NO315328B1 - Asfalt inneholdende interpolymerer modifisert med olefin/vinylidenaromatiskmonomer - Google Patents

Asfalt inneholdende interpolymerer modifisert med olefin/vinylidenaromatiskmonomer Download PDF

Info

Publication number: NO315328B1
Authority: NO; Norway
Prior art keywords: weight; component; units derived; ethylene; polymer units
Prior art date: 1996-11-21

Application number

NO19992410A

Other languages

English (en)

Norwegian (no)

Other versions

NO992410L (no

NO992410D0 (no

Inventor

James C Stevens

Francis J Timmers

Arnold L Gatzke

Corwin J Bredeweg

Kevin W Mckay

William A Gros

Charles F Diehl

Original Assignee

Dow Global Technologies Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1996-11-21

Filing date

1999-05-20

Publication date

2003-08-18

1999-05-20 Application filed by Dow Global Technologies Inc filed Critical Dow Global Technologies Inc

1999-05-20 Publication of NO992410D0 publication Critical patent/NO992410D0/no

1999-07-20 Publication of NO992410L publication Critical patent/NO992410L/no

2003-08-18 Publication of NO315328B1 publication Critical patent/NO315328B1/no

Links

239000010426 asphalt Substances 0.000 title claims description 85
239000000178 monomer Substances 0.000 title claims description 53
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title claims description 12
150000001336 alkenes Chemical group 0.000 title description 11
239000000203 mixture Substances 0.000 claims description 94
229920000642 polymer Polymers 0.000 claims description 80
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 69
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 38
239000005977 Ethylene Substances 0.000 claims description 38
229920002554 vinyl polymer Polymers 0.000 claims description 38
239000000463 material Substances 0.000 claims description 33
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 32
238000000034 method Methods 0.000 claims description 27
-1 aliphatic olefin Chemical class 0.000 claims description 18
238000002156 mixing Methods 0.000 claims description 16
239000006185 dispersion Substances 0.000 claims description 15
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 12
125000004432 carbon atom Chemical group C* 0.000 claims description 12
150000001993 dienes Chemical class 0.000 claims description 12
239000000839 emulsion Substances 0.000 claims description 12
238000004132 cross linking Methods 0.000 claims description 11
229910052717 sulfur Inorganic materials 0.000 claims description 10
239000011593 sulfur Substances 0.000 claims description 10
OJOWICOBYCXEKR-KRXBUXKQSA-N (5e)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C/C)/CC1C=C2 OJOWICOBYCXEKR-KRXBUXKQSA-N 0.000 claims description 7
239000000155 melt Substances 0.000 claims description 4
239000003054 catalyst Substances 0.000 description 26
239000002904 solvent Substances 0.000 description 20
239000001257 hydrogen Substances 0.000 description 16
229910052739 hydrogen Inorganic materials 0.000 description 16
238000006116 polymerization reaction Methods 0.000 description 16
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 14
239000000243 solution Substances 0.000 description 13
239000000126 substance Substances 0.000 description 13
BXOUVIIITJXIKB-UHFFFAOYSA-N ethene;styrene Chemical compound C=C.C=CC1=CC=CC=C1 BXOUVIIITJXIKB-UHFFFAOYSA-N 0.000 description 10
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
239000004711 α-olefin Substances 0.000 description 8
239000000654 additive Substances 0.000 description 7
239000010779 crude oil Substances 0.000 description 7
238000002360 preparation method Methods 0.000 description 7
230000001105 regulatory effect Effects 0.000 description 7
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
125000003118 aryl group Chemical group 0.000 description 6
229920001519 homopolymer Polymers 0.000 description 6
238000004519 manufacturing process Methods 0.000 description 6
239000003607 modifier Substances 0.000 description 6
239000003208 petroleum Substances 0.000 description 6
239000007787 solid Substances 0.000 description 6
238000012360 testing method Methods 0.000 description 6
OBAJXDYVZBHCGT-UHFFFAOYSA-N tris(pentafluorophenyl)borane Chemical compound FC1=C(F)C(F)=C(F)C(F)=C1B(C=1C(=C(F)C(F)=C(F)C=1F)F)C1=C(F)C(F)=C(F)C(F)=C1F OBAJXDYVZBHCGT-UHFFFAOYSA-N 0.000 description 6
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
125000001931 aliphatic group Chemical group 0.000 description 5
229910052799 carbon Inorganic materials 0.000 description 5
238000006243 chemical reaction Methods 0.000 description 5
239000003426 co-catalyst Substances 0.000 description 5
229920001577 copolymer Polymers 0.000 description 5
125000001183 hydrocarbyl group Chemical group 0.000 description 5
125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 5
241000196324 Embryophyta Species 0.000 description 4
YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 4
238000005481 NMR spectroscopy Methods 0.000 description 4
239000011230 binding agent Substances 0.000 description 4
239000007789 gas Substances 0.000 description 4
239000007788 liquid Substances 0.000 description 4
239000003921 oil Substances 0.000 description 4
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 4
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 description 3
OKTJSMMVPCPJKN-OUBTZVSYSA-N Carbon-13 Chemical compound [13C] OKTJSMMVPCPJKN-OUBTZVSYSA-N 0.000 description 3
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
125000000217 alkyl group Chemical group 0.000 description 3
229910052782 aluminium Inorganic materials 0.000 description 3
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
150000001875 compounds Chemical class 0.000 description 3
239000004035 construction material Substances 0.000 description 3
ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical compound C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 3
125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 description 3
125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 3
229910052736 halogen Inorganic materials 0.000 description 3
150000002367 halogens Chemical group 0.000 description 3
229930195733 hydrocarbon Natural products 0.000 description 3
150000002430 hydrocarbons Chemical class 0.000 description 3
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 3
238000010348 incorporation Methods 0.000 description 3
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
229920000098 polyolefin Polymers 0.000 description 3
238000003860 storage Methods 0.000 description 3
125000001424 substituent group Chemical group 0.000 description 3
239000011269 tar Substances 0.000 description 3
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical class C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
239000004215 Carbon black (E152) Substances 0.000 description 2
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
239000005864 Sulphur Substances 0.000 description 2
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
230000032683 aging Effects 0.000 description 2
XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 2
239000003963 antioxidant agent Substances 0.000 description 2
239000012298 atmosphere Substances 0.000 description 2
235000011089 carbon dioxide Nutrition 0.000 description 2
150000004696 coordination complex Chemical class 0.000 description 2
125000004122 cyclic group Chemical group 0.000 description 2
239000003085 diluting agent Substances 0.000 description 2
238000011010 flushing procedure Methods 0.000 description 2
150000002431 hydrogen Chemical class 0.000 description 2
239000012535 impurity Substances 0.000 description 2
238000002347 injection Methods 0.000 description 2
239000007924 injection Substances 0.000 description 2
229910052500 inorganic mineral Inorganic materials 0.000 description 2
230000003993 interaction Effects 0.000 description 2
QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
239000011707 mineral Substances 0.000 description 2
239000001301 oxygen Substances 0.000 description 2
229910052760 oxygen Inorganic materials 0.000 description 2
239000008188 pellet Substances 0.000 description 2
239000011295 pitch Substances 0.000 description 2
229920002959 polymer blend Polymers 0.000 description 2
239000000047 product Substances 0.000 description 2
230000001698 pyrogenic effect Effects 0.000 description 2
229920005989 resin Polymers 0.000 description 2
239000011347 resin Substances 0.000 description 2
238000005096 rolling process Methods 0.000 description 2
229920006395 saturated elastomer Polymers 0.000 description 2
238000000926 separation method Methods 0.000 description 2
239000000377 silicon dioxide Substances 0.000 description 2
235000012239 silicon dioxide Nutrition 0.000 description 2
239000002002 slurry Substances 0.000 description 2
238000013179 statistical model Methods 0.000 description 2
150000003440 styrenes Chemical class 0.000 description 2
125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 2
238000010998 test method Methods 0.000 description 2
239000010409 thin film Substances 0.000 description 2
KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 2
229910052719 titanium Inorganic materials 0.000 description 2
239000010936 titanium Substances 0.000 description 2
229910052726 zirconium Inorganic materials 0.000 description 2
PRBHEGAFLDMLAL-GQCTYLIASA-N (4e)-hexa-1,4-diene Chemical compound C\C=C\CC=C PRBHEGAFLDMLAL-GQCTYLIASA-N 0.000 description 1
PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical group C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 description 1
QPFMBZIOSGYJDE-QDNHWIQGSA-N 1,1,2,2-tetrachlorethane-d2 Chemical compound [2H]C(Cl)(Cl)C([2H])(Cl)Cl QPFMBZIOSGYJDE-QDNHWIQGSA-N 0.000 description 1
PBKONEOXTCPAFI-UHFFFAOYSA-N 1,2,4-trichlorobenzene Chemical compound ClC1=CC=C(Cl)C(Cl)=C1 PBKONEOXTCPAFI-UHFFFAOYSA-N 0.000 description 1
NVZWEEGUWXZOKI-UHFFFAOYSA-N 1-ethenyl-2-methylbenzene Chemical compound CC1=CC=CC=C1C=C NVZWEEGUWXZOKI-UHFFFAOYSA-N 0.000 description 1
JZHGRUMIRATHIU-UHFFFAOYSA-N 1-ethenyl-3-methylbenzene Chemical compound CC1=CC=CC(C=C)=C1 JZHGRUMIRATHIU-UHFFFAOYSA-N 0.000 description 1
LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 1
KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 1
238000005160 1H NMR spectroscopy Methods 0.000 description 1
YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Natural products C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 description 1
SBYMUDUGTIKLCR-UHFFFAOYSA-N 2-chloroethenylbenzene Chemical compound ClC=CC1=CC=CC=C1 SBYMUDUGTIKLCR-UHFFFAOYSA-N 0.000 description 1
AQZWEFBJYQSQEH-UHFFFAOYSA-N 2-methyloxaluminane Chemical group C[Al]1CCCCO1 AQZWEFBJYQSQEH-UHFFFAOYSA-N 0.000 description 1
DXIJHCSGLOHNES-UHFFFAOYSA-N 3,3-dimethylbut-1-enylbenzene Chemical compound CC(C)(C)C=CC1=CC=CC=C1 DXIJHCSGLOHNES-UHFFFAOYSA-N 0.000 description 1
JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
UCKITPBQPGXDHV-UHFFFAOYSA-N 7-methylocta-1,6-diene Chemical compound CC(C)=CCCCC=C UCKITPBQPGXDHV-UHFFFAOYSA-N 0.000 description 1
RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
GMWURZOLXOJQHG-UHFFFAOYSA-N C1(=CC=CC=C1)C=CC=CC1=CC=CC=C1.C[Si](C)=[Zr](C1C(=CC2=C(C=CC=C12)C1=CC=CC=C1)C)C1C(=CC2=C(C=CC=C12)C1=CC=CC=C1)C Chemical compound C1(=CC=CC=C1)C=CC=CC1=CC=CC=C1.C[Si](C)=[Zr](C1C(=CC2=C(C=CC=C12)C1=CC=CC=C1)C)C1C(=CC2=C(C=CC=C12)C1=CC=CC=C1)C GMWURZOLXOJQHG-UHFFFAOYSA-N 0.000 description 1
FLFNHHSXSLXYQB-UHFFFAOYSA-L CC1=CC(C(=CC=C2)C=3C=CC=CC=3)=C2C1[Zr](Cl)(Cl)(=[Si](C)C)C1C(C)=CC2=C1C=CC=C2C1=CC=CC=C1 Chemical compound CC1=CC(C(=CC=C2)C=3C=CC=CC=3)=C2C1[Zr](Cl)(Cl)(=[Si](C)C)C1C(C)=CC2=C1C=CC=C2C1=CC=CC=C1 FLFNHHSXSLXYQB-UHFFFAOYSA-L 0.000 description 1
XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
CUDSBWGCGSUXDB-UHFFFAOYSA-N Dibutyl disulfide Chemical group CCCCSSCCCC CUDSBWGCGSUXDB-UHFFFAOYSA-N 0.000 description 1
BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 description 1
OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 1
238000012565 NMR experiment Methods 0.000 description 1
240000007930 Oxalis acetosella Species 0.000 description 1
235000008098 Oxalis acetosella Nutrition 0.000 description 1
239000004793 Polystyrene Substances 0.000 description 1
KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
239000012963 UV stabilizer Substances 0.000 description 1
RSWGJHLUYNHPMX-ONCXSQPRSA-N abietic acid Chemical compound C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C(O)=O RSWGJHLUYNHPMX-ONCXSQPRSA-N 0.000 description 1
230000003213 activating effect Effects 0.000 description 1
239000008186 active pharmaceutical agent Substances 0.000 description 1
230000000996 additive effect Effects 0.000 description 1
238000013019 agitation Methods 0.000 description 1
150000001335 aliphatic alkanes Chemical class 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
229910000573 alkali metal alloy Inorganic materials 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
150000004703 alkoxides Chemical class 0.000 description 1
AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
230000003078 antioxidant effect Effects 0.000 description 1
238000013459 approach Methods 0.000 description 1
229910052786 argon Inorganic materials 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
NTBYNMBEYCCFPS-UHFFFAOYSA-N azane boric acid Chemical class N.N.N.OB(O)O NTBYNMBEYCCFPS-UHFFFAOYSA-N 0.000 description 1
125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
238000009529 body temperature measurement Methods 0.000 description 1
230000006583 body weight regulation Effects 0.000 description 1
210000000988 bone and bone Anatomy 0.000 description 1
MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
239000006227 byproduct Substances 0.000 description 1
CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
235000013539 calcium stearate Nutrition 0.000 description 1
239000008116 calcium stearate Substances 0.000 description 1
238000004364 calculation method Methods 0.000 description 1
150000001721 carbon Chemical group 0.000 description 1
229960004424 carbon dioxide Drugs 0.000 description 1
238000001460 carbon-13 nuclear magnetic resonance spectrum Methods 0.000 description 1
230000003197 catalytic effect Effects 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
XEHUIDSUOAGHBW-UHFFFAOYSA-N chromium;pentane-2,4-dione Chemical compound [Cr].CC(=O)CC(C)=O.CC(=O)CC(C)=O.CC(=O)CC(C)=O XEHUIDSUOAGHBW-UHFFFAOYSA-N 0.000 description 1
239000003245 coal Substances 0.000 description 1
239000011280 coal tar Substances 0.000 description 1
239000011294 coal tar pitch Substances 0.000 description 1
238000000576 coating method Methods 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
238000010276 construction Methods 0.000 description 1
238000005336 cracking Methods 0.000 description 1
239000003431 cross linking reagent Substances 0.000 description 1
230000007423 decrease Effects 0.000 description 1
230000001419 dependent effect Effects 0.000 description 1
230000001627 detrimental effect Effects 0.000 description 1
229910003460 diamond Inorganic materials 0.000 description 1
239000010432 diamond Substances 0.000 description 1
235000014113 dietary fatty acids Nutrition 0.000 description 1
238000010790 dilution Methods 0.000 description 1
239000012895 dilution Substances 0.000 description 1
239000000539 dimer Substances 0.000 description 1
AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 1
238000009826 distribution Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
239000003995 emulsifying agent Substances 0.000 description 1
125000002573 ethenylidene group Chemical group [*]=C=C([H])[H] 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
238000001704 evaporation Methods 0.000 description 1
230000008020 evaporation Effects 0.000 description 1
238000000605 extraction Methods 0.000 description 1
238000001125 extrusion Methods 0.000 description 1
239000000194 fatty acid Substances 0.000 description 1
229930195729 fatty acid Natural products 0.000 description 1
150000004665 fatty acids Chemical class 0.000 description 1
230000002349 favourable effect Effects 0.000 description 1
239000000945 filler Substances 0.000 description 1
238000001914 filtration Methods 0.000 description 1
125000003983 fluorenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3CC12)* 0.000 description 1
238000010528 free radical solution polymerization reaction Methods 0.000 description 1
229910052735 hafnium Inorganic materials 0.000 description 1
239000002638 heterogeneous catalyst Substances 0.000 description 1
125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
238000000265 homogenisation Methods 0.000 description 1
125000003454 indenyl group Chemical group C1(C=CC2=CC=CC=C12)* 0.000 description 1
239000003112 inhibitor Substances 0.000 description 1
230000007774 longterm Effects 0.000 description 1
239000000314 lubricant Substances 0.000 description 1
229920002521 macromolecule Polymers 0.000 description 1
238000005259 measurement Methods 0.000 description 1
238000002844 melting Methods 0.000 description 1
230000008018 melting Effects 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
125000001434 methanylylidene group Chemical group [H]C#[*] 0.000 description 1
CPOFMOWDMVWCLF-UHFFFAOYSA-N methyl(oxo)alumane Chemical class C[Al]=O CPOFMOWDMVWCLF-UHFFFAOYSA-N 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
239000002808 molecular sieve Substances 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
238000000655 nuclear magnetic resonance spectrum Methods 0.000 description 1
125000001181 organosilyl group Chemical group [SiH3]* 0.000 description 1
TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
239000003415 peat Substances 0.000 description 1
238000005453 pelletization Methods 0.000 description 1
125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
239000000546 pharmaceutical excipient Substances 0.000 description 1
239000012071 phase Substances 0.000 description 1
239000002530 phenolic antioxidant Substances 0.000 description 1
239000003504 photosensitizing agent Substances 0.000 description 1
239000000049 pigment Substances 0.000 description 1
PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 description 1
239000004014 plasticizer Substances 0.000 description 1
230000000379 polymerizing effect Effects 0.000 description 1
229920002223 polystyrene Polymers 0.000 description 1
239000000843 powder Substances 0.000 description 1
238000001556 precipitation Methods 0.000 description 1
238000012545 processing Methods 0.000 description 1
HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
239000001294 propane Substances 0.000 description 1
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
238000010926 purge Methods 0.000 description 1
239000011541 reaction mixture Substances 0.000 description 1
238000007670 refining Methods 0.000 description 1
238000011160 research Methods 0.000 description 1
239000011277 road tar Substances 0.000 description 1
239000011435 rock Substances 0.000 description 1
238000009666 routine test Methods 0.000 description 1
239000004576 sand Substances 0.000 description 1
229930195734 saturated hydrocarbon Natural products 0.000 description 1
229910052710 silicon Inorganic materials 0.000 description 1
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
239000007790 solid phase Substances 0.000 description 1
238000001228 spectrum Methods 0.000 description 1
230000003068 static effect Effects 0.000 description 1
238000003756 stirring Methods 0.000 description 1
239000000725 suspension Substances 0.000 description 1
229960002447 thiram Drugs 0.000 description 1
KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
238000012546 transfer Methods 0.000 description 1
238000005292 vacuum distillation Methods 0.000 description 1
239000006200 vaporizer Substances 0.000 description 1
239000003039 volatile agent Substances 0.000 description 1
239000002023 wood Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L95/00—Compositions of bituminous materials, e.g. asphalt, tar, pitch
- C08L95/005—Aqueous compositions, e.g. emulsions
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/08—Copolymers of styrene
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L95/00—Compositions of bituminous materials, e.g. asphalt, tar, pitch

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Civil Engineering (AREA)
Materials Engineering (AREA)
Structural Engineering (AREA)
Compositions Of Macromolecular Compounds (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

NO19992410A 1996-11-21 1999-05-20 Asfalt inneholdende interpolymerer modifisert med olefin/vinylidenaromatiskmonomer NO315328B1 (no)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US75465896A	1996-11-21	1996-11-21
PCT/US1997/012567 WO1998022535A1 (en)	1996-11-21	1997-07-10	Asphalt modified with olefin/vinylidene aromatic monomer interpolymers

Publications (3)

Publication Number	Publication Date
NO992410D0 NO992410D0 (no)	1999-05-20
NO992410L NO992410L (no)	1999-07-20
NO315328B1 true NO315328B1 (no)	2003-08-18

Family

ID=25035763

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NO19992410A NO315328B1 (no)	1996-11-21	1999-05-20	Asfalt inneholdende interpolymerer modifisert med olefin/vinylidenaromatiskmonomer

Country Status (18)

Country	Link
EP (1)	EP0939792B1 (de)
JP (1)	JP2001504536A (de)
KR (1)	KR20000057153A (de)
CN (1)	CN1238795A (de)
AR (1)	AR007846A1 (de)
AT (1)	ATE209232T1 (de)
AU (1)	AU3885397A (de)
BR (1)	BR9712775A (de)
CA (1)	CA2272105A1 (de)
CZ (1)	CZ179599A3 (de)
DE (1)	DE69709783T2 (de)
ES (1)	ES2163189T3 (de)
HU (1)	HUP9903925A3 (de)
ID (1)	ID19007A (de)
NO (1)	NO315328B1 (de)
TR (1)	TR199901591T2 (de)
WO (1)	WO1998022535A1 (de)
ZA (1)	ZA976136B (de)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JP2002121387A (ja) *	2000-10-13	2002-04-23	Jsr Corp	アスファルト改質材及び改質アスファルト組成物
KR100563802B1 (ko) *	2005-12-21	2006-03-28	주식회사 경우엔지니어링	초박층으로의 포장이 가능한 유색성 도로 포장재 (칼라마이크로 페이브)
US20180030276A1 (en) *	2015-02-26	2018-02-01	E. I. Du Pont De Nemours And Company	Process to modify bitumen
US11976198B2 (en)	2019-01-10	2024-05-07	Basell Poliolefine Italia S.R.L.	Mixtures of bitumen and polymer compositions
JP7638677B2 (ja) *	2020-11-24	2025-03-04	三井化学株式会社	エチレン・１－オクテン共重合体
JP7638678B2 (ja) *	2020-11-24	2025-03-04	三井化学株式会社	ペレット
EP4392491A4 (de) *	2021-08-27	2025-02-26	Kao Corporation	Asphaltzusammensetzung

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR2436160A1 (fr) *	1978-09-13	1980-04-11	Cib	Composition bitumineuse contenant des polymeres et ses applications
IT1217394B (it) *	1988-04-07	1990-03-22	Ausimont Spa	Membrane impermeabilizzanti base di bitume
NZ235032A (en) *	1989-08-31	1993-04-28	Dow Chemical Co	Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component

1997
- 1997-07-10 AT AT97936099T patent/ATE209232T1/de not_active IP Right Cessation
- 1997-07-10 AR ARP970103084A patent/AR007846A1/es not_active Application Discontinuation
- 1997-07-10 ZA ZA976136A patent/ZA976136B/xx unknown
- 1997-07-10 DE DE69709783T patent/DE69709783T2/de not_active Expired - Fee Related
- 1997-07-10 AU AU38853/97A patent/AU3885397A/en not_active Abandoned
- 1997-07-10 ID IDP972397A patent/ID19007A/id unknown
- 1997-07-10 KR KR1019990704428A patent/KR20000057153A/ko not_active Ceased
- 1997-07-10 CN CN97199965A patent/CN1238795A/zh active Pending
- 1997-07-10 TR TR1999/01591T patent/TR199901591T2/xx unknown
- 1997-07-10 BR BR9712775-2A patent/BR9712775A/pt unknown
- 1997-07-10 WO PCT/US1997/012567 patent/WO1998022535A1/en not_active Ceased
- 1997-07-10 ES ES97936099T patent/ES2163189T3/es not_active Expired - Lifetime
- 1997-07-10 EP EP97936099A patent/EP0939792B1/de not_active Expired - Lifetime
- 1997-07-10 JP JP52361798A patent/JP2001504536A/ja not_active Ceased
- 1997-07-10 HU HU9903925A patent/HUP9903925A3/hu unknown
- 1997-07-10 CA CA002272105A patent/CA2272105A1/en not_active Abandoned
- 1997-07-10 CZ CZ991795A patent/CZ179599A3/cs unknown
1999
- 1999-05-20 NO NO19992410A patent/NO315328B1/no unknown

Also Published As

Publication number	Publication date
ID19007A (id)	1998-05-28
AR007846A1 (es)	1999-11-24
CZ179599A3 (cs)	1999-12-15
TR199901591T2 (xx)	1999-10-21
KR20000057153A (ko)	2000-09-15
ES2163189T3 (es)	2002-01-16
NO992410L (no)	1999-07-20
EP0939792A1 (de)	1999-09-08
BR9712775A (pt)	1999-10-26
ZA976136B (en)	1999-01-11
ATE209232T1 (de)	2001-12-15
EP0939792B1 (de)	2001-11-21
JP2001504536A (ja)	2001-04-03
WO1998022535A1 (en)	1998-05-28
HUP9903925A2 (hu)	2000-03-28
CN1238795A (zh)	1999-12-15
CA2272105A1 (en)	1998-05-28
HUP9903925A3 (en)	2000-04-28
AU3885397A (en)	1998-06-10
NO992410D0 (no)	1999-05-20
DE69709783D1 (de)	2002-02-21
DE69709783T2 (de)	2002-05-23

Publication	Publication Date	Title
US6107374A (en)	2000-08-22	Asphalt modified with olefin/vinylidene aromatic monomer interpolymers
US6388014B1 (en)	2002-05-14	Blends of α-olefin/vinylidene aromatic monomer or hindered aliphatic vinylidene monomer interpolymers with polyolefins
EP0285865B1 (de)	1993-10-06	Bituminöse Zusammensetzung, die eine Mischung von Bitumen und einem thermoplastischen Elastomer enthält
US6117926A (en)	2000-09-12	Acid-reacted polymer-modified asphalt compositions and preparation thereof
KR101140075B1 (ko)	2012-04-30	역청 결합제 조성물 및 이의 제조방법
US4868233A (en)	1989-09-19	Polyethylene modified asphalts
US8697781B2 (en)	2014-04-15	Bituminous mixtures with a high polymer content
EP0850277A2 (de)	1998-07-01	Bituminöse zusammensetzung
RU2185403C2 (ru)	2002-07-20	Битумная композиция, способ увеличения ее срока службы, композиция блок-сополимера
US5854335A (en)	1998-12-29	Bituminous composition with diene/monovinyl aromatic block copolymer
NO315328B1 (no)	2003-08-18	Asfalt inneholdende interpolymerer modifisert med olefin/vinylidenaromatiskmonomer
HUP0004035A2 (en)	2001-03-28	Sulfonated substantially random interpolymers, blends therewith and articles made therefrom
US5393811A (en)	1995-02-28	Composition and method for improving the storage stability of polymer modified asphalts
EP0923620A1 (de)	1999-06-23	Mischungen aus interpolymeren von alpha-olefin-/vinylidenaromatischen monomeren und/oder gehinderten aliphatischen monomeren oder vinylidencycloaliphatischen monomeren
US5756563A (en)	1998-05-26	Process for the preparation of stable mixtures of bitumen and polymer
US2802798A (en)	1957-08-13	High grade paving asphalt and method of making same
GB2384240A (en)	2003-07-23	Preparation of polymer-modified bitumen compositions
RU2152412C1 (ru)	2000-07-10	Способ получения битумно-каучукового вяжущего
US20230002525A1 (en)	2023-01-05	Solution Polymerization Process for Making High-Density Polyethylene with Long-Chain Branching
US3265517A (en)	1966-08-09	Hydrodechlorination processes and products of chlorinated asphaltenes and thermoplastic hydrocarbon resins
US2935486A (en)	1960-05-03	Asphalt, isobutylene-styrene copolymer, hydrocarbon oil adhesive for laminates
WO1996037545A1 (en)	1996-11-28	Preparation process for polymer-modified bitumen
EP1205520A1 (de)	2002-05-15	Verfahren zur Herstellung von stabilen Mischungen von Bitumen und Polymeren