NO312131B1 - Fremgangsmåte for å fjerne natriumsulfat fra en fosfatlösning - Google Patents
Fremgangsmåte for å fjerne natriumsulfat fra en fosfatlösning Download PDFInfo
- Publication number
- NO312131B1 NO312131B1 NO20001137A NO20001137A NO312131B1 NO 312131 B1 NO312131 B1 NO 312131B1 NO 20001137 A NO20001137 A NO 20001137A NO 20001137 A NO20001137 A NO 20001137A NO 312131 B1 NO312131 B1 NO 312131B1
- Authority
- NO
- Norway
- Prior art keywords
- phosphate
- water
- solution
- absorption
- sodium
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 49
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 title claims abstract description 16
- 229910019142 PO4 Inorganic materials 0.000 title claims abstract description 15
- 239000010452 phosphate Substances 0.000 title claims abstract description 15
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 title claims abstract description 14
- 229910052938 sodium sulfate Inorganic materials 0.000 title claims abstract description 11
- 235000011152 sodium sulphate Nutrition 0.000 title claims abstract description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 24
- 238000010521 absorption reaction Methods 0.000 claims abstract description 17
- 238000001704 evaporation Methods 0.000 claims abstract description 15
- 230000008020 evaporation Effects 0.000 claims abstract description 15
- 239000002244 precipitate Substances 0.000 claims abstract description 10
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 claims abstract description 6
- 239000000706 filtrate Substances 0.000 claims abstract description 4
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 claims abstract description 3
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 claims description 52
- 239000007789 gas Substances 0.000 claims description 13
- 238000001556 precipitation Methods 0.000 claims description 7
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 claims description 4
- 235000010262 sodium metabisulphite Nutrition 0.000 claims description 4
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 claims description 2
- 239000012065 filter cake Substances 0.000 claims description 2
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 claims description 2
- 239000004289 sodium hydrogen sulphite Substances 0.000 claims description 2
- 238000012546 transfer Methods 0.000 claims description 2
- 239000000243 solution Substances 0.000 abstract description 14
- 238000001914 filtration Methods 0.000 abstract description 6
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 239000003546 flue gas Substances 0.000 abstract 1
- 230000009466 transformation Effects 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 17
- 239000007788 liquid Substances 0.000 description 14
- 229910021653 sulphate ion Inorganic materials 0.000 description 14
- 239000007787 solid Substances 0.000 description 13
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- 239000007853 buffer solution Substances 0.000 description 10
- 229910000397 disodium phosphate Inorganic materials 0.000 description 10
- 239000000872 buffer Substances 0.000 description 7
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 6
- 239000011734 sodium Substances 0.000 description 6
- 229910000162 sodium phosphate Inorganic materials 0.000 description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 5
- 239000001488 sodium phosphate Substances 0.000 description 5
- 235000011008 sodium phosphates Nutrition 0.000 description 5
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 238000011084 recovery Methods 0.000 description 4
- 230000001172 regenerating effect Effects 0.000 description 4
- 235000011121 sodium hydroxide Nutrition 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000002250 absorbent Substances 0.000 description 3
- 230000002745 absorbent Effects 0.000 description 3
- 239000012452 mother liquor Substances 0.000 description 3
- 238000000746 purification Methods 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- 239000011593 sulfur Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 238000005119 centrifugation Methods 0.000 description 2
- 239000000356 contaminant Substances 0.000 description 2
- 235000019800 disodium phosphate Nutrition 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- -1 hydronium ions Chemical class 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000010413 mother solution Substances 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- 230000008929 regeneration Effects 0.000 description 2
- 238000011069 regeneration method Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- 101100283604 Caenorhabditis elegans pigk-1 gene Proteins 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 229910004879 Na2S2O5 Inorganic materials 0.000 description 1
- 239000007832 Na2SO4 Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-L Phosphate ion(2-) Chemical compound OP([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-L 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000012062 aqueous buffer Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-M dihydrogenphosphate Chemical compound OP(O)([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-M 0.000 description 1
- 238000007323 disproportionation reaction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000002737 fuel gas Substances 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000020477 pH reduction Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000008363 phosphate buffer Substances 0.000 description 1
- 238000011085 pressure filtration Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 229910052979 sodium sulfide Inorganic materials 0.000 description 1
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- DHCDFWKWKRSZHF-UHFFFAOYSA-L thiosulfate(2-) Chemical compound [O-]S([S-])(=O)=O DHCDFWKWKRSZHF-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1425—Regeneration of liquid absorbents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1456—Removing acid components
- B01D53/1481—Removing sulfur dioxide or sulfur trioxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/73—After-treatment of removed components
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D5/00—Sulfates or sulfites of sodium, potassium or alkali metals in general
- C01D5/14—Preparation of sulfites
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D5/00—Sulfates or sulfites of sodium, potassium or alkali metals in general
- C01D5/14—Preparation of sulfites
- C01D5/145—Pyrosulfites or metabisulfites
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Biomedical Technology (AREA)
- Treating Waste Gases (AREA)
- External Artificial Organs (AREA)
- Removal Of Specific Substances (AREA)
- Detergent Compositions (AREA)
- Treatment Of Water By Ion Exchange (AREA)
Priority Applications (13)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NO20001137A NO312131B1 (no) | 2000-03-06 | 2000-03-06 | Fremgangsmåte for å fjerne natriumsulfat fra en fosfatlösning |
| EP01914246A EP1265692B1 (de) | 2000-03-06 | 2001-03-02 | Verfahren zur reinigung wässriger pufferlösungen |
| BRPI0109015-1A BR0109015B1 (pt) | 2000-03-06 | 2001-03-02 | processo para purificar solução tampão de fosfato de sódio utilizada para absorção de dióxido de enxofre de gases de combustão. |
| ES01914246T ES2211782T3 (es) | 2000-03-06 | 2001-03-02 | Procedimiento para purificar soluciones tampon acuosas. |
| CA002402057A CA2402057C (en) | 2000-03-06 | 2001-03-02 | Process for purifying aqueous buffer solutions |
| AU2001239591A AU2001239591A1 (en) | 2000-03-06 | 2001-03-02 | Process for purifying aqueous buffer solutions |
| AT01914246T ATE254950T1 (de) | 2000-03-06 | 2001-03-02 | Verfahren zur reinigung wässriger pufferlösungen |
| PCT/NO2001/000084 WO2001066235A1 (en) | 2000-03-06 | 2001-03-02 | Process for purifying aqueous buffer solutions |
| JP2001564880A JP4464592B2 (ja) | 2000-03-06 | 2001-03-02 | 水性緩衝溶液の精製方法 |
| MXPA02008809A MXPA02008809A (es) | 2000-03-06 | 2001-03-02 | Proceso para purificar soluciones amortiguadores acuosas. |
| CNB01806177XA CN1199715C (zh) | 2000-03-06 | 2001-03-02 | 净化含水缓冲溶液的方法 |
| US10/220,691 US6960332B2 (en) | 2000-03-06 | 2001-03-02 | Process for purifying aqueous buffer solutions |
| DE60101321T DE60101321T2 (de) | 2000-03-06 | 2001-03-02 | Verfahren zur reinigung wässriger pufferlösungen |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NO20001137A NO312131B1 (no) | 2000-03-06 | 2000-03-06 | Fremgangsmåte for å fjerne natriumsulfat fra en fosfatlösning |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| NO20001137D0 NO20001137D0 (no) | 2000-03-06 |
| NO20001137L NO20001137L (no) | 2001-09-07 |
| NO312131B1 true NO312131B1 (no) | 2002-03-25 |
Family
ID=19910840
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO20001137A NO312131B1 (no) | 2000-03-06 | 2000-03-06 | Fremgangsmåte for å fjerne natriumsulfat fra en fosfatlösning |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US6960332B2 (de) |
| EP (1) | EP1265692B1 (de) |
| JP (1) | JP4464592B2 (de) |
| CN (1) | CN1199715C (de) |
| AT (1) | ATE254950T1 (de) |
| AU (1) | AU2001239591A1 (de) |
| BR (1) | BR0109015B1 (de) |
| CA (1) | CA2402057C (de) |
| DE (1) | DE60101321T2 (de) |
| ES (1) | ES2211782T3 (de) |
| MX (1) | MXPA02008809A (de) |
| NO (1) | NO312131B1 (de) |
| WO (1) | WO2001066235A1 (de) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8545754B2 (en) | 2009-04-23 | 2013-10-01 | Medtronic, Inc. | Radial design oxygenator with heat exchanger |
| MX2013004816A (es) | 2010-10-29 | 2013-07-02 | Mecs Inc | Recuperacion regenerativa de dioxido de azufre de gases efluentes. |
| WO2013011092A1 (en) * | 2011-07-19 | 2013-01-24 | Pureteq A/S | Method for removing impurities from flue gas condensate |
| CN102992289B (zh) * | 2012-12-27 | 2014-09-17 | 广西明利化工有限公司 | 一种生产食品级磷酸的方法 |
| US10589223B1 (en) | 2019-04-18 | 2020-03-17 | Saudi Arabian Oil Company | Method and apparatus for treating a sulfur dioxide containing stream by hydrogen sulfide in aqueous conditions |
| CN114367170B (zh) * | 2021-12-13 | 2024-08-09 | 武钢资源集团有限公司 | 富集烟气中二氧化硫的方法 |
| CN114272731B (zh) * | 2022-01-10 | 2024-07-05 | 武钢资源集团乌龙泉矿业有限公司 | 一种烟气中二氧化硫回收与再利用的装置及方法 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3911093A (en) * | 1971-10-18 | 1975-10-07 | Stauffer Chemical Co | Recovery of SO{HD 2 {B from waste gas emissions |
| NO155684C (no) * | 1983-09-08 | 1987-05-13 | Sintef | Fremgangsmaate for fjernelse av svoveldioksyd fra avgasser. |
| US4519994A (en) * | 1984-02-27 | 1985-05-28 | Stauffer Chemical Company | Process for absorption of SO2 into phosphate absorbent |
| DD252978A5 (de) * | 1985-09-16 | 1988-01-06 | K | Verfahren zur reinigung von schwefeldioxid enthaltenden gasen |
| NO164218C (no) * | 1988-02-24 | 1990-09-12 | Sintef | Fremgangsmaate for rensing av vandige bufferloesninger. |
| US5785888A (en) * | 1995-03-24 | 1998-07-28 | Milmac Operating Company | Method for removal of sulfur dioxide |
-
2000
- 2000-03-06 NO NO20001137A patent/NO312131B1/no not_active IP Right Cessation
-
2001
- 2001-03-02 AT AT01914246T patent/ATE254950T1/de not_active IP Right Cessation
- 2001-03-02 JP JP2001564880A patent/JP4464592B2/ja not_active Expired - Fee Related
- 2001-03-02 DE DE60101321T patent/DE60101321T2/de not_active Expired - Lifetime
- 2001-03-02 EP EP01914246A patent/EP1265692B1/de not_active Expired - Lifetime
- 2001-03-02 MX MXPA02008809A patent/MXPA02008809A/es active IP Right Grant
- 2001-03-02 WO PCT/NO2001/000084 patent/WO2001066235A1/en not_active Ceased
- 2001-03-02 ES ES01914246T patent/ES2211782T3/es not_active Expired - Lifetime
- 2001-03-02 BR BRPI0109015-1A patent/BR0109015B1/pt not_active IP Right Cessation
- 2001-03-02 CA CA002402057A patent/CA2402057C/en not_active Expired - Fee Related
- 2001-03-02 US US10/220,691 patent/US6960332B2/en not_active Expired - Fee Related
- 2001-03-02 AU AU2001239591A patent/AU2001239591A1/en not_active Abandoned
- 2001-03-02 CN CNB01806177XA patent/CN1199715C/zh not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN1199715C (zh) | 2005-05-04 |
| JP4464592B2 (ja) | 2010-05-19 |
| NO20001137L (no) | 2001-09-07 |
| CA2402057A1 (en) | 2001-09-13 |
| US6960332B2 (en) | 2005-11-01 |
| US20030106852A1 (en) | 2003-06-12 |
| EP1265692A1 (de) | 2002-12-18 |
| CN1416360A (zh) | 2003-05-07 |
| DE60101321T2 (de) | 2004-09-09 |
| BR0109015A (pt) | 2007-05-29 |
| CA2402057C (en) | 2008-07-29 |
| MXPA02008809A (es) | 2004-10-15 |
| BR0109015B1 (pt) | 2010-06-15 |
| ES2211782T3 (es) | 2004-07-16 |
| EP1265692B1 (de) | 2003-11-26 |
| AU2001239591A1 (en) | 2001-09-17 |
| ATE254950T1 (de) | 2003-12-15 |
| JP2003525735A (ja) | 2003-09-02 |
| DE60101321D1 (de) | 2004-01-08 |
| NO20001137D0 (no) | 2000-03-06 |
| WO2001066235A1 (en) | 2001-09-13 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM1K | Lapsed by not paying the annual fees |