NO20093037L - Fremgangsmate for fremstilling av maursyre - Google Patents

Fremgangsmate for fremstilling av maursyre

Info

Publication number
NO20093037L
NO20093037L NO20093037A NO20093037A NO20093037L NO 20093037 L NO20093037 L NO 20093037L NO 20093037 A NO20093037 A NO 20093037A NO 20093037 A NO20093037 A NO 20093037A NO 20093037 L NO20093037 L NO 20093037L
Authority
NO
Norway
Prior art keywords
formic acid
residues
ammonium formate
hydrogenation
carbon atoms
Prior art date
Application number
NO20093037A
Other languages
English (en)
Inventor
Michael Roper
Nina Challand
Xavier Sava
Original Assignee
Basf Se
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se filed Critical Basf Se
Publication of NO20093037L publication Critical patent/NO20093037L/no

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/02—Preparation of carboxylic acids or their salts, halides or anhydrides from salts of carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C53/00—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
    • C07C53/02—Formic acid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/62—Reductions in general of inorganic substrates, e.g. formal hydrogenation, e.g. of N2
    • B01J2231/625—Reductions in general of inorganic substrates, e.g. formal hydrogenation, e.g. of N2 of CO2
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0202—Alcohols or phenols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0237—Amines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0271—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds also containing elements or functional groups covered by B01J31/0201 - B01J31/0231
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Foreliggende oppfinnelse vedrører fremgangsmåte for fremstilling av maursyre, hvor den katalytiske hydrogeneringen av karbondioksid med hydrogen over en katalysator som omfatter et metall fra gruppene 8 til 10 av det periodiske systemet i nærvær av et primært, sekundært og/eller tertiært amin genererer det tilsvarende ammoniumformiat og ammoniumformiatet blir splittet ved oppvarmning til maursyre og aminet, som omfatter selektering av primært, sekundært eller tertiært amin fra aminene med formel I eller blandinger derav hvor R1 til R3 er like eller forskjellige og er hver hydrogen, lineære eller forgrenede alkylrester som har fra 1 til 18 karbonatomer, cykloalifatiske rester som har fra 5 til 7 karbonatomer, arylrester og/eller arylalkylrester og minst én av R1 til R3 restene bærer en hydroksylgruppe og utførelse av hydrogeneringen i et løsningsmiddel som har et kokepunkt på = 105°C ved standardtrykk og oppnåelse av maursyre i reaksjonsblandingen fra hydrogeneringen omfattende det høyt-kokende løsningsmidlet ved termalt splitting av ammoniumformiatet og avdestillering av maursyre.
NO20093037A 2007-03-23 2009-09-22 Fremgangsmate for fremstilling av maursyre NO20093037L (no)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP07104745 2007-03-23
PCT/EP2008/053248 WO2008116799A1 (de) 2007-03-23 2008-03-18 Verfahren zur herstellung von ameisensäure

Publications (1)

Publication Number Publication Date
NO20093037L true NO20093037L (no) 2009-10-19

Family

ID=39469940

Family Applications (1)

Application Number Title Priority Date Filing Date
NO20093037A NO20093037L (no) 2007-03-23 2009-09-22 Fremgangsmate for fremstilling av maursyre

Country Status (10)

Country Link
US (1) US20100063320A1 (no)
EP (1) EP2139837A1 (no)
JP (1) JP2010521533A (no)
KR (1) KR20090123972A (no)
CN (1) CN101663259A (no)
AR (1) AR065807A1 (no)
BR (1) BRPI0809156A2 (no)
CA (1) CA2681508A1 (no)
NO (1) NO20093037L (no)
WO (1) WO2008116799A1 (no)

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102574762B (zh) * 2009-06-26 2014-08-13 巴斯夫欧洲公司 生产甲酸的方法
UA104324C2 (ru) * 2009-06-26 2014-01-27 Басф Се Способ получения муравьиной кислоты
CA2802927A1 (en) 2010-06-29 2012-01-05 Basf Se Process for preparing formic acid by reaction of carbon dioxide with hydrogen
US8877965B2 (en) 2010-06-29 2014-11-04 Basf Se Process for preparing formic acid by reaction of carbon dioxide with hydrogen
US8901350B2 (en) 2010-06-29 2014-12-02 Basf Se Process for the preparation of formic acid
EP2588438B1 (de) * 2010-06-29 2015-04-08 Basf Se Verfahren zur herstellung von ameisensäure durch umsetzung von kohlendioxid mit wasserstoff
SG186264A1 (en) 2010-06-29 2013-01-30 Basf Se Method for producing formic acid
US8791297B2 (en) 2010-06-29 2014-07-29 Basf Se Process for preparing formic acid by reaction of carbon dioxide with hydrogen
WO2012034991A1 (de) * 2010-09-17 2012-03-22 Basf Se Verfahren zur herstellung von formamiden
EP2655310B1 (de) 2010-12-21 2014-11-05 Basf Se Verfahren zur herstellung von ameisensäure durch umsetzung von kohlendioxid mit wasserstoff
DE102011000077A1 (de) * 2011-01-11 2012-07-12 Rheinisch-Westfälische Technische Hochschule Aachen CO2-Hydrierungsverfahren zu Ameisensäure
RU2013158468A (ru) * 2011-06-09 2015-07-20 Басф Се Способ получения муравьиной кислоты
WO2012168905A1 (en) * 2011-06-09 2012-12-13 Basf Se Process for preparing formic acid
JP2014522823A (ja) * 2011-07-07 2014-09-08 ビーエーエスエフ ソシエタス・ヨーロピア 二酸化炭素と水素との反応によるギ酸の製造方法
CN103974927A (zh) * 2011-10-07 2014-08-06 巴斯夫欧洲公司 通过使二氧化碳与氢气反应制备甲酸的方法
RU2014123397A (ru) * 2011-11-10 2015-12-20 Басф Се Способ получения муравьиной кислоты путем взаимодействия диоксида углерода с водородом
US8889905B2 (en) 2011-12-20 2014-11-18 Basf Se Process for preparing formic acid
CA2856959A1 (en) 2011-12-20 2013-06-27 Basf Se Process for preparing formic acid
US8835683B2 (en) 2011-12-20 2014-09-16 Basf Se Process for preparing formic acid
EP2794540A1 (de) * 2011-12-20 2014-10-29 Basf Se Verfahren zur herstellung von ameisensäure
DE102013201246A1 (de) * 2013-01-25 2014-07-31 Technische Universität Bergakademie Freiberg Verfahren zur in-situ Umsetzung von chemisch fixiertem Kohlendioxid in niedermolekulare Kohlenwasserstoffe
JP6289310B2 (ja) * 2014-08-27 2018-03-07 一般財団法人電力中央研究所 触媒又はその前駆体並びにこれらを利用した二酸化炭素の水素化方法及びギ酸塩の製造方法
CN105367404B (zh) * 2015-10-13 2018-04-10 大连理工大学 一种二氧化碳催化加氢制备甲酸盐的方法
CN108424359B (zh) * 2018-03-21 2020-11-13 大连理工大学 一种水相中钌配合物催化co2加氢还原制备甲酸盐/甲酸的方法
JP7405594B2 (ja) * 2019-03-08 2023-12-26 日東電工株式会社 ギ酸の製造方法
US20220177402A1 (en) * 2019-03-08 2022-06-09 Nitto Denko Corporation Method for producing formic acid
WO2021187057A1 (ja) * 2020-03-17 2021-09-23 日東電工株式会社 ギ酸塩の製造方法及びギ酸塩製造システム
CN117192002B (zh) * 2023-05-12 2026-02-06 广东省计量科学研究院（华南国家计量测试中心） 一种制备空气中甲酸气体标准物质的系统及方法

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4474959A (en) * 1982-05-22 1984-10-02 Bp Chemicals Limited Production of formate salts from carbon dioxide, hydrogen and amines
DE68920933T2 (de) * 1988-08-20 1995-05-24 Bp Chem Int Ltd Produktion von Formiat-Salzen von Stickstoffbasen.
DE4211141A1 (de) * 1992-04-03 1993-10-07 Basf Ag Verfahren zur Herstellung von Ameisensäure durch thermische Spaltung von quartären Ammoniumformiaten

Also Published As

Publication number Publication date
BRPI0809156A2 (pt) 2014-09-16
JP2010521533A (ja) 2010-06-24
CN101663259A (zh) 2010-03-03
WO2008116799A1 (de) 2008-10-02
KR20090123972A (ko) 2009-12-02
EP2139837A1 (de) 2010-01-06
AR065807A1 (es) 2009-07-01
CA2681508A1 (en) 2008-10-02
US20100063320A1 (en) 2010-03-11

Similar Documents

Publication Publication Date Title
Pingen et al. Direct amination of secondary alcohols using ammonia
CA2681508A1 (en) Process for preparing formic acid
EP3674285B1 (en) Process for producing m-xylylenediamine
EP2606029B1 (en) Process for making tertiary aminoalcohol compounds
DE602005006406D1 (de) Verfahren zur herstellung von hsicl3 durch katalytische hydrodehalogenierung von sicl4
JP2011001364A5 (no)
EP3665154A1 (en) Reactive separation process to convert cyclic alkylene ureas into their corresponding alkylene amines
MX2012006590A (es) Procedimiento para la preparacion de 2,2-difluoroetilamina, asi como de sus sales, partiendo de difluoroacetonitrilo.
US9561998B2 (en) Method for producing nitro compound
Kavitha et al. Simple and an efficient method for the synthesis of 1-[2-dimethylamino-1-(4-methoxy-phenyl)-ethyl]-cyclohexanol hydrochloride:(±) venlafaxine racemic mixtures
EP2720995B1 (en) Process for making tertiary aminoalcohol compounds
TWI370133B (en) Process for preparing acylphosphanes and derivatives thereof
TWI522335B (zh) 用於藉由氫化１，１－二氟－２－硝基乙烷製備２，２－二氟乙基胺之方法
JP2008230999A (ja) ジフェニルアミンの製造方法
JP2016537420A (ja) エステルの合成方法および該合成のための触媒
RU2547141C1 (ru) Способ получения n-(4-бромфенил)-n-(2-адамантил)амина (бромантана)
JP6301481B2 (ja) アルカノールの製造方法
TW200700426A (en) Process for synthesis of diorganosilanes by disproportionation of hydridosiloxanes
RU2344120C1 (ru) Способ совместного получения n-метилциклогексиламина и дициклогексиламина
CN103012154B (zh) 由苯磺酰胺衍生物氨解制备有机胺的方法
MX2019015134A (es) Proceso de síntesis de a-terpineol a partir de la hidratación de a-pineno utilizando un líquido iónico como solvente.
JP7700124B2 (ja) ピペリジン化合物を調製する方法
JP5981747B2 (ja) アザディールス−アルダー反応用触媒、それを用いたテトラヒドロピリジン化合物の製造方法
Zhang et al. Tri-n-butylphosphane catalyzed ring opening of aziridines with secondary amines
JP5173152B2 (ja) β−アラニン化合物、ピペリドン化合物及びアミノピペリジン化合物の製造方法

Legal Events

Date Code Title Description
FC2A Withdrawal, rejection or dismissal of laid open patent application