NO327769B1 - Fremgangsmate for fremstilling av et olefinprodukt fra et oksygenatrastoff samt fremgangsmate for fremstilling av molekylsil - Google Patents

Fremgangsmate for fremstilling av et olefinprodukt fra et oksygenatrastoff samt fremgangsmate for fremstilling av molekylsil Download PDF

Info

Publication number: NO327769B1
Authority: NO; Norway
Prior art keywords: molecular sieve; sapo; aluminum phosphate; catalyst; ppm
Prior art date: 2000-02-24

Application number

NO20023877A

Other languages

English (en)

Norwegian (no)

Other versions

NO20023877L (no

NO20023877D0 (no

Inventor

Teng Xu

Jefferey L White

Original Assignee

Exxonmobil Chem Patents Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2000-02-24

Filing date

2002-08-15

Publication date

2009-09-21

Family has litigation

First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=27057400&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=NO327769(B1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.

2000-02-24 Priority claimed from US09/511,943 external-priority patent/US6743747B1/en

2002-08-15 Application filed by Exxonmobil Chem Patents Inc filed Critical Exxonmobil Chem Patents Inc

2002-08-15 Publication of NO20023877L publication Critical patent/NO20023877L/no

2002-08-15 Publication of NO20023877D0 publication Critical patent/NO20023877D0/no

2009-09-21 Publication of NO327769B1 publication Critical patent/NO327769B1/no

Links

239000002808 molecular sieve Substances 0.000 title claims abstract description 100
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 title claims abstract description 100
150000001336 alkenes Chemical class 0.000 title claims abstract description 49
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title claims abstract description 33
238000000034 method Methods 0.000 title claims description 56
230000008569 process Effects 0.000 title claims description 30
125000004430 oxygen atom Chemical group O* 0.000 title claims description 10
238000002360 preparation method Methods 0.000 title description 5
150000001491 aromatic compounds Chemical class 0.000 claims abstract description 15
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 88
238000006243 chemical reaction Methods 0.000 claims description 78
GHTGICGKYCGOSY-UHFFFAOYSA-K aluminum silicon(4+) phosphate Chemical compound [Al+3].P(=O)([O-])([O-])[O-].[Si+4] GHTGICGKYCGOSY-UHFFFAOYSA-K 0.000 claims description 75
150000002430 hydrocarbons Chemical class 0.000 claims description 69
229930195733 hydrocarbon Natural products 0.000 claims description 68
239000004215 Carbon black (E152) Substances 0.000 claims description 61
239000000203 mixture Substances 0.000 claims description 42
239000007789 gas Substances 0.000 claims description 22
239000011148 porous material Substances 0.000 claims description 20
230000003197 catalytic effect Effects 0.000 claims description 19
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 17
239000001301 oxygen Substances 0.000 claims description 17
229910052760 oxygen Inorganic materials 0.000 claims description 17
230000015572 biosynthetic process Effects 0.000 claims description 15
238000004519 manufacturing process Methods 0.000 claims description 13
238000001228 spectrum Methods 0.000 claims description 13
229910052751 metal Inorganic materials 0.000 claims description 9
239000002184 metal Substances 0.000 claims description 9
238000000889 atomisation Methods 0.000 claims description 8
229910021419 crystalline silicon Inorganic materials 0.000 claims description 4
238000005481 NMR spectroscopy Methods 0.000 claims description 2
239000007787 solid Substances 0.000 claims description 2
239000003054 catalyst Substances 0.000 abstract description 133
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract description 18
239000005977 Ethylene Substances 0.000 abstract description 18
239000000463 material Substances 0.000 abstract description 16
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract description 14
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract description 14
239000013354 porous framework Substances 0.000 abstract description 9
239000011230 binding agent Substances 0.000 abstract description 2
239000000047 product Substances 0.000 description 33
125000003118 aryl group Chemical group 0.000 description 20
-1 polyethylene Polymers 0.000 description 15
230000008929 regeneration Effects 0.000 description 14
238000011069 regeneration method Methods 0.000 description 14
238000005755 formation reaction Methods 0.000 description 13
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 10
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 10
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 9
229920000098 polyolefin Polymers 0.000 description 9
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 8
125000001931 aliphatic group Chemical group 0.000 description 8
239000002994 raw material Substances 0.000 description 8
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 6
LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 6
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 6
ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 6
239000000654 additive Substances 0.000 description 6
150000001875 compounds Chemical class 0.000 description 6
239000003085 diluting agent Substances 0.000 description 6
230000000694 effects Effects 0.000 description 6
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 6
229910052757 nitrogen Inorganic materials 0.000 description 6
239000012071 phase Substances 0.000 description 6
229910052698 phosphorus Inorganic materials 0.000 description 6
239000011574 phosphorus Substances 0.000 description 6
238000003786 synthesis reaction Methods 0.000 description 6
229910052782 aluminium Inorganic materials 0.000 description 5
238000010438 heat treatment Methods 0.000 description 5
229910052734 helium Inorganic materials 0.000 description 5
239000001307 helium Substances 0.000 description 5
SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 5
229910052710 silicon Inorganic materials 0.000 description 5
239000010703 silicon Substances 0.000 description 5
239000000126 substance Substances 0.000 description 5
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
URLKBWYHVLBVBO-UHFFFAOYSA-N Para-Xylene Chemical group CC1=CC=C(C)C=C1 URLKBWYHVLBVBO-UHFFFAOYSA-N 0.000 description 4
NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical compound C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 description 4
JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 4
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
230000000996 additive effect Effects 0.000 description 4
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
PAFZNILMFXTMIY-UHFFFAOYSA-N cyclohexylamine Chemical compound NC1CCCCC1 PAFZNILMFXTMIY-UHFFFAOYSA-N 0.000 description 4
238000002474 experimental method Methods 0.000 description 4
239000011521 glass Substances 0.000 description 4
239000007788 liquid Substances 0.000 description 4
238000002156 mixing Methods 0.000 description 4
239000003921 oil Substances 0.000 description 4
VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
238000000371 solid-state nuclear magnetic resonance spectroscopy Methods 0.000 description 4
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
238000005004 MAS NMR spectroscopy Methods 0.000 description 3
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 3
229910052799 carbon Inorganic materials 0.000 description 3
229910002092 carbon dioxide Inorganic materials 0.000 description 3
239000003575 carbonaceous material Substances 0.000 description 3
239000012530 fluid Substances 0.000 description 3
239000007791 liquid phase Substances 0.000 description 3
CBXCPBUEXACCNR-UHFFFAOYSA-N tetraethylammonium Chemical class CC[N+](CC)(CC)CC CBXCPBUEXACCNR-UHFFFAOYSA-N 0.000 description 3
229940073455 tetraethylammonium hydroxide Drugs 0.000 description 3
LRGJRHZIDJQFCL-UHFFFAOYSA-M tetraethylazanium;hydroxide Chemical compound [OH-].CC[N+](CC)(CC)CC LRGJRHZIDJQFCL-UHFFFAOYSA-M 0.000 description 3
CZDYPVPMEAXLPK-UHFFFAOYSA-N tetramethylsilane Chemical compound C[Si](C)(C)C CZDYPVPMEAXLPK-UHFFFAOYSA-N 0.000 description 3
239000012808 vapor phase Substances 0.000 description 3
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
229910001868 water Inorganic materials 0.000 description 3
FYGHSUNMUKGBRK-UHFFFAOYSA-N 1,2,3-trimethylbenzene Chemical compound CC1=CC=CC(C)=C1C FYGHSUNMUKGBRK-UHFFFAOYSA-N 0.000 description 2
RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 2
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
XOBKSJJDNFUZPF-UHFFFAOYSA-N Methoxyethane Chemical compound CCOC XOBKSJJDNFUZPF-UHFFFAOYSA-N 0.000 description 2
YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
239000004698 Polyethylene Substances 0.000 description 2
239000004743 Polypropylene Substances 0.000 description 2
238000001994 activation Methods 0.000 description 2
150000001298 alcohols Chemical class 0.000 description 2
125000000217 alkyl group Chemical group 0.000 description 2
ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical class O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 description 2
229910052786 argon Inorganic materials 0.000 description 2
125000004429 atom Chemical group 0.000 description 2
125000004432 carbon atom Chemical group C* 0.000 description 2
239000003795 chemical substances by application Substances 0.000 description 2
239000003245 coal Substances 0.000 description 2
230000018044 dehydration Effects 0.000 description 2
238000006297 dehydration reaction Methods 0.000 description 2
238000013461 design Methods 0.000 description 2
IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 description 2
WEHWNAOGRSTTBQ-UHFFFAOYSA-N dipropylamine Chemical compound CCCNCCC WEHWNAOGRSTTBQ-UHFFFAOYSA-N 0.000 description 2
230000005284 excitation Effects 0.000 description 2
238000000855 fermentation Methods 0.000 description 2
230000004151 fermentation Effects 0.000 description 2
238000005243 fluidization Methods 0.000 description 2
238000004817 gas chromatography Methods 0.000 description 2
JJWLVOIRVHMVIS-UHFFFAOYSA-N isopropylamine Chemical compound CC(C)N JJWLVOIRVHMVIS-UHFFFAOYSA-N 0.000 description 2
238000011068 loading method Methods 0.000 description 2
TZIHFWKZFHZASV-UHFFFAOYSA-N methyl formate Chemical compound COC=O TZIHFWKZFHZASV-UHFFFAOYSA-N 0.000 description 2
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
239000003345 natural gas Substances 0.000 description 2
239000007800 oxidant agent Substances 0.000 description 2
239000003208 petroleum Substances 0.000 description 2
229920000573 polyethylene Polymers 0.000 description 2
229920001155 polypropylene Polymers 0.000 description 2
BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
239000005297 pyrex Substances 0.000 description 2
UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 2
239000000376 reactant Substances 0.000 description 2
239000011541 reaction mixture Substances 0.000 description 2
238000004064 recycling Methods 0.000 description 2
230000002829 reductive effect Effects 0.000 description 2
HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 2
229910010271 silicon carbide Inorganic materials 0.000 description 2
239000000243 solution Substances 0.000 description 2
241000894007 species Species 0.000 description 2
AJPPAKACCOFNEN-UHFFFAOYSA-K tetraethylazanium;phosphate Chemical compound [O-]P([O-])([O-])=O.CC[N+](CC)(CC)CC.CC[N+](CC)(CC)CC.CC[N+](CC)(CC)CC AJPPAKACCOFNEN-UHFFFAOYSA-K 0.000 description 2
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
239000010963 304 stainless steel Substances 0.000 description 1
MICRDKKVJPDJHX-UHFFFAOYSA-N 4-amino-3-ethylhexan-3-ol Chemical compound CCC(N)C(O)(CC)CC MICRDKKVJPDJHX-UHFFFAOYSA-N 0.000 description 1
241000269350 Anura Species 0.000 description 1
239000002028 Biomass Substances 0.000 description 1
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
229910052684 Cerium Inorganic materials 0.000 description 1
ZAFNJMIOTHYJRJ-UHFFFAOYSA-N Diisopropyl ether Chemical compound CC(C)OC(C)C ZAFNJMIOTHYJRJ-UHFFFAOYSA-N 0.000 description 1
229910052692 Dysprosium Inorganic materials 0.000 description 1
229910052691 Erbium Inorganic materials 0.000 description 1
229910052693 Europium Inorganic materials 0.000 description 1
229910052688 Gadolinium Inorganic materials 0.000 description 1
229910052689 Holmium Inorganic materials 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
229910052765 Lutetium Inorganic materials 0.000 description 1
LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 1
UAEPNZWRGJTJPN-UHFFFAOYSA-N Methylcyclohexane Natural products CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 1
229910052779 Neodymium Inorganic materials 0.000 description 1
229910019142 PO4 Inorganic materials 0.000 description 1
229910052777 Praseodymium Inorganic materials 0.000 description 1
229910000589 SAE 304 stainless steel Inorganic materials 0.000 description 1
229910052772 Samarium Inorganic materials 0.000 description 1
241000158147 Sator Species 0.000 description 1
UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
229910052771 Terbium Inorganic materials 0.000 description 1
BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 1
229910052775 Thulium Inorganic materials 0.000 description 1
229910052769 Ytterbium Inorganic materials 0.000 description 1
KMWBBMXGHHLDKL-UHFFFAOYSA-N [AlH3].[Si] Chemical compound [AlH3].[Si] KMWBBMXGHHLDKL-UHFFFAOYSA-N 0.000 description 1
239000002253 acid Substances 0.000 description 1
230000004913 activation Effects 0.000 description 1
150000001299 aldehydes Chemical class 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
229910052784 alkaline earth metal Inorganic materials 0.000 description 1
150000001342 alkaline earth metals Chemical class 0.000 description 1
WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
SMZOGRDCAXLAAR-UHFFFAOYSA-N aluminium isopropoxide Chemical compound [Al+3].CC(C)[O-].CC(C)[O-].CC(C)[O-] SMZOGRDCAXLAAR-UHFFFAOYSA-N 0.000 description 1
229910000147 aluminium phosphate Inorganic materials 0.000 description 1
VXAUWWUXCIMFIM-UHFFFAOYSA-M aluminum;oxygen(2-);hydroxide Chemical compound [OH-].[O-2].[Al+3] VXAUWWUXCIMFIM-UHFFFAOYSA-M 0.000 description 1
ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
150000003863 ammonium salts Chemical class 0.000 description 1
238000013459 approach Methods 0.000 description 1
238000002453 autothermal reforming Methods 0.000 description 1
230000009286 beneficial effect Effects 0.000 description 1
238000009529 body temperature measurement Methods 0.000 description 1
239000006227 byproduct Substances 0.000 description 1
238000001354 calcination Methods 0.000 description 1
239000001569 carbon dioxide Substances 0.000 description 1
229910002091 carbon monoxide Inorganic materials 0.000 description 1
150000004649 carbonic acid derivatives Chemical class 0.000 description 1
150000001728 carbonyl compounds Chemical class 0.000 description 1
150000001735 carboxylic acids Chemical class 0.000 description 1
238000004523 catalytic cracking Methods 0.000 description 1
238000006555 catalytic reaction Methods 0.000 description 1
238000005119 centrifugation Methods 0.000 description 1
ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 1
230000008859 change Effects 0.000 description 1
239000003638 chemical reducing agent Substances 0.000 description 1
229910052804 chromium Inorganic materials 0.000 description 1
238000001816 cooling Methods 0.000 description 1
239000000498 cooling water Substances 0.000 description 1
238000005336 cracking Methods 0.000 description 1
239000013078 crystal Substances 0.000 description 1
239000002178 crystalline material Substances 0.000 description 1
238000002425 crystallisation Methods 0.000 description 1
230000008025 crystallization Effects 0.000 description 1
AVKNGPAMCBSNSO-UHFFFAOYSA-N cyclohexylmethanamine Chemical compound NCC1CCCCC1 AVKNGPAMCBSNSO-UHFFFAOYSA-N 0.000 description 1
NISGSNTVMOOSJQ-UHFFFAOYSA-N cyclopentanamine Chemical compound NC1CCCC1 NISGSNTVMOOSJQ-UHFFFAOYSA-N 0.000 description 1
230000009849 deactivation Effects 0.000 description 1
230000020335 dealkylation Effects 0.000 description 1
238000006900 dealkylation reaction Methods 0.000 description 1
238000003795 desorption Methods 0.000 description 1
238000009792 diffusion process Methods 0.000 description 1
XNMQEEKYCVKGBD-UHFFFAOYSA-N dimethylacetylene Natural products CC#CC XNMQEEKYCVKGBD-UHFFFAOYSA-N 0.000 description 1
238000009826 distribution Methods 0.000 description 1
KBQHZAAAGSGFKK-UHFFFAOYSA-N dysprosium atom Chemical compound [Dy] KBQHZAAAGSGFKK-UHFFFAOYSA-N 0.000 description 1
UYAHIZSMUZPPFV-UHFFFAOYSA-N erbium Chemical compound [Er] UYAHIZSMUZPPFV-UHFFFAOYSA-N 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
150000002170 ethers Chemical class 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
OGPBJKLSAFTDLK-UHFFFAOYSA-N europium atom Chemical compound [Eu] OGPBJKLSAFTDLK-UHFFFAOYSA-N 0.000 description 1
239000000945 filler Substances 0.000 description 1
238000001914 filtration Methods 0.000 description 1
239000005350 fused silica glass Substances 0.000 description 1
UIWYJDYFSGRHKR-UHFFFAOYSA-N gadolinium atom Chemical compound [Gd] UIWYJDYFSGRHKR-UHFFFAOYSA-N 0.000 description 1
150000004820 halides Chemical class 0.000 description 1
229910052736 halogen Inorganic materials 0.000 description 1
150000002367 halogens Chemical class 0.000 description 1
YUWFEBAXEOLKSG-UHFFFAOYSA-N hexamethylbenzene Chemical compound CC1=C(C)C(C)=C(C)C(C)=C1C YUWFEBAXEOLKSG-UHFFFAOYSA-N 0.000 description 1
KJZYNXUDTRRSPN-UHFFFAOYSA-N holmium atom Chemical compound [Ho] KJZYNXUDTRRSPN-UHFFFAOYSA-N 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
238000005216 hydrothermal crystallization Methods 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
239000012442 inert solvent Substances 0.000 description 1
238000002347 injection Methods 0.000 description 1
239000007924 injection Substances 0.000 description 1
238000005342 ion exchange Methods 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
150000002576 ketones Chemical class 0.000 description 1
229910052747 lanthanoid Inorganic materials 0.000 description 1
150000002602 lanthanoids Chemical class 0.000 description 1
229910052746 lanthanum Inorganic materials 0.000 description 1
FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
OHSVLFRHMCKCQY-UHFFFAOYSA-N lutetium atom Chemical compound [Lu] OHSVLFRHMCKCQY-UHFFFAOYSA-N 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
229910052748 manganese Inorganic materials 0.000 description 1
239000012968 metallocene catalyst Substances 0.000 description 1
VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 1
WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
239000012229 microporous material Substances 0.000 description 1
QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 description 1
238000010899 nucleation Methods 0.000 description 1
150000002894 organic compounds Chemical class 0.000 description 1
239000011368 organic material Substances 0.000 description 1
238000013021 overheating Methods 0.000 description 1
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238000007254 oxidation reaction Methods 0.000 description 1
230000001590 oxidative effect Effects 0.000 description 1
239000002245 particle Substances 0.000 description 1
230000000737 periodic effect Effects 0.000 description 1
235000021317 phosphate Nutrition 0.000 description 1
150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
239000004033 plastic Substances 0.000 description 1
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PUDIUYLPXJFUGB-UHFFFAOYSA-N praseodymium atom Chemical compound [Pr] PUDIUYLPXJFUGB-UHFFFAOYSA-N 0.000 description 1
238000002203 pretreatment Methods 0.000 description 1
230000001737 promoting effect Effects 0.000 description 1
229910052761 rare earth metal Inorganic materials 0.000 description 1
150000002910 rare earth metals Chemical class 0.000 description 1
230000001172 regenerating effect Effects 0.000 description 1
KZUNJOHGWZRPMI-UHFFFAOYSA-N samarium atom Chemical compound [Sm] KZUNJOHGWZRPMI-UHFFFAOYSA-N 0.000 description 1
238000005070 sampling Methods 0.000 description 1
229910052706 scandium Inorganic materials 0.000 description 1
SIXSYDAISGFNSX-UHFFFAOYSA-N scandium atom Chemical compound [Sc] SIXSYDAISGFNSX-UHFFFAOYSA-N 0.000 description 1
238000000926 separation method Methods 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
229910001388 sodium aluminate Inorganic materials 0.000 description 1
239000002904 solvent Substances 0.000 description 1
238000010561 standard procedure Methods 0.000 description 1
238000004230 steam cracking Methods 0.000 description 1
238000000629 steam reforming Methods 0.000 description 1
238000003756 stirring Methods 0.000 description 1
125000001424 substituent group Chemical group 0.000 description 1
150000003463 sulfur Chemical class 0.000 description 1
239000011269 tar Substances 0.000 description 1
GZCRRIHWUXGPOV-UHFFFAOYSA-N terbium atom Chemical compound [Tb] GZCRRIHWUXGPOV-UHFFFAOYSA-N 0.000 description 1
HWCKGOZZJDHMNC-UHFFFAOYSA-M tetraethylammonium bromide Chemical compound [Br-].CC[N+](CC)(CC)CC HWCKGOZZJDHMNC-UHFFFAOYSA-M 0.000 description 1
YMBCJWGVCUEGHA-UHFFFAOYSA-M tetraethylammonium chloride Chemical compound [Cl-].CC[N+](CC)(CC)CC YMBCJWGVCUEGHA-UHFFFAOYSA-M 0.000 description 1
GTCDARUMAMVCRO-UHFFFAOYSA-M tetraethylazanium;acetate Chemical compound CC([O-])=O.CC[N+](CC)(CC)CC GTCDARUMAMVCRO-UHFFFAOYSA-M 0.000 description 1
QSUJAUYJBJRLKV-UHFFFAOYSA-M tetraethylazanium;fluoride Chemical compound [F-].CC[N+](CC)(CC)CC QSUJAUYJBJRLKV-UHFFFAOYSA-M 0.000 description 1
125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
229910052719 titanium Inorganic materials 0.000 description 1
229910052723 transition metal Inorganic materials 0.000 description 1
DQWPFSLDHJDLRL-UHFFFAOYSA-N triethyl phosphate Chemical compound CCOP(=O)(OCC)OCC DQWPFSLDHJDLRL-UHFFFAOYSA-N 0.000 description 1
150000005199 trimethylbenzenes Chemical class 0.000 description 1
239000002699 waste material Substances 0.000 description 1
239000008096 xylene Substances 0.000 description 1
150000003738 xylenes Chemical class 0.000 description 1
NAWDYIZEMPQZHO-UHFFFAOYSA-N ytterbium Chemical compound [Yb] NAWDYIZEMPQZHO-UHFFFAOYSA-N 0.000 description 1
229910052727 yttrium Inorganic materials 0.000 description 1
VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
239000010457 zeolite Substances 0.000 description 1
229910052725 zinc Inorganic materials 0.000 description 1
229910052726 zirconium Inorganic materials 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
- B01J37/082—Decomposition and pyrolysis
- B01J37/084—Decomposition of carbon-containing compounds into carbon
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/82—Phosphates
- B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
- B01J29/85—Silicoaluminophosphates [SAPO compounds]
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/14—After treatment, characterised by the effect to be obtained to alter the inside of the molecular sieve channels
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/34—Reaction with organic or organometallic compounds
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/82—Phosphates
- C07C2529/84—Aluminophosphates containing other elements, e.g. metals, boron
- C07C2529/85—Silicoaluminophosphates (SAPO compounds)
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/40—Ethylene production

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Chemical Kinetics & Catalysis (AREA)
Physics & Mathematics (AREA)
Thermal Sciences (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Catalysts (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

NO20023877A 2000-02-24 2002-08-15 Fremgangsmate for fremstilling av et olefinprodukt fra et oksygenatrastoff samt fremgangsmate for fremstilling av molekylsil NO327769B1 (no)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
US09/511,943 US6743747B1 (en)	2000-02-24	2000-02-24	Catalyst pretreatment in an oxgenate to olefins reaction system
US09/615,545 US6734330B1 (en)	2000-02-24	2000-07-13	Catalyst pretreatment in an oxygenate to olefins reaction system
PCT/US2001/006011 WO2001062382A2 (fr)	2000-02-24	2001-02-23	Pretraitement de catalyseur dans un systeme de reaction transformant des produits oxygenes en olefines

Publications (3)

Publication Number	Publication Date
NO20023877L NO20023877L (no)	2002-08-15
NO20023877D0 NO20023877D0 (no)	2002-08-15
NO327769B1 true NO327769B1 (no)	2009-09-21

Family

ID=27057400

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NO20023877A NO327769B1 (no)	2000-02-24	2002-08-15	Fremgangsmate for fremstilling av et olefinprodukt fra et oksygenatrastoff samt fremgangsmate for fremstilling av molekylsil

Country Status (10)

Country	Link
EP (1)	EP1257359B1 (fr)
CN (1)	CN1198686C (fr)
AT (1)	ATE342769T1 (fr)
AU (1)	AU776126B2 (fr)
CA (1)	CA2399232C (fr)
DE (1)	DE60123931T2 (fr)
ES (1)	ES2274870T3 (fr)
MX (1)	MXPA02008221A (fr)
NO (1)	NO327769B1 (fr)
WO (1)	WO2001062382A2 (fr)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US7132581B2 (en)	2003-11-12	2006-11-07	Exxonmobil Chemical Patents Inc.	Catalyst pretreatment with aldehyde in an oxygenate to olefins reaction system
US7057083B2 (en) *	2003-11-12	2006-06-06	Exxonmobil Chemical Patents Inc.	Catalyst pretreatment with C4-C7 olefins in an oxygenate to olefins reaction system
US7045672B2 (en) *	2003-11-12	2006-05-16	Exxonmobil Chemical Patents Inc.	Catalyst pretreatment with dimethyl ether in an oxygenate to olefins reaction system
US7199277B2 (en) *	2004-07-01	2007-04-03	Exxonmobil Chemical Patents Inc.	Pretreating a catalyst containing molecular sieve and active metal oxide
US7465845B2 (en)	2004-12-22	2008-12-16	Exxonmobil Chemical Patents Inc.	Increasing ethylene and/or propylene production in an oxygenate to olefins reaction systems
EP2098287A1 (fr)	2008-03-03	2009-09-09	ExxonMobil Chemical Patents Inc.	Procédé de formulation de composition de catalyseur de tamis moléculaire en contrôlant un ajout de composant
US8178741B2 (en)	2009-07-21	2012-05-15	Exxonmobil Chemical Patents Inc.	Method and apparatus for regenerating catalyst during oxygenates to olefins reaction
CN101695674B (zh) *	2009-11-04	2012-04-11	兆威兴业有限公司	对甲醇或二甲醚制低碳烯烃用的催化剂进行预处理的方法
CN102464536B (zh) *	2010-11-17	2014-03-26	中国石油化工股份有限公司	生产低碳烯烃的方法
WO2018096171A1 (fr)	2016-11-28	2018-05-31	Basf Se	Composite catalyseur comprenant un métal alcalino-terreux contenant une zéolite cha et son utilisation dans un procédé de conversion de composés oxygénés en oléfines
CN114425436B (zh) *	2020-10-09	2023-08-29	中国石油化工股份有限公司	分子筛流化床催化剂的制备方法及制备的催化剂和应用

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4499314A (en) *	1982-03-31	1985-02-12	Imperial Chemical Industries Plc	Methanol conversion to hydrocarbons with zeolites and cocatalysts
US4677242A (en) *	1982-10-04	1987-06-30	Union Carbide Corporation	Production of light olefins
US4499327A (en) *	1982-10-04	1985-02-12	Union Carbide Corporation	Production of light olefins
NO310106B1 (no) *	1996-03-13	2001-05-21	Norsk Hydro As	Mikroporöse, krystallinske metallofosfatforbindelser, en fremgangsmåte for fremstilling og anvendelse derav
US5952538A (en) *	1996-12-31	1999-09-14	Exxon Chemical Patents Inc.	Use of short contact time in oxygenate conversion
US5912393A (en) *	1997-12-09	1999-06-15	Uop Llc	Metallo aluminophosphate molecular sieve with novel crystal morphology and methanol to olefin process using the sieve

2001
- 2001-02-23 CA CA002399232A patent/CA2399232C/fr not_active Expired - Lifetime
- 2001-02-23 WO PCT/US2001/006011 patent/WO2001062382A2/fr not_active Ceased
- 2001-02-23 EP EP01911164A patent/EP1257359B1/fr not_active Revoked
- 2001-02-23 AT AT01911164T patent/ATE342769T1/de not_active IP Right Cessation
- 2001-02-23 MX MXPA02008221A patent/MXPA02008221A/es active IP Right Grant
- 2001-02-23 DE DE60123931T patent/DE60123931T2/de not_active Revoked
- 2001-02-23 AU AU38685/01A patent/AU776126B2/en not_active Expired
- 2001-02-23 ES ES01911164T patent/ES2274870T3/es not_active Expired - Lifetime
- 2001-02-23 CN CNB018055842A patent/CN1198686C/zh not_active Expired - Lifetime
2002
- 2002-08-15 NO NO20023877A patent/NO327769B1/no not_active IP Right Cessation

Also Published As

Publication number	Publication date
WO2001062382A3 (fr)	2002-01-10
EP1257359B1 (fr)	2006-10-18
ES2274870T3 (es)	2007-06-01
CA2399232A1 (fr)	2001-08-30
MXPA02008221A (es)	2003-02-27
AU776126B2 (en)	2004-08-26
WO2001062382A2 (fr)	2001-08-30
CN1438921A (zh)	2003-08-27
AU3868501A (en)	2001-09-03
NO20023877L (no)	2002-08-15
EP1257359A2 (fr)	2002-11-20
CN1198686C (zh)	2005-04-27
CA2399232C (fr)	2009-11-24
NO20023877D0 (no)	2002-08-15
DE60123931T2 (de)	2007-04-05
ATE342769T1 (de)	2006-11-15
DE60123931D1 (de)	2006-11-30

Legal Events

Date	Code	Title	Description
2021-03-08	MK1K	Patent expired

Publication	Publication Date	Title
KR100757613B1 (ko)	2007-09-10	산소화물로부터 올레핀 생성물을 제조하는 방법
KR100874805B1 (ko)	2008-12-19	올레핀의 제조 방법
EP1421044B1 (fr)	2007-03-07	Inhibition de la formation de coke sur un catalyseur au cours de la fabrication d'une olefine
US7014827B2 (en)	2006-03-21	Synthesis of silicoaluminophosphates
AU783368B2 (en)	2005-10-20	Catalytic production of olefins at high methanol partial pressures
US6403855B1 (en)	2002-06-11	Synthesis of crystalline silicoaluminophosphates and use in olefin production
ZA200110307B (en)	2003-04-30	Process for increasing the selectivity of a reaction to convert oxygenates to olefins.
MXPA01012624A (es)	2002-06-21	Tratamiento termico de un cedazo molecular y catalizador.
WO2008016423A1 (fr)	2008-02-07	Production d'oléfines légères
CA2399232C (fr)	2009-11-24	Pretraitement de catalyseur dans un systeme de reaction transformant des produits oxygenes en olefines
US6743747B1 (en)	2004-06-01	Catalyst pretreatment in an oxgenate to olefins reaction system
WO2001064340A1 (fr)	2001-09-07	Tamis moleculaire de silico-aluminophosphates contenant du thorium destine a la production d'olefines
ZA200701854B (en)	2008-05-28	Catalyst and process for the conversion of oxygenates to olefins
US20070100188A1 (en)	2007-05-03	Metalloaluminophosphate molecular sieves, their synthesis and use
WO2006044015A1 (fr)	2006-04-27	Catalyseur et procede de conversion d'oxygenates en olefines
MXPA02006585A (en)	2003-02-07	Synthesis of crystalline silicoaluminophosphates