NL8302574A - Produktie van zwavel uit een h2s bevattende gasstroom. - Google Patents

Produktie van zwavel uit een h2s bevattende gasstroom. Download PDF

Info

Publication number: NL8302574A
Authority: NL; Netherlands
Prior art keywords: sulfur; bep; reactor; reaction; temperature
Prior art date: 1982-12-09

Application number

NL8302574A

Other languages

English (en)

Dutch (nl)

Original Assignee

Mineral Chem Resource Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1982-12-09

Filing date

1983-07-19

Publication date

1984-07-02

1983-07-19 Application filed by Mineral Chem Resource Co filed Critical Mineral Chem Resource Co

1984-07-02 Publication of NL8302574A publication Critical patent/NL8302574A/nl

Links

NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title claims description 81
229910052717 sulfur Inorganic materials 0.000 title claims description 77
239000011593 sulfur Substances 0.000 title claims description 75
238000004519 manufacturing process Methods 0.000 title description 5
239000007789 gas Substances 0.000 claims description 57
238000006243 chemical reaction Methods 0.000 claims description 47
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 42
238000000034 method Methods 0.000 claims description 35
239000006096 absorbing agent Substances 0.000 claims description 22
239000002250 absorbent Substances 0.000 claims description 19
230000002745 absorbent Effects 0.000 claims description 19
238000002485 combustion reaction Methods 0.000 claims description 12
238000000926 separation method Methods 0.000 claims description 9
239000007787 solid Substances 0.000 claims description 9
UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 claims description 8
239000012071 phase Substances 0.000 claims description 4
239000007791 liquid phase Substances 0.000 claims description 3
238000002844 melting Methods 0.000 claims description 3
230000008018 melting Effects 0.000 claims description 3
GOCVCBDBQYEFQD-UHFFFAOYSA-N 3-[[2-ethylhexoxy(2-ethylhexyl)phosphoryl]oxymethyl]heptane Chemical compound CCCCC(CC)COP(=O)(CC(CC)CCCC)OCC(CC)CCCC GOCVCBDBQYEFQD-UHFFFAOYSA-N 0.000 description 86
RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 61
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 23
229910000037 hydrogen sulfide Inorganic materials 0.000 description 23
238000010521 absorption reaction Methods 0.000 description 22
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 14
238000009835 boiling Methods 0.000 description 12
238000001816 cooling Methods 0.000 description 9
239000002904 solvent Substances 0.000 description 9
229910002092 carbon dioxide Inorganic materials 0.000 description 7
239000007788 liquid Substances 0.000 description 7
230000015572 biosynthetic process Effects 0.000 description 4
ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 3
229930195733 hydrocarbon Natural products 0.000 description 3
150000002430 hydrocarbons Chemical class 0.000 description 3
239000003960 organic solvent Substances 0.000 description 3
239000012429 reaction media Substances 0.000 description 3
239000002912 waste gas Substances 0.000 description 3
HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
239000012736 aqueous medium Substances 0.000 description 2
239000003153 chemical reaction reagent Substances 0.000 description 2
238000003795 desorption Methods 0.000 description 2
ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 2
238000001914 filtration Methods 0.000 description 2
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
239000007800 oxidant agent Substances 0.000 description 2
230000003647 oxidation Effects 0.000 description 2
238000007254 oxidation reaction Methods 0.000 description 2
238000012856 packing Methods 0.000 description 2
150000003839 salts Chemical class 0.000 description 2
239000000126 substance Substances 0.000 description 2
239000012808 vapor phase Substances 0.000 description 2
JPGXOMADPRULAC-UHFFFAOYSA-N 1-[butoxy(butyl)phosphoryl]oxybutane Chemical compound CCCCOP(=O)(CCCC)OCCCC JPGXOMADPRULAC-UHFFFAOYSA-N 0.000 description 1
-1 2-ethylhexyl Chemical group 0.000 description 1
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
OEODWKRQWJHQSK-UHFFFAOYSA-N CCCCCCOP(O)=O Chemical compound CCCCCCOP(O)=O OEODWKRQWJHQSK-UHFFFAOYSA-N 0.000 description 1
101710178035 Chorismate synthase 2 Proteins 0.000 description 1
101710152694 Cysteine synthase 2 Proteins 0.000 description 1
238000002835 absorbance Methods 0.000 description 1
239000002253 acid Substances 0.000 description 1
230000006978 adaptation Effects 0.000 description 1
229910052614 beryl Inorganic materials 0.000 description 1
239000001569 carbon dioxide Substances 0.000 description 1
239000003054 catalyst Substances 0.000 description 1
230000003197 catalytic effect Effects 0.000 description 1
238000005119 centrifugation Methods 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
238000010276 construction Methods 0.000 description 1
239000013078 crystal Substances 0.000 description 1
238000002425 crystallisation Methods 0.000 description 1
230000008025 crystallization Effects 0.000 description 1
238000000354 decomposition reaction Methods 0.000 description 1
239000003085 diluting agent Substances 0.000 description 1
230000000694 effects Effects 0.000 description 1
239000003344 environmental pollutant Substances 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
239000011521 glass Substances 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
230000002209 hydrophobic effect Effects 0.000 description 1
229940060367 inert ingredients Drugs 0.000 description 1
231100000053 low toxicity Toxicity 0.000 description 1
239000002609 medium Substances 0.000 description 1
239000000203 mixture Substances 0.000 description 1
239000003345 natural gas Substances 0.000 description 1
230000007935 neutral effect Effects 0.000 description 1
210000002445 nipple Anatomy 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
231100000719 pollutant Toxicity 0.000 description 1
239000000047 product Substances 0.000 description 1
239000002002 slurry Substances 0.000 description 1
239000007921 spray Substances 0.000 description 1
150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
150000004764 thiosulfuric acid derivatives Chemical class 0.000 description 1
239000002351 wastewater Substances 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/52—Hydrogen sulfide

Landscapes

Engineering & Computer Science (AREA)
Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Biomedical Technology (AREA)
Environmental & Geological Engineering (AREA)
Analytical Chemistry (AREA)
General Chemical & Material Sciences (AREA)
Oil, Petroleum & Natural Gas (AREA)
Chemical Kinetics & Catalysis (AREA)
Treating Waste Gases (AREA)

NL8302574A 1982-12-09 1983-07-19 Produktie van zwavel uit een h2s bevattende gasstroom. NL8302574A (nl)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US06/448,200 US4479929A (en)	1982-06-07	1982-12-09	Production of sulfur from a H2 S-bearing gas stream
US44820082		1982-12-09

Publications (1)

Publication Number	Publication Date
NL8302574A true NL8302574A (nl)	1984-07-02

Family

ID=23779385

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NL8302574A NL8302574A (nl)	1982-12-09	1983-07-19	Produktie van zwavel uit een h2s bevattende gasstroom.

Country Status (6)

Country	Link
US (1)	US4479929A (2)
JP (1)	JPS59213605A (2)
CA (1)	CA1186133A (2)
DE (1)	DE3325025A1 (2)
GB (1)	GB2132179B (2)
NL (1)	NL8302574A (2)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE3607029A1 (de) *	1985-03-08	1986-10-02	Jgc Corp., Tokio/Tokyo	Verfahren zur entschwefelung von schwefelwasserstoff enthaltendem gas
US5851265A (en) *	1996-09-03	1998-12-22	Monsanto Company	Selective removal and recovery of sulfur dioxide from effluent gases using organic phosphorous solvents
EP2599536A1 (en) *	2011-11-29	2013-06-05	Nederlandse Organisatie voor toegepast -natuurwetenschappelijk onderzoek TNO	Method for depleting an exhaust gas stream in gaseous acid

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US2881047A (en) *	1956-05-29	1959-04-07	Laurence S Reid	Method of simultaneously removing hydrogen sulfide from gaseous mixtures and producing sulfur therefrom
FR1492013A (fr) *	1965-03-30	1967-08-18	Inst Francais Du Petrole	Procédé de conversion de l'hydrogène sulfuré en soufre élémentaire
OA02897A (fr) *	1967-10-20	1970-12-15	Isntitut Francais Du Petrole D	Procédé de conversion de l'hydrogène sulfuré et de l'anhydride sulfureux en soufre élémentaire.
DE2108284A1 (de) *	1971-02-20	1972-08-31	Basf Ag	Verfahren zur Umsetzung von Schwefelwasserstoff und Schwefeldioxid zu elementarem Schwefel
FR2358187A1 (fr) *	1976-07-12	1978-02-10	Raffinage Cie Francaise	Procede de purification d'un gaz hydrogene contenant des gaz acides et applications dudit procede

1982
- 1982-12-09 US US06/448,200 patent/US4479929A/en not_active Expired - Fee Related
1983
- 1983-07-08 GB GB08318507A patent/GB2132179B/en not_active Expired
- 1983-07-11 DE DE19833325025 patent/DE3325025A1/de not_active Withdrawn
- 1983-07-14 CA CA000432478A patent/CA1186133A/en not_active Expired
- 1983-07-18 JP JP58130732A patent/JPS59213605A/ja active Granted
- 1983-07-19 NL NL8302574A patent/NL8302574A/nl not_active Application Discontinuation

Also Published As

Publication number	Publication date
CA1186133A (en)	1985-04-30
GB2132179A (en)	1984-07-04
DE3325025A1 (de)	1984-06-20
JPS6344682B2 (2)	1988-09-06
JPS59213605A (ja)	1984-12-03
US4479929A (en)	1984-10-30
GB2132179B (en)	1987-02-11
GB8318507D0 (en)	1983-08-10

Legal Events

Date	Code	Title	Description
1985-01-01	A85	Still pending on 85-01-01
1988-03-01	BV	The patent application has lapsed

Publication	Publication Date	Title
US6818194B2 (en)	2004-11-16	Process for removing hydrogen sulfide from gas streams which include or are supplemented with sulfur dioxide, by scrubbing with a nonaqueous sorbent
US3911093A (en)	1975-10-07	Recovery of SO{HD 2 {B from waste gas emissions
US6544492B1 (en)	2003-04-08	Regeneration method for process which removes hydrogen sulfide from gas streams
CN101052588A (zh)	2007-10-10	适于处理高压气流的除硫方法
JP4303111B2 (ja)	2009-07-29	硫黄回収プロセスにおける硫黄成分の回収方法
EP0086919B1 (en)	1987-09-16	Process for the selective removal of hydrogen sulfide from gaseous stream
RU97112935A (ru)	1999-06-20	Способ почти полного удаления соединений серы h2s, so2, cos и/или cs2 из отходящего газа серной установки с извлечением этих соединений в виде серы
CA2302673C (en)	2009-05-12	High efficiency process for recovering sulfur from h2s-bearing gas
US4124685A (en)	1978-11-07	Method for substantially complete removal of hydrogen sulfide from sulfur bearing industrial gases
CN108495954A (zh)	2018-09-04	用于生产钾产品的二氧化硫洗涤系统和方法
EA001297B1 (ru)	2000-12-25	Селективное удаление и регенерация двуокиси серы из газообразных промышленных отходов путем применения фосфорорганических растворителей
JPH0712411B2 (ja)	1995-02-15	サワ−ガスの流れからの硫化水素の除去
JPS6097028A (ja)	1985-05-30	排ガスの処理方法
CA2232962A1 (en)	1998-02-05	Natural gas treatment process
CA1039030A (en)	1978-09-26	Method for removal of sulfur dioxide from gases
US4479929A (en)	1984-10-30	Production of sulfur from a H2 S-bearing gas stream
US2994588A (en)	1961-08-01	Process for production of sulphur from sour gas
AU8132198A (en)	1999-01-04	Method for desulfurizing off-gases
JPH11503105A (ja)	1999-03-23	二酸化硫黄源の硫酸への液相変換
Rosenbaum et al.	1973	Sulfur dioxide emission control by hydrogen sulfide reaction in aqueous solution: the citrate system
FI75329C (fi)	1988-06-09	Foerfarande foer avlaegsnande av svavelinnehaollet i en uttunnad svaveldioxidhaltig gas.
JP4391140B2 (ja)	2009-12-24	チオ硫酸アンモニウムの製造方法
NZ279780A (en)	1997-11-24	Removal of h2s from gas streams by contact with conc. sulphuric acid
SU1729277A3 (ru)	1992-04-23	Способ удалени окислов азота из отход щих газов
WO1984000951A1 (fr)	1984-03-15	Procede d'elimination de l'hydrogene sulfure contenu dans un melange gazeux