NO802142L - Olefin-polymerisasjonskatalysator, fremgangsmaate til polymerisasjon av olefiner og saaledes oppnaadde produkter - Google Patents

Olefin-polymerisasjonskatalysator, fremgangsmaate til polymerisasjon av olefiner og saaledes oppnaadde produkter

Info

Publication number: NO802142L
Authority: NO; Norway
Prior art keywords: compound; catalyst; titanium; catalyst according; vanadium
Prior art date: 1979-07-17

Application number

NO802142A

Other languages

English (en)

Norwegian (no)

Inventor

John Gabriel Speakman

Nicholas Philip Wilkinson

Original Assignee

Bp Chem Int Ltd

Univ Nottingham

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1979-07-17

Filing date

1980-07-16

Publication date

1981-01-19

Family has litigation

First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=10506552&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=NO802142(L) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.

1980-07-16 Application filed by Bp Chem Int Ltd, Univ Nottingham filed Critical Bp Chem Int Ltd

1981-01-19 Publication of NO802142L publication Critical patent/NO802142L/no

Links

238000006116 polymerization reaction Methods 0.000 title claims description 19
238000000034 method Methods 0.000 title claims description 10
150000001336 alkenes Chemical class 0.000 title description 2
239000002685 polymerization catalyst Substances 0.000 title description 2
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title 1
239000003054 catalyst Substances 0.000 claims abstract description 55
150000002902 organometallic compounds Chemical class 0.000 claims abstract description 29
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 24
150000003682 vanadium compounds Chemical class 0.000 claims abstract description 19
239000000463 material Substances 0.000 claims abstract description 16
239000012265 solid product Substances 0.000 claims abstract description 14
229910052736 halogen Inorganic materials 0.000 claims abstract description 12
150000002367 halogens Chemical class 0.000 claims abstract description 12
239000000377 silicon dioxide Substances 0.000 claims abstract description 12
150000003609 titanium compounds Chemical class 0.000 claims abstract description 8
125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 6
125000000217 alkyl group Chemical group 0.000 claims abstract description 5
230000002378 acidificating effect Effects 0.000 claims abstract description 4
239000010936 titanium Substances 0.000 claims description 22
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 16
229910052719 titanium Inorganic materials 0.000 claims description 16
150000001875 compounds Chemical class 0.000 claims description 8
XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims description 7
229910052782 aluminium Inorganic materials 0.000 claims description 6
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 6
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 6
239000000178 monomer Substances 0.000 claims description 6
235000012239 silicon dioxide Nutrition 0.000 claims description 6
-1 vanadyl chloride Chemical compound 0.000 claims description 6
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 5
125000004432 carbon atom Chemical group C* 0.000 claims description 5
239000011777 magnesium Substances 0.000 claims description 5
229910052749 magnesium Inorganic materials 0.000 claims description 5
229910052751 metal Inorganic materials 0.000 claims description 5
239000002184 metal Substances 0.000 claims description 5
239000011949 solid catalyst Substances 0.000 claims description 5
ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 4
229910052796 boron Inorganic materials 0.000 claims description 4
GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 claims description 4
229910052720 vanadium Inorganic materials 0.000 claims description 4
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 3
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 3
229910052710 silicon Inorganic materials 0.000 claims description 3
239000010703 silicon Substances 0.000 claims description 3
229910052725 zinc Inorganic materials 0.000 claims description 3
239000011701 zinc Substances 0.000 claims description 3
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 2
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 2
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
125000001183 hydrocarbyl group Chemical group 0.000 claims description 2
229910052744 lithium Inorganic materials 0.000 claims description 2
TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 2
239000001301 oxygen Substances 0.000 claims description 2
229910052760 oxygen Inorganic materials 0.000 claims description 2
ZCUFMDLYAMJYST-UHFFFAOYSA-N thorium dioxide Chemical compound O=[Th]=O ZCUFMDLYAMJYST-UHFFFAOYSA-N 0.000 claims description 2
229910003452 thorium oxide Inorganic materials 0.000 claims description 2
OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 2
RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims 1
229910001928 zirconium oxide Inorganic materials 0.000 claims 1
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract description 10
239000005977 Ethylene Substances 0.000 abstract description 10
239000012190 activator Substances 0.000 abstract description 10
150000001399 aluminium compounds Chemical class 0.000 abstract 1
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 9
239000012442 inert solvent Substances 0.000 description 8
239000002002 slurry Substances 0.000 description 8
238000006243 chemical reaction Methods 0.000 description 7
VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 7
238000004458 analytical method Methods 0.000 description 6
238000005470 impregnation Methods 0.000 description 6
NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 6
239000007788 liquid Substances 0.000 description 6
239000000203 mixture Substances 0.000 description 6
229910052757 nitrogen Inorganic materials 0.000 description 6
229910052723 transition metal Inorganic materials 0.000 description 6
150000003624 transition metals Chemical class 0.000 description 6
229930195733 hydrocarbon Natural products 0.000 description 5
238000002360 preparation method Methods 0.000 description 5
239000007787 solid Substances 0.000 description 5
239000002904 solvent Substances 0.000 description 5
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
239000004215 Carbon black (E152) Substances 0.000 description 4
150000002430 hydrocarbons Chemical class 0.000 description 4
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 4
229920000642 polymer Polymers 0.000 description 4
239000000047 product Substances 0.000 description 4
238000000926 separation method Methods 0.000 description 4
238000005406 washing Methods 0.000 description 4
239000012876 carrier material Substances 0.000 description 3
239000003085 diluting agent Substances 0.000 description 3
230000000694 effects Effects 0.000 description 3
239000001282 iso-butane Substances 0.000 description 3
238000004519 manufacturing process Methods 0.000 description 3
239000011343 solid material Substances 0.000 description 3
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 description 2
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
229910052786 argon Inorganic materials 0.000 description 2
239000007795 chemical reaction product Substances 0.000 description 2
239000003426 co-catalyst Substances 0.000 description 2
238000007334 copolymerization reaction Methods 0.000 description 2
YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
239000001257 hydrogen Substances 0.000 description 2
229910052739 hydrogen Inorganic materials 0.000 description 2
239000011261 inert gas Substances 0.000 description 2
QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
KJJBSBKRXUVBMX-UHFFFAOYSA-N magnesium;butane Chemical compound [Mg+2].CCC[CH2-].CCC[CH2-] KJJBSBKRXUVBMX-UHFFFAOYSA-N 0.000 description 2
239000002609 medium Substances 0.000 description 2
239000000155 melt Substances 0.000 description 2
125000002524 organometallic group Chemical group 0.000 description 2
150000003961 organosilicon compounds Chemical class 0.000 description 2
239000002245 particle Substances 0.000 description 2
YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 2
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
239000000126 substance Substances 0.000 description 2
150000003623 transition metal compounds Chemical class 0.000 description 2
VSYZXASVWVQEMR-UHFFFAOYSA-N 2-methylbuta-1,3-dienylalumane Chemical compound CC(=C[AlH2])C=C VSYZXASVWVQEMR-UHFFFAOYSA-N 0.000 description 1
WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 1
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 1
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
229910021552 Vanadium(IV) chloride Inorganic materials 0.000 description 1
230000004913 activation Effects 0.000 description 1
239000004411 aluminium Substances 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
239000012298 atmosphere Substances 0.000 description 1
125000004429 atom Chemical group 0.000 description 1
238000009835 boiling Methods 0.000 description 1
239000001506 calcium phosphate Substances 0.000 description 1
229910000389 calcium phosphate Inorganic materials 0.000 description 1
235000011010 calcium phosphates Nutrition 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
239000012986 chain transfer agent Substances 0.000 description 1
239000003153 chemical reaction reagent Substances 0.000 description 1
239000000460 chlorine Substances 0.000 description 1
229910052801 chlorine Inorganic materials 0.000 description 1
XFVGXQSSXWIWIO-UHFFFAOYSA-N chloro hypochlorite;titanium Chemical compound [Ti].ClOCl XFVGXQSSXWIWIO-UHFFFAOYSA-N 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
125000000753 cycloalkyl group Chemical group 0.000 description 1
HQWPLXHWEZZGKY-UHFFFAOYSA-N diethylzinc Chemical compound CC[Zn]CC HQWPLXHWEZZGKY-UHFFFAOYSA-N 0.000 description 1
AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 1
239000002612 dispersion medium Substances 0.000 description 1
238000001035 drying Methods 0.000 description 1
GCPCLEKQVMKXJM-UHFFFAOYSA-N ethoxy(diethyl)alumane Chemical compound CCO[Al](CC)CC GCPCLEKQVMKXJM-UHFFFAOYSA-N 0.000 description 1
229920001038 ethylene copolymer Polymers 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
238000011010 flushing procedure Methods 0.000 description 1
125000000524 functional group Chemical group 0.000 description 1
239000007789 gas Substances 0.000 description 1
239000001307 helium Substances 0.000 description 1
229910052734 helium Inorganic materials 0.000 description 1
SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
150000004678 hydrides Chemical class 0.000 description 1
125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
239000003701 inert diluent Substances 0.000 description 1
ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
239000001095 magnesium carbonate Substances 0.000 description 1
229910000021 magnesium carbonate Inorganic materials 0.000 description 1
235000014380 magnesium carbonate Nutrition 0.000 description 1
FRIJBUGBVQZNTB-UHFFFAOYSA-M magnesium;ethane;bromide Chemical compound [Mg+2].[Br-].[CH2-]C FRIJBUGBVQZNTB-UHFFFAOYSA-M 0.000 description 1
150000002736 metal compounds Chemical class 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
230000000737 periodic effect Effects 0.000 description 1
239000003208 petroleum Substances 0.000 description 1
229910052698 phosphorus Inorganic materials 0.000 description 1
229920000573 polyethylene Polymers 0.000 description 1
229920000098 polyolefin Polymers 0.000 description 1
239000011148 porous material Substances 0.000 description 1
239000011541 reaction mixture Substances 0.000 description 1
230000035484 reaction time Effects 0.000 description 1
238000005070 sampling Methods 0.000 description 1
HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
229910010271 silicon carbide Inorganic materials 0.000 description 1
229910000029 sodium carbonate Inorganic materials 0.000 description 1
235000017550 sodium carbonate Nutrition 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1
239000007858 starting material Substances 0.000 description 1
238000003756 stirring Methods 0.000 description 1
ZWYDDDAMNQQZHD-UHFFFAOYSA-L titanium(ii) chloride Chemical compound [Cl-].[Cl-].[Ti+2] ZWYDDDAMNQQZHD-UHFFFAOYSA-L 0.000 description 1
YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 description 1
SQBBHCOIQXKPHL-UHFFFAOYSA-N tributylalumane Chemical compound CCCC[Al](CCCC)CCCC SQBBHCOIQXKPHL-UHFFFAOYSA-N 0.000 description 1
QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
LALRXNPLTWZJIJ-UHFFFAOYSA-N triethylborane Chemical compound CCB(CC)CC LALRXNPLTWZJIJ-UHFFFAOYSA-N 0.000 description 1
JTJFQBNJBPPZRI-UHFFFAOYSA-J vanadium tetrachloride Chemical compound Cl[V](Cl)(Cl)Cl JTJFQBNJBPPZRI-UHFFFAOYSA-J 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
239000004711 α-olefin Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Catalysts (AREA)

NO802142A 1979-07-17 1980-07-16 Olefin-polymerisasjonskatalysator, fremgangsmaate til polymerisasjon av olefiner og saaledes oppnaadde produkter NO802142L (no)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
GB7924895		1979-07-17

Publications (1)

Publication Number	Publication Date
NO802142L true NO802142L (no)	1981-01-19

Family

ID=10506552

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NO802142A NO802142L (no)	1979-07-17	1980-07-16	Olefin-polymerisasjonskatalysator, fremgangsmaate til polymerisasjon av olefiner og saaledes oppnaadde produkter

Country Status (8)

Country	Link
US (1)	US4333851A (de)
EP (1)	EP0022658B1 (de)
JP (1)	JPS5649710A (de)
AT (1)	ATE11143T1 (de)
CA (1)	CA1145318A (de)
DE (1)	DE3069927D1 (de)
ES (1)	ES8200569A1 (de)
NO (1)	NO802142L (de)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4397762A (en) *	1982-01-27	1983-08-09	Bp Chemicals Limited	Polymerization catalyst
EP0085208A3 (de) *	1982-01-29	1983-09-21	BP Chemicals Limited	Polymerisationskatalysator
US4510299A (en) *	1982-03-29	1985-04-09	Chemplex Company	Polymerization method
US4455386A (en) *	1982-03-29	1984-06-19	Chemplex Company	Polymerization catalyst
DE3223331A1 (de) *	1982-06-23	1983-12-29	Ruhrchemie Ag, 4200 Oberhausen	Verfahren zur herstellung eines traegerkatalysators fuer die (co-)polymerisation von (alpha)-olefinen
CA1219996A (en) *	1982-11-10	1987-03-31	Kazuo Matsuura	Process for preparing polyolefins
IT1154555B (it) *	1982-11-11	1987-01-21	Anic Spa	Procedimento per la preparazione di polimeri dell'etilene e catalizzatore relativo
US4435520A (en)	1982-11-24	1984-03-06	Cities Service Co.	Catalyst composition
US4434242A (en)	1982-11-24	1984-02-28	Cities Service Co.	Polymerization catalyst
US4426317A (en)	1982-11-24	1984-01-17	Cities Service Company	Process for making olefin polymerization catalyst
US4435519A (en)	1982-11-24	1984-03-06	Cities Service Co.	Novel catalyst composition
US4435518A (en)	1982-11-24	1984-03-06	Cities Service Co.	Polymerization catalyst
US4593009A (en) *	1984-04-04	1986-06-03	Mobil Oil Corporation	Catalyst composition for polymerizing alpha-olefins
US4672096A (en) *	1984-04-04	1987-06-09	Mobil Oil Corporation	Catalyst composition for polymerizing alpha-olefins
US4614729A (en) *	1984-10-26	1986-09-30	Stauffer Chemical Company	Supported organometallic compounds for utilization in purification of fluids
US4612300A (en) *	1985-06-06	1986-09-16	The Dow Chemical Company	Novel catalyst for producing relatively narrow molecular weight distribution olefin polymers
US5124418A (en) *	1985-11-15	1992-06-23	Exxon Chemical Patents Inc.	Supported polymerization catalyst
SE458612B (sv) *	1987-08-19	1989-04-17	Neste Oy	Katalysatorkomposition baserad paa aktiverad silika och en reaktionsprodukt av vanadinpentoxid och ett kloreringsmedel samt saett att framstaella en olefinpolymer haermed
US5034483A (en) *	1988-01-15	1991-07-23	Mobil Oil Corporation	Process for preparing high density, broad molecular weight distribution alpha-olefin polymers
US5075271A (en) *	1988-01-15	1991-12-24	Mobil Oil Corporation	Olefin polymerization process for preparing high density or linear low density polymers of controlled molecular weight distribution
US4866021A (en) *	1988-01-15	1989-09-12	Mobil Oil Corp.	Catalyst composition for preparing high density, broad molecular weight distribution alpha-olefin polymers
US4972033A (en) *	1988-01-15	1990-11-20	Mobil Oil Corporation	Olefin polymerization process for preparing high density or linear low density polymers of controlled molecular weight distribution
US5006618A (en) *	1988-01-15	1991-04-09	Mobil Oil Corporation	Process for preparing high density or medium density polymers
US4831000A (en) *	1988-01-15	1989-05-16	Mobil Oil Corporatiion	Catalyst composition for preparing high density or linear low density olefin polymers of controlled molecular weight distribution
US4912074A (en) *	1988-01-15	1990-03-27	Mobil Oil Corporation	Catalyst composition for preparing high density or medium density olefin polymers
US5246900A (en) *	1991-08-23	1993-09-21	Phillips Petroleum Company	Olefin polymerization catalysts and processes of making the same
US6677266B1 (en)	2002-07-09	2004-01-13	Eastman Chemical Company	Process for preparing a vanadium/titanium catalyst and use in olefin polymerization

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR2040154A5 (en) *	1969-04-01	1971-01-15	Int Synthetic Rubber	Catalyst useful for polymerisation of ole - fins
JPS4948475B1 (de) *	1970-08-11	1974-12-21
US3899477A (en) *	1973-02-16	1975-08-12	Monsanto Co	Polymerization of ethylene
NL7702323A (nl) *	1977-03-04	1978-09-06	Stamicarbon	Katalysator voor de bereiding van polyalkenen.
US4232140A (en) *	1978-10-23	1980-11-04	Cities Service Company	Process for polymerizing olefins

1980
- 1980-07-04 CA CA000355450A patent/CA1145318A/en not_active Expired
- 1980-07-07 US US06/166,197 patent/US4333851A/en not_active Expired - Lifetime
- 1980-07-09 DE DE8080302327T patent/DE3069927D1/de not_active Expired
- 1980-07-09 EP EP80302327A patent/EP0022658B1/de not_active Expired
- 1980-07-09 AT AT80302327T patent/ATE11143T1/de active
- 1980-07-16 NO NO802142A patent/NO802142L/no unknown
- 1980-07-16 ES ES493422A patent/ES8200569A1/es not_active Expired
- 1980-07-16 JP JP9742780A patent/JPS5649710A/ja active Pending

Also Published As

Publication number	Publication date
US4333851A (en)	1982-06-08
EP0022658B1 (de)	1985-01-09
EP0022658A1 (de)	1981-01-21
DE3069927D1 (en)	1985-02-21
CA1145318A (en)	1983-04-26
ES493422A0 (es)	1981-11-01
ATE11143T1 (de)	1985-01-15
JPS5649710A (en)	1981-05-06
ES8200569A1 (es)	1981-11-01

Publication	Publication Date	Title
NO802142L (no)	1981-01-19	Olefin-polymerisasjonskatalysator, fremgangsmaate til polymerisasjon av olefiner og saaledes oppnaadde produkter
CA1187863A (en)	1985-05-28	Polymerization catalyst
US4256865A (en)	1981-03-17	Polymerization catalyst
US4396533A (en)	1983-08-02	Polymerization catalyst
US4105585A (en)	1978-08-08	Polymerization catalyst
US4397762A (en)	1983-08-09	Polymerization catalyst
GB1562200A (en)	1980-03-05	Process for the production of a supported ziegler catalystcomponent
EP0057589B1 (de)	1985-07-03	Polymerisationskatalysator
EP0358264B1 (de)	1994-10-12	Katalysatorbestandteil und Katalysator zur Produktion von Polyolefinen mit sehr hohem Molekulargewicht
GB2053939A (en)	1981-02-11	Oxide supported vanadium halide catalyst components
US4170568A (en)	1979-10-09	Polymerization catalyst
EP0072591B1 (de)	1986-05-28	Verfahren zur Herstellung eines Katalysatorbestandteils und Polymerisation von 1-Olefinen mit Hilfe dieses Katalysatorbestandteils
GB2073761A (en)	1981-10-21	Olefin polymerisation catalyst
US3944529A (en)	1976-03-16	Process for the preparation of polybutene-1
EP0027346B1 (de)	1984-06-13	Polymerisations-Katalysator und Verfahren
US4145312A (en)	1979-03-20	Polymerization catalyst
EP0085208A2 (de)	1983-08-10	Polymerisationskatalysator
GB2082603A (en)	1982-03-10	Polymerisation catalyst
EP0085207B1 (de)	1986-08-20	Polymerisationskatalysator
GB2082602A (en)	1982-03-10	Polymerisation catalyst
CA1168214A (en)	1984-05-29	Polymerisation catalyst
WO1996040804A1 (en)	1996-12-19	Supported catalyst composition for polymerization of olefins
GB1559172A (en)	1980-01-16	Supported ziegler catalyst component
GB2112004A (en)	1983-07-13	Transition metal component of Ziegler polymerisation catalyst
NO770675L (no)	1977-09-02	Fremgangsm}te til fremstilling av en katalysator.