NO780112L - Katalytiske materialer for olefinpolymerisering - Google Patents

Katalytiske materialer for olefinpolymerisering

Info

Publication number: NO780112L
Authority: NO; Norway
Prior art keywords: chromium; compound; aluminum; support; catalyst
Prior art date: 1977-01-13

Application number

NO780112A

Other languages

English (en)

Norwegian (no)

Inventor

Stanley Julius Katzen

Louis Joseph Rekers

Original Assignee

Nat Petro Chem

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1977-01-13

Filing date

1978-01-12

Publication date

1978-07-14

1978-01-12 Application filed by Nat Petro Chem filed Critical Nat Petro Chem

1978-07-14 Publication of NO780112L publication Critical patent/NO780112L/no

Links

238000006116 polymerization reaction Methods 0.000 title claims description 23
239000000463 material Substances 0.000 title claims description 22
230000003197 catalytic effect Effects 0.000 title description 3
239000003054 catalyst Substances 0.000 claims description 74
239000011651 chromium Substances 0.000 claims description 44
229910052782 aluminium Inorganic materials 0.000 claims description 39
229910052804 chromium Inorganic materials 0.000 claims description 35
-1 aluminum compound Chemical class 0.000 claims description 32
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 28
230000004913 activation Effects 0.000 claims description 26
239000003638 chemical reducing agent Substances 0.000 claims description 25
238000000034 method Methods 0.000 claims description 25
229910052739 hydrogen Inorganic materials 0.000 claims description 22
239000001257 hydrogen Substances 0.000 claims description 22
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 18
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 15
239000011148 porous material Substances 0.000 claims description 15
150000001875 compounds Chemical class 0.000 claims description 14
125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 14
150000001336 alkenes Chemical class 0.000 claims description 13
WGLPBDUCMAPZCE-UHFFFAOYSA-N chromium trioxide Inorganic materials O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 claims description 13
239000012298 atmosphere Substances 0.000 claims description 12
238000001354 calcination Methods 0.000 claims description 12
125000000217 alkyl group Chemical group 0.000 claims description 10
LALRXNPLTWZJIJ-UHFFFAOYSA-N triethylborane Chemical group CCB(CC)CC LALRXNPLTWZJIJ-UHFFFAOYSA-N 0.000 claims description 10
150000001845 chromium compounds Chemical class 0.000 claims description 9
125000004432 carbon atom Chemical group C* 0.000 claims description 8
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 8
229940117975 chromium trioxide Drugs 0.000 claims description 7
GAMDZJFZMJECOS-UHFFFAOYSA-N chromium(6+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Cr+6] GAMDZJFZMJECOS-UHFFFAOYSA-N 0.000 claims description 7
238000004519 manufacturing process Methods 0.000 claims description 7
239000007795 chemical reaction product Substances 0.000 claims description 6
238000000354 decomposition reaction Methods 0.000 claims description 6
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 5
125000000753 cycloalkyl group Chemical group 0.000 claims description 5
150000002903 organophosphorus compounds Chemical class 0.000 claims description 5
229910052760 oxygen Inorganic materials 0.000 claims description 5
239000001301 oxygen Substances 0.000 claims description 5
125000003710 aryl alkyl group Chemical group 0.000 claims description 4
125000003118 aryl group Chemical group 0.000 claims description 4
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 4
239000002685 polymerization catalyst Substances 0.000 claims description 4
FIPWRIJSWJWJAI-UHFFFAOYSA-N Butyl carbitol 6-propylpiperonyl ether Chemical compound C1=C(CCC)C(COCCOCCOCCCC)=CC2=C1OCO2 FIPWRIJSWJWJAI-UHFFFAOYSA-N 0.000 claims description 3
239000012876 carrier material Substances 0.000 claims description 3
150000002431 hydrogen Chemical class 0.000 claims description 3
229960005235 piperonyl butoxide Drugs 0.000 claims description 3
230000008569 process Effects 0.000 claims description 3
229910002028 silica xerogel Inorganic materials 0.000 claims description 3
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 2
DJXODKBXEDSGRG-UHFFFAOYSA-N [SiH3][Cr] Chemical class [SiH3][Cr] DJXODKBXEDSGRG-UHFFFAOYSA-N 0.000 claims description 2
229910052783 alkali metal Inorganic materials 0.000 claims description 2
150000001340 alkali metals Chemical class 0.000 claims description 2
229910052790 beryllium Inorganic materials 0.000 claims description 2
ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 claims description 2
150000001844 chromium Chemical class 0.000 claims description 2
238000003776 cleavage reaction Methods 0.000 claims description 2
150000004678 hydrides Chemical class 0.000 claims description 2
229910052749 magnesium Inorganic materials 0.000 claims description 2
239000011777 magnesium Substances 0.000 claims description 2
230000007017 scission Effects 0.000 claims description 2
239000007787 solid Substances 0.000 claims description 2
125000005234 alkyl aluminium group Chemical group 0.000 claims 1
230000000379 polymerizing effect Effects 0.000 claims 1
YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical group ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 18
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 18
229920000642 polymer Polymers 0.000 description 12
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 9
238000000576 coating method Methods 0.000 description 8
230000000694 effects Effects 0.000 description 8
239000000203 mixture Substances 0.000 description 8
239000011248 coating agent Substances 0.000 description 7
239000004698 Polyethylene Substances 0.000 description 6
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
238000006243 chemical reaction Methods 0.000 description 6
229910000423 chromium oxide Inorganic materials 0.000 description 6
239000000499 gel Substances 0.000 description 6
229920000573 polyethylene Polymers 0.000 description 6
VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 6
238000000151 deposition Methods 0.000 description 5
238000005984 hydrogenation reaction Methods 0.000 description 5
238000006317 isomerization reaction Methods 0.000 description 5
229910052751 metal Inorganic materials 0.000 description 5
239000002184 metal Substances 0.000 description 5
229910002027 silica gel Inorganic materials 0.000 description 5
239000000741 silica gel Substances 0.000 description 5
239000000377 silicon dioxide Substances 0.000 description 5
MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 5
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 4
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 4
URLKBWYHVLBVBO-UHFFFAOYSA-N Para-Xylene Chemical group CC1=CC=C(C)C=C1 URLKBWYHVLBVBO-UHFFFAOYSA-N 0.000 description 4
230000015572 biosynthetic process Effects 0.000 description 4
229910052796 boron Inorganic materials 0.000 description 4
239000003426 co-catalyst Substances 0.000 description 4
238000002474 experimental method Methods 0.000 description 4
239000000155 melt Substances 0.000 description 4
125000002524 organometallic group Chemical group 0.000 description 4
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
239000005977 Ethylene Substances 0.000 description 3
239000004411 aluminium Substances 0.000 description 3
125000004429 atom Chemical group 0.000 description 3
239000002585 base Substances 0.000 description 3
UOUJSJZBMCDAEU-UHFFFAOYSA-N chromium(3+);oxygen(2-) Chemical class [O-2].[O-2].[O-2].[Cr+3].[Cr+3] UOUJSJZBMCDAEU-UHFFFAOYSA-N 0.000 description 3
238000010438 heat treatment Methods 0.000 description 3
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
239000003960 organic solvent Substances 0.000 description 3
TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 3
229920000098 polyolefin Polymers 0.000 description 3
239000000047 product Substances 0.000 description 3
229910052814 silicon oxide Inorganic materials 0.000 description 3
238000011282 treatment Methods 0.000 description 3
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
239000008096 xylene Substances 0.000 description 3
YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 2
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 2
QRRWWGNBSQSBAM-UHFFFAOYSA-N alumane;chromium Chemical compound [AlH3].[Cr] QRRWWGNBSQSBAM-UHFFFAOYSA-N 0.000 description 2
229910052799 carbon Inorganic materials 0.000 description 2
238000006555 catalytic reaction Methods 0.000 description 2
ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical class [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 2
AYTAKQFHWFYBMA-UHFFFAOYSA-N chromium dioxide Chemical compound O=[Cr]=O AYTAKQFHWFYBMA-UHFFFAOYSA-N 0.000 description 2
239000000571 coke Substances 0.000 description 2
238000005336 cracking Methods 0.000 description 2
230000008021 deposition Effects 0.000 description 2
239000012442 inert solvent Substances 0.000 description 2
239000013067 intermediate product Substances 0.000 description 2
IVSZLXZYQVIEFR-UHFFFAOYSA-N m-xylene Chemical group CC1=CC=CC(C)=C1 IVSZLXZYQVIEFR-UHFFFAOYSA-N 0.000 description 2
230000007246 mechanism Effects 0.000 description 2
230000004048 modification Effects 0.000 description 2
238000012986 modification Methods 0.000 description 2
239000003607 modifier Substances 0.000 description 2
229910052757 nitrogen Inorganic materials 0.000 description 2
239000012299 nitrogen atmosphere Substances 0.000 description 2
239000002245 particle Substances 0.000 description 2
239000000843 powder Substances 0.000 description 2
230000004044 response Effects 0.000 description 2
239000002002 slurry Substances 0.000 description 2
238000003756 stirring Methods 0.000 description 2
DQWPFSLDHJDLRL-UHFFFAOYSA-N triethyl phosphate Chemical compound CCOP(=O)(OCC)OCC DQWPFSLDHJDLRL-UHFFFAOYSA-N 0.000 description 2
238000007740 vapor deposition Methods 0.000 description 2
238000009736 wetting Methods 0.000 description 2
JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
CQBWEBXPMRPCSI-UHFFFAOYSA-M O[Cr](O[SiH3])(=O)=O Chemical class O[Cr](O[SiH3])(=O)=O CQBWEBXPMRPCSI-UHFFFAOYSA-M 0.000 description 1
229910019142 PO4 Inorganic materials 0.000 description 1
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
239000002253 acid Substances 0.000 description 1
230000009471 action Effects 0.000 description 1
230000003213 activating effect Effects 0.000 description 1
239000012190 activator Substances 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
150000004703 alkoxides Chemical class 0.000 description 1
125000005907 alkyl ester group Chemical group 0.000 description 1
230000029936 alkylation Effects 0.000 description 1
238000005804 alkylation reaction Methods 0.000 description 1
SMZOGRDCAXLAAR-UHFFFAOYSA-N aluminium isopropoxide Chemical compound [Al+3].CC(C)[O-].CC(C)[O-].CC(C)[O-] SMZOGRDCAXLAAR-UHFFFAOYSA-N 0.000 description 1
VIJYFGMFEVJQHU-UHFFFAOYSA-N aluminum oxosilicon(2+) oxygen(2-) Chemical compound [O-2].[Al+3].[Si+2]=O VIJYFGMFEVJQHU-UHFFFAOYSA-N 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
SIPUZPBQZHNSDW-UHFFFAOYSA-N bis(2-methylpropyl)aluminum Chemical compound CC(C)C[Al]CC(C)C SIPUZPBQZHNSDW-UHFFFAOYSA-N 0.000 description 1
230000000903 blocking effect Effects 0.000 description 1
238000004364 calculation method Methods 0.000 description 1
239000000969 carrier Substances 0.000 description 1
238000004517 catalytic hydrocracking Methods 0.000 description 1
KYYSIVCCYWZZLR-UHFFFAOYSA-N cobalt(2+);dioxido(dioxo)molybdenum Chemical compound [Co+2].[O-][Mo]([O-])(=O)=O KYYSIVCCYWZZLR-UHFFFAOYSA-N 0.000 description 1
239000012967 coordination catalyst Substances 0.000 description 1
230000020335 dealkylation Effects 0.000 description 1
238000006900 dealkylation reaction Methods 0.000 description 1
230000006735 deficit Effects 0.000 description 1
238000006356 dehydrogenation reaction Methods 0.000 description 1
238000006477 desulfuration reaction Methods 0.000 description 1
HJXBDPDUCXORKZ-UHFFFAOYSA-N diethylalumane Chemical compound CC[AlH]CC HJXBDPDUCXORKZ-UHFFFAOYSA-N 0.000 description 1
238000005516 engineering process Methods 0.000 description 1
AIGRXSNSLVJMEA-FQEVSTJZSA-N ethoxy-(4-nitrophenoxy)-phenyl-sulfanylidene-$l^{5}-phosphane Chemical compound O([P@@](=S)(OCC)C=1C=CC=CC=1)C1=CC=C([N+]([O-])=O)C=C1 AIGRXSNSLVJMEA-FQEVSTJZSA-N 0.000 description 1
MGDOJPNDRJNJBK-UHFFFAOYSA-N ethylaluminum Chemical compound [Al].C[CH2] MGDOJPNDRJNJBK-UHFFFAOYSA-N 0.000 description 1
230000006203 ethylation Effects 0.000 description 1
238000006200 ethylation reaction Methods 0.000 description 1
230000002349 favourable effect Effects 0.000 description 1
238000001914 filtration Methods 0.000 description 1
238000001640 fractional crystallisation Methods 0.000 description 1
239000000446 fuel Substances 0.000 description 1
229910052733 gallium Inorganic materials 0.000 description 1
239000007789 gas Substances 0.000 description 1
229910002053 high pore volume silica gel Inorganic materials 0.000 description 1
BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
238000005470 impregnation Methods 0.000 description 1
229910010272 inorganic material Inorganic materials 0.000 description 1
239000011147 inorganic material Substances 0.000 description 1
229910052809 inorganic oxide Inorganic materials 0.000 description 1
229910052744 lithium Inorganic materials 0.000 description 1
239000000314 lubricant Substances 0.000 description 1
230000008018 melting Effects 0.000 description 1
238000002844 melting Methods 0.000 description 1
150000002736 metal compounds Chemical class 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
NRQNMMBQPIGPTB-UHFFFAOYSA-N methylaluminum Chemical compound [CH3].[Al] NRQNMMBQPIGPTB-UHFFFAOYSA-N 0.000 description 1
239000004005 microsphere Substances 0.000 description 1
229910052759 nickel Inorganic materials 0.000 description 1
229910052755 nonmetal Inorganic materials 0.000 description 1
RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
229910052763 palladium Inorganic materials 0.000 description 1
239000003208 petroleum Substances 0.000 description 1
235000021317 phosphate Nutrition 0.000 description 1
150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
239000011591 potassium Substances 0.000 description 1
238000002407 reforming Methods 0.000 description 1
230000008929 regeneration Effects 0.000 description 1
238000011069 regeneration method Methods 0.000 description 1
239000011347 resin Substances 0.000 description 1
229920005989 resin Polymers 0.000 description 1
239000003079 shale oil Substances 0.000 description 1
238000007493 shaping process Methods 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
239000002904 solvent Substances 0.000 description 1
239000000126 substance Substances 0.000 description 1
239000006228 supernatant Substances 0.000 description 1
ZCUFMDLYAMJYST-UHFFFAOYSA-N thorium dioxide Chemical compound O=[Th]=O ZCUFMDLYAMJYST-UHFFFAOYSA-N 0.000 description 1
229910003452 thorium oxide Inorganic materials 0.000 description 1
239000010936 titanium Substances 0.000 description 1
229910052719 titanium Inorganic materials 0.000 description 1
WOZZOSDBXABUFO-UHFFFAOYSA-N tri(butan-2-yloxy)alumane Chemical compound [Al+3].CCC(C)[O-].CCC(C)[O-].CCC(C)[O-] WOZZOSDBXABUFO-UHFFFAOYSA-N 0.000 description 1
WXRGABKACDFXMG-UHFFFAOYSA-N trimethylborane Chemical compound CB(C)C WXRGABKACDFXMG-UHFFFAOYSA-N 0.000 description 1
XDSSGQHOYWGIKC-UHFFFAOYSA-N tris(2-methylpropyl)borane Chemical compound CC(C)CB(CC(C)C)CC(C)C XDSSGQHOYWGIKC-UHFFFAOYSA-N 0.000 description 1
210000004291 uterus Anatomy 0.000 description 1
229910052720 vanadium Inorganic materials 0.000 description 1
GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
150000003738 xylenes Chemical class 0.000 description 1
229910001928 zirconium oxide Inorganic materials 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Polymerization Catalysts (AREA)
Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
Catalysts (AREA)

NO780112A 1977-01-13 1978-01-12 Katalytiske materialer for olefinpolymerisering NO780112L (no)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US05/759,213 US4100104A (en)	1977-01-13	1977-01-13	Catalytic materials as for olefin polymerization

Publications (1)

Publication Number	Publication Date
NO780112L true NO780112L (no)	1978-07-14

Family

ID=25054822

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NO780112A NO780112L (no)	1977-01-13	1978-01-12	Katalytiske materialer for olefinpolymerisering

Country Status (8)

Country	Link
US (2)	US4100104A (fr)
JP (1)	JPS5389895A (fr)
AU (1)	AU3222178A (fr)
BE (1)	BE862904A (fr)
DE (1)	DE2801240A1 (fr)
FR (2)	FR2390204A1 (fr)
NL (1)	NL190872C (fr)
NO (1)	NO780112L (fr)

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Publication number	Priority date	Publication date	Assignee	Title
US4192775A (en) *	1975-03-14	1980-03-11	National Petro Chemicals Corporation	Olefin polymerization catalyst
US4290914A (en) *	1977-01-13	1981-09-22	National Petro Chemicals Corp.	Catalytic materials as for olefin polymerization
US4593079A (en) *	1977-05-25	1986-06-03	National Distillers And Chemical Corporation	Resin rheology control process and catalyst therefor
CA1094749A (fr) *	1977-05-25	1981-01-27	Louis J. Rekers	Catalyseur et procede pour le controle de la rheologie des resines
AU3589578A (en) *	1977-05-25	1979-11-15	Nat Petro Chem	Supported heat activated chromium containing catalyst containing polymeric h/c aluminate
USRE31443E (en) *	1977-12-05	1983-11-15	Phillips Petroleum Company	Treatment of silica
USRE31390E (en) *	1977-12-05	1983-09-20	Phillips Petroleum Company	Treatment of silica
US4248735A (en) *	1979-06-01	1981-02-03	Phillips Petroleum Company	Treatment of silica
US4238353A (en) *	1978-07-14	1980-12-09	National Petro Chemicals Corp.	Olefin polymerization catalyst
DE2925987A1 (de) *	1978-07-14	1980-01-24	Nat Petro Chem	Katalysator fuer die polymerisation von olefinen und verfahren zu seiner herstellung
US4297460A (en) *	1979-06-01	1981-10-27	Phillips Petroleum Co.	Treatment of silica
US4297461A (en) *	1979-06-08	1981-10-27	National Petro Chemicals Corp.	Olefin polymerization catalyst
US4260706A (en) *	1979-06-21	1981-04-07	National Petro Chemicals Corp.	Olefin polymerization catalyst
US4356294A (en) *	1980-10-24	1982-10-26	National Petro Chemicals Corp.	Production of polyolefins having improved ESCR
US4379075A (en) *	1981-03-13	1983-04-05	National Petro Chemicals Corp.	Process for polymerizing high melt index olefins and polymerization catalysts used therefore
DE3635710A1 (de) *	1986-10-21	1988-04-28	Basf Ag	Verfahren zum herstellen von homo- sowie copolymerisaten des ethens durch phillips-katalyse
MY105477A (en) *	1990-03-29	1994-10-31	Sumitomo Chemical Co	Thermosetting resin composition and use thereof for an electronic part.
EP0562203A1 (fr) *	1992-03-24	1993-09-29	Bp Chemicals S.N.C.	Procédé de préparation d'un catalyseur de polymérisation
DE19802753A1 (de) *	1998-01-26	1999-07-29	Merck Patent Gmbh	Coreaktive Trägermaterialien zur Heterogenisierung von Katalysatoren, Cokatalysatoren und Liganden
EP1207170A1 (fr) †	2000-11-20	2002-05-22	BP Chemicals S.N.C.	Procédé de (co-)polymérisation continu des oléfines en phase gazeuse dans un réacteur en lit fluidisé
US10000931B1 (en)	2016-12-13	2018-06-19	Daniel T. Daugherty	Apparatus and method for moss remediation

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
NL128404C (fr) *	1959-12-24
US3639381A (en) *	1968-05-10	1972-02-01	Allied Chem	Polyethylene process and catalyst
DE2000031A1 (de) *	1969-01-06	1970-08-27	Phillips Petroleum Co	Verfahren zum Polymerisieren von 1-Olefinen und Katalysatorsystem
US3960826A (en) *	1973-07-27	1976-06-01	National Petro Chemicals Corporation	Olefin polymerization process
US3985676A (en) *	1974-01-24	1976-10-12	National Petro Chemicals Corporation	Catalyst composition and method for the preparation thereof
GB1505818A (en) *	1974-06-11	1978-03-30	British Petroleum Co	Polymerisation process
US3984351A (en) *	1975-03-14	1976-10-05	National Petro Chemicals Corporation	Olefin polymerization catalyst
US4049896A (en) *	1975-03-14	1977-09-20	National Petro Chemicals Corporation	Olefin polymerization catalyst

1977
- 1977-01-13 US US05/759,213 patent/US4100104A/en not_active Expired - Lifetime
1978
- 1978-01-06 AU AU32221/78A patent/AU3222178A/en active Pending
- 1978-01-12 NO NO780112A patent/NO780112L/no unknown
- 1978-01-12 DE DE19782801240 patent/DE2801240A1/de active Pending
- 1978-01-12 FR FR7800785A patent/FR2390204A1/fr not_active Withdrawn
- 1978-01-13 JP JP208278A patent/JPS5389895A/ja active Pending
- 1978-01-13 BE BE184316A patent/BE862904A/fr unknown
- 1978-01-13 NL NL7800464A patent/NL190872C/xx not_active IP Right Cessation
- 1978-03-06 US US05/883,566 patent/US4150209A/en not_active Expired - Lifetime
- 1978-08-31 FR FR7825210A patent/FR2390205A1/fr not_active Withdrawn

Also Published As

Publication number	Publication date
US4100104A (en)	1978-07-11
JPS5389895A (en)	1978-08-08
NL190872B (nl)	1994-05-02
NL7800464A (nl)	1978-07-17
US4150209A (en)	1979-04-17
NL190872C (nl)	1994-10-03
BE862904A (fr)	1978-07-13
AU3222178A (en)	1979-07-12
DE2801240A1 (de)	1978-07-20
FR2390204A1 (fr)	1978-12-08
FR2390205A1 (fr)	1978-12-08

Publication	Publication Date	Title
NO780112L (no)	1978-07-14	Katalytiske materialer for olefinpolymerisering
NO152300B (no)	1985-05-28	Katalysatorsystem for oljefinpolymerisering, fremgangsmaate for dens fremstilling av anvendelse derav
WO1992017511A1 (fr)	1992-10-15	Catalyseurs mixtes de chrome et polymerisations les utilisant
GB2090268A (en)	1982-07-07	Phosphate-supported chromium-containing olefin polymerisation catalysts
US4049896A (en)	1977-09-20	Olefin polymerization catalyst
US4981927A (en)	1991-01-01	Chromium catalyst compositions and polymerization utilizing same
US4290914A (en)	1981-09-22	Catalytic materials as for olefin polymerization
CA1307619C (fr)	1992-09-15	Compositions catalytiques de chrome et polymerisation a l'aide de celles-ci
GB1584469A (en)	1981-02-11	Polymerization catalyst
US5081089A (en)	1992-01-14	Chromium catalyst compositions and polymerization utilizing same
US3153634A (en)	1964-10-20	Gamma alumina supported titanium and zirconium subhalides polymerization catalysts and preparation thereof
US5021379A (en)	1991-06-04	Olefin polymerization
US4192775A (en)	1980-03-11	Olefin polymerization catalyst
US5104950A (en)	1992-04-14	Olefin polymerization
WO2007111499A1 (fr)	2007-10-04	Procede de fabrication d'un polyethylene lineaire
US4189402A (en)	1980-02-19	Supported catalyst for olefin polymerization
CA1080207A (fr)	1980-06-24	Catalyseur de la polymerisation des olefines
JPS5837012A (ja)	1983-03-04	触媒成分の製造方法
US3255167A (en)	1966-06-07	Olefin polymerization in presence of a reduced titanium halide supported on gamma alumina and an organometallic compound
US4276399A (en)	1981-06-30	Supported catalyst from chromium for olefin polymerization
CA1173820A (fr)	1984-09-04	Catalyseur et methode de polymerisation des olefines
US4211671A (en)	1980-07-08	Olefin polymerization catalyst
US4260706A (en)	1981-04-07	Olefin polymerization catalyst
Werber	2006	Polymerization of olefins on supported catalysts
BiaŁek et al.	2009	Chlorotitanium (IV) tetradentate Schiff‐base complex immobilized on inorganic supports: Support type and other factors having effect on ethylene polymerization activity