NO801038L - Fremgangsmaate for fremstilling av polymere produkter - Google Patents

Fremgangsmaate for fremstilling av polymere produkter

Info

Publication number: NO801038L
Authority: NO; Norway
Prior art keywords: polymer; product; parts; approx; dispersion
Prior art date: 1979-04-11

Application number

NO801038A

Other languages

English (en)

Norwegian (no)

Inventor

Vincent Wen-Hwa Ting

Original Assignee

Scm Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1979-04-11

Filing date

1980-04-10

Publication date

1980-10-13

1980-04-10 Application filed by Scm Corp filed Critical Scm Corp

1980-10-13 Publication of NO801038L publication Critical patent/NO801038L/no

Links

229920000642 polymer Polymers 0.000 title claims abstract description 68
238000000034 method Methods 0.000 title claims abstract description 49
238000004519 manufacturing process Methods 0.000 title claims description 30
239000000178 monomer Substances 0.000 claims abstract description 148
239000007787 solid Substances 0.000 claims abstract description 146
239000003822 epoxy resin Substances 0.000 claims abstract description 106
229920000647 polyepoxide Polymers 0.000 claims abstract description 106
229920005989 resin Polymers 0.000 claims abstract description 100
239000011347 resin Substances 0.000 claims abstract description 100
229920000578 graft copolymer Polymers 0.000 claims abstract description 71
238000011065 in-situ storage Methods 0.000 claims abstract description 25
238000012644 addition polymerization Methods 0.000 claims abstract description 16
125000001931 aliphatic group Chemical group 0.000 claims abstract description 9
230000008569 process Effects 0.000 claims abstract description 7
239000000047 product Substances 0.000 claims description 172
239000007795 chemical reaction product Substances 0.000 claims description 120
239000006185 dispersion Substances 0.000 claims description 99
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 88
239000002253 acid Substances 0.000 claims description 79
238000006116 polymerization reaction Methods 0.000 claims description 48
239000002904 solvent Substances 0.000 claims description 45
229920002554 vinyl polymer Polymers 0.000 claims description 38
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 32
238000000576 coating method Methods 0.000 claims description 30
239000000463 material Substances 0.000 claims description 27
239000004593 Epoxy Substances 0.000 claims description 25
239000011248 coating agent Substances 0.000 claims description 23
239000003795 chemical substances by application Substances 0.000 claims description 22
239000011541 reaction mixture Substances 0.000 claims description 21
239000008365 aqueous carrier Substances 0.000 claims description 17
239000007788 liquid Substances 0.000 claims description 13
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 12
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 10
125000003118 aryl group Chemical group 0.000 claims description 10
125000003700 epoxy group Chemical group 0.000 claims description 10
125000004432 carbon atom Chemical group C* 0.000 claims description 9
239000003973 paint Substances 0.000 claims description 9
229910052799 carbon Inorganic materials 0.000 claims description 7
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 7
239000000725 suspension Substances 0.000 claims description 6
238000010559 graft polymerization reaction Methods 0.000 claims description 5
230000007062 hydrolysis Effects 0.000 claims description 4
238000006460 hydrolysis reaction Methods 0.000 claims description 4
OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 claims description 3
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 3
239000012453 solvate Substances 0.000 claims description 3
239000003505 polymerization initiator Substances 0.000 claims description 2
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
125000002843 carboxylic acid group Chemical group 0.000 claims 1
239000003999 initiator Substances 0.000 abstract description 30
230000000977 initiatory effect Effects 0.000 abstract description 2
230000000379 polymerizing effect Effects 0.000 abstract 1
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 116
239000000203 mixture Substances 0.000 description 99
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 63
238000006243 chemical reaction Methods 0.000 description 59
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 49
229910052757 nitrogen Inorganic materials 0.000 description 34
239000002966 varnish Substances 0.000 description 32
239000004342 Benzoyl peroxide Substances 0.000 description 28
OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 28
235000019400 benzoyl peroxide Nutrition 0.000 description 28
239000004922 lacquer Substances 0.000 description 25
238000003756 stirring Methods 0.000 description 25
150000001412 amines Chemical class 0.000 description 21
239000004971 Cross linker Substances 0.000 description 20
239000012467 final product Substances 0.000 description 18
LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 16
CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 16
-1 aromatic monocarboxylic acids Chemical class 0.000 description 15
239000002245 particle Substances 0.000 description 15
239000002585 base Substances 0.000 description 14
UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 description 13
229960002887 deanol Drugs 0.000 description 13
239000012972 dimethylethanolamine Substances 0.000 description 13
229910052751 metal Inorganic materials 0.000 description 13
239000002184 metal Substances 0.000 description 13
239000003513 alkali Substances 0.000 description 12
CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 12
JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 12
238000003860 storage Methods 0.000 description 12
239000004094 surface-active agent Substances 0.000 description 12
229920003180 amino resin Polymers 0.000 description 11
IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 11
238000002156 mixing Methods 0.000 description 11
239000000243 solution Substances 0.000 description 11
JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 10
PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 10
238000005507 spraying Methods 0.000 description 10
229920003270 Cymel® Polymers 0.000 description 9
239000003960 organic solvent Substances 0.000 description 9
239000000049 pigment Substances 0.000 description 9
238000010926 purge Methods 0.000 description 9
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 8
230000008901 benefit Effects 0.000 description 8
239000003054 catalyst Substances 0.000 description 8
JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 8
239000002994 raw material Substances 0.000 description 8
XWGJFPHUCFXLBL-UHFFFAOYSA-M rongalite Chemical compound [Na+].OCS([O-])=O XWGJFPHUCFXLBL-UHFFFAOYSA-M 0.000 description 8
150000001732 carboxylic acid derivatives Chemical class 0.000 description 7
239000002952 polymeric resin Substances 0.000 description 7
238000002360 preparation method Methods 0.000 description 7
229910052708 sodium Inorganic materials 0.000 description 7
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
150000007513 acids Chemical class 0.000 description 6
235000013361 beverage Nutrition 0.000 description 6
238000001723 curing Methods 0.000 description 6
150000002148 esters Chemical class 0.000 description 6
WSFSSNUMVMOOMR-UHFFFAOYSA-N formaldehyde Substances O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
238000010438 heat treatment Methods 0.000 description 6
239000011734 sodium Substances 0.000 description 6
239000000126 substance Substances 0.000 description 6
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 5
239000000443 aerosol Substances 0.000 description 5
ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 5
239000012298 atmosphere Substances 0.000 description 5
238000004132 cross linking Methods 0.000 description 5
230000000694 effects Effects 0.000 description 5
235000013305 food Nutrition 0.000 description 5
LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 5
238000013007 heat curing Methods 0.000 description 5
150000002978 peroxides Chemical class 0.000 description 5
230000002829 reductive effect Effects 0.000 description 5
150000003335 secondary amines Chemical class 0.000 description 5
HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 4
OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 4
XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 description 4
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 4
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 4
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical group O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
OKKRPWIIYQTPQF-UHFFFAOYSA-N Trimethylolpropane trimethacrylate Chemical compound CC(=C)C(=O)OCC(CC)(COC(=O)C(C)=C)COC(=O)C(C)=C OKKRPWIIYQTPQF-UHFFFAOYSA-N 0.000 description 4
239000000654 additive Substances 0.000 description 4
238000004458 analytical method Methods 0.000 description 4
235000013405 beer Nutrition 0.000 description 4
239000003153 chemical reaction reagent Substances 0.000 description 4
239000008199 coating composition Substances 0.000 description 4
229920001577 copolymer Polymers 0.000 description 4
238000011010 flushing procedure Methods 0.000 description 4
239000004310 lactic acid Substances 0.000 description 4
235000014655 lactic acid Nutrition 0.000 description 4
238000005259 measurement Methods 0.000 description 4
238000001556 precipitation Methods 0.000 description 4
230000009467 reduction Effects 0.000 description 4
239000000758 substrate Substances 0.000 description 4
150000003512 tertiary amines Chemical class 0.000 description 4
125000001302 tertiary amino group Chemical group 0.000 description 4
239000000080 wetting agent Substances 0.000 description 4
239000008096 xylene Substances 0.000 description 4
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 3
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 3
229920000877 Melamine resin Polymers 0.000 description 3
239000004159 Potassium persulphate Substances 0.000 description 3
125000005250 alkyl acrylate group Chemical group 0.000 description 3
125000003277 amino group Chemical group 0.000 description 3
239000012736 aqueous medium Substances 0.000 description 3
230000015572 biosynthetic process Effects 0.000 description 3
KAKZBPTYRLMSJV-UHFFFAOYSA-N butadiene group Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 3
239000003638 chemical reducing agent Substances 0.000 description 3
MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
VAYGXNSJCAHWJZ-UHFFFAOYSA-N dimethyl sulfate Chemical compound COS(=O)(=O)OC VAYGXNSJCAHWJZ-UHFFFAOYSA-N 0.000 description 3
238000001035 drying Methods 0.000 description 3
229920001002 functional polymer Polymers 0.000 description 3
239000001257 hydrogen Substances 0.000 description 3
229910052739 hydrogen Inorganic materials 0.000 description 3
239000004615 ingredient Substances 0.000 description 3
239000002609 medium Substances 0.000 description 3
239000012299 nitrogen atmosphere Substances 0.000 description 3
238000009928 pasteurization Methods 0.000 description 3
JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 3
USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 3
235000019394 potassium persulphate Nutrition 0.000 description 3
239000000843 powder Substances 0.000 description 3
239000001632 sodium acetate Substances 0.000 description 3
235000017281 sodium acetate Nutrition 0.000 description 3
239000007921 spray Substances 0.000 description 3
OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 2
JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 description 2
SZNYYWIUQFZLLT-UHFFFAOYSA-N 2-methyl-1-(2-methylpropoxy)propane Chemical compound CC(C)COCC(C)C SZNYYWIUQFZLLT-UHFFFAOYSA-N 0.000 description 2
BNCADMBVWNPPIZ-UHFFFAOYSA-N 2-n,2-n,4-n,4-n,6-n,6-n-hexakis(methoxymethyl)-1,3,5-triazine-2,4,6-triamine Chemical compound COCN(COC)C1=NC(N(COC)COC)=NC(N(COC)COC)=N1 BNCADMBVWNPPIZ-UHFFFAOYSA-N 0.000 description 2
AOHAPDDBNAPPIN-UHFFFAOYSA-N 3-Methoxy-4,5-methylenedioxybenzoic acid Chemical compound COC1=CC(C(O)=O)=CC2=C1OCO2 AOHAPDDBNAPPIN-UHFFFAOYSA-N 0.000 description 2
HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 description 2
HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 2
SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Natural products CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
229920001807 Urea-formaldehyde Polymers 0.000 description 2
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 2
150000001299 aldehydes Chemical class 0.000 description 2
125000000217 alkyl group Chemical group 0.000 description 2
229910001870 ammonium persulfate Inorganic materials 0.000 description 2
125000000129 anionic group Chemical group 0.000 description 2
WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical compound CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 2
150000001875 compounds Chemical class 0.000 description 2
239000003431 cross linking reagent Substances 0.000 description 2
XJOBOFWTZOKMOH-UHFFFAOYSA-N decanoyl decaneperoxoate Chemical compound CCCCCCCCCC(=O)OOC(=O)CCCCCCCCC XJOBOFWTZOKMOH-UHFFFAOYSA-N 0.000 description 2
210000003298 dental enamel Anatomy 0.000 description 2
ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 2
GRWZHXKQBITJKP-UHFFFAOYSA-N dithionous acid Chemical compound OS(=O)S(O)=O GRWZHXKQBITJKP-UHFFFAOYSA-N 0.000 description 2
POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
150000002118 epoxides Chemical class 0.000 description 2
230000032050 esterification Effects 0.000 description 2
238000005886 esterification reaction Methods 0.000 description 2
238000009472 formulation Methods 0.000 description 2
IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 description 2
230000000670 limiting effect Effects 0.000 description 2
BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
230000004048 modification Effects 0.000 description 2
238000012986 modification Methods 0.000 description 2
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 2
150000001451 organic peroxides Chemical class 0.000 description 2
SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 description 2
150000003141 primary amines Chemical class 0.000 description 2
125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 2
YKYONYBAUNKHLG-UHFFFAOYSA-N propyl acetate Chemical compound CCCOC(C)=O YKYONYBAUNKHLG-UHFFFAOYSA-N 0.000 description 2
150000003254 radicals Chemical class 0.000 description 2
238000010992 reflux Methods 0.000 description 2
VYGBQXDNOUHIBZ-UHFFFAOYSA-L sodium formaldehyde sulphoxylate Chemical compound [Na+].[Na+].O=C.[O-]S[O-] VYGBQXDNOUHIBZ-UHFFFAOYSA-L 0.000 description 2
CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 2
238000000638 solvent extraction Methods 0.000 description 2
230000009469 supplementation Effects 0.000 description 2
239000004408 titanium dioxide Substances 0.000 description 2
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
238000012546 transfer Methods 0.000 description 2
238000009736 wetting Methods 0.000 description 2
239000002023 wood Substances 0.000 description 2
DTGKSKDOIYIVQL-WEDXCCLWSA-N (+)-borneol Chemical group C1C[C@@]2(C)[C@@H](O)C[C@@H]1C2(C)C DTGKSKDOIYIVQL-WEDXCCLWSA-N 0.000 description 1
OXYKVVLTXXXVRT-UHFFFAOYSA-N (4-chlorobenzoyl) 4-chlorobenzenecarboperoxoate Chemical compound C1=CC(Cl)=CC=C1C(=O)OOC(=O)C1=CC=C(Cl)C=C1 OXYKVVLTXXXVRT-UHFFFAOYSA-N 0.000 description 1
229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 description 1
BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
VZXTWGWHSMCWGA-UHFFFAOYSA-N 1,3,5-triazine-2,4-diamine Chemical compound NC1=NC=NC(N)=N1 VZXTWGWHSMCWGA-UHFFFAOYSA-N 0.000 description 1
XQUPVDVFXZDTLT-UHFFFAOYSA-N 1-[4-[[4-(2,5-dioxopyrrol-1-yl)phenyl]methyl]phenyl]pyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C(C=C1)=CC=C1CC1=CC=C(N2C(C=CC2=O)=O)C=C1 XQUPVDVFXZDTLT-UHFFFAOYSA-N 0.000 description 1
HNAGHMKIPMKKBB-UHFFFAOYSA-N 1-benzylpyrrolidine-3-carboxamide Chemical compound C1C(C(=O)N)CCN1CC1=CC=CC=C1 HNAGHMKIPMKKBB-UHFFFAOYSA-N 0.000 description 1
PAOHAQSLJSMLAT-UHFFFAOYSA-N 1-butylperoxybutane Chemical group CCCCOOCCCC PAOHAQSLJSMLAT-UHFFFAOYSA-N 0.000 description 1
CISIJYCKDJSTMX-UHFFFAOYSA-N 2,2-dichloroethenylbenzene Chemical compound ClC(Cl)=CC1=CC=CC=C1 CISIJYCKDJSTMX-UHFFFAOYSA-N 0.000 description 1
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Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/10—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polymers containing more than one epoxy radical per molecule
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/18—Suspension polymerisation
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F285/00—Macromolecular compounds obtained by polymerising monomers on to preformed graft polymers

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Graft Or Block Polymers (AREA)
Processes Of Treating Macromolecular Substances (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Compositions Of Macromolecular Compounds (AREA)
Polymerisation Methods In General (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Paints Or Removers (AREA)
Artificial Filaments (AREA)
Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)

NO801038A 1979-04-11 1980-04-10 Fremgangsmaate for fremstilling av polymere produkter NO801038L (no)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US06/029,106 US4285847A (en)	1979-04-11	1979-04-11	Polymerization process and product

Publications (1)

Publication Number	Publication Date
NO801038L true NO801038L (no)	1980-10-13

Family

ID=21847253

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NO801038A NO801038L (no)	1979-04-11	1980-04-10	Fremgangsmaate for fremstilling av polymere produkter

Country Status (18)

Country	Link
US (1)	US4285847A (de)
EP (1)	EP0017911B1 (de)
JP (1)	JPS55157614A (de)
KR (1)	KR840000121B1 (de)
AT (1)	ATE6784T1 (de)
AU (1)	AU540403B2 (de)
BR (1)	BR8002231A (de)
CA (1)	CA1166780A (de)
DE (1)	DE3067092D1 (de)
DK (1)	DK154280A (de)
ES (1)	ES490417A0 (de)
FI (1)	FI801122A7 (de)
GB (1)	GB2046767B (de)
HK (1)	HK62284A (de)
NO (1)	NO801038L (de)
NZ (1)	NZ193385A (de)
SG (1)	SG35284G (de)
ZA (1)	ZA802087B (de)

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1979
- 1979-04-11 US US06/029,106 patent/US4285847A/en not_active Expired - Lifetime
1980
- 1980-04-08 GB GB8011486A patent/GB2046767B/en not_active Expired
- 1980-04-09 FI FI801122A patent/FI801122A7/fi not_active Application Discontinuation
- 1980-04-09 ZA ZA00802087A patent/ZA802087B/xx unknown
- 1980-04-09 NZ NZ193385A patent/NZ193385A/xx unknown
- 1980-04-10 ES ES490417A patent/ES490417A0/es active Granted
- 1980-04-10 DK DK154280A patent/DK154280A/da not_active IP Right Cessation
- 1980-04-10 DE DE8080101901T patent/DE3067092D1/de not_active Expired
- 1980-04-10 AT AT80101901T patent/ATE6784T1/de not_active IP Right Cessation
- 1980-04-10 NO NO801038A patent/NO801038L/no unknown
- 1980-04-10 BR BR8002231A patent/BR8002231A/pt unknown
- 1980-04-10 CA CA000349594A patent/CA1166780A/en not_active Expired
- 1980-04-10 KR KR1019800001500A patent/KR840000121B1/ko not_active Expired
- 1980-04-10 EP EP80101901A patent/EP0017911B1/de not_active Expired
- 1980-04-11 AU AU57292/80A patent/AU540403B2/en not_active Ceased
- 1980-04-11 JP JP4791180A patent/JPS55157614A/ja active Pending
1984
- 1984-05-04 SG SG352/84A patent/SG35284G/en unknown
- 1984-08-09 HK HK622/84A patent/HK62284A/xx unknown

Also Published As

Publication number	Publication date
DK154280A (da)	1980-10-12
CA1166780A (en)	1984-05-01
EP0017911A1 (de)	1980-10-29
HK62284A (en)	1984-08-17
SG35284G (en)	1985-04-04
JPS55157614A (en)	1980-12-08
AU5729280A (en)	1980-10-16
AU540403B2 (en)	1984-11-15
NZ193385A (en)	1982-08-17
GB2046767B (en)	1983-04-20
BR8002231A (pt)	1980-12-02
DE3067092D1 (en)	1984-04-26
KR840000121B1 (ko)	1984-02-16
KR830002819A (ko)	1983-05-30
GB2046767A (en)	1980-11-19
ATE6784T1 (de)	1984-04-15
ES8104352A1 (es)	1981-04-16
ES490417A0 (es)	1981-04-16
ZA802087B (en)	1981-04-29
FI801122A7 (fi)	1981-01-01
US4285847A (en)	1981-08-25
EP0017911B1 (de)	1984-03-21

Publication	Publication Date	Title
EP0017911B1 (de)	1984-03-21	Polymer-Zusammensetzungen und ihre Herstellung
US4443568A (en)	1984-04-17	Polymerization process and product
US4399241A (en)	1983-08-16	Base for a graft polymer, novel graft polymer compositions, solvents and water-reducible coatings incorporating the novel graft polymers, and processes for making them
US4482671A (en)	1984-11-13	Base for a graft polymer, novel graft polymer compositions, solvent and water-reducible coatings incorporating the novel graft polymers, and processes for making them
US4308185A (en)	1981-12-29	Graft polymer compositions of terminated epoxy resin, processes for making and using same, and substrates coated therewith
US4446258A (en)	1984-05-01	Aqueous coating comprising dispersible epoxy resin-acid polymer ester and diluent polymer, and method of preparation
US4476262A (en)	1984-10-09	Aqueous coatings comprising ionic polymer ester and diluent polymer with reduced monomer residue and method of preparation
US6306934B1 (en)	2001-10-23	Aqueous coating composition
US5554671A (en)	1996-09-10	Low VOC, aqueous dispersed acrylic epoxy microgels
US4190693A (en)	1980-02-26	Coating method using compositions comprising acrylic oligomers, high polymers and crosslinkers
US5508325A (en)	1996-04-16	Aqueous dispersed, acrylic grafted epoxy microgel protective coatings
NO770723L (no)	1977-09-06	Fremgangsm}te for fremstilling av en vandig emulsjon av en kopolymer
DE69511169T2 (de)	1999-11-25	Vorbereitung von Überzugszusammensetzungen enthaltend wässrig dispergierte epoxy-vernetzte Mikrogelpolymere
US5532297A (en)	1996-07-02	Divinyl benzene modified, aqueous dispersed, acrylic graft coatings
US6034157A (en)	2000-03-07	Process for producing a coating composition
EP0116225B1 (de)	1989-05-03	Wässrige Überzugsmittel und Verfahren zur Herstellung
US5428084A (en)	1995-06-27	Defunctionalized epoxy resins useful in coatings
US4897434A (en)	1990-01-30	Aqueous coating resin compositions and process for producing same
US4501831A (en)	1985-02-26	Aqueous coating compositions and process for their preparation from epoxy acidic acrylic polymer and polyfunctional amine
EP0979249B1 (de)	2003-07-30	Verfahren zur herstellung einer beschichtungsstoffzusammensetzung
NO149140B (no)	1983-11-14	Polymert produkt av diepoksyharpiks og etylenisk umettet monomer, fremgangsmaate for fremstilling av et saadant polymert produkt, samt anvendelse derav
EP0445863A1 (de)	1991-09-11	Wässrige Hybridpolymerdispersion und Beschichtungszusammensetzung
JPH09279088A (ja)	1997-10-28	水性被覆組成物及び被膜
JPH047366B2 (de)	1992-02-10
JPH06329742A (ja)	1994-11-29	アミノ樹脂変性物