 229910052747 lanthanoid Inorganic materials 0.000 description 2
- 150000002602 lanthanoids Chemical class 0.000 description 2
- 150000002736 metal compounds Chemical class 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 235000011149 sulphuric acid Nutrition 0.000 description 2
- 239000002912 waste gas Substances 0.000 description 2
- 229910052727 yttrium Inorganic materials 0.000 description 2
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 229910003638 H2SiF6 Inorganic materials 0.000 description 1
- 229910017855 NH 4 F Inorganic materials 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- VYOZKLLJJHRFNA-UHFFFAOYSA-N [F].N Chemical compound [F].N VYOZKLLJJHRFNA-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910000148 ammonium phosphate Inorganic materials 0.000 description 1
- ZRIUUUJAJJNDSS-UHFFFAOYSA-N ammonium phosphates Chemical compound [NH4+].[NH4+].[NH4+].[O-]P([O-])([O-])=O ZRIUUUJAJJNDSS-UHFFFAOYSA-N 0.000 description 1
- 159000000009 barium salts Chemical class 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 235000011950 custard Nutrition 0.000 description 1
- 150000004683 dihydrates Chemical class 0.000 description 1
- RXKJFZQQPQGTFL-UHFFFAOYSA-N dihydroxyacetone Chemical compound OCC(=O)CO RXKJFZQQPQGTFL-UHFFFAOYSA-N 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- LRCFXGAMWKDGLA-UHFFFAOYSA-N dioxosilane;hydrate Chemical compound O.O=[Si]=O LRCFXGAMWKDGLA-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 235000015243 ice cream Nutrition 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- ZPLUZNXSYCCJOE-UHFFFAOYSA-N phosphoric acid;propan-2-one Chemical compound CC(C)=O.OP(O)(O)=O ZPLUZNXSYCCJOE-UHFFFAOYSA-N 0.000 description 1
- YXJYBPXSEKMEEJ-UHFFFAOYSA-N phosphoric acid;sulfuric acid Chemical compound OP(O)(O)=O.OS(O)(=O)=O YXJYBPXSEKMEEJ-UHFFFAOYSA-N 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- ZEFWRWWINDLIIV-UHFFFAOYSA-N tetrafluorosilane;dihydrofluoride Chemical compound F.F.F[Si](F)(F)F ZEFWRWWINDLIIV-UHFFFAOYSA-N 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- JCMLRUNDSXARRW-UHFFFAOYSA-N trioxouranium Chemical compound O=[U](=O)=O JCMLRUNDSXARRW-UHFFFAOYSA-N 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B60/00—Obtaining metals of atomic number 87 or higher, i.e. radioactive metals
- C22B60/02—Obtaining thorium, uranium, or other actinides
- C22B60/0204—Obtaining thorium, uranium, or other actinides obtaining uranium
- C22B60/0217—Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes
- C22B60/0252—Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes treatment or purification of solutions or of liquors or of slurries
- C22B60/0278—Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes treatment or purification of solutions or of liquors or of slurries by chemical methods
- C22B60/0282—Solutions containing P ions, e.g. treatment of solutions resulting from the leaching of phosphate ores or recovery of uranium from wet-process phosphoric acid
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/16—Oxyacids of phosphorus; Salts thereof
- C01B25/46—Preparation involving solvent-solvent extraction
- C01B25/461—Preparation involving solvent-solvent extraction the phosphoric acid present in the medium obtained after reaction being first extracted from the liquid phase formed or separated then re-extracted as free acid by using water or as a phosphate by using a basic compound
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/16—Oxyacids of phosphorus; Salts thereof
- C01B25/46—Preparation involving solvent-solvent extraction
- C01B25/461—Preparation involving solvent-solvent extraction the phosphoric acid present in the medium obtained after reaction being first extracted from the liquid phase formed or separated then re-extracted as free acid by using water or as a phosphate by using a basic compound
- C01B25/463—Preparation involving solvent-solvent extraction the phosphoric acid present in the medium obtained after reaction being first extracted from the liquid phase formed or separated then re-extracted as free acid by using water or as a phosphate by using a basic compound the extracting agent being a ketone or a mixture of ketones
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Analytical Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Geology (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Removal Of Specific Substances (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Priority Applications (8)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL8006571A NL8006571A (nl) | 1980-12-03 | 1980-12-03 | Werkwijze voor het winnen van een uraniumbevattend concentraat en fosforzuur, alsmede uraniumbevattend concentraat en fosforzuur verkregen volgens deze werkwijze. |
| EP81201220A EP0053409A1 (fr) | 1980-12-03 | 1981-10-30 | Procédé de récupération d'un concentrat d'uranium et d'acide phosphorique |
| MA19548A MA19344A1 (fr) | 1980-12-03 | 1981-12-01 | Procede d'obtention d'un concentrat contenant de l'uranium et d'acide phosphorique , ainsi que du concentrat , contenant de l'uranium et de l'acide phosphorique , obtenu par la misen oeuvre de ce procede . |
| IL64437A IL64437A (en) | 1980-12-03 | 1981-12-01 | Recovery of uranium-containing concentrate and phosphoric acid from phosphate rock |
| CA000391306A CA1184388A (fr) | 1980-12-03 | 1981-12-01 | Methode de separation d'un concentre a teneur d'uranium et d'acide phosphorique, et concentre et acide ainsi obtenus |
| ES507639A ES507639A0 (es) | 1980-12-03 | 1981-12-02 | Procedimiento para la recuperacion de un concentrado que contiene uranio,y acido fosforico . |
| ZA818362A ZA818362B (en) | 1980-12-03 | 1981-12-02 | Process for the recovery of a uranium-containing concentrate and phosphoric acid,and uranium-containing concentrate and phosphoric acid obtained by this process |
| JP56194330A JPS57118032A (en) | 1980-12-03 | 1981-12-02 | Recovery of uranium-containing condensate and phosphoric acid and uranium-containing condensate and phosphoric acid recovered thereby |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL8006571 | 1980-12-03 | ||
| NL8006571A NL8006571A (nl) | 1980-12-03 | 1980-12-03 | Werkwijze voor het winnen van een uraniumbevattend concentraat en fosforzuur, alsmede uraniumbevattend concentraat en fosforzuur verkregen volgens deze werkwijze. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| NL8006571A true NL8006571A (nl) | 1982-07-01 |
Family
ID=19836277
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NL8006571A NL8006571A (nl) | 1980-12-03 | 1980-12-03 | Werkwijze voor het winnen van een uraniumbevattend concentraat en fosforzuur, alsmede uraniumbevattend concentraat en fosforzuur verkregen volgens deze werkwijze. |
Country Status (8)
| Country | Link |
|---|---|
| EP (1) | EP0053409A1 (fr) |
| JP (1) | JPS57118032A (fr) |
| CA (1) | CA1184388A (fr) |
| ES (1) | ES507639A0 (fr) |
| IL (1) | IL64437A (fr) |
| MA (1) | MA19344A1 (fr) |
| NL (1) | NL8006571A (fr) |
| ZA (1) | ZA818362B (fr) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2531698A2 (fr) * | 1981-11-17 | 1984-02-17 | Pechiney Ugine Kuhlmann Uran | Traitement de purification d'un concentre uranifere |
| CN104906920B (zh) * | 2015-06-03 | 2017-01-18 | 贵阳开磷化肥有限公司 | 一种湿法磷酸尾气处理回收氟、硅资源的系统及其回收方法 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2819145A (en) * | 1952-10-15 | 1958-01-07 | Robert F Mccullough | Metal value recovery from leached zone material |
| BE755133A (fr) * | 1969-08-23 | 1971-02-22 | Bayer Ag | Procede pour separer le phosphate d'un acide fluosilicique approprie a la fabrication du fluorure d'ammonium |
| DE2347485C3 (de) * | 1973-09-21 | 1980-09-04 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung von Ammoniumfluorid aus Kieselfluorwasserstoffsäure |
| EP0015589B1 (fr) * | 1979-01-25 | 1983-11-30 | Stamicarbon B.V. | Procédé de récupération d'un concentrat contenant de l'uranium et d'acide phosphorique purifié à partir d'acide phosphorique obtenu par voie humide et produits ainsi obtenus |
-
1980
- 1980-12-03 NL NL8006571A patent/NL8006571A/nl not_active Application Discontinuation
-
1981
- 1981-10-30 EP EP81201220A patent/EP0053409A1/fr not_active Withdrawn
- 1981-12-01 MA MA19548A patent/MA19344A1/fr unknown
- 1981-12-01 CA CA000391306A patent/CA1184388A/fr not_active Expired
- 1981-12-01 IL IL64437A patent/IL64437A/xx unknown
- 1981-12-02 JP JP56194330A patent/JPS57118032A/ja active Pending
- 1981-12-02 ZA ZA818362A patent/ZA818362B/xx unknown
- 1981-12-02 ES ES507639A patent/ES507639A0/es active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| MA19344A1 (fr) | 1982-07-01 |
| IL64437A0 (en) | 1982-03-31 |
| IL64437A (en) | 1984-04-30 |
| CA1184388A (fr) | 1985-03-26 |
| ES8207095A1 (es) | 1982-09-01 |
| JPS57118032A (en) | 1982-07-22 |
| ZA818362B (en) | 1982-10-27 |
| EP0053409A1 (fr) | 1982-06-09 |
| ES507639A0 (es) | 1982-09-01 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A1B | A search report has been drawn up | ||
| BV | The patent application has lapsed |