NL8701799A - Bereiding van polymeren. - Google Patents

Bereiding van polymeren. Download PDF

Info

Publication number: NL8701799A
Authority: NL; Netherlands
Prior art keywords: catalyst composition; groups; process according; component; mixture
Prior art date: 1987-07-30

Application number

NL8701799A

Other languages

English (en)

Dutch (nl)

Original Assignee

Shell Int Research

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1987-07-30

Filing date

1987-07-30

Publication date

1989-02-16

1987-07-30 Application filed by Shell Int Research filed Critical Shell Int Research

1987-07-30 Priority to NL8701799A priority Critical patent/NL8701799A/nl

1988-07-26 Priority to EP88201617A priority patent/EP0301664A3/fr

1988-07-28 Priority to AU20120/88A priority patent/AU606975B2/en

1988-07-28 Priority to JP63189540A priority patent/JPS6462326A/ja

1988-07-29 Priority to US07/225,996 priority patent/US4877860A/en

1989-02-16 Publication of NL8701799A publication Critical patent/NL8701799A/nl

Links

229920000642 polymer Polymers 0.000 title claims description 34
238000002360 preparation method Methods 0.000 title claims description 14
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 81
239000000203 mixture Substances 0.000 claims description 63
239000003054 catalyst Substances 0.000 claims description 42
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 30
238000000034 method Methods 0.000 claims description 27
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 23
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 23
229910002091 carbon monoxide Inorganic materials 0.000 claims description 23
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 21
150000002576 ketones Chemical class 0.000 claims description 19
150000001875 compounds Chemical class 0.000 claims description 16
ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims description 15
229910052763 palladium Inorganic materials 0.000 claims description 15
125000004432 carbon atom Chemical group C* 0.000 claims description 14
-1 aliphatic ketones Chemical class 0.000 claims description 10
150000001298 alcohols Chemical class 0.000 claims description 9
150000001450 anions Chemical class 0.000 claims description 9
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 8
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 7
239000005977 Ethylene Substances 0.000 claims description 7
239000002253 acid Substances 0.000 claims description 7
229910052698 phosphorus Inorganic materials 0.000 claims description 7
125000001424 substituent group Chemical group 0.000 claims description 7
150000002941 palladium compounds Chemical class 0.000 claims description 6
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 5
125000003118 aryl group Chemical group 0.000 claims description 5
239000011574 phosphorus Substances 0.000 claims description 5
JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 claims description 5
AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 claims description 4
FRASJONUBLZVQX-UHFFFAOYSA-N 1,4-naphthoquinone Chemical compound C1=CC=C2C(=O)C=CC(=O)C2=C1 FRASJONUBLZVQX-UHFFFAOYSA-N 0.000 claims description 4
DTQVDTLACAAQTR-UHFFFAOYSA-N Trifluoroacetic acid Chemical compound OC(=O)C(F)(F)F DTQVDTLACAAQTR-UHFFFAOYSA-N 0.000 claims description 4
150000002430 hydrocarbons Chemical class 0.000 claims description 4
229910052757 nitrogen Inorganic materials 0.000 claims description 4
150000002894 organic compounds Chemical class 0.000 claims description 4
YJVFFLUZDVXJQI-UHFFFAOYSA-L palladium(ii) acetate Chemical compound [Pd+2].CC([O-])=O.CC([O-])=O YJVFFLUZDVXJQI-UHFFFAOYSA-L 0.000 claims description 4
125000004204 2-methoxyphenyl group Chemical group [H]C1=C([H])C(*)=C(OC([H])([H])[H])C([H])=C1[H] 0.000 claims description 3
125000003545 alkoxy group Chemical group 0.000 claims description 3
229910052787 antimony Inorganic materials 0.000 claims description 3
WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 3
229910052785 arsenic Inorganic materials 0.000 claims description 3
RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims description 3
229930195733 hydrocarbon Natural products 0.000 claims description 3
125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims description 3
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 3
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 3
229930195735 unsaturated hydrocarbon Natural products 0.000 claims description 3
229940005561 1,4-benzoquinone Drugs 0.000 claims description 2
LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims description 2
125000004429 atom Chemical group 0.000 claims description 2
150000001879 copper Chemical class 0.000 claims description 2
150000002940 palladium Chemical class 0.000 claims description 2
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 2
125000004437 phosphorous atom Chemical group 0.000 claims description 2
125000003107 substituted aryl group Chemical group 0.000 claims description 2
229910052723 transition metal Inorganic materials 0.000 claims description 2
150000001735 carboxylic acids Chemical class 0.000 claims 2
230000002378 acidificating effect Effects 0.000 claims 1
125000001931 aliphatic group Chemical group 0.000 claims 1
238000006116 polymerization reaction Methods 0.000 description 33
229920001577 copolymer Polymers 0.000 description 28
239000003085 diluting agent Substances 0.000 description 17
239000000243 solution Substances 0.000 description 12
238000006243 chemical reaction Methods 0.000 description 11
229920001038 ethylene copolymer Polymers 0.000 description 10
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 9
LVEYOSJUKRVCCF-UHFFFAOYSA-N 1,3-bis(diphenylphosphino)propane Chemical compound C=1C=CC=CC=1P(C=1C=CC=CC=1)CCCP(C=1C=CC=CC=1)C1=CC=CC=C1 LVEYOSJUKRVCCF-UHFFFAOYSA-N 0.000 description 8
RLSSMJSEOOYNOY-UHFFFAOYSA-N m-cresol Chemical compound CC1=CC=CC(O)=C1 RLSSMJSEOOYNOY-UHFFFAOYSA-N 0.000 description 6
239000000178 monomer Substances 0.000 description 6
WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
BARUNXKDFNLHEV-UHFFFAOYSA-N [3-diphenylphosphanyl-2-(diphenylphosphanylmethyl)-2-methylpropyl]-diphenylphosphane Chemical compound C=1C=CC=CC=1P(C=1C=CC=CC=1)CC(CP(C=1C=CC=CC=1)C=1C=CC=CC=1)(C)CP(C=1C=CC=CC=1)C1=CC=CC=C1 BARUNXKDFNLHEV-UHFFFAOYSA-N 0.000 description 3
229910052799 carbon Inorganic materials 0.000 description 3
230000000694 effects Effects 0.000 description 3
229910052739 hydrogen Inorganic materials 0.000 description 3
239000001257 hydrogen Substances 0.000 description 3
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 3
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
PFCHFHIRKBAQGU-UHFFFAOYSA-N 3-hexanone Chemical compound CCCC(=O)CC PFCHFHIRKBAQGU-UHFFFAOYSA-N 0.000 description 2
HCFAJYNVAYBARA-UHFFFAOYSA-N 4-heptanone Chemical compound CCCC(=O)CCC HCFAJYNVAYBARA-UHFFFAOYSA-N 0.000 description 2
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
RJUFJBKOKNCXHH-UHFFFAOYSA-N Methyl propionate Chemical compound CCC(=O)OC RJUFJBKOKNCXHH-UHFFFAOYSA-N 0.000 description 2
AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 2
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical group C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
238000001816 cooling Methods 0.000 description 2
ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 2
ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 2
229940017219 methyl propionate Drugs 0.000 description 2
FDPIMTJIUBPUKL-UHFFFAOYSA-N pentan-3-one Chemical compound CCC(=O)CC FDPIMTJIUBPUKL-UHFFFAOYSA-N 0.000 description 2
150000003839 salts Chemical class 0.000 description 2
239000000725 suspension Substances 0.000 description 2
150000004057 1,4-benzoquinones Chemical class 0.000 description 1
150000000191 1,4-naphthoquinones Chemical class 0.000 description 1
WHFHDVDXYKOSKI-UHFFFAOYSA-N 1-ethenyl-4-ethylbenzene Chemical compound CCC1=CC=C(C=C)C=C1 WHFHDVDXYKOSKI-UHFFFAOYSA-N 0.000 description 1
LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 1
238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 description 1
JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
241000234282 Allium Species 0.000 description 1
235000002732 Allium cepa var. cepa Nutrition 0.000 description 1
239000004215 Carbon black (E152) Substances 0.000 description 1
NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
YSVZGWAJIHWNQK-UHFFFAOYSA-N [3-(hydroxymethyl)-2-bicyclo[2.2.1]heptanyl]methanol Chemical compound C1CC2C(CO)C(CO)C1C2 YSVZGWAJIHWNQK-UHFFFAOYSA-N 0.000 description 1
150000007933 aliphatic carboxylic acids Chemical class 0.000 description 1
150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
125000000217 alkyl group Chemical group 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
125000004106 butoxy group Chemical group [*]OC([H])([H])C([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
239000001569 carbon dioxide Substances 0.000 description 1
229910002092 carbon dioxide Inorganic materials 0.000 description 1
238000005119 centrifugation Methods 0.000 description 1
239000000356 contaminant Substances 0.000 description 1
125000004663 dialkyl amino group Chemical group 0.000 description 1
125000002147 dimethylamino group Chemical group [H]C([H])([H])N(*)C([H])([H])[H] 0.000 description 1
238000001914 filtration Methods 0.000 description 1
125000005842 heteroatom Chemical group 0.000 description 1
125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
238000011835 investigation Methods 0.000 description 1
229960004592 isopropanol Drugs 0.000 description 1
LRHPLDYGYMQRHN-UHFFFAOYSA-N n-Butanol Substances CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 1
230000001151 other effect Effects 0.000 description 1
PIBWKRNGBLPSSY-UHFFFAOYSA-L palladium(II) chloride Chemical compound Cl[Pd]Cl PIBWKRNGBLPSSY-UHFFFAOYSA-L 0.000 description 1
238000003825 pressing Methods 0.000 description 1
239000011541 reaction mixture Substances 0.000 description 1
229910052709 silver Inorganic materials 0.000 description 1
239000004332 silver Substances 0.000 description 1
150000003440 styrenes Chemical class 0.000 description 1
229920001897 terpolymer Polymers 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
239000004711 α-olefin Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G67/00—Macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing oxygen or oxygen and carbon, not provided for in groups C08G2/00 - C08G65/00
- C08G67/02—Copolymers of carbon monoxide and aliphatic unsaturated compounds

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Polyethers (AREA)

NL8701799A 1987-07-30 1987-07-30 Bereiding van polymeren. NL8701799A (nl)

Priority Applications (5)

Application Number	Priority Date	Filing Date	Title
NL8701799A NL8701799A (nl)	1987-07-30	1987-07-30	Bereiding van polymeren.
EP88201617A EP0301664A3 (fr)	1987-07-30	1988-07-26	Préparation de polymères
AU20120/88A AU606975B2 (en)	1987-07-30	1988-07-28	A process for the preparation of polymers of carbon monoxide with one or more olefinically unsaturated compounds using a ketone/alcohol mixture
JP63189540A JPS6462326A (en)	1987-07-30	1988-07-28	Production of polymer
US07/225,996 US4877860A (en)	1987-07-30	1988-07-29	Catalytic copolymerization of carbon monoxide/olefin with ketone/alcohol diluent

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
NL8701799A NL8701799A (nl)	1987-07-30	1987-07-30	Bereiding van polymeren.
NL8701799		1987-07-30

Publications (1)

Publication Number	Publication Date
NL8701799A true NL8701799A (nl)	1989-02-16

Family

ID=19850396

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NL8701799A NL8701799A (nl)	1987-07-30	1987-07-30	Bereiding van polymeren.

Country Status (5)

Country	Link
US (1)	US4877860A (fr)
EP (1)	EP0301664A3 (fr)
JP (1)	JPS6462326A (fr)
AU (1)	AU606975B2 (fr)
NL (1)	NL8701799A (fr)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
AU612173B2 (en) *	1987-08-28	1991-07-04	Shell Internationale Research Maatschappij B.V.	Preparation of olefin/CO copolymers
CA1330132C (fr) *	1987-11-12	1994-06-07	Eit Drent	Polymeres polycetoniques
GB8826324D0 (en) *	1988-11-10	1988-12-14	Shell Int Research	Thermosetting resin compositions
US5059678A (en) *	1989-10-26	1991-10-22	Shell Oil Company	Polymerization of olefin/carbon monoxide with palladium salt, bidentate ligand and carboxylic acid ester or anhydride
NL9001255A (nl) *	1990-06-01	1992-01-02	Shell Int Research	Bereiding van polymeren.
US5057593A (en) *	1990-06-11	1991-10-15	E. I. Du Pont De Nemours And Company	Free radical copolymerization of ethylene and CO with acetone
WO1992007019A1 (fr) *	1990-10-10	1992-04-30	Akzo N.V.	Copolymere de monoxyde de carbone et de propylene ainsi que son procede de formation
US5270441A (en) *	1990-10-10	1993-12-14	Akzo Nv	Copolymer of carbon monoxide and propylene produced in water/ketone solvent
US5218084A (en) *	1990-12-11	1993-06-08	Shell Oil Company	Polymerization of carbon monoxide/propylene with aromatic amine
GB9114488D0 (en) *	1991-07-04	1991-08-21	British Petroleum Co Plc	Process for preparing polyketones
ZA953387B (en) *	1994-04-29	1995-11-29	Shell Int Research	Catalyst system and process for the preparation of copolymers of carbon monoxide and olefinically unsaturated compounds
DE19846053A1 (de) *	1998-10-07	2000-04-13	Basf Ag	Verfahren zur Herstellung von linearen, alternierenden Kohlenmonoxidcopolymeren
WO2000029462A1 (fr) *	1998-11-16	2000-05-25	Shell Internationale Research Maatschappij B.V.	Procede de preparation de polymeres de polycetone
CA2447769C (fr)	2001-06-13	2011-07-26	Energy & Environmental International, L.C.	Reacteurs de polymerisation en masse et procedes de polymerisation
KR101145176B1 (ko) *	2011-06-16	2012-05-14	아주대학교산학협력단	일산화탄소/올레핀 공중합 촉매 및 이를 이용한 현탁 중합

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US2495286A (en) *	1949-06-08	1950-01-24	Du Pont	Interpolymers of carbon monoxide and method for preparing the same
US3083184A (en) *	1960-08-25	1963-03-26	Union Carbide Corp	Interpolymerization of carbon monoxide and alpha-monoolefins
GB1081304A (en) *	1965-03-23	1967-08-31	Ici Ltd	Improvements in or relating to chemical compounds
US3689460A (en) *	1971-03-04	1972-09-05	Shell Oil Co	Interpolymers of carbon monoxide and process for preparing same
US3694412A (en) *	1971-03-04	1972-09-26	Shell Oil Co	Process for preparing interpolymers of carbon monoxide in the presence of aryl phosphine-palladium halide complex
US3780140A (en) *	1971-08-06	1973-12-18	Du Pont	Ethylene/carbon monoxide polymer compositions
US4137382A (en) *	1977-09-12	1979-01-30	National Distillers And Chemical Corporation	Process for copolymerizing ethylene, vinyl acetate and carbon monoxide to provide copolymers of reduced melt flow rate
EP0121965B1 (fr) *	1983-04-06	1989-12-27	Shell Internationale Researchmaatschappij B.V.	Procédé pour la préparation de polycétones
NL8403035A (nl) *	1984-10-05	1986-05-01	Shell Int Research	Werkwijze ter bereiding van polyketonen.
IN167917B (fr) *	1985-11-14	1991-01-05	Shell Int Research
US4810774A (en) *	1986-06-24	1989-03-07	Shell Oil Company	Catalytic copolymerization of CO/olefin with ketone additive.
IN171627B (fr) *	1986-08-26	1992-11-28	Shell Int Research

1987
- 1987-07-30 NL NL8701799A patent/NL8701799A/nl not_active Application Discontinuation
1988
- 1988-07-26 EP EP88201617A patent/EP0301664A3/fr not_active Withdrawn
- 1988-07-28 AU AU20120/88A patent/AU606975B2/en not_active Ceased
- 1988-07-28 JP JP63189540A patent/JPS6462326A/ja active Pending
- 1988-07-29 US US07/225,996 patent/US4877860A/en not_active Expired - Lifetime

Also Published As

Publication number	Publication date
EP0301664A3 (fr)	1989-05-17
JPS6462326A (en)	1989-03-08
EP0301664A2 (fr)	1989-02-01
AU2012088A (en)	1989-02-02
AU606975B2 (en)	1991-02-21
US4877860A (en)	1989-10-31

Legal Events

Date	Code	Title	Description
1989-08-01	BI	The patent application has been withdrawn

Publication	Publication Date	Title
EP0257663B1 (fr)	1992-01-15	Compositions de catalyseur, procédé de copolymérisation d'oléfines-monoxyde de carbone et composés de bisphosphine
NL8602164A (nl)	1988-03-16	Katalysatorcomposities.
EP0296687B1 (fr)	1994-02-02	Compositions de catalyseur
CA1315460C (fr)	1993-03-30	Preparation de copolymeres olefine-co
EP0272727A2 (fr)	1988-06-29	Polymères de monoxyde de carbone et de composés éthyléniquement insaturés en alpha
CA1338576C (fr)	1996-09-03	Preparation de polymere polycetonique
US5340787A (en)	1994-08-23	Polymerization process
US4877860A (en)	1989-10-31	Catalytic copolymerization of carbon monoxide/olefin with ketone/alcohol diluent
US5247064A (en)	1993-09-21	Polymerization of co/olefin with p bidentate ligand
US4940774A (en)	1990-07-10	Carbon monoxide/olefin polymerization with diluent comprising aprotic solvent and water
US5091507A (en)	1992-02-25	Polymerization of carbon monoxide/olefin with polyalkoxyalkane
EP0460743A2 (fr)	1991-12-11	Préparation de polymères à base de monoxyde de carbone et de composés oléfiniquement non-saturés
EP0508502B1 (fr)	1996-07-24	Compositions de catalyseur
US5227464A (en)	1993-07-13	Gas phase polymerization of co/olefin with particular catalyst support
US5350725A (en)	1994-09-27	Polymerization process
US5095091A (en)	1992-03-10	Polymerization of co/olefin with two distinct temperatures
EP0443687A2 (fr)	1991-08-28	Procédé de préparation de polymères à base d'oxyde de carbone et d'un ou de plusieurs composés oléfiniquement non-saturés
US5066778A (en)	1991-11-19	Carbon monoxide/cyclopenten copolymer and preparation with aromatic dinitro compound
EP0322018A2 (fr)	1989-06-28	Préparation de polycétones
US5229475A (en)	1993-07-20	Co/olefin polymerization with carboxylic acid or phenol
EP0361584B1 (fr)	1993-12-22	Préparation de polycétons
US5091506A (en)	1992-02-25	Polymerization of carbon monoxide/norbornene with p bidentate ligand
JP2771223B2 (ja)	1998-07-02	一酸化炭素とエテンとのポリマー
US5723572A (en)	1998-03-03	Process for the preparation of a linear alternating copolymer of carbon monoxide with ethene and another olefinically unsaturated compound
NL8702879A (nl)	1989-07-03	Katalysatorcomposities.