NL9400722A - Werkwijze voor de bereiding van metaalsilicaten. - Google Patents

Werkwijze voor de bereiding van metaalsilicaten. Download PDF

Info

Publication number: NL9400722A
Authority: NL; Netherlands
Prior art keywords: catalyst; alkali metal; metal silicate; organic base; mixture
Prior art date: 1993-05-03

Application number

NL9400722A

Other languages

English (en)

Dutch (nl)

Original Assignee

Intevep Sa

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1993-05-03

Filing date

1994-05-02

Publication date

1994-12-01

1994-05-02 Application filed by Intevep Sa filed Critical Intevep Sa

1994-12-01 Publication of NL9400722A publication Critical patent/NL9400722A/nl

Links

238000000034 method Methods 0.000 title claims description 61
229910052914 metal silicate Inorganic materials 0.000 title claims description 49
238000002360 preparation method Methods 0.000 title claims description 14
239000003054 catalyst Substances 0.000 claims description 94
239000000203 mixture Substances 0.000 claims description 67
229910052783 alkali metal Inorganic materials 0.000 claims description 36
239000003795 chemical substances by application Substances 0.000 claims description 36
150000001340 alkali metals Chemical class 0.000 claims description 30
150000007530 organic bases Chemical class 0.000 claims description 28
239000000017 hydrogel Substances 0.000 claims description 26
230000002378 acidificating effect Effects 0.000 claims description 22
230000032683 aging Effects 0.000 claims description 22
238000007493 shaping process Methods 0.000 claims description 22
238000006243 chemical reaction Methods 0.000 claims description 20
229910052710 silicon Inorganic materials 0.000 claims description 20
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 18
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 18
238000010438 heat treatment Methods 0.000 claims description 18
239000010703 silicon Substances 0.000 claims description 18
238000003756 stirring Methods 0.000 claims description 17
239000007864 aqueous solution Substances 0.000 claims description 16
229930195733 hydrocarbon Natural products 0.000 claims description 16
150000002430 hydrocarbons Chemical class 0.000 claims description 16
239000000654 additive Substances 0.000 claims description 15
230000000996 additive effect Effects 0.000 claims description 15
229910052733 gallium Inorganic materials 0.000 claims description 15
GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims description 13
150000003839 salts Chemical class 0.000 claims description 13
-1 alkyl phosphonium salts Chemical class 0.000 claims description 12
239000011651 chromium Substances 0.000 claims description 11
238000000465 moulding Methods 0.000 claims description 11
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 10
230000007935 neutral effect Effects 0.000 claims description 9
239000000377 silicon dioxide Substances 0.000 claims description 9
239000011701 zinc Substances 0.000 claims description 9
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 8
229910052782 aluminium Inorganic materials 0.000 claims description 8
238000005899 aromatization reaction Methods 0.000 claims description 8
229910052804 chromium Inorganic materials 0.000 claims description 8
229910052681 coesite Inorganic materials 0.000 claims description 8
229910052906 cristobalite Inorganic materials 0.000 claims description 8
239000000706 filtrate Substances 0.000 claims description 8
235000012239 silicon dioxide Nutrition 0.000 claims description 8
229910052682 stishovite Inorganic materials 0.000 claims description 8
229910052905 tridymite Inorganic materials 0.000 claims description 8
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 7
150000001768 cations Chemical class 0.000 claims description 6
238000001035 drying Methods 0.000 claims description 6
ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 5
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 5
229910052796 boron Inorganic materials 0.000 claims description 5
239000013078 crystal Substances 0.000 claims description 5
229910052742 iron Inorganic materials 0.000 claims description 5
230000003068 static effect Effects 0.000 claims description 5
238000005406 washing Methods 0.000 claims description 5
229910052725 zinc Inorganic materials 0.000 claims description 5
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 4
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 4
150000003973 alkyl amines Chemical class 0.000 claims description 4
229910002091 carbon monoxide Inorganic materials 0.000 claims description 4
230000018044 dehydration Effects 0.000 claims description 4
238000006297 dehydration reaction Methods 0.000 claims description 4
150000004820 halides Chemical class 0.000 claims description 4
229910052739 hydrogen Inorganic materials 0.000 claims description 4
239000001257 hydrogen Substances 0.000 claims description 4
238000006317 isomerization reaction Methods 0.000 claims description 4
238000006384 oligomerization reaction Methods 0.000 claims description 4
230000000737 periodic effect Effects 0.000 claims description 4
238000006116 polymerization reaction Methods 0.000 claims description 4
238000002407 reforming Methods 0.000 claims description 4
238000007363 ring formation reaction Methods 0.000 claims description 4
DDFHBQSCUXNBSA-UHFFFAOYSA-N 5-(5-carboxythiophen-2-yl)thiophene-2-carboxylic acid Chemical compound S1C(C(=O)O)=CC=C1C1=CC=C(C(O)=O)S1 DDFHBQSCUXNBSA-UHFFFAOYSA-N 0.000 claims description 3
KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 claims description 3
KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims description 3
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 3
125000005210 alkyl ammonium group Chemical group 0.000 claims description 3
125000000217 alkyl group Chemical group 0.000 claims description 3
238000004517 catalytic hydrocracking Methods 0.000 claims description 3
238000006356 dehydrogenation reaction Methods 0.000 claims description 3
229910000040 hydrogen fluoride Inorganic materials 0.000 claims description 3
229910052719 titanium Inorganic materials 0.000 claims description 3
239000010936 titanium Substances 0.000 claims description 3
229910052720 vanadium Inorganic materials 0.000 claims description 3
229910052845 zircon Inorganic materials 0.000 claims description 3
GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 claims description 3
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 2
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Chemical class [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 claims description 2
229910052814 silicon oxide Inorganic materials 0.000 claims description 2
BGQMOFGZRJUORO-UHFFFAOYSA-M tetrapropylammonium bromide Chemical group [Br-].CCC[N+](CCC)(CCC)CCC BGQMOFGZRJUORO-UHFFFAOYSA-M 0.000 claims description 2
LPSKDVINWQNWFE-UHFFFAOYSA-M tetrapropylazanium;hydroxide Chemical group [OH-].CCC[N+](CCC)(CCC)CCC LPSKDVINWQNWFE-UHFFFAOYSA-M 0.000 claims description 2
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical group [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims 1
125000002947 alkylene group Chemical group 0.000 claims 1
235000011114 ammonium hydroxide Nutrition 0.000 claims 1
RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical class O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims 1
150000003376 silicon Chemical class 0.000 claims 1
LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims 1
239000000243 solution Substances 0.000 description 34
239000002184 metal Substances 0.000 description 29
229910052751 metal Inorganic materials 0.000 description 28
150000002739 metals Chemical class 0.000 description 17
229910052784 alkaline earth metal Inorganic materials 0.000 description 13
BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 12
238000005342 ion exchange Methods 0.000 description 11
239000004215 Carbon black (E152) Substances 0.000 description 10
229910052799 carbon Inorganic materials 0.000 description 10
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 10
239000000047 product Substances 0.000 description 10
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 9
ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 8
239000003513 alkali Substances 0.000 description 8
229910004298 SiO 2 Inorganic materials 0.000 description 7
150000001342 alkaline earth metals Chemical class 0.000 description 7
229910000323 aluminium silicate Inorganic materials 0.000 description 7
230000015572 biosynthetic process Effects 0.000 description 7
238000005470 impregnation Methods 0.000 description 7
238000002156 mixing Methods 0.000 description 7
230000001590 oxidative effect Effects 0.000 description 7
238000003786 synthesis reaction Methods 0.000 description 7
239000004809 Teflon Substances 0.000 description 6
229920006362 Teflon® Polymers 0.000 description 6
238000001354 calcination Methods 0.000 description 6
239000006185 dispersion Substances 0.000 description 5
229910001220 stainless steel Inorganic materials 0.000 description 5
239000010935 stainless steel Substances 0.000 description 5
238000000705 flame atomic absorption spectrometry Methods 0.000 description 4
239000000463 material Substances 0.000 description 4
239000001294 propane Substances 0.000 description 4
229910005183 Ga(NO3)3.9H2O Inorganic materials 0.000 description 3
229910021536 Zeolite Inorganic materials 0.000 description 3
230000029936 alkylation Effects 0.000 description 3
238000005804 alkylation reaction Methods 0.000 description 3
239000007900 aqueous suspension Substances 0.000 description 3
238000005336 cracking Methods 0.000 description 3
230000020335 dealkylation Effects 0.000 description 3
238000006900 dealkylation reaction Methods 0.000 description 3
238000005984 hydrogenation reaction Methods 0.000 description 3
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 3
150000004679 hydroxides Chemical class 0.000 description 3
239000000725 suspension Substances 0.000 description 3
238000010555 transalkylation reaction Methods 0.000 description 3
239000010457 zeolite Substances 0.000 description 3
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
239000004110 Zinc silicate Substances 0.000 description 2
230000003197 catalytic effect Effects 0.000 description 2
239000003245 coal Substances 0.000 description 2
ZOIVSVWBENBHNT-UHFFFAOYSA-N dizinc;silicate Chemical compound [Zn+2].[Zn+2].[O-][Si]([O-])([O-])[O-] ZOIVSVWBENBHNT-UHFFFAOYSA-N 0.000 description 2
230000000694 effects Effects 0.000 description 2
239000008240 homogeneous mixture Substances 0.000 description 2
229910052708 sodium Inorganic materials 0.000 description 2
239000011734 sodium Substances 0.000 description 2
GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 2
235000019352 zinc silicate Nutrition 0.000 description 2
241001101998 Galium Species 0.000 description 1
YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
239000003377 acid catalyst Substances 0.000 description 1
238000013019 agitation Methods 0.000 description 1
150000008044 alkali metal hydroxides Chemical class 0.000 description 1
229910001413 alkali metal ion Inorganic materials 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
230000001588 bifunctional effect Effects 0.000 description 1
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
230000018109 developmental process Effects 0.000 description 1
238000001704 evaporation Methods 0.000 description 1
230000008020 evaporation Effects 0.000 description 1
239000004744 fabric Substances 0.000 description 1
239000000499 gel Substances 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
230000004048 modification Effects 0.000 description 1
238000012986 modification Methods 0.000 description 1
150000003003 phosphines Chemical class 0.000 description 1
239000002243 precursor Substances 0.000 description 1
239000000376 reactant Substances 0.000 description 1
238000007670 refining Methods 0.000 description 1
238000009987 spinning Methods 0.000 description 1
239000000126 substance Substances 0.000 description 1
125000005270 trialkylamine group Chemical group 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
- C01B39/12—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the replacing atoms being at least boron atoms
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
- C01B39/065—Galloaluminosilicates; Group IVB- metalloaluminosilicates; Ferroaluminosilicates
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
- C01B39/08—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the aluminium atoms being wholly replaced
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
- C01B39/08—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the aluminium atoms being wholly replaced
- C01B39/082—Gallosilicates
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S423/00—Chemistry of inorganic compounds
- Y10S423/22—MFI, e.g. ZSM-5. silicalite, LZ-241

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
General Life Sciences & Earth Sciences (AREA)
Geology (AREA)
Organic Chemistry (AREA)
Materials Engineering (AREA)
Chemical Kinetics & Catalysis (AREA)
Engineering & Computer Science (AREA)
Inorganic Chemistry (AREA)
Crystallography & Structural Chemistry (AREA)
Catalysts (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Silicates, Zeolites, And Molecular Sieves (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

NL9400722A 1993-05-03 1994-05-02 Werkwijze voor de bereiding van metaalsilicaten. NL9400722A (nl)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US08/055,089 US5354719A (en)	1993-05-03	1993-05-03	Method of manufacturing metallosilicates
US5508993		1993-05-03

Publications (1)

Publication Number	Publication Date
NL9400722A true NL9400722A (nl)	1994-12-01

Family

ID=21995520

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NL9400722A NL9400722A (nl)	1993-05-03	1994-05-02	Werkwijze voor de bereiding van metaalsilicaten.

Country Status (6)

Country	Link
US (1)	US5354719A (fr)
JP (1)	JP2648452B2 (fr)
BE (1)	BE1007474A3 (fr)
BR (1)	BR9401681A (fr)
DE (1)	DE4415403C2 (fr)
NL (1)	NL9400722A (fr)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
EP0655277A1 (fr) *	1993-11-01	1995-05-31	Csir	Catalyseurs d'aluminosilicate amorphe
US5830427A (en) *	1995-08-21	1998-11-03	Uop Llc	Metallochalcogenide microporous compositions having metal-metal bonds
US5618512A (en) *	1995-11-30	1997-04-08	Arco Chemical Technology, L.P.	Niobium-containing zeolites
JPH10328561A (ja) *	1997-06-03	1998-12-15	Honda Motor Co Ltd	耐熱性ｈｃ吸着剤
US6096674A (en) *	1997-06-03	2000-08-01	Honda Giken Kogyo Kabushiki Kaisha	Heat-resistant HC adsorbent
US6790803B2 (en)	2001-08-17	2004-09-14	Intevep, S.A.	Catalytic system for hydroconversion of naphtha
AU2002356941A1 (en) *	2001-11-15	2003-06-10	Pq Holding, Inc.	Method for controlling synthesis conditions during molecular sieve synthesis using combinations of quaternary ammonium hydroxides and halides
US6887457B2 (en)	2002-08-28	2005-05-03	Akzo Nobel N.V.	Process for the preparation of catalysts comprising a pentasil-type zeolite
AU2003264147A1 (en) *	2002-08-29	2004-03-19	Albemarle Netherlands B.V.	Catalyst for the production of light olefins
US20070060780A1 (en) *	2002-08-29	2007-03-15	Dennis Stamires	Catalyst for the production of light olefins
WO2009146954A1 (fr) *	2008-06-06	2009-12-10	Total Petrochemicals Research Feluy	Procédé de production de métallosilicates cristallins
ES2430404B1 (es) *	2012-04-18	2014-09-29	Consejo Superior De Investigaciones Científicas (Csic)	Material ITQ-49, su procedimiento de obtención y su uso
JP6633440B2 (ja) *	2016-03-31	2020-01-22	三菱ケミカル株式会社	アルカン脱水素用触媒及びこれを用いたアルケンの製造方法
CA3260567A1 (fr)	2022-06-29	2024-01-04	W.R. Grace & Co.-Conn.	Procédé fcc utile pour la production de produits pétrochimiques
CN118950007A (zh) *	2024-07-29	2024-11-15	中国石油大学(华东)	一种多孔多金属催化材料的应用

Citations (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
EP0007081A1 (fr) *	1978-07-13	1980-01-23	BASF Aktiengesellschaft	Procédé pour la préparation de silicates de métaux cristallins ayant une structure zéolithique et contenant de l'azote, silicates de métaux préparés selon cette méthode et leur utilisation comme catalyseurs
US4205053A (en) *	1979-02-01	1980-05-27	Mobil Oil Corporation	Manufacture of nitrogenous zeolites
EP0021445A2 (fr) *	1979-06-29	1981-01-07	Montedison S.p.A.	Procédé de préparation de zéolites, zéolites obtenues selon ce procédé et leur utilisation dans la conversion d'hydrocarbures
EP0178687A2 (fr) *	1984-07-13	1986-04-23	Exxon Research And Engineering Company	Préparation de catalyseurs zéolitiques
EP0304852A2 (fr) *	1987-08-26	1989-03-01	BASF Aktiengesellschaft	Préparation non alcaline de gros cristaux de pentasil comme catalyseurs en coquille d oeuf ou massique
FR2688775A1 (fr) *	1992-03-20	1993-09-24	Elf Aquitaine	Zeolithe de type mfi renfermant du vanadium sa synthese et son utilisation comme catalyseur d'oxydation.

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5182090A (en) *	1977-04-04	1993-01-26	Mobil Oil Corp.	Synthesis of large crystal size zsm-5
FR2386483A1 (fr) *	1977-04-04	1978-11-03	Mobil Oil	Synthese de zeolites de type zsm-5 en l'absence de metal alcalin
JPS55129232A (en) *	1979-03-29	1980-10-06	Teijin Yuka Kk	Isomerization of xylenes
EP0063436B1 (fr) *	1981-04-14	1986-12-30	Imperial Chemical Industries Plc	Zéolithes
US4495166A (en) *	1982-07-19	1985-01-22	Mobil Oil Corporation	Synthesis of ZSM-5 utilizing a mixture of quaternary ammonium ions and amines
FR2567868A1 (fr) *	1984-07-20	1986-01-24	Raffinage Cie Francaise	Nouveau procede de synthese de zeolites du type aluminosilicate, produits obtenus par ce procede et utilisation de ces produits
EP0473509A3 (fr) *	1990-08-29	1992-03-18	Rhone-Poulenc Chimie	Procédé de préparation de zéolithes à base de silice et éventuellement d'oxydes d'éléments tétravalents
DE4138155A1 (de) *	1991-11-21	1993-05-27	Basf Ag	Verfahren zur herstellung von im wesentlichen alkalifreien titansilikat-kristallen mit zeolithstruktur

1993
- 1993-05-03 US US08/055,089 patent/US5354719A/en not_active Expired - Lifetime
1994
- 1994-04-28 JP JP6090826A patent/JP2648452B2/ja not_active Expired - Fee Related
- 1994-05-02 BR BR9401681A patent/BR9401681A/pt not_active IP Right Cessation
- 1994-05-02 NL NL9400722A patent/NL9400722A/nl active Search and Examination
- 1994-05-03 BE BE9400452A patent/BE1007474A3/fr not_active IP Right Cessation
- 1994-05-03 DE DE4415403A patent/DE4415403C2/de not_active Expired - Fee Related

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
EP0007081A1 (fr) *	1978-07-13	1980-01-23	BASF Aktiengesellschaft	Procédé pour la préparation de silicates de métaux cristallins ayant une structure zéolithique et contenant de l'azote, silicates de métaux préparés selon cette méthode et leur utilisation comme catalyseurs
US4205053A (en) *	1979-02-01	1980-05-27	Mobil Oil Corporation	Manufacture of nitrogenous zeolites
EP0021445A2 (fr) *	1979-06-29	1981-01-07	Montedison S.p.A.	Procédé de préparation de zéolites, zéolites obtenues selon ce procédé et leur utilisation dans la conversion d'hydrocarbures
EP0178687A2 (fr) *	1984-07-13	1986-04-23	Exxon Research And Engineering Company	Préparation de catalyseurs zéolitiques
EP0304852A2 (fr) *	1987-08-26	1989-03-01	BASF Aktiengesellschaft	Préparation non alcaline de gros cristaux de pentasil comme catalyseurs en coquille d oeuf ou massique
FR2688775A1 (fr) *	1992-03-20	1993-09-24	Elf Aquitaine	Zeolithe de type mfi renfermant du vanadium sa synthese et son utilisation comme catalyseur d'oxydation.

Also Published As

Publication number	Publication date
DE4415403A1 (de)	1994-11-10
BE1007474A3 (fr)	1995-07-11
BR9401681A (pt)	1994-12-27
JPH0789715A (ja)	1995-04-04
US5354719A (en)	1994-10-11
JP2648452B2 (ja)	1997-08-27
DE4415403C2 (de)	2003-10-16

Legal Events

Date	Code	Title
1994-12-01	A1A	A request for search or an international-type search has been filed
1995-04-03	BB	A search report has been drawn up
1995-05-01	BC	A request for examination has been filed
2002-12-02	BN	A decision not to publish the application has become irrevocable

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NO882508L (no)	1988-12-09	Fremgangsmaate for overfoering av ethan til flytende aromatiske hydrocarboner.
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NZ204310A (en)	1986-06-11	Controlled removal of aluminium from crystalline alumino silicate zeolites and disproportionating toluene to benzene and xylene using the zeolites
US4323481A (en)	1982-04-06	Synthesis of molecular sieves using beta-diketones as organic templates
EP0138617A2 (fr)	1985-04-24	Procédé pour l'hydrodéalkylation et/ou l'isomérisation d'hydrocarbures alkylaromatiques