NO120579B - - Google Patents

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Info

Publication number: NO120579B
Authority: NO; Norway
Prior art keywords: catalyst; feed; reaction zone; reaction mixture; reaction
Prior art date: 1966-08-29

Application number

NO169530A

Other languages

English (en)

Norwegian (no)

Inventor

D Carson

W Borst

Original Assignee

Universal Oil Prod Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1966-08-29

Filing date

1967-08-28

Publication date

1970-11-09

1967-08-28 Application filed by Universal Oil Prod Co filed Critical Universal Oil Prod Co

1970-11-09 Publication of NO120579B publication Critical patent/NO120579B/no

Links

238000006243 chemical reaction Methods 0.000 claims description 40
239000003054 catalyst Substances 0.000 claims description 38
229930195733 hydrocarbon Natural products 0.000 claims description 36
150000002430 hydrocarbons Chemical class 0.000 claims description 34
KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 claims description 27
238000005804 alkylation reaction Methods 0.000 claims description 27
238000000034 method Methods 0.000 claims description 25
239000011541 reaction mixture Substances 0.000 claims description 20
239000000203 mixture Substances 0.000 claims description 17
229910000040 hydrogen fluoride Inorganic materials 0.000 claims description 15
NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical group CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 claims description 14
238000004519 manufacturing process Methods 0.000 claims description 8
239000001282 iso-butane Substances 0.000 claims description 7
230000008569 process Effects 0.000 claims description 6
-1 propylene, butylenes Chemical class 0.000 claims description 6
238000001816 cooling Methods 0.000 claims description 5
150000001336 alkenes Chemical class 0.000 claims description 4
239000007788 liquid Substances 0.000 claims description 4
238000011144 upstream manufacturing Methods 0.000 claims description 2
239000004215 Carbon black (E152) Substances 0.000 description 21
239000002253 acid Substances 0.000 description 19
230000029936 alkylation Effects 0.000 description 14
239000000376 reactant Substances 0.000 description 12
239000012071 phase Substances 0.000 description 9
238000000926 separation method Methods 0.000 description 6
238000006116 polymerization reaction Methods 0.000 description 5
239000000047 product Substances 0.000 description 5
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
238000003442 catalytic alkylation reaction Methods 0.000 description 4
230000005484 gravity Effects 0.000 description 4
238000003780 insertion Methods 0.000 description 4
230000037431 insertion Effects 0.000 description 4
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 4
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
230000008901 benefit Effects 0.000 description 3
239000007795 chemical reaction product Substances 0.000 description 3
230000000694 effects Effects 0.000 description 3
239000000446 fuel Substances 0.000 description 3
238000007086 side reaction Methods 0.000 description 3
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical class CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
239000000654 additive Substances 0.000 description 2
150000001338 aliphatic hydrocarbons Chemical class 0.000 description 2
VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
238000009835 boiling Methods 0.000 description 2
WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical compound FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 description 2
IAQRGUVFOMOMEM-UHFFFAOYSA-N but-2-ene Chemical compound CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 2
238000005260 corrosion Methods 0.000 description 2
230000007797 corrosion Effects 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
238000012423 maintenance Methods 0.000 description 2
QPJSUIGXIBEQAC-UHFFFAOYSA-N n-(2,4-dichloro-5-propan-2-yloxyphenyl)acetamide Chemical compound CC(C)OC1=CC(NC(C)=O)=C(Cl)C=C1Cl QPJSUIGXIBEQAC-UHFFFAOYSA-N 0.000 description 2
TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 2
238000005086 pumping Methods 0.000 description 2
230000006903 response to temperature Effects 0.000 description 2
MRMOZBOQVYRSEM-UHFFFAOYSA-N tetraethyllead Chemical compound CC[Pb](CC)(CC)CC MRMOZBOQVYRSEM-UHFFFAOYSA-N 0.000 description 2
125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 2
YUHZIUAREWNXJT-UHFFFAOYSA-N (2-fluoropyridin-3-yl)boronic acid Chemical class OB(O)C1=CC=CN=C1F YUHZIUAREWNXJT-UHFFFAOYSA-N 0.000 description 1
ZGEGCLOFRBLKSE-UHFFFAOYSA-N 1-Heptene Chemical class CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 description 1
229910015900 BF3 Inorganic materials 0.000 description 1
VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 1
239000004480 active ingredient Substances 0.000 description 1
229910000147 aluminium phosphate Inorganic materials 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
230000008859 change Effects 0.000 description 1
230000006835 compression Effects 0.000 description 1
238000007906 compression Methods 0.000 description 1
239000000356 contaminant Substances 0.000 description 1
239000002826 coolant Substances 0.000 description 1
238000011161 development Methods 0.000 description 1
238000010586 diagram Methods 0.000 description 1
238000010790 dilution Methods 0.000 description 1
239000012895 dilution Substances 0.000 description 1
AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 1
XNMQEEKYCVKGBD-UHFFFAOYSA-N dimethylacetylene Natural products CC#CC XNMQEEKYCVKGBD-UHFFFAOYSA-N 0.000 description 1
238000009826 distribution Methods 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
238000000605 extraction Methods 0.000 description 1
238000005194 fractionation Methods 0.000 description 1
125000004836 hexamethylene group Chemical class [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
239000007791 liquid phase Substances 0.000 description 1
239000000463 material Substances 0.000 description 1
239000010705 motor oil Substances 0.000 description 1
238000013021 overheating Methods 0.000 description 1
230000000737 periodic effect Effects 0.000 description 1
238000005504 petroleum refining Methods 0.000 description 1
238000012545 processing Methods 0.000 description 1
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
239000012429 reaction media Substances 0.000 description 1
238000004064 recycling Methods 0.000 description 1
230000009467 reduction Effects 0.000 description 1
238000011160 research Methods 0.000 description 1
239000000126 substance Substances 0.000 description 1
FAQYAMRNWDIXMY-UHFFFAOYSA-N trichloroborane Chemical compound ClB(Cl)Cl FAQYAMRNWDIXMY-UHFFFAOYSA-N 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
- C07C2/56—Addition to acyclic hydrocarbons
- C07C2/58—Catalytic processes
- C07C2/62—Catalytic processes with acids
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- C07C2527/06—Halogens; Compounds thereof
- C07C2527/08—Halides
- C07C2527/12—Fluorides
- C07C2527/1206—Hydrogen fluoride

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

NO169530A 1966-08-29 1967-08-28 NO120579B (fr)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US57575466A	1966-08-29	1966-08-29

Publications (1)

Publication Number	Publication Date
NO120579B true NO120579B (fr)	1970-11-09

Family

ID=24301566

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NO169530A NO120579B (fr)	1966-08-29	1967-08-28

Country Status (14)

Country	Link
AT (1)	AT286949B (fr)
BE (1)	BE702967A (fr)
BG (1)	BG15749A3 (fr)
CH (1)	CH495303A (fr)
DE (1)	DE1668772C3 (fr)
DK (1)	DK135709B (fr)
ES (1)	ES344493A1 (fr)
FI (1)	FI50994C (fr)
GB (1)	GB1188844A (fr)
GR (1)	GR34315B (fr)
NL (1)	NL155249B (fr)
NO (1)	NO120579B (fr)
OA (1)	OA02492A (fr)
SE (1)	SE340616B (fr)

1967
- 1967-08-23 BE BE702967D patent/BE702967A/xx not_active IP Right Cessation
- 1967-08-24 SE SE11854/67A patent/SE340616B/xx unknown
- 1967-08-25 GB GB39235/67A patent/GB1188844A/en not_active Expired
- 1967-08-25 DE DE1668772A patent/DE1668772C3/de not_active Expired
- 1967-08-25 CH CH1192267A patent/CH495303A/de not_active IP Right Cessation
- 1967-08-25 GR GR670134315A patent/GR34315B/el unknown
- 1967-08-25 OA OA53036A patent/OA02492A/fr unknown
- 1967-08-25 AT AT786967A patent/AT286949B/de not_active IP Right Cessation
- 1967-08-26 ES ES344493A patent/ES344493A1/es not_active Expired
- 1967-08-28 DK DK433667AA patent/DK135709B/da unknown
- 1967-08-28 NL NL676711777A patent/NL155249B/xx not_active IP Right Cessation
- 1967-08-28 NO NO169530A patent/NO120579B/no unknown
- 1967-08-29 FI FI672320A patent/FI50994C/fi active
- 1967-11-01 BG BG008819A patent/BG15749A3/bg unknown

Also Published As

Publication number	Publication date
DK135709B (da)	1977-06-13
GB1188844A (en)	1970-04-22
FI50994B (fr)	1976-05-31
FI50994C (fi)	1976-09-10
DE1668772A1 (de)	1972-04-27
ES344493A1 (es)	1968-10-16
BE702967A (fr)	1968-01-15
SE340616B (fr)	1971-11-29
NL6711777A (fr)	1968-03-01
CH495303A (de)	1970-08-31
BG15749A3 (bg)	1976-05-10
NL155249B (nl)	1977-12-15
OA02492A (fr)	1970-05-05
DE1668772C3 (de)	1974-02-07
AT286949B (de)	1970-12-28
GR34315B (el)	1968-04-16
DE1668772B2 (de)	1973-07-05
DK135709C (fr)	1977-11-14

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