NL8103990A - Werkwijze ter bereiding van zouten van dithiofosforzuren. - Google Patents

Werkwijze ter bereiding van zouten van dithiofosforzuren. Download PDF

Info

Publication number: NL8103990A
Authority: NL; Netherlands
Prior art keywords: quaternary ammonium; compounds; dithiophosphoric; process according; dithiophosphoric acids
Prior art date: 1981-08-27

Application number

NL8103990A

Other languages

English (en)

Dutch (nl)

Original Assignee

Shell Int Research

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1981-08-27

Filing date

1981-08-27

Publication date

1983-03-16

1981-08-27 Application filed by Shell Int Research filed Critical Shell Int Research

1981-08-27 Priority to NL8103990A priority Critical patent/NL8103990A/nl

1982-08-25 Priority to BE0/208870A priority patent/BE894196A/fr

1982-08-25 Priority to GB08224337A priority patent/GB2104898A/en

1982-08-25 Priority to FR8214587A priority patent/FR2512029A1/fr

1983-03-16 Publication of NL8103990A publication Critical patent/NL8103990A/nl

Links

239000002253 acid Substances 0.000 title claims description 48
150000007513 acids Chemical class 0.000 title claims description 34
238000004519 manufacturing process Methods 0.000 title claims description 6
238000000034 method Methods 0.000 claims description 22
150000003856 quaternary ammonium compounds Chemical class 0.000 claims description 22
150000001875 compounds Chemical class 0.000 claims description 21
NAGJZTKCGNOGPW-UHFFFAOYSA-N dithiophosphoric acid Chemical compound OP(O)(S)=S NAGJZTKCGNOGPW-UHFFFAOYSA-N 0.000 claims description 19
150000003839 salts Chemical class 0.000 claims description 16
239000000203 mixture Substances 0.000 claims description 15
150000003819 basic metal compounds Chemical class 0.000 claims description 14
239000010687 lubricating oil Substances 0.000 claims description 13
125000004432 carbon atom Chemical group C* 0.000 claims description 10
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 9
239000000314 lubricant Substances 0.000 claims description 8
230000003472 neutralizing effect Effects 0.000 claims description 8
125000003118 aryl group Chemical group 0.000 claims description 7
150000002736 metal compounds Chemical class 0.000 claims description 7
238000006386 neutralization reaction Methods 0.000 claims description 7
125000002877 alkyl aryl group Chemical group 0.000 claims description 6
125000003710 aryl alkyl group Chemical group 0.000 claims description 6
238000002360 preparation method Methods 0.000 claims description 6
NHGXDBSUJJNIRV-UHFFFAOYSA-M tetrabutylammonium chloride Chemical compound [Cl-].CCCC[N+](CCCC)(CCCC)CCCC NHGXDBSUJJNIRV-UHFFFAOYSA-M 0.000 claims description 6
150000003752 zinc compounds Chemical class 0.000 claims description 6
125000000217 alkyl group Chemical group 0.000 claims description 5
125000000547 substituted alkyl group Chemical group 0.000 claims description 5
OKIZCWYLBDKLSU-UHFFFAOYSA-M N,N,N-Trimethylmethanaminium chloride Chemical compound [Cl-].C[N+](C)(C)C OKIZCWYLBDKLSU-UHFFFAOYSA-M 0.000 claims description 4
150000002430 hydrocarbons Chemical class 0.000 claims description 4
-1 quaternary ammonium halides Chemical class 0.000 claims description 4
239000002904 solvent Substances 0.000 claims description 4
229930195733 hydrocarbon Natural products 0.000 claims description 3
IMGHCWMUWVHYCO-UHFFFAOYSA-N nonan-1-amine;hydrochloride Chemical compound [Cl-].CCCCCCCCC[NH3+] IMGHCWMUWVHYCO-UHFFFAOYSA-N 0.000 claims description 3
VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical class OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 claims description 3
239000004215 Carbon black (E152) Substances 0.000 claims description 2
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 2
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
229910052788 barium Inorganic materials 0.000 claims description 2
DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims description 2
229910052793 cadmium Inorganic materials 0.000 claims description 2
BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims description 2
125000000753 cycloalkyl group Chemical group 0.000 claims description 2
229910052749 magnesium Inorganic materials 0.000 claims description 2
239000011777 magnesium Substances 0.000 claims description 2
150000002823 nitrates Chemical class 0.000 claims description 2
230000000737 periodic effect Effects 0.000 claims description 2
125000001453 quaternary ammonium group Chemical group 0.000 claims description 2
229910052712 strontium Inorganic materials 0.000 claims description 2
CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 claims description 2
150000003467 sulfuric acid derivatives Chemical class 0.000 claims description 2
JRMUNVKIHCOMHV-UHFFFAOYSA-M tetrabutylammonium bromide Chemical compound [Br-].CCCC[N+](CCCC)(CCCC)CCCC JRMUNVKIHCOMHV-UHFFFAOYSA-M 0.000 claims description 2
AQZSPJRLCJSOED-UHFFFAOYSA-M trimethyl(octyl)azanium;chloride Chemical compound [Cl-].CCCCCCCC[N+](C)(C)C AQZSPJRLCJSOED-UHFFFAOYSA-M 0.000 claims description 2
229910052725 zinc Inorganic materials 0.000 claims description 2
239000011701 zinc Substances 0.000 claims description 2
241000036848 Porzana carolina Species 0.000 claims 1
235000019270 ammonium chloride Nutrition 0.000 claims 1
150000003842 bromide salts Chemical class 0.000 claims 1
DDFYFBUWEBINLX-UHFFFAOYSA-M tetramethylammonium bromide Chemical compound [Br-].C[N+](C)(C)C DDFYFBUWEBINLX-UHFFFAOYSA-M 0.000 claims 1
238000006243 chemical reaction Methods 0.000 description 28
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 10
238000002474 experimental method Methods 0.000 description 8
150000001298 alcohols Chemical class 0.000 description 6
239000011787 zinc oxide Substances 0.000 description 5
239000010688 mineral lubricating oil Substances 0.000 description 4
239000007858 starting material Substances 0.000 description 4
VDZOOKBUILJEDG-UHFFFAOYSA-M tetrabutylammonium hydroxide Chemical compound [OH-].CCCC[N+](CCCC)(CCCC)CCCC VDZOOKBUILJEDG-UHFFFAOYSA-M 0.000 description 4
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 3
239000000654 additive Substances 0.000 description 3
239000007795 chemical reaction product Substances 0.000 description 3
OHHBFEVZJLBKEH-UHFFFAOYSA-N ethylenediamine dihydrochloride Chemical compound Cl.Cl.NCCN OHHBFEVZJLBKEH-UHFFFAOYSA-N 0.000 description 3
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
WMYJOZQKDZZHAC-UHFFFAOYSA-H trizinc;dioxido-sulfanylidene-sulfido-$l^{5}-phosphane Chemical class [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([S-])=S.[O-]P([O-])([S-])=S WMYJOZQKDZZHAC-UHFFFAOYSA-H 0.000 description 3
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
230000002378 acidificating effect Effects 0.000 description 2
239000003963 antioxidant agent Substances 0.000 description 2
AYJRCSIUFZENHW-UHFFFAOYSA-L barium carbonate Chemical compound [Ba+2].[O-]C([O-])=O AYJRCSIUFZENHW-UHFFFAOYSA-L 0.000 description 2
QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 2
150000001649 bromium compounds Chemical class 0.000 description 2
238000005119 centrifugation Methods 0.000 description 2
150000001805 chlorine compounds Chemical class 0.000 description 2
230000000052 comparative effect Effects 0.000 description 2
229910052751 metal Inorganic materials 0.000 description 2
239000002184 metal Substances 0.000 description 2
XKBGEWXEAPTVCK-UHFFFAOYSA-M methyltrioctylammonium chloride Chemical compound [Cl-].CCCCCCCC[N+](C)(CCCCCCCC)CCCCCCCC XKBGEWXEAPTVCK-UHFFFAOYSA-M 0.000 description 2
229910017464 nitrogen compound Inorganic materials 0.000 description 2
235000011007 phosphoric acid Nutrition 0.000 description 2
239000000047 product Substances 0.000 description 2
239000000376 reactant Substances 0.000 description 2
239000011541 reaction mixture Substances 0.000 description 2
239000010689 synthetic lubricating oil Substances 0.000 description 2
238000004448 titration Methods 0.000 description 2
VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 description 1
PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 1
CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
MHZGKXUYDGKKIU-UHFFFAOYSA-N Decylamine Chemical compound CCCCCCCCCCN MHZGKXUYDGKKIU-UHFFFAOYSA-N 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
FMRLDPWIRHBCCC-UHFFFAOYSA-L Zinc carbonate Chemical compound [Zn+2].[O-]C([O-])=O FMRLDPWIRHBCCC-UHFFFAOYSA-L 0.000 description 1
125000003545 alkoxy group Chemical group 0.000 description 1
125000005210 alkyl ammonium group Chemical group 0.000 description 1
229910000147 aluminium phosphate Inorganic materials 0.000 description 1
125000003277 amino group Chemical group 0.000 description 1
229910021529 ammonia Inorganic materials 0.000 description 1
239000002518 antifoaming agent Substances 0.000 description 1
239000013556 antirust agent Substances 0.000 description 1
125000004104 aryloxy group Chemical group 0.000 description 1
239000002199 base oil Substances 0.000 description 1
WGQKYBSKWIADBV-UHFFFAOYSA-O benzylaminium Chemical compound [NH3+]CC1=CC=CC=C1 WGQKYBSKWIADBV-UHFFFAOYSA-O 0.000 description 1
AONXKRQOHOLGQY-UHFFFAOYSA-N bis(4-butylphenoxy)-sulfanyl-sulfanylidene-lambda5-phosphane Chemical compound C(CCC)C1=CC=C(C=C1)OP(S)(OC1=CC=C(C=C1)CCCC)=S AONXKRQOHOLGQY-UHFFFAOYSA-N 0.000 description 1
KURZBXWWTUWWGB-UHFFFAOYSA-N bis(8-methylnonoxy)-sulfanyl-sulfanylidene-$l^{5}-phosphane Chemical compound CC(C)CCCCCCCOP(S)(=S)OCCCCCCCC(C)C KURZBXWWTUWWGB-UHFFFAOYSA-N 0.000 description 1
ZDARREGFOHVNLC-UHFFFAOYSA-N bis(phenylmethoxy)-sulfanyl-sulfanylidene-$l^{5}-phosphane Chemical compound C=1C=CC=CC=1COP(=S)(S)OCC1=CC=CC=C1 ZDARREGFOHVNLC-UHFFFAOYSA-N 0.000 description 1
HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 1
UTDOJTBJZVYMNB-UHFFFAOYSA-N butane-1,4-diamine dihydrobromide Chemical compound [Br-].[Br-].[NH3+]CCCC[NH3+] UTDOJTBJZVYMNB-UHFFFAOYSA-N 0.000 description 1
PLLZRTNVEXYBNA-UHFFFAOYSA-L cadmium hydroxide Chemical compound [OH-].[OH-].[Cd+2] PLLZRTNVEXYBNA-UHFFFAOYSA-L 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
239000011575 calcium Substances 0.000 description 1
229910000019 calcium carbonate Inorganic materials 0.000 description 1
BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
239000000292 calcium oxide Substances 0.000 description 1
ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
239000004202 carbamide Substances 0.000 description 1
239000004927 clay Substances 0.000 description 1
239000000470 constituent Substances 0.000 description 1
238000010924 continuous production Methods 0.000 description 1
239000010779 crude oil Substances 0.000 description 1
ODMQWSYIRPQTAL-UHFFFAOYSA-N di(cyclodecyloxy)-sulfanyl-sulfanylidene-lambda5-phosphane Chemical compound C1(CCCCCCCCC1)OP(S)(OC1CCCCCCCCC1)=S ODMQWSYIRPQTAL-UHFFFAOYSA-N 0.000 description 1
IWHTZOQGVGHYQT-UHFFFAOYSA-N dicyclohexyloxy-sulfanyl-sulfanylidene-$l^{5}-phosphane Chemical compound C1CCCCC1OP(=S)(S)OC1CCCCC1 IWHTZOQGVGHYQT-UHFFFAOYSA-N 0.000 description 1
HPNMFZURTQLUMO-UHFFFAOYSA-O diethylammonium Chemical compound CC[NH2+]CC HPNMFZURTQLUMO-UHFFFAOYSA-O 0.000 description 1
239000003085 diluting agent Substances 0.000 description 1
CKSHRDPCFLDKPV-UHFFFAOYSA-N diphenoxy-sulfanyl-sulfanylidene-$l^{5}-phosphane Chemical compound C=1C=CC=CC=1OP(=S)(S)OC1=CC=CC=C1 CKSHRDPCFLDKPV-UHFFFAOYSA-N 0.000 description 1
DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 1
XPPKVPWEQAFLFU-UHFFFAOYSA-N diphosphoric acid Chemical compound OP(O)(=O)OP(O)(O)=O XPPKVPWEQAFLFU-UHFFFAOYSA-N 0.000 description 1
XWBDWHCCBGMXKG-UHFFFAOYSA-N ethanamine;hydron;chloride Chemical compound Cl.CCN XWBDWHCCBGMXKG-UHFFFAOYSA-N 0.000 description 1
125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
QUSNBJAOOMFDIB-UHFFFAOYSA-O ethylaminium Chemical compound CC[NH3+] QUSNBJAOOMFDIB-UHFFFAOYSA-O 0.000 description 1
150000004820 halides Chemical class 0.000 description 1
125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
229910052500 inorganic mineral Inorganic materials 0.000 description 1
VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
239000000347 magnesium hydroxide Substances 0.000 description 1
229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
239000000395 magnesium oxide Substances 0.000 description 1
CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
235000010755 mineral Nutrition 0.000 description 1
MFHKEJIIHDNPQE-UHFFFAOYSA-N n-nonylnonan-1-amine Chemical compound CCCCCCCCCNCCCCCCCCC MFHKEJIIHDNPQE-UHFFFAOYSA-N 0.000 description 1
229910017604 nitric acid Inorganic materials 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
150000002830 nitrogen compounds Chemical class 0.000 description 1
FJDUDHYHRVPMJZ-UHFFFAOYSA-N nonan-1-amine Chemical compound CCCCCCCCCN FJDUDHYHRVPMJZ-UHFFFAOYSA-N 0.000 description 1
NOUWNNABOUGTDQ-UHFFFAOYSA-N octane Chemical compound CCCCCCC[CH2+] NOUWNNABOUGTDQ-UHFFFAOYSA-N 0.000 description 1
HTKPDYSCAPSXIR-UHFFFAOYSA-N octyltrimethylammonium ion Chemical compound CCCCCCCC[N+](C)(C)C HTKPDYSCAPSXIR-UHFFFAOYSA-N 0.000 description 1
239000003921 oil Substances 0.000 description 1
150000004010 onium ions Chemical class 0.000 description 1
239000003208 petroleum Substances 0.000 description 1
150000003016 phosphoric acids Chemical class 0.000 description 1
229910052698 phosphorus Inorganic materials 0.000 description 1
239000011574 phosphorus Substances 0.000 description 1
CYQAYERJWZKYML-UHFFFAOYSA-N phosphorus pentasulfide Chemical compound S1P(S2)(=S)SP3(=S)SP1(=S)SP2(=S)S3 CYQAYERJWZKYML-UHFFFAOYSA-N 0.000 description 1
238000000746 purification Methods 0.000 description 1
UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
229910052705 radium Inorganic materials 0.000 description 1
238000000926 separation method Methods 0.000 description 1
239000002002 slurry Substances 0.000 description 1
238000000638 solvent extraction Methods 0.000 description 1
238000001179 sorption measurement Methods 0.000 description 1
238000003756 stirring Methods 0.000 description 1
239000000126 substance Substances 0.000 description 1
125000001424 substituent group Chemical group 0.000 description 1
XHHCAOIBPBKHGK-UHFFFAOYSA-N sulfanyl-sulfanylidene-di(tetradecoxy)-$l^{5}-phosphane Chemical compound CCCCCCCCCCCCCCOP(S)(=S)OCCCCCCCCCCCCCC XHHCAOIBPBKHGK-UHFFFAOYSA-N 0.000 description 1
239000004094 surface-active agent Substances 0.000 description 1
YBRBMKDOPFTVDT-UHFFFAOYSA-N tert-butylamine Chemical compound CC(C)(C)N YBRBMKDOPFTVDT-UHFFFAOYSA-N 0.000 description 1
238000010626 work up procedure Methods 0.000 description 1
239000011667 zinc carbonate Substances 0.000 description 1
229910000010 zinc carbonate Inorganic materials 0.000 description 1
235000004416 zinc carbonate Nutrition 0.000 description 1
UGZADUVQMDAIAO-UHFFFAOYSA-L zinc hydroxide Chemical compound [OH-].[OH-].[Zn+2] UGZADUVQMDAIAO-UHFFFAOYSA-L 0.000 description 1
229910021511 zinc hydroxide Inorganic materials 0.000 description 1
229940007718 zinc hydroxide Drugs 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/16—Esters of thiophosphoric acids or thiophosphorous acids
- C07F9/165—Esters of thiophosphoric acids
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M137/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus
- C10M137/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus having no phosphorus-to-carbon bond
- C10M137/04—Phosphate esters
- C10M137/10—Thio derivatives

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Health & Medical Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Biochemistry (AREA)
General Health & Medical Sciences (AREA)
Molecular Biology (AREA)
Chemical Kinetics & Catalysis (AREA)
General Chemical & Material Sciences (AREA)
Oil, Petroleum & Natural Gas (AREA)
Lubricants (AREA)

NL8103990A 1981-08-27 1981-08-27 Werkwijze ter bereiding van zouten van dithiofosforzuren. NL8103990A (nl)

Priority Applications (4)

Application Number	Priority Date	Filing Date	Title
NL8103990A NL8103990A (nl)	1981-08-27	1981-08-27	Werkwijze ter bereiding van zouten van dithiofosforzuren.
BE0/208870A BE894196A (fr)	1981-08-27	1982-08-25	Procede de preparation de sels d'acides dithiophosphoriques
GB08224337A GB2104898A (en)	1981-08-27	1982-08-25	Process for the preparation of salts of dithiophosphoric acids
FR8214587A FR2512029A1 (fr)	1981-08-27	1982-08-25	Procede de preparation de sels d'acides dithiophosphoriques

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
NL8103990A NL8103990A (nl)	1981-08-27	1981-08-27	Werkwijze ter bereiding van zouten van dithiofosforzuren.
NL8103990		1981-08-27

Publications (1)

Publication Number	Publication Date
NL8103990A true NL8103990A (nl)	1983-03-16

Family

ID=19837982

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NL8103990A NL8103990A (nl)	1981-08-27	1981-08-27	Werkwijze ter bereiding van zouten van dithiofosforzuren.

Country Status (4)

Country	Link
BE (1)	BE894196A (fr)
FR (1)	FR2512029A1 (fr)
GB (1)	GB2104898A (fr)
NL (1)	NL8103990A (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4577037A (en) *	1984-02-10	1986-03-18	Chevron Research	Methods for preventing the precipitation of mixed zinc dialkyldithiophosphates which contain high percentages of a lower alkyl group

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3471540A (en) *	1967-03-22	1969-10-07	Phillips Petroleum Co	Production of metal salts of dihydrocarbyldithiophosphoric acids
US4085053A (en) *	1977-05-23	1978-04-18	Standard Oil Company (Indiana)	Metal dithiophosphate process and/composition
US4215067A (en) *	1978-12-29	1980-07-29	Standard Oil Company (Indiana)	Process for the preparation of zinc salts of dihydrocarbyldithiophosphoric acids

1981
- 1981-08-27 NL NL8103990A patent/NL8103990A/nl not_active Application Discontinuation
1982
- 1982-08-25 BE BE0/208870A patent/BE894196A/fr not_active IP Right Cessation
- 1982-08-25 GB GB08224337A patent/GB2104898A/en not_active Withdrawn
- 1982-08-25 FR FR8214587A patent/FR2512029A1/fr active Pending

Also Published As

Publication number	Publication date
GB2104898A (en)	1983-03-16
BE894196A (fr)	1983-02-25
FR2512029A1 (fr)	1983-03-04

Legal Events

Date	Code	Title	Description
1984-04-02	BV	The patent application has lapsed

Publication	Publication Date	Title
DE3882609T3 (de)	1998-08-20	Getriebeschmiermittelzusammensetzung.
EP0095322B1 (fr)	1992-07-29	Procédé de production d'un alkylphénolate sulfuré surbasique d'un métal alcalino-terreux
EP0325977A1 (fr)	1989-08-02	Additifs de phosphite amine pour lubrifiant
US4137183A (en)	1979-01-30	Hydrocarbyl titanate dithiophosphate compositions and processes
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