NO331777B1 - Fremgangsmate for fremstilling av en katalysator samt fremgangsmate for polymerisering, kopolymerisering og terpolymerisering av olefin-umettede forbindelser - Google Patents

Fremgangsmate for fremstilling av en katalysator samt fremgangsmate for polymerisering, kopolymerisering og terpolymerisering av olefin-umettede forbindelser Download PDF

Info

Publication number: NO331777B1
Authority: NO; Norway
Prior art keywords: silica; catalyst; stated; titanium; weight
Prior art date: 2001-12-20

Application number

NO20042535A

Other languages

English (en)

Norwegian (no)

Other versions

NO20042535L (no

Inventor

Mario Polesello

Anna Sommazzi

Francesco Masi

Antonio Proto

Roberto Santi

Andrea Vallieri

Original Assignee

Polimeri Europa Spa

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2001-12-20

Filing date

2004-06-17

Publication date

2012-03-26

2004-06-17 Application filed by Polimeri Europa Spa filed Critical Polimeri Europa Spa

2004-09-20 Publication of NO20042535L publication Critical patent/NO20042535L/no

2012-03-26 Publication of NO331777B1 publication Critical patent/NO331777B1/no

Links

239000003054 catalyst Substances 0.000 title claims abstract description 86
150000001875 compounds Chemical class 0.000 title claims abstract description 42
238000006116 polymerization reaction Methods 0.000 title claims abstract description 22
238000000034 method Methods 0.000 title claims description 47
238000007334 copolymerization reaction Methods 0.000 title claims description 17
230000008569 process Effects 0.000 title claims description 12
238000004519 manufacturing process Methods 0.000 title description 10
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 110
239000010936 titanium Substances 0.000 claims abstract description 104
239000011777 magnesium Substances 0.000 claims abstract description 82
239000000377 silicon dioxide Substances 0.000 claims abstract description 55
229910052719 titanium Inorganic materials 0.000 claims abstract description 47
239000011148 porous material Substances 0.000 claims abstract description 44
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 40
229910052782 aluminium Inorganic materials 0.000 claims abstract description 28
229910052749 magnesium Inorganic materials 0.000 claims abstract description 27
238000002360 preparation method Methods 0.000 claims abstract description 19
238000006243 chemical reaction Methods 0.000 claims abstract description 17
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 14
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 14
230000003197 catalytic effect Effects 0.000 claims abstract description 11
239000000203 mixture Substances 0.000 claims description 70
239000000460 chlorine Substances 0.000 claims description 67
229910052801 chlorine Inorganic materials 0.000 claims description 33
239000002904 solvent Substances 0.000 claims description 33
-1 hydrocarbyl radical Chemical class 0.000 claims description 28
230000001186 cumulative effect Effects 0.000 claims description 24
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 20
239000005977 Ethylene Substances 0.000 claims description 20
239000002245 particle Substances 0.000 claims description 19
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 19
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 19
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 18
239000000725 suspension Substances 0.000 claims description 18
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 14
125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 12
125000001309 chloro group Chemical group Cl* 0.000 claims description 10
239000004711 α-olefin Substances 0.000 claims description 10
238000010438 heat treatment Methods 0.000 claims description 9
125000001188 haloalkyl group Chemical group 0.000 claims description 8
150000001993 dienes Chemical class 0.000 claims description 7
238000005406 washing Methods 0.000 claims description 7
239000006227 byproduct Substances 0.000 claims description 6
150000003609 titanium compounds Chemical class 0.000 claims description 6
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 5
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical group BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 5
229910052794 bromium Inorganic materials 0.000 claims description 5
125000004432 carbon atom Chemical group C* 0.000 claims description 5
238000000151 deposition Methods 0.000 claims description 5
230000008030 elimination Effects 0.000 claims description 5
238000003379 elimination reaction Methods 0.000 claims description 5
125000003837 (C1-C20) alkyl group Chemical group 0.000 claims description 4
239000004215 Carbon black (E152) Substances 0.000 claims description 4
229930195733 hydrocarbon Natural products 0.000 claims description 4
150000002430 hydrocarbons Chemical class 0.000 claims description 4
229910052710 silicon Inorganic materials 0.000 claims description 4
230000008021 deposition Effects 0.000 claims description 3
125000005843 halogen group Chemical group 0.000 claims description 3
150000002681 magnesium compounds Chemical class 0.000 claims description 3
238000011084 recovery Methods 0.000 claims description 3
ZBZJXHCVGLJWFG-UHFFFAOYSA-N trichloromethyl(.) Chemical compound Cl[C](Cl)Cl ZBZJXHCVGLJWFG-UHFFFAOYSA-N 0.000 claims description 3
ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims description 2
238000004438 BET method Methods 0.000 claims description 2
239000004411 aluminium Substances 0.000 claims description 2
229910052736 halogen Inorganic materials 0.000 claims description 2
150000002367 halogens Chemical group 0.000 claims description 2
239000003701 inert diluent Substances 0.000 claims description 2
239000012442 inert solvent Substances 0.000 claims description 2
229910052740 iodine Inorganic materials 0.000 claims description 2
239000011630 iodine Substances 0.000 claims description 2
239000002002 slurry Substances 0.000 claims description 2
150000002899 organoaluminium compounds Chemical class 0.000 claims 1
AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 abstract description 2
239000003426 co-catalyst Substances 0.000 abstract 1
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 129
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 76
239000000243 solution Substances 0.000 description 61
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 55
229910052757 nitrogen Inorganic materials 0.000 description 50
238000003756 stirring Methods 0.000 description 41
239000007787 solid Substances 0.000 description 22
230000015572 biosynthetic process Effects 0.000 description 21
238000003786 synthesis reaction Methods 0.000 description 21
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 20
229920000642 polymer Polymers 0.000 description 20
CMAOLVNGLTWICC-UHFFFAOYSA-N 2-fluoro-5-methylbenzonitrile Chemical compound CC1=CC=C(F)C(C#N)=C1 CMAOLVNGLTWICC-UHFFFAOYSA-N 0.000 description 19
239000012299 nitrogen atmosphere Substances 0.000 description 18
238000012360 testing method Methods 0.000 description 16
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 15
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 12
ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 12
238000000921 elemental analysis Methods 0.000 description 11
238000001704 evaporation Methods 0.000 description 11
OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 10
238000004458 analytical method Methods 0.000 description 10
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
238000004090 dissolution Methods 0.000 description 9
238000010992 reflux Methods 0.000 description 9
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 8
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 8
TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 8
229910052681 coesite Inorganic materials 0.000 description 8
229910052906 cristobalite Inorganic materials 0.000 description 8
230000008020 evaporation Effects 0.000 description 8
238000001914 filtration Methods 0.000 description 8
235000012239 silicon dioxide Nutrition 0.000 description 8
229910052682 stishovite Inorganic materials 0.000 description 8
229910052905 tridymite Inorganic materials 0.000 description 8
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 7
229920001577 copolymer Polymers 0.000 description 7
235000019441 ethanol Nutrition 0.000 description 7
OJOWICOBYCXEKR-APPZFPTMSA-N (1S,4R)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound CC=C1C[C@@H]2C[C@@H]1C=C2 OJOWICOBYCXEKR-APPZFPTMSA-N 0.000 description 6
XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 6
229910000831 Steel Inorganic materials 0.000 description 6
239000007789 gas Substances 0.000 description 6
125000001183 hydrocarbyl group Chemical group 0.000 description 6
239000011541 reaction mixture Substances 0.000 description 6
230000001105 regulatory effect Effects 0.000 description 6
239000010959 steel Substances 0.000 description 6
YNJBWRMUSHSURL-UHFFFAOYSA-N trichloroacetic acid Chemical compound OC(=O)C(Cl)(Cl)Cl YNJBWRMUSHSURL-UHFFFAOYSA-N 0.000 description 6
LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 5
238000013019 agitation Methods 0.000 description 5
238000012512 characterization method Methods 0.000 description 5
239000000706 filtrate Substances 0.000 description 5
229920001897 terpolymer Polymers 0.000 description 5
NXERUYGRZMHUMK-UHFFFAOYSA-N 4,4,4-trichlorobut-2-enoic acid Chemical compound OC(=O)C=CC(Cl)(Cl)Cl NXERUYGRZMHUMK-UHFFFAOYSA-N 0.000 description 4
229920002943 EPDM rubber Polymers 0.000 description 4
238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 4
229910010062 TiCl3 Inorganic materials 0.000 description 4
229910052786 argon Inorganic materials 0.000 description 4
238000009835 boiling Methods 0.000 description 4
229910052799 carbon Inorganic materials 0.000 description 4
238000001816 cooling Methods 0.000 description 4
238000001035 drying Methods 0.000 description 4
238000002474 experimental method Methods 0.000 description 4
229910001629 magnesium chloride Inorganic materials 0.000 description 4
239000000463 material Substances 0.000 description 4
230000001376 precipitating effect Effects 0.000 description 4
150000003608 titanium Chemical class 0.000 description 4
YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 description 4
JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 4
RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Chemical compound C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 description 4
PBKONEOXTCPAFI-UHFFFAOYSA-N 1,2,4-trichlorobenzene Chemical compound ClC1=CC=C(Cl)C(Cl)=C1 PBKONEOXTCPAFI-UHFFFAOYSA-N 0.000 description 3
YKZUNWLMLRCVCW-UHFFFAOYSA-N 4-[2-(4-bicyclo[2.2.1]hept-2-enyl)ethyl]bicyclo[2.2.1]hept-2-ene Chemical compound C1CC(C2)C=CC21CCC1(C=C2)CC2CC1 YKZUNWLMLRCVCW-UHFFFAOYSA-N 0.000 description 3
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
239000004743 Polypropylene Substances 0.000 description 3
239000002253 acid Substances 0.000 description 3
125000001931 aliphatic group Chemical group 0.000 description 3
239000003849 aromatic solvent Substances 0.000 description 3
238000011088 calibration curve Methods 0.000 description 3
239000003795 chemical substances by application Substances 0.000 description 3
HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 3
238000011010 flushing procedure Methods 0.000 description 3
125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 3
239000003446 ligand Substances 0.000 description 3
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VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
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GQHTUMJGOHRCHB-UHFFFAOYSA-N 2,3,4,6,7,8,9,10-octahydropyrimido[1,2-a]azepine Chemical compound C1CCCCN2CCCN=C21 GQHTUMJGOHRCHB-UHFFFAOYSA-N 0.000 description 2
GXMWLJKTGBZMBH-UHFFFAOYSA-N 2-(2,4-dichlorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=C(Cl)C=C1Cl GXMWLJKTGBZMBH-UHFFFAOYSA-N 0.000 description 2
FUDNBFMOXDUIIE-UHFFFAOYSA-N 3,7-dimethylocta-1,6-diene Chemical compound C=CC(C)CCC=C(C)C FUDNBFMOXDUIIE-UHFFFAOYSA-N 0.000 description 2
KXPULUVMTDIQOQ-UHFFFAOYSA-N 4,4,4-trichlorobutanoic acid Chemical compound OC(=O)CCC(Cl)(Cl)Cl KXPULUVMTDIQOQ-UHFFFAOYSA-N 0.000 description 2
WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
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RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 2
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JGFZNNIVVJXRND-UHFFFAOYSA-N N,N-Diisopropylethylamine (DIPEA) Chemical compound CCN(C(C)C)C(C)C JGFZNNIVVJXRND-UHFFFAOYSA-N 0.000 description 2
229910010165 TiCu Inorganic materials 0.000 description 2
239000012190 activator Substances 0.000 description 2
150000001338 aliphatic hydrocarbons Chemical class 0.000 description 2
150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
125000003118 aryl group Chemical group 0.000 description 2
238000000712 atomic emission detection Methods 0.000 description 2
230000008901 benefit Effects 0.000 description 2
UEFCTIFSLILEPA-UHFFFAOYSA-N butyl 4,4,4-trichlorobut-2-enoate Chemical compound CCCCOC(=O)C=CC(Cl)(Cl)Cl UEFCTIFSLILEPA-UHFFFAOYSA-N 0.000 description 2
DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 2
238000009826 distribution Methods 0.000 description 2
SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
239000003480 eluent Substances 0.000 description 2
UAIZDWNSWGTKFZ-UHFFFAOYSA-L ethylaluminum(2+);dichloride Chemical compound CC[Al](Cl)Cl UAIZDWNSWGTKFZ-UHFFFAOYSA-L 0.000 description 2
238000005227 gel permeation chromatography Methods 0.000 description 2
150000003977 halocarboxylic acids Chemical class 0.000 description 2
239000002638 heterogeneous catalyst Substances 0.000 description 2
229910052739 hydrogen Inorganic materials 0.000 description 2
125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
238000009616 inductively coupled plasma Methods 0.000 description 2
238000002955 isolation Methods 0.000 description 2
QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
229920002521 macromolecule Polymers 0.000 description 2
150000002680 magnesium Chemical class 0.000 description 2
238000005259 measurement Methods 0.000 description 2
TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 2
239000003960 organic solvent Substances 0.000 description 2
239000003208 petroleum Substances 0.000 description 2
FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 2
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239000012265 solid product Substances 0.000 description 2
238000004611 spectroscopical analysis Methods 0.000 description 2
VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
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VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 2
238000001665 trituration Methods 0.000 description 2
RSJKGSCJYJTIGS-UHFFFAOYSA-N undecane Chemical compound CCCCCCCCCCC RSJKGSCJYJTIGS-UHFFFAOYSA-N 0.000 description 2
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125000004169 (C1-C6) alkyl group Chemical group 0.000 description 1
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IPJGAEWUPXWFPL-UHFFFAOYSA-N 1-[3-(2,5-dioxopyrrol-1-yl)phenyl]pyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C1=CC=CC(N2C(C=CC2=O)=O)=C1 IPJGAEWUPXWFPL-UHFFFAOYSA-N 0.000 description 1
PPWUTZVGSFPZOC-UHFFFAOYSA-N 1-methyl-2,3,3a,4-tetrahydro-1h-indene Chemical group C1C=CC=C2C(C)CCC21 PPWUTZVGSFPZOC-UHFFFAOYSA-N 0.000 description 1
238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 description 1
238000005160 1H NMR spectroscopy Methods 0.000 description 1
GVGFEJPTKINGLP-UHFFFAOYSA-N 2,2-dichlorocyclopropane-1-carboxylic acid Chemical compound OC(=O)C1CC1(Cl)Cl GVGFEJPTKINGLP-UHFFFAOYSA-N 0.000 description 1
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241001481828 Glyptocephalus cynoglossus Species 0.000 description 1
239000007832 Na2SO4 Substances 0.000 description 1
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239000004698 Polyethylene Substances 0.000 description 1
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229910019891 RuCl3 Inorganic materials 0.000 description 1
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PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
229910010068 TiCl2 Inorganic materials 0.000 description 1
230000009102 absorption Effects 0.000 description 1
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150000001450 anions Chemical class 0.000 description 1
238000010533 azeotropic distillation Methods 0.000 description 1
JQOREDBDOLZSJY-UHFFFAOYSA-H bis(2,2-dioxo-1,3,2,4-dioxathialumetan-4-yl) sulfate hexahydrate Chemical compound O.O.O.O.O.O.[Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O JQOREDBDOLZSJY-UHFFFAOYSA-H 0.000 description 1
HQMRIBYCTLBDAK-UHFFFAOYSA-M bis(2-methylpropyl)alumanylium;chloride Chemical compound CC(C)C[Al](Cl)CC(C)C HQMRIBYCTLBDAK-UHFFFAOYSA-M 0.000 description 1
229910052796 boron Inorganic materials 0.000 description 1
230000005587 bubbling Effects 0.000 description 1
WXCZUWHSJWOTRV-UHFFFAOYSA-N but-1-ene;ethene Chemical compound C=C.CCC=C WXCZUWHSJWOTRV-UHFFFAOYSA-N 0.000 description 1
NPJFDDAYIMBZPZ-UHFFFAOYSA-N butyl 2,4,4,4-tetrachlorobut-2-enoate Chemical compound CCCCOC(=O)C(Cl)=CC(Cl)(Cl)Cl NPJFDDAYIMBZPZ-UHFFFAOYSA-N 0.000 description 1
AIYRDJYEPYQPRQ-UHFFFAOYSA-N butyl 2,4,4,4-tetrachlorobutanoate Chemical compound CCCCOC(=O)C(Cl)CC(Cl)(Cl)Cl AIYRDJYEPYQPRQ-UHFFFAOYSA-N 0.000 description 1
CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
150000007942 carboxylates Chemical class 0.000 description 1
150000001735 carboxylic acids Chemical class 0.000 description 1
239000012986 chain transfer agent Substances 0.000 description 1
230000008859 change Effects 0.000 description 1
PBAYDYUZOSNJGU-UHFFFAOYSA-N chelidonic acid Natural products OC(=O)C1=CC(=O)C=C(C(O)=O)O1 PBAYDYUZOSNJGU-UHFFFAOYSA-N 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
239000003153 chemical reaction reagent Substances 0.000 description 1
HYZXMVILOKSUKA-UHFFFAOYSA-K chloro(dimethyl)alumane;dichloro(methyl)alumane Chemical compound C[Al](C)Cl.C[Al](Cl)Cl HYZXMVILOKSUKA-UHFFFAOYSA-K 0.000 description 1
238000013375 chromatographic separation Methods 0.000 description 1
JZCCFEFSEZPSOG-UHFFFAOYSA-L copper(II) sulfate pentahydrate Chemical compound O.O.O.O.O.[Cu+2].[O-]S([O-])(=O)=O JZCCFEFSEZPSOG-UHFFFAOYSA-L 0.000 description 1
125000004122 cyclic group Chemical group 0.000 description 1
125000000392 cycloalkenyl group Chemical group 0.000 description 1
125000000753 cycloalkyl group Chemical group 0.000 description 1
UVJHQYIOXKWHFD-UHFFFAOYSA-N cyclohexa-1,4-diene Chemical compound C1C=CCC=C1 UVJHQYIOXKWHFD-UHFFFAOYSA-N 0.000 description 1
238000010908 decantation Methods 0.000 description 1
238000007872 degassing Methods 0.000 description 1
DHCWLIOIJZJFJE-UHFFFAOYSA-L dichlororuthenium Chemical compound Cl[Ru]Cl DHCWLIOIJZJFJE-UHFFFAOYSA-L 0.000 description 1
WIWBLJMBLGWSIN-UHFFFAOYSA-L dichlorotris(triphenylphosphine)ruthenium(ii) Chemical compound [Cl-].[Cl-].[Ru+2].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 WIWBLJMBLGWSIN-UHFFFAOYSA-L 0.000 description 1
YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 1
238000000113 differential scanning calorimetry Methods 0.000 description 1
SBZXBUIDTXKZTM-UHFFFAOYSA-N diglyme Chemical compound COCCOCCOC SBZXBUIDTXKZTM-UHFFFAOYSA-N 0.000 description 1
AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 1
JGHYBJVUQGTEEB-UHFFFAOYSA-M dimethylalumanylium;chloride Chemical compound C[Al](C)Cl JGHYBJVUQGTEEB-UHFFFAOYSA-M 0.000 description 1
230000008034 disappearance Effects 0.000 description 1
230000000694 effects Effects 0.000 description 1
229920001971 elastomer Polymers 0.000 description 1
239000000806 elastomer Substances 0.000 description 1
239000011521 glass Substances 0.000 description 1
230000009477 glass transition Effects 0.000 description 1
DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
239000012433 hydrogen halide Substances 0.000 description 1
229910000039 hydrogen halide Inorganic materials 0.000 description 1
239000011261 inert gas Substances 0.000 description 1
238000011835 investigation Methods 0.000 description 1
PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical group II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 1
HQPMOXUTKURVDV-UHFFFAOYSA-L iron(2+);sulfate;pentahydrate Chemical compound O.O.O.O.O.[Fe+2].[O-]S([O-])(=O)=O HQPMOXUTKURVDV-UHFFFAOYSA-L 0.000 description 1
239000001095 magnesium carbonate Substances 0.000 description 1
ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
235000014380 magnesium carbonate Nutrition 0.000 description 1
229910000021 magnesium carbonate Inorganic materials 0.000 description 1
159000000003 magnesium salts Chemical class 0.000 description 1
RNTDHWHPCNOQMU-UHFFFAOYSA-L magnesium;2-(2,4-dichlorophenyl)acetate;chloride Chemical compound [Mg+2].[Cl-].[O-]C(=O)CC1=CC=C(Cl)C=C1Cl RNTDHWHPCNOQMU-UHFFFAOYSA-L 0.000 description 1
NTGYRCWVGOJRQZ-UHFFFAOYSA-L magnesium;4,4,4-trichlorobut-2-enoate Chemical compound [Mg+2].[O-]C(=O)C=CC(Cl)(Cl)Cl.[O-]C(=O)C=CC(Cl)(Cl)Cl NTGYRCWVGOJRQZ-UHFFFAOYSA-L 0.000 description 1
AJMRGAUVLMRFAF-UHFFFAOYSA-L magnesium;4,4,4-trichlorobutanoate Chemical compound [Mg+2].[O-]C(=O)CCC(Cl)(Cl)Cl.[O-]C(=O)CCC(Cl)(Cl)Cl AJMRGAUVLMRFAF-UHFFFAOYSA-L 0.000 description 1
FINPUQMERHPXJQ-UHFFFAOYSA-L magnesium;4,4,4-trichlorobutanoate;chloride Chemical compound [Mg+2].[Cl-].[O-]C(=O)CCC(Cl)(Cl)Cl FINPUQMERHPXJQ-UHFFFAOYSA-L 0.000 description 1
125000001827 mesitylenyl group Chemical class [H]C1=C(C(*)=C(C([H])=C1C([H])([H])[H])C([H])([H])[H])C([H])([H])[H] 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 1
239000012046 mixed solvent Substances 0.000 description 1
230000007935 neutral effect Effects 0.000 description 1
229910017604 nitric acid Inorganic materials 0.000 description 1
239000012454 non-polar solvent Substances 0.000 description 1
ZCYXXKJEDCHMGH-UHFFFAOYSA-N nonane Chemical compound CCCC[CH]CCCC ZCYXXKJEDCHMGH-UHFFFAOYSA-N 0.000 description 1
BKIMMITUMNQMOS-UHFFFAOYSA-N normal nonane Natural products CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 description 1
TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
125000005592 polycycloalkyl group Polymers 0.000 description 1
229920000573 polyethylene Polymers 0.000 description 1
239000002685 polymerization catalyst Substances 0.000 description 1
229920002223 polystyrene Polymers 0.000 description 1
235000010333 potassium nitrate Nutrition 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
238000002203 pretreatment Methods 0.000 description 1
238000000746 purification Methods 0.000 description 1
YBCAZPLXEGKKFM-UHFFFAOYSA-K ruthenium(iii) chloride Chemical compound [Cl-].[Cl-].[Cl-].[Ru+3] YBCAZPLXEGKKFM-UHFFFAOYSA-K 0.000 description 1
239000012047 saturated solution Substances 0.000 description 1
238000010898 silica gel chromatography Methods 0.000 description 1
150000004760 silicates Chemical class 0.000 description 1
239000010703 silicon Substances 0.000 description 1
229910052938 sodium sulfate Inorganic materials 0.000 description 1
235000011152 sodium sulphate Nutrition 0.000 description 1
239000011949 solid catalyst Substances 0.000 description 1
238000001228 spectrum Methods 0.000 description 1
239000000126 substance Substances 0.000 description 1
125000001424 substituent group Chemical group 0.000 description 1
229910052716 thallium Inorganic materials 0.000 description 1
NOWYCQCNAMKYFK-UHFFFAOYSA-K titanium(3+);4,4,4-trichlorobut-2-enoate Chemical compound [Ti+3].[O-]C(=O)C=CC(Cl)(Cl)Cl.[O-]C(=O)C=CC(Cl)(Cl)Cl.[O-]C(=O)C=CC(Cl)(Cl)Cl NOWYCQCNAMKYFK-UHFFFAOYSA-K 0.000 description 1
ZWYDDDAMNQQZHD-UHFFFAOYSA-L titanium(ii) chloride Chemical compound [Cl-].[Cl-].[Ti+2] ZWYDDDAMNQQZHD-UHFFFAOYSA-L 0.000 description 1
FAQYAMRNWDIXMY-UHFFFAOYSA-N trichloroborane Chemical compound ClB(Cl)Cl FAQYAMRNWDIXMY-UHFFFAOYSA-N 0.000 description 1
MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 1
LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 description 1
238000004876 x-ray fluorescence Methods 0.000 description 1
239000008096 xylene Substances 0.000 description 1
150000003738 xylenes Chemical class 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C53/00—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
- C07C53/15—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen containing halogen
- C07C53/16—Halogenated acetic acids
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C53/00—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
- C07C53/15—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen containing halogen
- C07C53/19—Acids containing three or more carbon atoms
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
- C07C57/52—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms containing halogen
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
- C07C57/52—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms containing halogen
- C07C57/58—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms containing halogen containing six-membered aromatic rings
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
- C07F3/003—Compounds containing elements of Groups 2 or 12 of the Periodic Table without C-Metal linkages
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/14—Monomers containing five or more carbon atoms
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/02—Ethene
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
- C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers

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Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

NO20042535A 2001-12-20 2004-06-17 Fremgangsmate for fremstilling av en katalysator samt fremgangsmate for polymerisering, kopolymerisering og terpolymerisering av olefin-umettede forbindelser NO331777B1 (no)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
IT2001MI002710A ITMI20012710A1 (it)	2001-12-20	2001-12-20	Catalizzatore supportato contenente titanio attivo nella omo-,co-, e ter-polimerizzazione di composti olefinicamente insaturi
PCT/EP2002/013954 WO2003054034A2 (fr)	2001-12-20	2002-12-06	Catalyseur supporte contenant du titane actif utilise dans l'homopolymerisation, la copolymerisation et la terpolymerisation de composes non satures en olefines

Publications (2)

Publication Number	Publication Date
NO20042535L NO20042535L (no)	2004-09-20
NO331777B1 true NO331777B1 (no)	2012-03-26

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NO20042535A NO331777B1 (no)	2001-12-20	2004-06-17	Fremgangsmate for fremstilling av en katalysator samt fremgangsmate for polymerisering, kopolymerisering og terpolymerisering av olefin-umettede forbindelser

Country Status (10)

Country	Link
US (1)	US7449528B2 (fr)
EP (1)	EP1456254B1 (fr)
AT (1)	ATE461945T1 (fr)
AU (1)	AU2002361996A1 (fr)
CA (1)	CA2470179C (fr)
DE (1)	DE60235769D1 (fr)
ES (1)	ES2343240T3 (fr)
IT (1)	ITMI20012710A1 (fr)
NO (1)	NO331777B1 (fr)
WO (1)	WO2003054034A2 (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
EP1682587B1 (fr) *	2003-11-14	2017-11-01	versalis S.p.A.	Composante catalytique solide amelioree
WO2013156491A1 (fr) *	2012-04-19	2013-10-24	Ineos Europe Ag	Catalyseur utilisable en vue de la polymérisation d'oléfines, son procédé de production et son utilisation
CN117772272B (zh) *	2022-09-20	2026-07-14	中国石油化工股份有限公司	一种丁二烯环化三聚方法、采用的催化剂及其催化剂的制备方法

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* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3875075A (en) *	1973-04-16	1975-04-01	Standard Oil Co	Catalyst for the polymerization of ethylene and terminal olefins
SE9504539D0 (sv) *	1995-12-19	1995-12-19	Borealis As	Procatalyst and process for the preparation of a multimodal ethylene homopolymer and/or ethylene/ 1-olefin copolymer by gas-phase polymerisation

2001
- 2001-12-20 IT IT2001MI002710A patent/ITMI20012710A1/it unknown
2002
- 2002-12-06 AT AT02796594T patent/ATE461945T1/de not_active IP Right Cessation
- 2002-12-06 WO PCT/EP2002/013954 patent/WO2003054034A2/fr not_active Ceased
- 2002-12-06 AU AU2002361996A patent/AU2002361996A1/en not_active Abandoned
- 2002-12-06 DE DE60235769T patent/DE60235769D1/de not_active Expired - Lifetime
- 2002-12-06 EP EP02796594A patent/EP1456254B1/fr not_active Expired - Lifetime
- 2002-12-06 US US10/497,549 patent/US7449528B2/en not_active Expired - Lifetime
- 2002-12-06 ES ES02796594T patent/ES2343240T3/es not_active Expired - Lifetime
- 2002-12-06 CA CA2470179A patent/CA2470179C/fr not_active Expired - Lifetime
2004
- 2004-06-17 NO NO20042535A patent/NO331777B1/no not_active IP Right Cessation

Also Published As

Publication number	Publication date
ES2343240T3 (es)	2010-07-27
ITMI20012710A1 (it)	2003-06-20
NO20042535L (no)	2004-09-20
ATE461945T1 (de)	2010-04-15
EP1456254A2 (fr)	2004-09-15
US20060014631A1 (en)	2006-01-19
CA2470179A1 (fr)	2003-07-03
WO2003054034A2 (fr)	2003-07-03
AU2002361996A8 (en)	2003-07-09
EP1456254B1 (fr)	2010-03-24
AU2002361996A1 (en)	2003-07-09
DE60235769D1 (de)	2010-05-06
US7449528B2 (en)	2008-11-11
WO2003054034A3 (fr)	2003-08-21
CA2470179C (fr)	2013-05-07

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Publication	Publication Date	Title
US9637508B2 (en)	2017-05-02	Ligand compound, catalyst system for olefin oligomerization, and method for olefin oligomerization using the same
JP5485415B2 (ja)	2014-05-07	オレフィンの（共）三量体化用触媒系、その調製方法ならびにその触媒系を用いるオレフィンの（共）三量体化用およびオレフィンオリゴマーの（共）重合用プロセス
CN103492397A (zh)	2014-01-01	吡啶基二氨基过渡金属络合物，其生产方法和用途
CN106715490B (zh)	2019-09-10	用于α-烯烃的(共)聚合的固体催化剂和用于其制备的工艺
KR100955739B1 (ko)	2010-04-30	올레핀 중합체
JP6290304B2 (ja)	2018-03-07	固体触媒成分、前記固体成分を含む触媒、及びα−オレフィン類の（共）重合のためのプロセス
NO300272B1 (no)	1997-05-05	Fremgangsmåte for fremstilling av en fast katalysatorbestanddel, en katalysator omfattende en slik, og anvendelse av katalysatoren ved en fremgangsmåte for polymerisasjon av <alfa>-olefiner
US20180265605A1 (en)	2018-09-20	Metallocene-supported catalyst and method of preparing polyolefin using the same
JP2006516954A (ja)	2006-07-13	オレフィン性モノマーの（共）重合用遷移金属触媒
US7498390B2 (en)	2009-03-03	Chromium complexes and their use in olefin polymerization
CA2470179C (fr)	2013-05-07	Catalyseur contenant du titane sur support pour l'homopolymerisation, la copolymerisatio et la terpolymerisation d'olefines
US10138257B2 (en)	2018-11-27	Transition metal complexes, production and use thereof
ES2435101T3 (es)	2013-12-18	Procedimiento de obtención de (co)polímeros cristalinos de etileno
JP2019529656A (ja)	2019-10-17	ハロゲン化マグネシウム担持チタン（前駆）触媒
RU2444533C2 (ru)	2012-03-10	Ванадиевая каталитическая система сополимеризации этилена, пропилена и диена (варианты) и способ получения сополимеров этилена с пропиленом и диенами
ES2379381T3 (es)	2012-04-25	Componentes de catalizador para la polimerización de olefinas
ES2296935T3 (es)	2008-05-01	Catalizadores de titanio, preparacion y utilizacion en copolimerizacion y terpolimerizacion de alfa-olefinas.
KR20070118144A (ko)	2007-12-13	올레핀 중합용 촉매 성분
JP2026505373A (ja)	2026-02-13	共重合のための触媒
JPH0339082B2 (fr)	1991-06-12
JP2008248243A (ja)	2008-10-16	オレフィン重合触媒及びオレフィンの重合方法
WO2018038880A1 (fr)	2018-03-01	Complexes de métaux de transition, leur production et leur utilisation
JPH05504990A (ja)	1993-07-29	オレフィンの重合のための触媒の製造法
JP2000007719A (ja)	2000-01-11	銅化合物を用いた重合体の製造方法
MXPA99010612A (en)	2002-06-05	Catalysts based on vanadium, their preparation and use in the (co)polymerization of alpha-olefins