NO310350B1 - Trinnvis hydrokarbonsynteseprosess - Google Patents

Trinnvis hydrokarbonsynteseprosess Download PDF

Info

Publication number: NO310350B1
Authority: NO; Norway
Prior art keywords: shift; hydrocarbon synthesis; catalyst; reaction; feed
Prior art date: 1994-04-29

Application number

NO19951572A

Other languages

English (en)

Norwegian (no)

Other versions

NO951572L (no

NO951572D0 (no

Inventor

David Chester Long

Original Assignee

Exxon Research Engineering Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1994-04-29

Filing date

1995-04-25

Publication date

2001-06-25

1995-04-25 Application filed by Exxon Research Engineering Co filed Critical Exxon Research Engineering Co

1995-04-25 Publication of NO951572D0 publication Critical patent/NO951572D0/no

1995-10-30 Publication of NO951572L publication Critical patent/NO951572L/no

2001-06-25 Publication of NO310350B1 publication Critical patent/NO310350B1/no

Links

238000003786 synthesis reaction Methods 0.000 title claims description 33
229930195733 hydrocarbon Natural products 0.000 title claims description 32
150000002430 hydrocarbons Chemical class 0.000 title claims description 32
230000015572 biosynthetic process Effects 0.000 title claims description 30
239000004215 Carbon black (E152) Substances 0.000 title claims description 25
238000000034 method Methods 0.000 title claims description 17
238000006243 chemical reaction Methods 0.000 claims description 28
239000003054 catalyst Substances 0.000 claims description 26
239000007789 gas Substances 0.000 claims description 24
239000000047 product Substances 0.000 claims description 16
229910052739 hydrogen Inorganic materials 0.000 claims description 13
239000001257 hydrogen Substances 0.000 claims description 13
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 12
229910002091 carbon monoxide Inorganic materials 0.000 claims description 11
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 9
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 8
229910017052 cobalt Inorganic materials 0.000 claims description 5
239000010941 cobalt Substances 0.000 claims description 5
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 5
229910052742 iron Inorganic materials 0.000 claims description 4
239000007795 chemical reaction product Substances 0.000 claims description 3
230000000694 effects Effects 0.000 claims description 2
239000007788 liquid Substances 0.000 claims description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 6
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 5
239000000463 material Substances 0.000 description 5
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 3
239000000470 constituent Substances 0.000 description 3
229910052707 ruthenium Inorganic materials 0.000 description 3
OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 3
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
150000001298 alcohols Chemical class 0.000 description 2
150000001299 aldehydes Chemical class 0.000 description 2
150000001336 alkenes Chemical class 0.000 description 2
239000012263 liquid product Substances 0.000 description 2
238000004519 manufacturing process Methods 0.000 description 2
TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
238000004064 recycling Methods 0.000 description 2
229910052702 rhenium Inorganic materials 0.000 description 2
WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 2
229910052814 silicon oxide Inorganic materials 0.000 description 2
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
229910052684 Cerium Inorganic materials 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
238000009903 catalytic hydrogenation reaction Methods 0.000 description 1
238000006555 catalytic reaction Methods 0.000 description 1
ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
238000001816 cooling Methods 0.000 description 1
230000001066 destructive effect Effects 0.000 description 1
238000010586 diagram Methods 0.000 description 1
239000000446 fuel Substances 0.000 description 1
239000002737 fuel gas Substances 0.000 description 1
229910052735 hafnium Inorganic materials 0.000 description 1
VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 1
150000002431 hydrogen Chemical class 0.000 description 1
239000007791 liquid phase Substances 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
-1 olefins Chemical class 0.000 description 1
239000012188 paraffin wax Substances 0.000 description 1
239000012071 phase Substances 0.000 description 1
238000005191 phase separation Methods 0.000 description 1
239000002574 poison Substances 0.000 description 1
231100000614 poison Toxicity 0.000 description 1
239000000376 reactant Substances 0.000 description 1
238000007086 side reaction Methods 0.000 description 1
238000004088 simulation Methods 0.000 description 1
239000002002 slurry Substances 0.000 description 1
239000007787 solid Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
- C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
- C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
- C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
- C07C1/0485—Set-up of reactors or accessories; Multi-step processes
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/74—Iron group metals
- C07C2523/745—Iron
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/74—Iron group metals
- C07C2523/75—Cobalt

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Oil, Petroleum & Natural Gas (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
General Chemical & Material Sciences (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Catalysts (AREA)

NO19951572A 1994-04-29 1995-04-25 Trinnvis hydrokarbonsynteseprosess NO310350B1 (no)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US08/236,905 US5498638A (en)	1994-04-29	1994-04-29	Staged hydrocarbon synthesis process

Publications (3)

Publication Number	Publication Date
NO951572D0 NO951572D0 (no)	1995-04-25
NO951572L NO951572L (no)	1995-10-30
NO310350B1 true NO310350B1 (no)	2001-06-25

Family

ID=22891486

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NO19951572A NO310350B1 (no)	1994-04-29	1995-04-25	Trinnvis hydrokarbonsynteseprosess

Country Status (7)

Country	Link
US (1)	US5498638A (de)
EP (1)	EP0679620B1 (de)
AU (1)	AU689220B2 (de)
CA (1)	CA2146178C (de)
DE (1)	DE69513558T2 (de)
MY (1)	MY112616A (de)
NO (1)	NO310350B1 (de)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US6368997B2 (en)	1998-05-22	2002-04-09	Conoco Inc.	Fischer-Tropsch processes and catalysts using fluorided supports
US6191066B1 (en)	1998-05-27	2001-02-20	Energy International Corporation	Fischer-Tropsch activity for non-promoted cobalt-on-alumina catalysts
DZ2966A1 (fr) *	1999-02-15	2004-03-15	Shell Int Research	Procédé de préparation d'hydrocarbures à partir demonoxyde de carbone et d'hydrogène.
US6262132B1 (en) *	1999-05-21	2001-07-17	Energy International Corporation	Reducing fischer-tropsch catalyst attrition losses in high agitation reaction systems
US6169120B1 (en)	1999-09-17	2001-01-02	Syntroleum Corporation	Extended catalyst life two stage hydrocarbon synthesis process
US6239184B1 (en)	1999-09-22	2001-05-29	Syntroleum Corporation	Extended catalyst life Fischer-Tropsch process
US6255358B1 (en)	2000-03-17	2001-07-03	Energy International Corporation	Highly active Fischer-Tropsch synthesis using doped, thermally stable catalyst support
US7432310B2 (en) *	2003-08-22	2008-10-07	Sasol Technology (Proprietary) Limited	Process for synthesising hydrocarbons
US6992113B2 (en)	2003-11-25	2006-01-31	Chevron U.S.A. Inc.	Control of CO2 emissions from a fischer-tropsch facility by use of dual functional syngas conversion
US6992114B2 (en) *	2003-11-25	2006-01-31	Chevron U.S.A. Inc.	Control of CO2 emissions from a Fischer-Tropsch facility by use of multiple reactors
US7030166B2 (en) *	2004-04-08	2006-04-18	Syntroleum Corporation	Process to enhance catalyst life and removal of debris
PL1861478T3 (pl)	2005-03-16	2012-07-31	Fuelcor Llc	Układy i sposoby do wytwarzania syntetycznych związków węglowodorowych
WO2008000784A1 (en) *	2006-06-30	2008-01-03	Shell Internationale Research Maatschappij B.V.	Optimisation of a multi-stage fischer-tropsch synthesis process
WO2008069251A1 (ja) *	2006-12-05	2008-06-12	Nagasaki Institute Of Applied Science	バイオマスからの液体燃料製造装置および製造方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
NL8006484A (nl) *	1980-11-28	1982-06-16	Shell Int Research	Werkwijze voor de bereiding van koolwaterstoffen.
NL8103397A (nl) *	1981-07-17	1983-02-16	Shell Int Research	Werkwijze voor de bereiding van organische verbindingen .
NL8400608A (nl) *	1984-02-28	1985-09-16	Shell Int Research	Werkwijze voor de bereiding van koolwaterstoffen.
US4624968A (en) *	1985-12-30	1986-11-25	Exxon Research And Engineering Company	Multi-stage Fischer-Tropsch process
US5028634A (en) *	1989-08-23	1991-07-02	Exxon Research & Engineering Company	Two stage process for hydrocarbon synthesis
FR2694013B1 (fr) *	1992-07-27	1994-09-30	Inst Francais Du Petrole	Catalyseur à base de cobalt et procédé de conversion du gaz de synthèse en hydrocarbures.

1994
- 1994-04-29 US US08/236,905 patent/US5498638A/en not_active Expired - Lifetime
1995
- 1995-04-03 CA CA002146178A patent/CA2146178C/en not_active Expired - Fee Related
- 1995-04-24 MY MYPI95001063A patent/MY112616A/en unknown
- 1995-04-25 NO NO19951572A patent/NO310350B1/no not_active IP Right Cessation
- 1995-04-26 EP EP95201074A patent/EP0679620B1/de not_active Expired - Lifetime
- 1995-04-26 DE DE69513558T patent/DE69513558T2/de not_active Expired - Lifetime
- 1995-04-27 AU AU17763/95A patent/AU689220B2/en not_active Expired

Also Published As

Publication number	Publication date
NO951572L (no)	1995-10-30
EP0679620A2 (de)	1995-11-02
AU1776395A (en)	1995-11-09
CA2146178C (en)	2005-07-26
NO951572D0 (no)	1995-04-25
DE69513558D1 (de)	2000-01-05
US5498638A (en)	1996-03-12
CA2146178A1 (en)	1995-10-30
EP0679620B1 (de)	1999-12-01
EP0679620A3 (de)	1996-11-13
DE69513558T2 (de)	2000-04-27
AU689220B2 (en)	1998-03-26
MY112616A (en)	2001-07-31

Legal Events

Date	Code	Title	Description
2004-12-27	MM1K	Lapsed by not paying the annual fees

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