NO326200B1 - Polymerer med termofortyknings egenskaper og fremgangsmate for fremstilling derav - Google Patents

Polymerer med termofortyknings egenskaper og fremgangsmate for fremstilling derav Download PDF

Info

Publication number: NO326200B1
Authority: NO; Norway
Prior art keywords: polymer; water; thermo; parts; thickening
Prior art date: 1998-12-14

Application number

NO20012923A

Other languages

English (en)

Norwegian (no)

Other versions

NO20012923D0 (no

NO20012923L (no

Inventor

Pascale Corpart

Dominique Charmot

Dominic Wai Kwing Yeung

Leo Zhaoqing Liu

Bruno R C Langlois

Original Assignee

Rhodia

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1998-12-14

Filing date

2001-06-13

Publication date

2008-10-20

2001-06-13 Application filed by Rhodia filed Critical Rhodia

2001-06-13 Publication of NO20012923D0 publication Critical patent/NO20012923D0/no

2001-08-13 Publication of NO20012923L publication Critical patent/NO20012923L/no

2008-10-20 Publication of NO326200B1 publication Critical patent/NO326200B1/no

Links

229920000642 polymer Polymers 0.000 title claims description 88
238000000034 method Methods 0.000 title claims description 34
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238000006116 polymerization reaction Methods 0.000 claims description 20
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238000004519 manufacturing process Methods 0.000 claims description 9
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235000015112 vegetable and seed oil Nutrition 0.000 description 1
239000008158 vegetable oil Substances 0.000 description 1
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/32—Polymerisation in water-in-oil emulsions
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
- C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
- C08F290/06—Polymers provided for in subclass C08G
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G81/00—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers
- C08G81/02—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers at least one of the polymers being obtained by reactions involving only carbon-to-carbon unsaturated bonds
- C08G81/024—Block or graft polymers containing sequences of polymers of C08C or C08F and of polymers of C08G
- C08G81/025—Block or graft polymers containing sequences of polymers of C08C or C08F and of polymers of C08G containing polyether sequences

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Oil, Petroleum & Natural Gas (AREA)
Polymerisation Methods In General (AREA)
Cosmetics (AREA)
Compositions Of Macromolecular Compounds (AREA)
Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
Materials For Medical Uses (AREA)
Medicinal Preparation (AREA)
Graft Or Block Polymers (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Macromonomer-Based Addition Polymer (AREA)
Silicon Polymers (AREA)
Polyesters Or Polycarbonates (AREA)

NO20012923A 1998-12-14 2001-06-13 Polymerer med termofortyknings egenskaper og fremgangsmate for fremstilling derav NO326200B1 (no)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US11230698P	1998-12-14	1998-12-14
PCT/US1999/029177 WO2000035961A1 (en)	1998-12-14	1999-12-09	Polymers which exhibit thermothickening properties and process making same

Publications (3)

Publication Number	Publication Date
NO20012923D0 NO20012923D0 (no)	2001-06-13
NO20012923L NO20012923L (no)	2001-08-13
NO326200B1 true NO326200B1 (no)	2008-10-20

Family

ID=22343182

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NO20012923A NO326200B1 (no)	1998-12-14	2001-06-13	Polymerer med termofortyknings egenskaper og fremgangsmate for fremstilling derav

Country Status (9)

Country	Link
US (1)	US6838514B2 (de)
EP (1)	EP1141032B1 (de)
AT (1)	ATE281475T1 (de)
AU (1)	AU2047700A (de)
CA (2)	CA2640611C (de)
DE (1)	DE69921687T2 (de)
MX (1)	MXPA01005983A (de)
NO (1)	NO326200B1 (de)
WO (1)	WO2000035961A1 (de)

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR2811995B1 (fr)	2000-07-21	2003-06-06	Oreal	Polymere comprenant des unites hydrosolubles et des unites a lcst, et composition aqueuse le comprenant
FR2815637B1 (fr) *	2000-10-20	2006-08-04	Rhodia Chimie Sa	Procede de preparation d'une emulsion dont la phase huileuse est de forte viscosite
JP4908674B2 (ja) *	2000-10-24	2012-04-04	株式会社日本触媒	多孔質架橋ポリマー材料の製法
FR2819415B1 (fr)	2001-01-15	2003-11-21	Oreal	Dispersions stabilisees a des temperatures des 4 a 50 au moyen d'un polymere comportant des unites hydrosolubles et des unites a lcst
FR2819429B1 (fr)	2001-01-15	2003-03-07	Oreal	Emulsions et compositions moussantes contenant un polymere comprenant des unites hydrosolubles et des unites a lcst, notamment pour des applications cosmetiques
FR2819397B1 (fr) *	2001-01-15	2003-03-07	Oreal	Compositions a effet optique, notamment cosmetiques
FR2819416B1 (fr) *	2001-01-15	2004-12-17	Oreal	Composition moussante tehrmogelifiante et mousse obtenue
FR2824832B1 (fr)	2001-05-16	2005-05-27	Oreal	Polymeres hydrosolubles a squelette hydrosoluble et a unites laterales a lcst, leur procede de preparation, compositions aqueuses les contenant, et leur utilisation dans le domaine cosmetique
KR20050053725A (ko) *	2002-10-04	2005-06-08	도아고세이가부시키가이샤	수용성 증점제 및 액상 산성 세정제
WO2004078165A1 (ja) *	2003-03-07	2004-09-16	Toagosei Co., Ltd.	貼付剤用基剤及びそれを用いた貼付剤
US7776958B2 (en) *	2004-06-30	2010-08-17	Nalco Company	Inverse emulsion polymer and method of use thereof
FR2932070B1 (fr)	2008-06-10	2012-08-17	Oreal	Ensemble de maquillage et/ou de soin des cils
FR2940761B1 (fr)	2009-01-07	2012-12-28	Polymerexpert Sa	Composition anti-ronflement contenant un polymere thermogelifiant
US9580639B2 (en)	2011-07-18	2017-02-28	Saudi Arabian Oil Company	Controlled release of surfactants for enhanced oil recovery
US10626294B2 (en)	2012-10-15	2020-04-21	L'oreal	Aqueous wax dispersions containing volatile solvents
US10413496B2 (en)	2012-10-15	2019-09-17	L'oreal	Aqueous wax dispersions
US9408785B2 (en)	2012-10-15	2016-08-09	L'oreal	Hair styling compositions containing aqueous wax dispersions
DE102013007680A1 (de) *	2013-05-03	2014-11-06	Tougas Oilfield Solutions Gmbh	Elektrolythaltige wässrige Polymerlösung und Verfahren zur Tertiärförderung von Erdöl
US10561596B2 (en)	2014-04-11	2020-02-18	L'oreal	Compositions and dispersions containing particles comprising a polymer
GB2533055B (en)	2014-05-17	2016-11-02	Halliburton Energy Services Inc	Thermal thickening in invert emulsion treatment fluids
CN108586671B (zh) *	2018-04-07	2019-06-04	四川大学	一种阴离子型热增黏水溶性聚合物及其制备方法和应用
US11434416B2 (en) *	2018-04-19	2022-09-06	ExxonMobil Technology and Engineering Company	Formation of in-situ activated injection fluids for enhanced oil recovery applications
FR3091996B1 (fr)	2019-01-24	2021-01-29	Les Laboratoires Brothier	Composition cicatrisante

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
NL226509A (de) *	1957-04-02
US3284393A (en)	1959-11-04	1966-11-08	Dow Chemical Co	Water-in-oil emulsion polymerization process for polymerizing watersoluble monomers
US4268641A (en) *	1979-04-24	1981-05-19	Union Carbide Corporation	Acrylic acid-acrylate copolymer thickening agents
US4384096A (en) *	1979-08-27	1983-05-17	The Dow Chemical Company	Liquid emulsion polymers useful as pH responsive thickeners for aqueous systems
US4351754A (en) *	1979-09-17	1982-09-28	Rohm And Haas Company	Thickening agent for aqueous compositions
US4421902A (en) *	1982-09-30	1983-12-20	Rohm And Haas Company	Alkyl, poly(oxyethylene) poly(carbonyloxyethylene) acrylate emulsion copolymers for thickening purposes
US4892916A (en) *	1984-08-15	1990-01-09	Allied Colloids Limited	Polymeric thickeners and their production
USRE33156E (en) *	1984-08-23	1990-01-30	Desoto, Inc.	Alkali soluble latex thickeners
EP0215565B1 (de) *	1985-08-12	1991-07-24	Ciba Specialty Chemicals Water Treatments Limited	Dispergiermittel
US4616074A (en) *	1985-10-01	1986-10-07	Alco Chemical Corporation	Acrylic-methylene succinic ester emulsion copolymers for thickening aqueous systems
US4873086A (en) *	1986-03-03	1989-10-10	Ciba-Geigy Corporation	Hydrogels with increased organic solvent soluble active agent loading capacity, their preparation and the use thereof
US4722962A (en)	1986-06-12	1988-02-02	Desoto, Inc.	Nonionic associative thickeners
US5478602A (en)	1992-05-29	1995-12-26	Union Carbide Chemicals & Plastics Technology Corporation	Polymers containing macromonomers and their use in a method of coating substrates
US5461100A (en)	1992-05-29	1995-10-24	Union Carbide Chemicals & Plastics Technology Corporation	Aircraft anti-icing fluids
US5451641A (en) *	1992-08-24	1995-09-19	Rohm And Haas Company	Multi-stage polymer particles having a hydrophobically-modified, ionically-soluble stage
US5294692A (en) *	1993-06-30	1994-03-15	National Starch And Chemical Investment Holding Corporation	Associative monomers and polymers
AU6385796A (en)	1995-06-16	1997-01-15	Medlogic Global Corporation	Responsive polymer networks and methods of their use
CA2263411A1 (en) *	1996-08-12	1998-02-19	Eyal S. Ron	Composition for pharmaceutical applications
US6018033A (en) *	1997-05-13	2000-01-25	Purdue Research Foundation	Hydrophilic, hydrophobic, and thermoreversible saccharide gels and forms, and methods for producing same

1999
- 1999-12-09 AT AT99964182T patent/ATE281475T1/de not_active IP Right Cessation
- 1999-12-09 MX MXPA01005983A patent/MXPA01005983A/es active IP Right Grant
- 1999-12-09 CA CA2640611A patent/CA2640611C/en not_active Expired - Lifetime
- 1999-12-09 AU AU20477/00A patent/AU2047700A/en not_active Abandoned
- 1999-12-09 EP EP99964182A patent/EP1141032B1/de not_active Expired - Lifetime
- 1999-12-09 CA CA002355598A patent/CA2355598C/en not_active Expired - Lifetime
- 1999-12-09 DE DE69921687T patent/DE69921687T2/de not_active Expired - Lifetime
- 1999-12-09 WO PCT/US1999/029177 patent/WO2000035961A1/en not_active Ceased
2001
- 2001-06-13 NO NO20012923A patent/NO326200B1/no not_active IP Right Cessation
2003
- 2003-04-09 US US10/410,637 patent/US6838514B2/en not_active Expired - Lifetime

Also Published As

Publication number	Publication date
CA2355598A1 (en)	2000-06-22
CA2640611C (en)	2010-06-08
EP1141032B1 (de)	2004-11-03
CA2640611A1 (en)	2000-06-22
CA2355598C (en)	2010-02-02
MXPA01005983A (es)	2002-05-14
ATE281475T1 (de)	2004-11-15
DE69921687D1 (de)	2004-12-09
US6838514B2 (en)	2005-01-04
EP1141032A1 (de)	2001-10-10
NO20012923D0 (no)	2001-06-13
DE69921687T2 (de)	2005-11-03
WO2000035961A1 (en)	2000-06-22
AU2047700A (en)	2000-07-03
US20030204014A1 (en)	2003-10-30
NO20012923L (no)	2001-08-13

Legal Events

Date	Code	Title	Description
2020-01-13	MK1K	Patent expired

Publication	Publication Date	Title
EP1141032B1 (de)	2004-11-03	Polymere mit thermoverdickungs-eigenschaften und verfahren zu deren herstellung
RU2157382C2 (ru)	2000-10-10	Водная полимерная дисперсия и способ ее получения
CA2166195C (en)	2000-10-03	Processes for preparing aqueous polymer emulsions
US5075401A (en)	1991-12-24	Method of making graft copolymers
JP3034847B2 (ja)	2000-04-17	新規な会合型ポリマーと、逆相乳化重合によるその製造方法
JP2005144346A (ja)	2005-06-09	凝集処理剤及びその使用方法
JP2007529589A (ja)	2007-10-25	水性系のための液体分散ポリマー増粘剤
Durand et al.	2000	Thermoassociative graft copolymers based on poly (N‐isopropylacrylamide): Relation between the chemical structure and the rheological properties
JP2015504455A (ja)	2015-02-12	会合性モノマーに基づく少なくとも１種のポリマーを含有する増粘剤
CN105378026B (zh)	2019-05-31	含电解质的水性聚合物溶液以及石油的三次采油的方法
JP4840995B2 (ja)	2011-12-21	油中水型分散液の希釈液、その調製方法及びその使用方法
JP4130699B2 (ja)	2008-08-06	カルボン酸とポリオレフィン性不飽和カルボン酸誘導体とのコポリマー並びに増粘剤及び分散剤としてのその使用
US20060229369A1 (en)	2006-10-12	Use of 2-hydroxy-2-sulfinato acetic acid or the salts thereof as an initiator in w/o emulsions
EP0642540A1 (de)	1995-03-15	Komplexe hydrophobe verbindungen, makromonomere und polymere, die makromonomere enthalten.
JP2015163659A (ja)	2015-09-10	乳化重合用安定剤
AU2023263724B2 (en)	2024-11-21	Cementitious composition comprising a polymeric micro-gel as an anti-gas migration agent
JP2772479B2 (ja)	1998-07-02	アルキル（メタ）アクリレートに基づいた熱架橋性重合体の水性分散液、その製造法及び特に結合剤及び／又は含浸剤としてのその用途
KR20150013862A (ko)	2015-02-05	음이온성 또는 비이온성 중합체 및 안정화제를 함유하는 역 분산액
JPH02292350A (ja)	1990-12-03	ワックス系水性エマルジョンおよびその製造方法
UA69434C2 (uk)	2004-09-15	Водні емульсії пероксидів
Sarac et al.	2003	Effect of initiators and ethoxylation degree of non‐ionic emulsifiers on vinyl acetate and butyl acrylate emulsion copolymerization in the loop reactor
TW201038693A (en)	2010-11-01	Aqueous adhesive
US4118355A (en)	1978-10-03	Method and composition of a polymer in convenient liquid form
JP5561759B2 (ja)	2014-07-30	油中水型エマルジョン、その製造方法およびその使用方法
CA3251264C (en)	2026-03-17	Cementitious composition comprising a polymeric micro-gel as an anti-gas migration agent