NO784070L - Fremgangsmaate ved fremstilling av klorert fenol - Google Patents

Fremgangsmaate ved fremstilling av klorert fenol

Info

Publication number: NO784070L
Authority: NO; Norway
Prior art keywords: reaction; reaction medium; dichlorophenol; trichlorophenol; catalyst
Prior art date: 1977-12-06

Application number

NO784070A

Other languages

English (en)

Norwegian (no)

Inventor

Eric Cuthbertson

Original Assignee

Sterwin Ag

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1977-12-06

Filing date

1978-12-04

Publication date

1979-06-07

1978-12-04 Application filed by Sterwin Ag filed Critical Sterwin Ag

1979-06-07 Publication of NO784070L publication Critical patent/NO784070L/no

Links

238000000034 method Methods 0.000 title claims description 21
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical class OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 title 1
239000012429 reaction media Substances 0.000 claims description 23
238000006243 chemical reaction Methods 0.000 claims description 17
RANCECPPZPIPNO-UHFFFAOYSA-N 2,5-dichlorophenol Chemical compound OC1=CC(Cl)=CC=C1Cl RANCECPPZPIPNO-UHFFFAOYSA-N 0.000 claims description 15
LHJGJYXLEPZJPM-UHFFFAOYSA-N 2,4,5-trichlorophenol Chemical compound OC1=CC(Cl)=C(Cl)C=C1Cl LHJGJYXLEPZJPM-UHFFFAOYSA-N 0.000 claims description 13
239000011968 lewis acid catalyst Substances 0.000 claims description 11
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 9
239000000460 chlorine Substances 0.000 claims description 9
229910052801 chlorine Inorganic materials 0.000 claims description 9
VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims description 8
238000005660 chlorination reaction Methods 0.000 claims description 7
XGCHAIDDPMFRLJ-UHFFFAOYSA-N 2,3,6-trichlorophenol Chemical compound OC1=C(Cl)C=CC(Cl)=C1Cl XGCHAIDDPMFRLJ-UHFFFAOYSA-N 0.000 claims description 5
239000007788 liquid Substances 0.000 claims description 5
239000000203 mixture Substances 0.000 claims description 5
239000000376 reactant Substances 0.000 claims description 4
239000011541 reaction mixture Substances 0.000 claims description 4
WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 claims description 3
230000015572 biosynthetic process Effects 0.000 claims description 3
239000012430 organic reaction media Substances 0.000 claims description 3
239000002904 solvent Substances 0.000 claims description 3
239000000126 substance Substances 0.000 claims description 3
239000003054 catalyst Substances 0.000 claims 6
150000001875 compounds Chemical class 0.000 claims 5
239000006227 byproduct Substances 0.000 claims 4
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims 3
YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 claims 3
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims 3
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims 3
150000008280 chlorinated hydrocarbons Chemical class 0.000 claims 3
230000007062 hydrolysis Effects 0.000 claims 3
238000006460 hydrolysis reaction Methods 0.000 claims 3
LQNUZADURLCDLV-UHFFFAOYSA-N nitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 claims 3
JHBKHLUZVFWLAG-UHFFFAOYSA-N 1,2,4,5-tetrachlorobenzene Chemical compound ClC1=CC(Cl)=C(Cl)C=C1Cl JHBKHLUZVFWLAG-UHFFFAOYSA-N 0.000 claims 2
KZMGYPLQYOPHEL-UHFFFAOYSA-N Boron trifluoride etherate Chemical compound FB(F)F.CCOCC KZMGYPLQYOPHEL-UHFFFAOYSA-N 0.000 claims 2
MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 claims 2
238000004519 manufacturing process Methods 0.000 claims 2
JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 claims 2
TXUICONDJPYNPY-UHFFFAOYSA-N (1,10,13-trimethyl-3-oxo-4,5,6,7,8,9,11,12,14,15,16,17-dodecahydrocyclopenta[a]phenanthren-17-yl) heptanoate Chemical compound C1CC2CC(=O)C=C(C)C2(C)C2C1C1CCC(OC(=O)CCCCCC)C1(C)CC2 TXUICONDJPYNPY-UHFFFAOYSA-N 0.000 claims 1
SMYMJHWAQXWPDB-UHFFFAOYSA-N (2,4,5-trichlorophenoxy)acetic acid Chemical compound OC(=O)COC1=CC(Cl)=C(Cl)C=C1Cl SMYMJHWAQXWPDB-UHFFFAOYSA-N 0.000 claims 1
HGUFODBRKLSHSI-UHFFFAOYSA-N 2,3,7,8-tetrachloro-dibenzo-p-dioxin Chemical compound O1C2=CC(Cl)=C(Cl)C=C2OC2=C1C=C(Cl)C(Cl)=C2 HGUFODBRKLSHSI-UHFFFAOYSA-N 0.000 claims 1
239000003559 2,4,5-trichlorophenoxyacetic acid Substances 0.000 claims 1
AVYGCQXNNJPXSS-UHFFFAOYSA-N 2,5-dichloroaniline Chemical compound NC1=CC(Cl)=CC=C1Cl AVYGCQXNNJPXSS-UHFFFAOYSA-N 0.000 claims 1
VBZBVAZQSYTWLB-UHFFFAOYSA-N 3-benzyl-3,4,4,5,5,6-hexachlorocyclohexene Chemical compound ClC1C(C(C(C=C1)(CC1=CC=CC=C1)Cl)(Cl)Cl)(Cl)Cl VBZBVAZQSYTWLB-UHFFFAOYSA-N 0.000 claims 1
KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 claims 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
229910021626 Tin(II) chloride Inorganic materials 0.000 claims 1
125000002723 alicyclic group Chemical group 0.000 claims 1
125000001931 aliphatic group Chemical group 0.000 claims 1
230000000844 anti-bacterial effect Effects 0.000 claims 1
VMPVEPPRYRXYNP-UHFFFAOYSA-I antimony(5+);pentachloride Chemical compound Cl[Sb](Cl)(Cl)(Cl)Cl VMPVEPPRYRXYNP-UHFFFAOYSA-I 0.000 claims 1
125000003118 aryl group Chemical group 0.000 claims 1
239000003899 bactericide agent Substances 0.000 claims 1
230000003197 catalytic effect Effects 0.000 claims 1
FOCAUTSVDIKZOP-UHFFFAOYSA-N chloroacetic acid Chemical compound OC(=O)CCl FOCAUTSVDIKZOP-UHFFFAOYSA-N 0.000 claims 1
229940106681 chloroacetic acid Drugs 0.000 claims 1
239000002537 cosmetic Substances 0.000 claims 1
238000006193 diazotization reaction Methods 0.000 claims 1
230000008020 evaporation Effects 0.000 claims 1
238000001704 evaporation Methods 0.000 claims 1
230000002363 herbicidal effect Effects 0.000 claims 1
239000004009 herbicide Substances 0.000 claims 1
ACGUYXCXAPNIKK-UHFFFAOYSA-N hexachlorophene Chemical compound OC1=C(Cl)C=C(Cl)C(Cl)=C1CC1=C(O)C(Cl)=CC(Cl)=C1Cl ACGUYXCXAPNIKK-UHFFFAOYSA-N 0.000 claims 1
229960004068 hexachlorophene Drugs 0.000 claims 1
239000001257 hydrogen Substances 0.000 claims 1
229910052739 hydrogen Inorganic materials 0.000 claims 1
239000000463 material Substances 0.000 claims 1
WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims 1
LQNUZADURLCDLV-IDEBNGHGSA-N nitrobenzene Chemical group [O-][N+](=O)[13C]1=[13CH][13CH]=[13CH][13CH]=[13CH]1 LQNUZADURLCDLV-IDEBNGHGSA-N 0.000 claims 1
239000000047 product Substances 0.000 claims 1
239000000344 soap Substances 0.000 claims 1
239000001119 stannous chloride Substances 0.000 claims 1
235000011150 stannous chloride Nutrition 0.000 claims 1
239000007858 starting material Substances 0.000 claims 1
PUGUQINMNYINPK-UHFFFAOYSA-N tert-butyl 4-(2-chloroacetyl)piperazine-1-carboxylate Chemical compound CC(C)(C)OC(=O)N1CCN(C(=O)CCl)CC1 PUGUQINMNYINPK-UHFFFAOYSA-N 0.000 claims 1
XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims 1
231100000331 toxic Toxicity 0.000 claims 1
230000002588 toxic effect Effects 0.000 claims 1
230000007306 turnover Effects 0.000 claims 1
239000011592 zinc chloride Substances 0.000 claims 1
235000005074 zinc chloride Nutrition 0.000 claims 1
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
VGVRPFIJEJYOFN-UHFFFAOYSA-N 2,3,4,6-tetrachlorophenol Chemical compound OC1=C(Cl)C=C(Cl)C(Cl)=C1Cl VGVRPFIJEJYOFN-UHFFFAOYSA-N 0.000 description 2
150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
239000003513 alkali Substances 0.000 description 1
230000000903 blocking effect Effects 0.000 description 1
239000012320 chlorinating reagent Substances 0.000 description 1
238000004587 chromatography analysis Methods 0.000 description 1
239000000356 contaminant Substances 0.000 description 1
230000000694 effects Effects 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
238000000605 extraction Methods 0.000 description 1
238000001914 filtration Methods 0.000 description 1
239000002198 insoluble material Substances 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
230000020477 pH reduction Effects 0.000 description 1
239000007787 solid Substances 0.000 description 1
238000003756 stirring Methods 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
- C07C37/62—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by introduction of halogen; by substitution of halogen atoms by other halogen atoms

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Catalysts (AREA)

NO784070A 1977-12-06 1978-12-04 Fremgangsmaate ved fremstilling av klorert fenol NO784070L (no)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
GB5077377		1977-12-06

Publications (1)

Publication Number	Publication Date
NO784070L true NO784070L (no)	1979-06-07

Family

ID=10457294

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NO784070A NO784070L (no)	1977-12-06	1978-12-04	Fremgangsmaate ved fremstilling av klorert fenol

Country Status (6)

Country	Link
US (1)	US4237321A (de)
EP (1)	EP0002373A1 (de)
AT (1)	AT360507B (de)
DK (1)	DK548478A (de)
FI (1)	FI783731A7 (de)
NO (1)	NO784070L (de)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4346248A (en) *	1980-02-20	1982-08-24	Vertac Chemical Corporation	Preparation of 2,4,5-trichlorophenol and 2,4,5-trichlorophenoxyacetic acid free of 2,3,7,8-tetrachloro-dibenzo-p-dioxin contamination
DE3132692A1 (de) *	1981-08-19	1983-03-17	Bayer Ag, 5090 Leverkusen	Verfahren zur halogenierung von organischen verbindungen
US4564714A (en) *	1984-10-30	1986-01-14	Givaudan Corporation	Process for the preparation of 2,4,5-trichlorophenol under acidic conditions
FR2587332B1 (fr) *	1985-09-19	1989-02-17	Rhone Poulenc Spec Chim	Procede de chloration selective de composes phenoliques
FR2601001B1 (fr) *	1986-07-02	1988-11-10	Rhone Poulenc Chim Base	Procede de chloration de composes phenoliques
FR2611702B1 (fr) *	1987-03-05	1989-06-09	Rhone Poulenc Chimie	Procede de chloration de l'orthochlorophenol
FR2611701B1 (fr) *	1987-03-05	1989-06-16	Rhone Poulenc Chimie	Procede de chloration de composes phenoliques
FR2618144B1 (fr) *	1987-07-17	1989-11-24	Rhone Poulenc Chimie	Procede de chloration de composes phenoliques

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE527393C (de) *	1929-06-09	1931-06-19	I G Farbenindustrie Akt Ges	Verfahren zur Herstellung von chlorierten Phenolen
US2494993A (en) *	1943-04-21	1950-01-17	Ici Ltd	Manufacture of chlorocresols
US2665314A (en) *	1951-04-04	1954-01-05	Du Pont	Selective chlorination of 2, 5-dichlorophenal to 2, 4, 5-trichlorophenol in the presence of 2, 4-dichlorophenal
US2756260A (en) *	1952-08-14	1956-07-24	Dow Chemical Co	Method of making trichlorophenol mixtures which are rich in the 2, 4, 5-isomer
NL274287A (de) *	1961-02-03

1978
- 1978-12-01 EP EP78300722A patent/EP0002373A1/de not_active Withdrawn
- 1978-12-04 NO NO784070A patent/NO784070L/no unknown
- 1978-12-04 DK DK548478A patent/DK548478A/da unknown
- 1978-12-04 US US05/966,101 patent/US4237321A/en not_active Expired - Lifetime
- 1978-12-05 AT AT869278A patent/AT360507B/de not_active IP Right Cessation
- 1978-12-05 FI FI783731A patent/FI783731A7/fi unknown

Also Published As

Publication number	Publication date
AT360507B (de)	1981-01-12
EP0002373A1 (de)	1979-06-13
ATA869278A (de)	1980-06-15
FI783731A7 (fi)	1979-06-07
DK548478A (da)	1979-06-07
US4237321A (en)	1980-12-02

Publication	Publication Date	Title
NO176093B (no)	1994-10-24	Reaktive forbindelser som inneholder perfluorvinylgrupper, og anvendelse av slike forbindelser
NO784070L (no)	1979-06-07	Fremgangsmaate ved fremstilling av klorert fenol
US4209457A (en)	1980-06-24	Production of halogenated benzonitriles
DK170156B1 (da)	1995-06-06	Fremgangsmåde til fremstilling af 0-methallyloxyphenol
NO300629B1 (no)	1997-06-30	Fremgangsmåte for fremstilling av jern(III)klorid i vandig opplösning fra fortynnet saltsyre
CA1340042C (fr)	1998-09-15	Procede de preparation du chlorure ferrique a partir du chlorure ferreux
EP0084158B1 (de)	1986-07-23	Verfahren zur Herstellung von 4-Hydroxy-2,4,6-trimethylcyclohexa-2,5-dien-1-on
US4324930A (en)	1982-04-13	2,3-Dichloro-2-trifluoromethyl-1,1,1,3,4,4,5,5,5-nonafluoropentane and process for its manufacture
DK170798B1 (da)	1996-01-22	Fremgangsmåde til fremstilling af monochlorpinacolin ved chlorering af pinacolin med gasformigt chlor
Chalmers	1932	Preparation of the Ethers of Vinyl Alcohol
US4326089A (en)	1982-04-20	Thermal process for preparing 3-phenoxybenzyl bromide
US4259496A (en)	1981-03-31	Halogenation of pyridine compounds
US4365101A (en)	1982-12-21	Process for preparing benzotrifluoride and its derivatives
US6372921B1 (en)	2002-04-16	Process for producing isochromanones and intermediates thereof
US4393257A (en)	1983-07-12	Process for preparing benzotrifluoride and its derivatives
CA1092613A (en)	1980-12-30	Liquid phase fluorination process
GB913987A (en)	1962-12-28	A process for the production of chlorinated phenols with recovery of hydrochloric acid
EP1116720A1 (de)	2001-07-18	Verfahren zur herstellung von isochromanonen und zwischenprodukten für deren herstellung
US4268457A (en)	1981-05-19	Process for the preparation of paraphenoxybenzoylchloride
EP0010013B1 (de)	1981-10-21	Verfahren zur Herstellung von Äthylenchlorhydrin
JPS6116252B2 (de)	1986-04-28
US4377713A (en)	1983-03-22	Chemical process for preparing 3-phenoxybenzyl chloride
US2841593A (en)	1958-07-01	Reaction of substituted benzene, chlorine, and substituted maleic anhydride and products thereof
US3137694A (en)	1964-06-16	Method for isolating tetrameric cyanogen halide from its reaction mixture
CA1230617A (en)	1987-12-22	Selective bromination process