NO134122B - - Google Patents

Download PDF

Info

Publication number: NO134122B
Authority: NO; Norway
Prior art keywords: copper; salicyl; aqueous; organic solvent; parts
Prior art date: 1973-08-30

Application number

NO3423/73A

Other languages

English (en)

Norwegian (no)

Other versions

NO342373L (fr

NO134122C (fr

Inventor

N Ackerley

P A Mack

Original Assignee

Ici Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1973-08-30

Filing date

1973-08-30

Publication date

1976-05-10

1973-08-30 Application filed by Ici Ltd filed Critical Ici Ltd

1973-08-30 Priority to NO342373A priority Critical patent/NO134122C/no

1975-03-03 Publication of NO342373L publication Critical patent/NO342373L/no

1976-05-10 Publication of NO134122B publication Critical patent/NO134122B/no

1976-08-18 Publication of NO134122C publication Critical patent/NO134122C/no

Links

RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 30
229910052802 copper Inorganic materials 0.000 claims description 30
239000010949 copper Substances 0.000 claims description 30
239000000243 solution Substances 0.000 claims description 24
239000007864 aqueous solution Substances 0.000 claims description 22
238000000034 method Methods 0.000 claims description 18
239000003960 organic solvent Substances 0.000 claims description 15
239000000203 mixture Substances 0.000 claims description 13
-1 5-nonyl groups Chemical group 0.000 claims description 12
239000008346 aqueous phase Substances 0.000 claims description 10
ORIHZIZPTZTNCU-YVMONPNESA-N salicylaldoxime Chemical compound O\N=C/C1=CC=CC=C1O ORIHZIZPTZTNCU-YVMONPNESA-N 0.000 claims description 10
JZWFDVDETGFGFC-UHFFFAOYSA-N salacetamide Chemical group CC(=O)NC(=O)C1=CC=CC=C1O JZWFDVDETGFGFC-UHFFFAOYSA-N 0.000 claims description 8
125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 7
JRZJOMJEPLMPRA-UHFFFAOYSA-N 1-nonene Chemical compound CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 4
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 4
125000000217 alkyl group Chemical group 0.000 claims description 4
238000009833 condensation Methods 0.000 claims description 3
230000005494 condensation Effects 0.000 claims description 3
125000004432 carbon atom Chemical group C* 0.000 claims description 2
229910052739 hydrogen Inorganic materials 0.000 claims description 2
239000001257 hydrogen Substances 0.000 claims description 2
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
238000000622 liquid--liquid extraction Methods 0.000 claims 1
238000000638 solvent extraction Methods 0.000 claims 1
239000002904 solvent Substances 0.000 description 26
238000000605 extraction Methods 0.000 description 19
229910052751 metal Inorganic materials 0.000 description 15
239000002184 metal Substances 0.000 description 15
150000001875 compounds Chemical class 0.000 description 10
229930195733 hydrocarbon Natural products 0.000 description 9
150000002430 hydrocarbons Chemical class 0.000 description 9
239000004215 Carbon black (E152) Substances 0.000 description 8
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 6
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 6
MJUVQSGLWOGIOB-GHRIWEEISA-N 2-[(E)-hydroxyiminomethyl]-4-nonylphenol Chemical compound [H]\C(=N/O)C1=CC(CCCCCCCCC)=CC=C1O MJUVQSGLWOGIOB-GHRIWEEISA-N 0.000 description 5
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 5
239000003350 kerosene Substances 0.000 description 5
239000003446 ligand Substances 0.000 description 5
IGFHQQFPSIBGKE-UHFFFAOYSA-N 4-nonylphenol Chemical compound CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 4
235000019441 ethanol Nutrition 0.000 description 4
150000002739 metals Chemical class 0.000 description 4
238000000926 separation method Methods 0.000 description 4
UWGTVLYQSJNUFP-SILNSSARSA-N 4-dodecyl-2-[(Z)-hydroxyiminomethyl]phenol Chemical compound [H]\C(=N\O)C1=C(O)C=CC(CCCCCCCCCCCC)=C1 UWGTVLYQSJNUFP-SILNSSARSA-N 0.000 description 3
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
230000015572 biosynthetic process Effects 0.000 description 3
229910017052 cobalt Inorganic materials 0.000 description 3
239000010941 cobalt Substances 0.000 description 3
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 3
150000004699 copper complex Chemical class 0.000 description 3
229910052742 iron Inorganic materials 0.000 description 3
239000007788 liquid Substances 0.000 description 3
238000002156 mixing Methods 0.000 description 3
238000010992 reflux Methods 0.000 description 3
KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 2
SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
WTDHULULXKLSOZ-UHFFFAOYSA-N Hydroxylamine hydrochloride Chemical compound Cl.ON WTDHULULXKLSOZ-UHFFFAOYSA-N 0.000 description 2
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
239000002253 acid Substances 0.000 description 2
239000003795 chemical substances by application Substances 0.000 description 2
ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 2
230000002349 favourable effect Effects 0.000 description 2
230000005484 gravity Effects 0.000 description 2
239000012074 organic phase Substances 0.000 description 2
239000012071 phase Substances 0.000 description 2
238000005191 phase separation Methods 0.000 description 2
SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 description 2
239000000047 product Substances 0.000 description 2
150000003839 salts Chemical class 0.000 description 2
229910052725 zinc Inorganic materials 0.000 description 2
239000011701 zinc Substances 0.000 description 2
FZENGILVLUJGJX-NSCUHMNNSA-N (E)-acetaldehyde oxime Chemical compound C\C=N\O FZENGILVLUJGJX-NSCUHMNNSA-N 0.000 description 1
UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 description 1
XFRVVPUIAFSTFO-UHFFFAOYSA-N 1-Tridecanol Chemical compound CCCCCCCCCCCCCO XFRVVPUIAFSTFO-UHFFFAOYSA-N 0.000 description 1
ORIHZIZPTZTNCU-UHFFFAOYSA-N 2-(hydroxyiminomethyl)phenol Chemical compound ON=CC1=CC=CC=C1O ORIHZIZPTZTNCU-UHFFFAOYSA-N 0.000 description 1
MJUVQSGLWOGIOB-UHFFFAOYSA-N 2-[(Z)-hydroxyiminomethyl]-4-nonylphenol Chemical compound OC1=C(C=N/O)C=C(C=C1)CCCCCCCCC MJUVQSGLWOGIOB-UHFFFAOYSA-N 0.000 description 1
PLLBRTOLHQQAQQ-UHFFFAOYSA-N 8-methylnonan-1-ol Chemical compound CC(C)CCCCCCCO PLLBRTOLHQQAQQ-UHFFFAOYSA-N 0.000 description 1
ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 1
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 description 1
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 1
241000609103 Sarcophaga africa Species 0.000 description 1
VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
239000013543 active substance Substances 0.000 description 1
238000013019 agitation Methods 0.000 description 1
150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
239000003513 alkali Substances 0.000 description 1
230000029936 alkylation Effects 0.000 description 1
238000005804 alkylation reaction Methods 0.000 description 1
QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
239000001099 ammonium carbonate Substances 0.000 description 1
235000012501 ammonium carbonate Nutrition 0.000 description 1
239000011260 aqueous acid Substances 0.000 description 1
150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
125000004429 atom Chemical group 0.000 description 1
238000001311 chemical methods and process Methods 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
239000013065 commercial product Substances 0.000 description 1
238000010668 complexation reaction Methods 0.000 description 1
239000012141 concentrate Substances 0.000 description 1
230000003750 conditioning effect Effects 0.000 description 1
150000004696 coordination complex Chemical class 0.000 description 1
150000001879 copper Chemical class 0.000 description 1
229910000365 copper sulfate Inorganic materials 0.000 description 1
230000001627 detrimental effect Effects 0.000 description 1
238000004821 distillation Methods 0.000 description 1
125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
239000000839 emulsion Substances 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
150000002170 ethers Chemical class 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
239000000706 filtrate Substances 0.000 description 1
125000002485 formyl group Chemical group [H]C(*)=O 0.000 description 1
150000008282 halocarbons Chemical class 0.000 description 1
238000005984 hydrogenation reaction Methods 0.000 description 1
125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
238000002329 infrared spectrum Methods 0.000 description 1
229910052500 inorganic mineral Inorganic materials 0.000 description 1
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
239000011707 mineral Substances 0.000 description 1
125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
229910052759 nickel Inorganic materials 0.000 description 1
229910017604 nitric acid Inorganic materials 0.000 description 1
150000002989 phenols Chemical class 0.000 description 1
235000011056 potassium acetate Nutrition 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
230000001737 promoting effect Effects 0.000 description 1
239000011541 reaction mixture Substances 0.000 description 1
238000011084 recovery Methods 0.000 description 1
230000009467 reduction Effects 0.000 description 1
230000008929 regeneration Effects 0.000 description 1
238000011069 regeneration method Methods 0.000 description 1
239000003923 scrap metal Substances 0.000 description 1
239000001632 sodium acetate Substances 0.000 description 1
235000017281 sodium acetate Nutrition 0.000 description 1
238000003756 stirring Methods 0.000 description 1
150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
239000006188 syrup Substances 0.000 description 1
235000020357 syrup Nutrition 0.000 description 1
125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
229950011008 tetrachloroethylene Drugs 0.000 description 1
230000007704 transition Effects 0.000 description 1
UBOXGVDOUJQMTN-UHFFFAOYSA-N trichloroethylene Natural products ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 description 1
229940087291 tridecyl alcohol Drugs 0.000 description 1
239000002699 waste material Substances 0.000 description 1

Landscapes

Extraction Or Liquid Replacement (AREA)
Manufacture And Refinement Of Metals (AREA)

NO342373A 1973-08-30 1973-08-30 NO134122C (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
NO342373A NO134122C (fr)	1973-08-30	1973-08-30

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
NO342373A NO134122C (fr)	1973-08-30	1973-08-30

Publications (3)

Publication Number	Publication Date
NO342373L NO342373L (fr)	1975-03-03
NO134122B true NO134122B (fr)	1976-05-10
NO134122C NO134122C (fr)	1976-08-18

Family

ID=19879604

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NO342373A NO134122C (fr)	1973-08-30	1973-08-30

Country Status (1)

Country	Link
NO (1)	NO134122C (fr)

1973
- 1973-08-30 NO NO342373A patent/NO134122C/no unknown

Also Published As

Publication number	Publication date
NO342373L (fr)	1975-03-03
NO134122C (fr)	1976-08-18

Publication	Publication Date	Title
US4020106A (en)	1977-04-26	Metal extraction process
US4142952A (en)	1979-03-06	Copper extraction with salicylaldoxime-p-nonylphenol mixtures
US3428449A (en)	1969-02-18	Extraction of copper from acidic liquors with a phenolic oxime
CA1056855A (fr)	1979-06-19	5-heptyl-2-hydroxybenzaldoximes
NO171319B (no)	1992-11-16	Middel, fremgangsmaate og opploesning for ekstraksjon av metaller fra vandige loesninger av metallsalter
US4563256A (en)	1986-01-07	Solvent extraction process for recovery of zinc
NO146227B (no)	1982-05-18	Aerosolinhaleringsanordning.
FI97395C (fi)	1996-12-10	Nikkelin uutosprosessi
CA2400673A1 (fr)	2001-08-23	Procede de recuperation de metaux provenant de minerais charges en metaux
AU710560B2 (en)	1999-09-23	Copper recovery process
US3981968A (en)	1976-09-21	Solvent extraction of nickel from ammoniacal solutions
CA1111825A (fr)	1981-11-03	Regeneration de produits d'extraction organiques renfermant des alpha-hydroxyoximes
JPH06509845A (ja)	1994-11-02	銅の回収方法
FI60702B (fi)	1981-11-30	Blandning av 5-nonyl-2-hydroxibensaldoximer anvaendbar foer extraktion av koppar
US3703573A (en)	1972-11-21	Process for extracting copper,cobalt and nickel values from aqueous solution
WO2020211757A1 (fr)	2020-10-22	Procédé de récupération de cuivre à partir d'une solution contenant un agent d'extraction à base d'acide phosphorique
US4587111A (en)	1986-05-06	Method of liquid-liquid extraction of gallium from a basic aqueous solution
US4194905A (en)	1980-03-25	Solvent-extraction process for recovery and separation of metal values
Kekesi	2007	Gallium extraction from synthetic Bayer liquors using Kelex 100-kerosene, the effect of loading and stripping conditions on selectivity
NO134122B (fr)	1976-05-10
SU648123A3 (ru)	1979-02-15	Способ экстракции меди
Rickelton	1998	The removal of cadmium impurities from cobalt–nickel solutions by precipitation with sodium diisobutyldithiophosphinate
CA1061574A (fr)	1979-09-04	Recuperation des metaux au moyen d'un solvant derive de la quinoline
US3796787A (en)	1974-03-12	Metal extraction process
RU2699142C1 (ru)	2019-09-03	Способ извлечения серебра из солянокислых растворов