NO20023228L - Aktivering av hydrokarbonsyntesekatalysator med hydrogen og ammoniakk - Google Patents

Aktivering av hydrokarbonsyntesekatalysator med hydrogen og ammoniakk Download PDF

Info

Publication number: NO20023228L
Authority: NO; Norway
Prior art keywords: catalyst; reducing gas; ammonia; hydrogen; hydrocarbon synthesis
Prior art date: 2000-01-04

Application number

NO20023228A

Other languages

English (en)

Norwegian (no)

Other versions

NO20023228D0 (no

Inventor

Albert L Vovich Lapidus

Alla Jurievna Krylova

Original Assignee

Exxonmobil Res & Eng Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2000-01-04

Filing date

2002-07-03

Publication date

2002-08-28

2002-07-03 Application filed by Exxonmobil Res & Eng Co filed Critical Exxonmobil Res & Eng Co

2002-07-03 Publication of NO20023228D0 publication Critical patent/NO20023228D0/no

2002-08-28 Publication of NO20023228L publication Critical patent/NO20023228L/no

Links

QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 title claims description 140
239000003054 catalyst Substances 0.000 title claims description 114
230000015572 biosynthetic process Effects 0.000 title claims description 81
238000003786 synthesis reaction Methods 0.000 title claims description 81
229930195733 hydrocarbon Natural products 0.000 title claims description 72
150000002430 hydrocarbons Chemical class 0.000 title claims description 72
239000001257 hydrogen Substances 0.000 title claims description 56
229910052739 hydrogen Inorganic materials 0.000 title claims description 56
239000004215 Carbon black (E152) Substances 0.000 title claims description 53
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims description 50
229910021529 ammonia Inorganic materials 0.000 title claims description 34
230000004913 activation Effects 0.000 title description 8
239000007789 gas Substances 0.000 claims description 94
238000000034 method Methods 0.000 claims description 59
239000000203 mixture Substances 0.000 claims description 46
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 30
239000002243 precursor Substances 0.000 claims description 30
229910052751 metal Inorganic materials 0.000 claims description 27
239000002184 metal Substances 0.000 claims description 27
230000003197 catalytic effect Effects 0.000 claims description 21
230000008569 process Effects 0.000 claims description 20
239000012018 catalyst precursor Substances 0.000 claims description 15
238000006243 chemical reaction Methods 0.000 claims description 13
239000002002 slurry Substances 0.000 claims description 12
239000007788 liquid Substances 0.000 claims description 10
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 8
229910044991 metal oxide Inorganic materials 0.000 claims description 8
150000004706 metal oxides Chemical class 0.000 claims description 8
239000000377 silicon dioxide Substances 0.000 claims description 7
239000007787 solid Substances 0.000 claims description 6
229910052707 ruthenium Inorganic materials 0.000 claims description 5
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 4
229910000323 aluminium silicate Inorganic materials 0.000 claims description 3
229910002091 carbon monoxide Inorganic materials 0.000 claims description 3
238000005194 fractionation Methods 0.000 claims description 3
230000009467 reduction Effects 0.000 description 43
229910000069 nitrogen hydride Inorganic materials 0.000 description 36
239000000047 product Substances 0.000 description 17
239000008188 pellet Substances 0.000 description 16
239000010453 quartz Substances 0.000 description 15
239000000243 solution Substances 0.000 description 14
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 12
238000001354 calcination Methods 0.000 description 9
239000002131 composite material Substances 0.000 description 9
238000001994 activation Methods 0.000 description 8
229910017052 cobalt Inorganic materials 0.000 description 8
239000010941 cobalt Substances 0.000 description 8
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 8
150000002431 hydrogen Chemical class 0.000 description 7
238000012360 testing method Methods 0.000 description 7
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
239000012263 liquid product Substances 0.000 description 6
239000002245 particle Substances 0.000 description 6
230000000694 effects Effects 0.000 description 5
239000003921 oil Substances 0.000 description 5
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
239000000356 contaminant Substances 0.000 description 4
239000012535 impurity Substances 0.000 description 4
238000002360 preparation method Methods 0.000 description 4
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
150000001875 compounds Chemical class 0.000 description 3
230000003247 decreasing effect Effects 0.000 description 3
239000000446 fuel Substances 0.000 description 3
239000011491 glass wool Substances 0.000 description 3
238000004519 manufacturing process Methods 0.000 description 3
239000000463 material Substances 0.000 description 3
OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 3
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
229910002651 NO3 Inorganic materials 0.000 description 2
150000001336 alkenes Chemical class 0.000 description 2
229910052786 argon Inorganic materials 0.000 description 2
235000011089 carbon dioxide Nutrition 0.000 description 2
230000008021 deposition Effects 0.000 description 2
238000009826 distribution Methods 0.000 description 2
239000012530 fluid Substances 0.000 description 2
238000004817 gas chromatography Methods 0.000 description 2
238000005470 impregnation Methods 0.000 description 2
238000005342 ion exchange Methods 0.000 description 2
229910052742 iron Inorganic materials 0.000 description 2
229940057995 liquid paraffin Drugs 0.000 description 2
-1 methanol Chemical class 0.000 description 2
229910052759 nickel Inorganic materials 0.000 description 2
230000003647 oxidation Effects 0.000 description 2
238000007254 oxidation reaction Methods 0.000 description 2
238000012545 processing Methods 0.000 description 2
239000003870 refractory metal Substances 0.000 description 2
238000005303 weighing Methods 0.000 description 2
239000010457 zeolite Substances 0.000 description 2
229910052726 zirconium Inorganic materials 0.000 description 2
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
229910052776 Thorium Inorganic materials 0.000 description 1
229910052770 Uranium Inorganic materials 0.000 description 1
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
150000001299 aldehydes Chemical class 0.000 description 1
239000011959 amorphous silica alumina Substances 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
238000004523 catalytic cracking Methods 0.000 description 1
238000004517 catalytic hydrocracking Methods 0.000 description 1
238000006555 catalytic reaction Methods 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
238000000975 co-precipitation Methods 0.000 description 1
229910000428 cobalt oxide Inorganic materials 0.000 description 1
IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 1
238000001816 cooling Methods 0.000 description 1
239000010779 crude oil Substances 0.000 description 1
238000007865 diluting Methods 0.000 description 1
238000010790 dilution Methods 0.000 description 1
239000012895 dilution Substances 0.000 description 1
239000012153 distilled water Substances 0.000 description 1
238000005553 drilling Methods 0.000 description 1
238000001035 drying Methods 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
230000003203 everyday effect Effects 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
229910052735 hafnium Inorganic materials 0.000 description 1
238000011065 in-situ storage Methods 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
239000003350 kerosene Substances 0.000 description 1
150000002576 ketones Chemical class 0.000 description 1
238000004898 kneading Methods 0.000 description 1
229910052746 lanthanum Inorganic materials 0.000 description 1
239000007791 liquid phase Substances 0.000 description 1
230000001050 lubricating effect Effects 0.000 description 1
239000010687 lubricating oil Substances 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
150000002736 metal compounds Chemical class 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
238000005555 metalworking Methods 0.000 description 1
238000002156 mixing Methods 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
239000010705 motor oil Substances 0.000 description 1
150000002823 nitrates Chemical class 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
150000007524 organic acids Chemical class 0.000 description 1
235000005985 organic acids Nutrition 0.000 description 1
230000033116 oxidation-reduction process Effects 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
230000000737 periodic effect Effects 0.000 description 1
239000012071 phase Substances 0.000 description 1
239000002574 poison Substances 0.000 description 1
231100000614 poison Toxicity 0.000 description 1
238000001556 precipitation Methods 0.000 description 1
239000000376 reactant Substances 0.000 description 1
229910052702 rhenium Inorganic materials 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
239000000741 silica gel Substances 0.000 description 1
229910002027 silica gel Inorganic materials 0.000 description 1
238000002791 soaking Methods 0.000 description 1
239000002904 solvent Substances 0.000 description 1
238000004230 steam cracking Methods 0.000 description 1
238000003756 stirring Methods 0.000 description 1
239000000126 substance Substances 0.000 description 1
238000012546 transfer Methods 0.000 description 1
239000001993 wax Substances 0.000 description 1
229910001928 zirconium oxide Inorganic materials 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
- C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/75—Cobalt
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/16—Reducing
- B01J37/18—Reducing with gases containing free hydrogen
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
- C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
- C07C1/0425—Catalysts; their physical properties
- C07C1/0445—Preparation; Activation
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
- C07C2521/04—Alumina
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- C07C2521/08—Silica
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/12—Silica and alumina
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
- C07C2523/46—Ruthenium, rhodium, osmium or iridium
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/74—Iron group metals
- C07C2523/75—Cobalt
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with noble metals

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Engineering & Computer Science (AREA)
Oil, Petroleum & Natural Gas (AREA)
General Chemical & Material Sciences (AREA)
Materials Engineering (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Catalysts (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

NO20023228A 2000-01-04 2002-07-03 Aktivering av hydrokarbonsyntesekatalysator med hydrogen og ammoniakk NO20023228L (no)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US09/477,531 US6337353B1 (en)	2000-01-04	2000-01-04	Activation of hydrocarbon synthesis catalysts with hydrogen and ammonia
PCT/US2000/035328 WO2001049808A1 (fr)	2000-01-04	2000-12-26	Activation de catalyseurs de synthese d'hydrocarbures avec de l'hydrogene et de l'ammoniac

Publications (2)

Publication Number	Publication Date
NO20023228D0 NO20023228D0 (no)	2002-07-03
NO20023228L true NO20023228L (no)	2002-08-28

Family

ID=23896301

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NO20023228A NO20023228L (no)	2000-01-04	2002-07-03	Aktivering av hydrokarbonsyntesekatalysator med hydrogen og ammoniakk

Country Status (11)

Country	Link
US (2)	US6337353B1 (fr)
EP (1)	EP1246885B1 (fr)
JP (1)	JP2003519010A (fr)
AR (1)	AR029219A1 (fr)
AT (1)	ATE288953T1 (fr)
AU (1)	AU777839B2 (fr)
CA (1)	CA2396185C (fr)
DE (1)	DE60018111T2 (fr)
MY (1)	MY117520A (fr)
NO (1)	NO20023228L (fr)
WO (1)	WO2001049808A1 (fr)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US6706661B1 (en) *	2000-09-01	2004-03-16	Exxonmobil Research And Engineering Company	Fischer-Tropsch catalyst enhancement
AU2002303819B2 (en)	2001-05-17	2007-03-01	Xenogen Corporation	Method and apparatus for determining target depth, brightness and size within a body region
GB0115850D0 (en)	2001-06-28	2001-08-22	Isis Innovations Ltd	Catalyst
GB2410449B (en)	2004-01-28	2008-05-21	Statoil Asa	Fischer-Tropsch catalysts
RU2389548C2 (ru) *	2004-09-23	2010-05-20	Статоил Аса	Промотированный катализатор синтеза фишера-тропша, способ его получения и способ синтеза углеводородов фишера-тропша
US7524787B2 (en) *	2005-01-11	2009-04-28	Sasol Technology (Proprietary Limited)	Producing supported cobalt catalysts for the Fisher-Tropsch synthesis
EP1853382B1 (fr) *	2005-01-11	2014-11-19	Sasol Technology (Proprietary) Limited	Production de catalyseurs au cobalt supportes pour la synthese de fisher-tropsch
US9295976B2 (en)	2006-08-25	2016-03-29	Nippon Steel Engineering Co., Ltd	Catalyst for producing hydrocarbon from syngas, method for producing catalyst, method for regenerating catalyst, and method for producing hydrocarbon from sysngas
AU2007332615B2 (en) *	2006-12-12	2010-11-11	Shell Internationale Research Maatschappij B.V.	Process for preparing a catalyst
US7381676B1 (en) *	2007-01-16	2008-06-03	Exxonmobil Chemical Patents Inc.	Catalyst composition and its use thereof in aromatics alkylation
WO2008135941A2 (fr) *	2007-05-04	2008-11-13	Sasol Technology (Proprietary) Limited	Catalyseurs
KR100918105B1 (ko) *	2008-03-27	2009-09-22	한국화학연구원	피셔-트롭쉬 합성용 코발트／지르코늄-인/실리카 촉매와이의 제조방법
GB2473071B (en)	2009-09-01	2013-09-11	Gtl F1 Ag	Fischer-tropsch catalysts
GB2475492B (en)	2009-11-18	2014-12-31	Gtl F1 Ag	Fischer-Tropsch synthesis
GB201001144D0 (en) *	2010-01-25	2010-03-10	Compactgtl Plc	Catalytic reactor treatment process
WO2012004808A1 (fr) *	2010-07-08	2012-01-12	Indian Oil Corporation Ltd.	Appareil et procédé de conversion gaz-liquide (gtl)
CN103249481B (zh)	2010-08-09	2015-11-25	Gtl.F1公司	费托催化剂
JP5698851B2 (ja) *	2012-09-21	2015-04-08	Ｊｘ日鉱日石エネルギー株式会社	フィッシャー・トロプシュ合成用触媒及びその製造方法、並びに炭化水素の製造方法
KR101373823B1 (ko) *	2013-10-22	2014-03-11	한국에너지기술연구원	선택적 합성오일 생성을 위한 피셔-트롭쉬 반응용 금속 구조체 기반 코발트계 촉매 및 그 제조 방법, 이 금속 구조체 기반 코발트계 촉매를 이용한 선택적 합성 오일 제조 방법
AU2016313770B2 (en) *	2015-09-04	2019-12-05	Shell Internationale Research Maatschappij B.V.	Fischer-Tropsch process

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB728602A (en)	1951-07-21	1955-04-20	Rheinpreussen Ag	A process for the synthesis of hydrocarbons and oxygen-containing organic compounds
US4086262A (en)	1976-09-20	1978-04-25	Mobil Oil Corporation	Conversion of synthesis gas to hydrocarbon mixtures
US4196100A (en)	1978-01-10	1980-04-01	The International Nickel Co., Inc.	Catalyst useful for methanation and preparation thereof
FR2523957A1 (fr) *	1982-03-26	1983-09-30	Inst Francais Du Petrole	Procede de fabrication d'un melange de methanol et d'alcools superieurs, a partir de gaz de synthese
US4492774A (en)	1982-12-27	1985-01-08	Gulf Research & Development Company	Method for converting synthesis gas using an activated cobalt-substituted layered aluminosilicate
US5545674A (en)	1987-05-07	1996-08-13	Exxon Research And Engineering Company	Surface supported cobalt catalysts, process utilizing these catalysts for the preparation of hydrocarbons from synthesis gas and process for the preparation of said catalysts

2000
- 2000-01-04 US US09/477,531 patent/US6337353B1/en not_active Expired - Fee Related
- 2000-12-26 AT AT00986750T patent/ATE288953T1/de not_active IP Right Cessation
- 2000-12-26 CA CA2396185A patent/CA2396185C/fr not_active Expired - Fee Related
- 2000-12-26 EP EP00986750A patent/EP1246885B1/fr not_active Expired - Lifetime
- 2000-12-26 AU AU22932/01A patent/AU777839B2/en not_active Ceased
- 2000-12-26 DE DE60018111T patent/DE60018111T2/de not_active Expired - Lifetime
- 2000-12-26 WO PCT/US2000/035328 patent/WO2001049808A1/fr not_active Ceased
- 2000-12-26 JP JP2001550338A patent/JP2003519010A/ja active Pending
2001
- 2001-01-03 MY MYPI20010012A patent/MY117520A/en unknown
- 2001-01-04 AR ARP010100033A patent/AR029219A1/es unknown
- 2001-05-25 US US09/865,796 patent/US6486221B2/en not_active Expired - Fee Related
2002
- 2002-07-03 NO NO20023228A patent/NO20023228L/no not_active Application Discontinuation

Also Published As

Publication number	Publication date
JP2003519010A (ja)	2003-06-17
AR029219A1 (es)	2003-06-18
WO2001049808A1 (fr)	2001-07-12
CA2396185A1 (fr)	2001-07-12
AU777839B2 (en)	2004-11-04
DE60018111T2 (de)	2005-12-29
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US6486221B2 (en)	2002-11-26
US6337353B1 (en)	2002-01-08
US20010051663A1 (en)	2001-12-13
EP1246885B1 (fr)	2005-02-09
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