NO20073689L - Membrane for filtration of molecular gases, such as hydrogen, and their preparation - Google Patents

Membrane for filtration of molecular gases, such as hydrogen, and their preparation

Info

Publication number
NO20073689L
NO20073689L NO20073689A NO20073689A NO20073689L NO 20073689 L NO20073689 L NO 20073689L NO 20073689 A NO20073689 A NO 20073689A NO 20073689 A NO20073689 A NO 20073689A NO 20073689 L NO20073689 L NO 20073689L
Authority
NO
Norway
Prior art keywords
membrane
filtration
hydrogen
preparation
molecular gases
Prior art date
Application number
NO20073689A
Other languages
Norwegian (no)
Other versions
NO344504B1 (en
Inventor
Laurent Lelait
Philippe Stevens
Ludmila Gautier
Anatoly Vladimirovich Soudarev
Vladimir Gennadievich Konakov
Andrey Andreevich Souryaninov
Vitaly Yuryevich Tikhoplay
Original Assignee
Electricite De France
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Electricite De France filed Critical Electricite De France
Publication of NO20073689L publication Critical patent/NO20073689L/en
Publication of NO344504B1 publication Critical patent/NO344504B1/en

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/22Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
    • B01D53/228Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion characterised by specific membranes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D67/00Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0039Inorganic membrane manufacture
    • B01D67/0048Inorganic membrane manufacture by sol-gel transition
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D69/00Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/10Supported membranes; Membrane supports
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D69/00Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/10Supported membranes; Membrane supports
    • B01D69/105Support pretreatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D71/00Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/02Inorganic material
    • B01D71/024Oxides
    • B01D71/027Silicium oxide
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/50Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification
    • C01B3/501Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification by diffusion
    • C01B3/503Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification by diffusion characterised by membranes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/06Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0662Treatment of gaseous reactants or gaseous residues, e.g. cleaning
    • H01M8/0687Reactant purification by the use of membranes or filters
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2323/00Details relating to membrane preparation
    • B01D2323/08Specific temperatures applied
    • B01D2323/081Heating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2323/00Details relating to membrane preparation
    • B01D2323/08Specific temperatures applied
    • B01D2323/082Cooling
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2323/00Details relating to membrane preparation
    • B01D2323/48Influencing the pH
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2325/00Details relating to properties of membranes
    • B01D2325/02Details relating to pores or porosity of the membranes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2325/00Details relating to properties of membranes
    • B01D2325/04Characteristic thickness
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0405Purification by membrane separation
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465Composition of the impurity
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465Composition of the impurity
    • C01B2203/047Composition of the impurity the impurity being carbon monoxide
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465Composition of the impurity
    • C01B2203/0475Composition of the impurity the impurity being carbon dioxide
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465Composition of the impurity
    • C01B2203/0485Composition of the impurity the impurity being a sulfur compound
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Electrochemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)

Abstract

Oppfinnelsen gjelder en membran for filtrering av molekylære gasser slik som hydrogen som består av en keramisk porøs bærer som hovedsakelig omfatter magnesium aluminium spinnel, der den gitte bæreren har blitt impregnert med et silika basert xerogel lag. Oppfinnelsen gjelder også en fremgangsmåte for å fremstille en slik membran. Oppfinnelsen gjelder videre anvendelsen av en bærer som hovedsakelig omfatter magnesium aluminium spinell i en hydrogen filtreringsmembran.The invention relates to a membrane for the filtration of molecular gases such as hydrogen consisting of a ceramic porous support comprising mainly magnesium aluminum spindle, wherein the given carrier has been impregnated with a silica based xerogel layer. The invention also relates to a process for making such a membrane. The invention further relates to the use of a carrier which mainly comprises magnesium aluminum spinel in a hydrogen filtration membrane.

NO20073689A 2004-12-20 2007-07-17 Membrane for filtration of molecular gases, such as hydrogen, and their preparation NO344504B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0413561A FR2879475B1 (en) 2004-12-20 2004-12-20 MOLECULAR GAS FILTRATION MEMBRANE SUCH AS HYDROGEN AND PROCESS FOR PREPARING THE SAME
PCT/EP2005/056988 WO2006067156A1 (en) 2004-12-20 2005-12-20 Membrane for the filtration of molecular gases, such as hydrogen, and preparation method thereof

Publications (2)

Publication Number Publication Date
NO20073689L true NO20073689L (en) 2007-08-23
NO344504B1 NO344504B1 (en) 2020-01-20

Family

ID=34952909

Family Applications (1)

Application Number Title Priority Date Filing Date
NO20073689A NO344504B1 (en) 2004-12-20 2007-07-17 Membrane for filtration of molecular gases, such as hydrogen, and their preparation

Country Status (4)

Country Link
EP (1) EP1824584A1 (en)
FR (1) FR2879475B1 (en)
NO (1) NO344504B1 (en)
WO (1) WO2006067156A1 (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2946801B1 (en) * 2009-06-11 2011-06-17 Electricite De France FUEL CELL WITH INTEGRATED HYDROGEN PURIFICATION MEMBRANE
CN103143398B (en) * 2011-12-06 2015-04-15 福州大学 Magnesium aluminate spinel carrier, and preparation method and application thereof
FR2999167B1 (en) 2012-12-12 2014-12-26 Herakles PYROTECHNIC PROCESS FOR PROVIDING VERY HIGH PURITY HYDROGEN AND ASSOCIATED DEVICE
FR3003092B1 (en) 2013-03-05 2015-04-03 Herakles METHOD AND DEVICE FOR SUPPLYING A FUEL CELL
CN110559872B (en) * 2019-08-14 2022-03-01 浙江理工大学 Preparation method of shaft disc type rotating ceramic membrane

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4254086A (en) * 1978-12-27 1981-03-03 Sanders Alfred P Endothermal water decomposition unit for producing hydrogen and oxygen
US5342431A (en) * 1989-10-23 1994-08-30 Wisconsin Alumni Research Foundation Metal oxide membranes for gas separation
DE4227720C2 (en) * 1991-09-18 1998-05-20 Fraunhofer Ges Forschung Process for the production of coatings from spinel and use of the carrier produced thereafter
DE4138273A1 (en) * 1991-11-21 1993-05-27 Abb Patent Gmbh METHOD FOR PRODUCING A CERAMIC FUEL CELL SUPPORT
EP1487563A4 (en) * 2002-03-05 2005-07-20 Eltron Research Inc HYDROGEN TRANSPORT MEMBRANES
KR100460450B1 (en) * 2002-10-04 2004-12-08 한국화학연구원 Preparation of the silica composite membranes with thermal stability by Soaking-Rolling method

Also Published As

Publication number Publication date
FR2879475B1 (en) 2007-08-10
WO2006067156A1 (en) 2006-06-29
FR2879475A1 (en) 2006-06-23
EP1824584A1 (en) 2007-08-29
NO344504B1 (en) 2020-01-20

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