NL8902934A - Bereiding van polymeren. - Google Patents
Bereiding van polymeren. Download PDFInfo
- Publication number
- NL8902934A NL8902934A NL8902934A NL8902934A NL8902934A NL 8902934 A NL8902934 A NL 8902934A NL 8902934 A NL8902934 A NL 8902934A NL 8902934 A NL8902934 A NL 8902934A NL 8902934 A NL8902934 A NL 8902934A
- Authority
- NL
- Netherlands
- Prior art keywords
- process according
- viii metal
- group viii
- polymers
- catalyst
- Prior art date
Links
- 229920000642 polymer Polymers 0.000 title claims abstract description 83
- 238000002360 preparation method Methods 0.000 title claims abstract description 23
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 54
- 239000003054 catalyst Substances 0.000 claims abstract description 43
- 238000000034 method Methods 0.000 claims abstract description 40
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims abstract description 31
- 229910002091 carbon monoxide Inorganic materials 0.000 claims abstract description 31
- 150000001875 compounds Chemical class 0.000 claims abstract description 23
- 239000003085 diluting agent Substances 0.000 claims abstract description 20
- 239000000178 monomer Substances 0.000 claims abstract description 7
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 36
- 229910052751 metal Inorganic materials 0.000 claims description 30
- 239000002184 metal Substances 0.000 claims description 30
- 229910052763 palladium Inorganic materials 0.000 claims description 18
- 239000003446 ligand Substances 0.000 claims description 14
- 229910052698 phosphorus Inorganic materials 0.000 claims description 13
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 12
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 11
- 239000011574 phosphorus Substances 0.000 claims description 11
- 239000002253 acid Substances 0.000 claims description 10
- 150000001450 anions Chemical class 0.000 claims description 9
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 8
- 239000005977 Ethylene Substances 0.000 claims description 8
- DTQVDTLACAAQTR-UHFFFAOYSA-N Trifluoroacetic acid Chemical compound OC(=O)C(F)(F)F DTQVDTLACAAQTR-UHFFFAOYSA-N 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 7
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 6
- 229910052757 nitrogen Inorganic materials 0.000 claims description 6
- 229910052717 sulfur Inorganic materials 0.000 claims description 6
- 239000011593 sulfur Substances 0.000 claims description 6
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 5
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 5
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 claims description 4
- FRASJONUBLZVQX-UHFFFAOYSA-N 1,4-naphthoquinone Chemical compound C1=CC=C2C(=O)C=CC(=O)C2=C1 FRASJONUBLZVQX-UHFFFAOYSA-N 0.000 claims description 4
- SXXPTCXIFIOPQF-UHFFFAOYSA-N 3-bis(2-methoxyphenyl)phosphanylpropyl-bis(2-methoxyphenyl)phosphane Chemical compound COC1=CC=CC=C1P(C=1C(=CC=CC=1)OC)CCCP(C=1C(=CC=CC=1)OC)C1=CC=CC=C1OC SXXPTCXIFIOPQF-UHFFFAOYSA-N 0.000 claims description 4
- 150000002430 hydrocarbons Chemical group 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- 229940005561 1,4-benzoquinone Drugs 0.000 claims description 2
- 125000002029 aromatic hydrocarbon group Chemical group 0.000 claims description 2
- 150000003977 halocarboxylic acids Chemical class 0.000 claims description 2
- 229930195733 hydrocarbon Natural products 0.000 claims description 2
- 125000004437 phosphorous atom Chemical group 0.000 claims description 2
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 claims description 2
- 229930195735 unsaturated hydrocarbon Natural products 0.000 claims description 2
- 239000002002 slurry Substances 0.000 claims 8
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims 1
- 239000000725 suspension Substances 0.000 abstract description 9
- 238000003756 stirring Methods 0.000 abstract description 6
- 229920001897 terpolymer Polymers 0.000 description 26
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 9
- 238000011835 investigation Methods 0.000 description 5
- 238000012545 processing Methods 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- LPIQUOYDBNQMRZ-UHFFFAOYSA-N cyclopentene Chemical compound C1CC=CC1 LPIQUOYDBNQMRZ-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000012634 fragment Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- YJVFFLUZDVXJQI-UHFFFAOYSA-L palladium(ii) acetate Chemical compound [Pd+2].CC([O-])=O.CC([O-])=O YJVFFLUZDVXJQI-UHFFFAOYSA-L 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- 229910052723 transition metal Inorganic materials 0.000 description 2
- -1 transition metal salt Chemical class 0.000 description 2
- CIYDRAJJTMIKGP-UHFFFAOYSA-N 1,1-bis(ethylsulfanyl)ethane Chemical compound CCSC(C)SCC CIYDRAJJTMIKGP-UHFFFAOYSA-N 0.000 description 1
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 1
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 1
- HXVJDHROZFWXHT-UHFFFAOYSA-N 2-diphenylphosphanylbenzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 HXVJDHROZFWXHT-UHFFFAOYSA-N 0.000 description 1
- XSGPGVXRRDQPDJ-UHFFFAOYSA-N 3-diphenylphosphanylpropane-1-sulfonic acid Chemical compound C=1C=CC=CC=1P(CCCS(=O)(=O)O)C1=CC=CC=C1 XSGPGVXRRDQPDJ-UHFFFAOYSA-N 0.000 description 1
- ROFVEXUMMXZLPA-UHFFFAOYSA-N Bipyridyl Chemical compound N1=CC=CC=C1C1=CC=CC=N1 ROFVEXUMMXZLPA-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 238000005481 NMR spectroscopy Methods 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- RZVCNFNSLCXUMM-QXMHVHEDSA-N [(z)-2-benzylsulfanylethenyl]sulfanylmethylbenzene Chemical group C=1C=CC=CC=1CS\C=C/SCC1=CC=CC=C1 RZVCNFNSLCXUMM-QXMHVHEDSA-N 0.000 description 1
- DGEZNRSVGBDHLK-UHFFFAOYSA-N [1,10]phenanthroline Chemical compound C1=CN=C2C3=NC=CC=C3C=CC2=C1 DGEZNRSVGBDHLK-UHFFFAOYSA-N 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 150000002505 iron Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- JFNLZVQOOSMTJK-KNVOCYPGSA-N norbornene Chemical compound C1[C@@H]2CC[C@H]1C=C2 JFNLZVQOOSMTJK-KNVOCYPGSA-N 0.000 description 1
- 229910052762 osmium Inorganic materials 0.000 description 1
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 1
- PBDBXAQKXCXZCJ-UHFFFAOYSA-L palladium(2+);2,2,2-trifluoroacetate Chemical compound [Pd+2].[O-]C(=O)C(F)(F)F.[O-]C(=O)C(F)(F)F PBDBXAQKXCXZCJ-UHFFFAOYSA-L 0.000 description 1
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000012958 reprocessing Methods 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 238000013022 venting Methods 0.000 description 1
- 238000010626 work up procedure Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G67/00—Macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing oxygen or oxygen and carbon, not provided for in groups C08G2/00 - C08G65/00
- C08G67/02—Copolymers of carbon monoxide and aliphatic unsaturated compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyethers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Graft Or Block Polymers (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Priority Applications (14)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL8902934A NL8902934A (nl) | 1989-11-28 | 1989-11-28 | Bereiding van polymeren. |
| KR1019900019113A KR100206456B1 (ko) | 1989-11-28 | 1990-11-24 | 중합체 제조방법 |
| ZA909469A ZA909469B (en) | 1989-11-28 | 1990-11-26 | Process for the preparation of polymers |
| NO90905105A NO905105L (no) | 1989-11-28 | 1990-11-26 | Fremgangsmaate for fremstilling av polymerer. |
| AU66985/90A AU631699B2 (en) | 1989-11-28 | 1990-11-26 | Process for the preparation of polymers |
| JP2322249A JP2963533B2 (ja) | 1989-11-28 | 1990-11-26 | ポリマーの調整方法 |
| CA002030896A CA2030896A1 (en) | 1989-11-28 | 1990-11-26 | Process for the preparation of polymers |
| BR909005972A BR9005972A (pt) | 1989-11-28 | 1990-11-26 | Processo para a preparacao de polimeros,polimeros e objetos moldados |
| AT90203139T ATE149537T1 (de) | 1989-11-28 | 1990-11-27 | Verfahren zur herstellung von polyketonpolymeren |
| DE69030075T DE69030075T2 (de) | 1989-11-28 | 1990-11-27 | Verfahren zur Herstellung von Polyketonpolymeren |
| ES90203139T ES2098245T3 (es) | 1989-11-28 | 1990-11-27 | Procedimiento para la preparacion de polimeros de policetona. |
| CN90109444A CN1029556C (zh) | 1989-11-28 | 1990-11-27 | 制备聚合物的方法 |
| EP90203139A EP0440997B1 (de) | 1989-11-28 | 1990-11-27 | Verfahren zur Herstellung von Polyketonpolymeren |
| US07/676,159 US5145947A (en) | 1989-11-28 | 1991-03-27 | Copolymerization of co/olefin by transmitting power to polymer slurry |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL8902934A NL8902934A (nl) | 1989-11-28 | 1989-11-28 | Bereiding van polymeren. |
| NL8902934 | 1989-11-28 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| NL8902934A true NL8902934A (nl) | 1991-06-17 |
Family
ID=19855707
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NL8902934A NL8902934A (nl) | 1989-11-28 | 1989-11-28 | Bereiding van polymeren. |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US5145947A (de) |
| EP (1) | EP0440997B1 (de) |
| JP (1) | JP2963533B2 (de) |
| KR (1) | KR100206456B1 (de) |
| CN (1) | CN1029556C (de) |
| AT (1) | ATE149537T1 (de) |
| AU (1) | AU631699B2 (de) |
| BR (1) | BR9005972A (de) |
| CA (1) | CA2030896A1 (de) |
| DE (1) | DE69030075T2 (de) |
| ES (1) | ES2098245T3 (de) |
| NL (1) | NL8902934A (de) |
| NO (1) | NO905105L (de) |
| ZA (1) | ZA909469B (de) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5247064A (en) * | 1991-08-06 | 1993-09-21 | Shell Oil Company | Polymerization of co/olefin with p bidentate ligand |
| EP0646147A1 (de) * | 1992-06-15 | 1995-04-05 | Akzo Nobel N.V. | Verbessertes gasphasenverfahren zur herstellung von polyketonen |
| EP0702046B1 (de) * | 1994-09-15 | 2000-05-24 | Shell Internationale Researchmaatschappij B.V. | Verfahren zur Copolymerisation von Kohlenmonoxid mit einer olefinisch ungesättigten Verbindung |
| EP0733663B1 (de) * | 1995-03-22 | 1999-12-22 | Shell Internationale Researchmaatschappij B.V. | Verfahren zur Copolymerisation von Kohlenmonoxid mit olefinisch ungesättigten Verbindungen |
| EP0733660B1 (de) * | 1995-03-22 | 1999-12-22 | Shell Internationale Researchmaatschappij B.V. | Verfahren zur Copolymerisation von Kohlenmonoxid mit olefinisch ungesättigten Verbindungen |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3694412A (en) * | 1971-03-04 | 1972-09-26 | Shell Oil Co | Process for preparing interpolymers of carbon monoxide in the presence of aryl phosphine-palladium halide complex |
| EP0121965B1 (de) * | 1983-04-06 | 1989-12-27 | Shell Internationale Researchmaatschappij B.V. | Verfahren zur Herstellung von Polyketonen |
| NL8403035A (nl) * | 1984-10-05 | 1986-05-01 | Shell Int Research | Werkwijze ter bereiding van polyketonen. |
| IN166314B (de) * | 1985-08-29 | 1990-04-07 | Shell Int Research | |
| IE60363B1 (en) * | 1986-05-27 | 1994-07-13 | Shell Int Research | Process for the preparation of polymers |
| CA1338576C (en) * | 1988-02-10 | 1996-09-03 | Maarten Marinus Geuze | Polyketone polymer preparation |
| CA1338577C (en) * | 1988-04-27 | 1996-09-03 | Jacobus Adrianus Bakkum | Process for the preparation of polymers of carbon monoxide with unsaturated compounds |
| CA1338578C (en) * | 1988-04-29 | 1996-09-03 | Gerrit Gerardus Rosenbrand | Process for the preparation of polymers of carbon monoxide with unsaturated compounds |
| US5010171A (en) * | 1988-09-22 | 1991-04-23 | Shell Oil Company | Carbon monoxide/olefin polymerization with catalyst comprising p. bidentate ligand having non-hydrocarbyl substituent |
| NL8802391A (nl) * | 1988-09-29 | 1990-04-17 | Shell Int Research | Bereiding van polymeren. |
-
1989
- 1989-11-28 NL NL8902934A patent/NL8902934A/nl not_active Application Discontinuation
-
1990
- 1990-11-24 KR KR1019900019113A patent/KR100206456B1/ko not_active Expired - Fee Related
- 1990-11-26 AU AU66985/90A patent/AU631699B2/en not_active Ceased
- 1990-11-26 JP JP2322249A patent/JP2963533B2/ja not_active Expired - Fee Related
- 1990-11-26 ZA ZA909469A patent/ZA909469B/xx unknown
- 1990-11-26 NO NO90905105A patent/NO905105L/no unknown
- 1990-11-26 CA CA002030896A patent/CA2030896A1/en not_active Abandoned
- 1990-11-26 BR BR909005972A patent/BR9005972A/pt not_active IP Right Cessation
- 1990-11-27 AT AT90203139T patent/ATE149537T1/de not_active IP Right Cessation
- 1990-11-27 CN CN90109444A patent/CN1029556C/zh not_active Expired - Fee Related
- 1990-11-27 ES ES90203139T patent/ES2098245T3/es not_active Expired - Lifetime
- 1990-11-27 DE DE69030075T patent/DE69030075T2/de not_active Expired - Fee Related
- 1990-11-27 EP EP90203139A patent/EP0440997B1/de not_active Expired - Lifetime
-
1991
- 1991-03-27 US US07/676,159 patent/US5145947A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| AU6698590A (en) | 1991-06-06 |
| CN1029556C (zh) | 1995-08-23 |
| CA2030896A1 (en) | 1991-05-29 |
| ATE149537T1 (de) | 1997-03-15 |
| BR9005972A (pt) | 1991-09-24 |
| ES2098245T3 (es) | 1997-05-01 |
| DE69030075D1 (de) | 1997-04-10 |
| NO905105D0 (no) | 1990-11-26 |
| KR910009745A (ko) | 1991-06-28 |
| NO905105L (no) | 1991-05-29 |
| DE69030075T2 (de) | 1997-07-24 |
| CN1052487A (zh) | 1991-06-26 |
| US5145947A (en) | 1992-09-08 |
| EP0440997A2 (de) | 1991-08-14 |
| JPH03181520A (ja) | 1991-08-07 |
| EP0440997A3 (en) | 1992-03-18 |
| EP0440997B1 (de) | 1997-03-05 |
| AU631699B2 (en) | 1992-12-03 |
| ZA909469B (en) | 1991-08-28 |
| KR100206456B1 (ko) | 1999-07-01 |
| JP2963533B2 (ja) | 1999-10-18 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| BI | The patent application has been withdrawn |