NO810527L - Pyrrolidinderivater for stabilisering av polymermaterialer - Google Patents

Pyrrolidinderivater for stabilisering av polymermaterialer

Info

Publication number: NO810527L
Authority: NO; Norway
Prior art keywords: stabilizers; ingrediates; pyrrolide; acid ester; polymer materials
Prior art date: 1980-02-19

Application number

NO810527A

Other languages

English (en)

Norwegian (no)

Inventor

Silvestro Costanzi

Francesco Tessarolo

Adriano Ballabio

Original Assignee

Anic Spa

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1980-02-19

Filing date

1981-02-17

Publication date

1981-08-20

1981-02-17 Application filed by Anic Spa filed Critical Anic Spa

1981-08-20 Publication of NO810527L publication Critical patent/NO810527L/no

Links

230000000087 stabilizing effect Effects 0.000 title claims description 6
KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 title 1
239000002861 polymer material Substances 0.000 title 1
-1 straight-chain fatty acid ester Chemical class 0.000 claims description 20
229920000642 polymer Polymers 0.000 claims description 11
RWRDLPDLKQPQOW-UHFFFAOYSA-N Pyrrolidine Chemical group C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 claims description 7
229920000098 polyolefin Polymers 0.000 claims description 7
150000001875 compounds Chemical class 0.000 claims description 6
238000000034 method Methods 0.000 claims description 6
230000005855 radiation Effects 0.000 claims description 5
125000004433 nitrogen atom Chemical group N* 0.000 claims description 3
239000000126 substance Substances 0.000 claims description 3
230000009931 harmful effect Effects 0.000 claims description 2
239000003795 chemical substances by application Substances 0.000 claims 2
229940070765 laurate Drugs 0.000 claims 1
125000005480 straight-chain fatty acid group Chemical group 0.000 claims 1
239000003381 stabilizer Substances 0.000 description 9
239000004743 Polypropylene Substances 0.000 description 8
229920001155 polypropylene Polymers 0.000 description 8
239000000047 product Substances 0.000 description 7
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
239000012963 UV stabilizer Substances 0.000 description 6
239000004698 Polyethylene Substances 0.000 description 4
238000009835 boiling Methods 0.000 description 4
POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 4
IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 4
229920000573 polyethylene Polymers 0.000 description 4
238000002360 preparation method Methods 0.000 description 4
239000011541 reaction mixture Substances 0.000 description 4
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
239000005639 Lauric acid Substances 0.000 description 3
235000021314 Palmitic acid Nutrition 0.000 description 3
ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 3
230000015556 catabolic process Effects 0.000 description 3
WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 3
238000009281 ultraviolet germicidal irradiation Methods 0.000 description 3
FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 2
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
238000004566 IR spectroscopy Methods 0.000 description 2
RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 2
239000012965 benzophenone Substances 0.000 description 2
239000003054 catalyst Substances 0.000 description 2
238000007796 conventional method Methods 0.000 description 2
235000014113 dietary fatty acids Nutrition 0.000 description 2
229930195729 fatty acid Natural products 0.000 description 2
239000000194 fatty acid Substances 0.000 description 2
229910052739 hydrogen Inorganic materials 0.000 description 2
239000001257 hydrogen Substances 0.000 description 2
239000007788 liquid Substances 0.000 description 2
239000000203 mixture Substances 0.000 description 2
238000012360 testing method Methods 0.000 description 2
AAEJQHLAJICLHR-UHFFFAOYSA-N 1,2,2,3,3,4-hexamethylpyrrolidine Chemical compound CC1CN(C)C(C)(C)C1(C)C AAEJQHLAJICLHR-UHFFFAOYSA-N 0.000 description 1
YAYNEUUHHLGGAH-UHFFFAOYSA-N 1-chlorododecane Chemical compound CCCCCCCCCCCCCl YAYNEUUHHLGGAH-UHFFFAOYSA-N 0.000 description 1
CLWAXFZCVYJLLM-UHFFFAOYSA-N 1-chlorohexadecane Chemical compound CCCCCCCCCCCCCCCCCl CLWAXFZCVYJLLM-UHFFFAOYSA-N 0.000 description 1
NOXHNAYUTJEYNN-UHFFFAOYSA-N 2,2,3,4,5,5-hexamethylpyrrolidine Chemical compound CC1C(C)C(C)(C)NC1(C)C NOXHNAYUTJEYNN-UHFFFAOYSA-N 0.000 description 1
OCAQNEYBPDEIGD-UHFFFAOYSA-N C(CCCCCCCCCCC)(=O)OCC.CC1C(C(N(C1)C)(C)C)(C)C Chemical compound C(CCCCCCCCCCC)(=O)OCC.CC1C(C(N(C1)C)(C)C)(C)C OCAQNEYBPDEIGD-UHFFFAOYSA-N 0.000 description 1
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
238000005481 NMR spectroscopy Methods 0.000 description 1
235000021355 Stearic acid Nutrition 0.000 description 1
238000010521 absorption reaction Methods 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
230000033228 biological regulation Effects 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
239000013065 commercial product Substances 0.000 description 1
230000006835 compression Effects 0.000 description 1
238000007906 compression Methods 0.000 description 1
238000012790 confirmation Methods 0.000 description 1
125000004122 cyclic group Chemical group 0.000 description 1
238000006731 degradation reaction Methods 0.000 description 1
230000000368 destabilizing effect Effects 0.000 description 1
MCPKSFINULVDNX-UHFFFAOYSA-N drometrizole Chemical compound CC1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 MCPKSFINULVDNX-UHFFFAOYSA-N 0.000 description 1
230000000694 effects Effects 0.000 description 1
239000012259 ether extract Substances 0.000 description 1
150000004665 fatty acids Chemical class 0.000 description 1
239000000706 filtrate Substances 0.000 description 1
IPCSVZSSVZVIGE-UHFFFAOYSA-M hexadecanoate Chemical compound CCCCCCCCCCCCCCCC([O-])=O IPCSVZSSVZVIGE-UHFFFAOYSA-M 0.000 description 1
230000001788 irregular Effects 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
238000004949 mass spectrometry Methods 0.000 description 1
238000005259 measurement Methods 0.000 description 1
239000000155 melt Substances 0.000 description 1
238000002156 mixing Methods 0.000 description 1
QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
239000012044 organic layer Substances 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
238000003825 pressing Methods 0.000 description 1
JKANAVGODYYCQF-UHFFFAOYSA-N prop-2-yn-1-amine Chemical compound NCC#C JKANAVGODYYCQF-UHFFFAOYSA-N 0.000 description 1
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
230000001681 protective effect Effects 0.000 description 1
239000007787 solid Substances 0.000 description 1
230000006641 stabilisation Effects 0.000 description 1
238000011105 stabilization Methods 0.000 description 1
239000007858 starting material Substances 0.000 description 1
239000008117 stearic acid Substances 0.000 description 1
239000010902 straw Substances 0.000 description 1
238000003786 synthesis reaction Methods 0.000 description 1
238000010998 test method Methods 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
- C07D295/04—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms
- C07D295/08—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by singly bound oxygen or sulfur atoms
- C07D295/084—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by singly bound oxygen or sulfur atoms with the ring nitrogen atoms and the oxygen or sulfur atoms attached to the same carbon chain, which is not interrupted by carbocyclic rings
- C07D295/088—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by singly bound oxygen or sulfur atoms with the ring nitrogen atoms and the oxygen or sulfur atoms attached to the same carbon chain, which is not interrupted by carbocyclic rings to an acyclic saturated chain
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
- C08K5/3415—Five-membered rings

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Compositions Of Macromolecular Compounds (AREA)
Hydrogenated Pyridines (AREA)
Nitrogen Condensed Heterocyclic Rings (AREA)
Cosmetics (AREA)

NO810527A 1980-02-19 1981-02-17 Pyrrolidinderivater for stabilisering av polymermaterialer NO810527L (no)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
IT20001/80A IT1174663B (it)	1980-02-19	1980-02-19	Composizioni pirrolidiniche e loro uso quali stabilizzanti uv per materie plastiche

Publications (1)

Publication Number	Publication Date
NO810527L true NO810527L (no)	1981-08-20

Family

ID=11162984

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NO810527A NO810527L (no)	1980-02-19	1981-02-17	Pyrrolidinderivater for stabilisering av polymermaterialer

Country Status (14)

Country	Link
US (1)	US4325864A (fr)
JP (1)	JPS56131644A (fr)
BE (1)	BE887565A (fr)
CH (1)	CH652730A5 (fr)
DE (1)	DE3106217C2 (fr)
DK (1)	DK56081A (fr)
FR (1)	FR2476105A1 (fr)
GB (2)	GB2069507B (fr)
IE (1)	IE50926B1 (fr)
IT (1)	IT1174663B (fr)
LU (1)	LU83146A1 (fr)
NL (1)	NL8100835A (fr)
NO (1)	NO810527L (fr)
SE (1)	SE8100746L (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
IT1196327B (it) *	1984-11-16	1988-11-16	Consiglio Nazionale Ricerche	3-aza-7-idrossi-2,2,4,4-tetraalchilbiciclo (3.3.0) ottani,procedimento per la loro preparazione,intermedi adatti allo scopo e procedimento per l'ottenimento di questi ultimi
US5350786A (en) *	1986-06-30	1994-09-27	Enichem Synthesis S.P.A.	Process of (co)polymerization of α-olefins in the presence of stabilizers

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE923915C (de) *	1951-05-05	1955-02-24	Upjohn Co	Verfahren zur Herstellung von spasmolytisch wirksamen Pyrrolidinverbindungen
GB1398414A (en) *	1972-07-28	1975-06-18	Ciba Geigy Ag	Piperidine derivatives
GB1437002A (en) *	1972-09-13	1976-05-26	Ici Ltd	Cyclic amines
DE2459331A1 (de) *	1973-12-28	1975-07-10	Ciba Geigy Ag	Pyrrolidin-dicarbonsaeuren und ihre ester als lichtstabilisatoren
GB1467672A (en) *	1974-04-11	1977-03-16	Ciba Geigy Ag	Stabilised epoxy resin
US4093586A (en) *	1975-01-15	1978-06-06	Ciba-Geigy Corporation	Pyrrolidine dicarboxylic acids and esters and stabilized compositions
US4111901A (en) *	1977-06-06	1978-09-05	Borg-Warner Corporation	Hindered five-membered nitrogen rings as polyolefin stabilizers
IT1160064B (it) *	1978-11-10	1987-03-04	Anic Spa	Procedimento per la stabilizzazione di polimeri mediante impiego di sali di nichel di pirrolidinditiocarbammati sostituiti

1980
- 1980-02-19 IT IT20001/80A patent/IT1174663B/it active
- 1980-12-05 US US06/213,653 patent/US4325864A/en not_active Expired - Lifetime
1981
- 1981-01-30 SE SE8100746A patent/SE8100746L/xx not_active Application Discontinuation
- 1981-02-04 GB GB8103466A patent/GB2069507B/en not_active Expired
- 1981-02-10 DK DK56081A patent/DK56081A/da not_active Application Discontinuation
- 1981-02-16 CH CH1015/81A patent/CH652730A5/it not_active IP Right Cessation
- 1981-02-17 FR FR8103117A patent/FR2476105A1/fr active Granted
- 1981-02-17 NO NO810527A patent/NO810527L/no unknown
- 1981-02-18 IE IE322/81A patent/IE50926B1/en unknown
- 1981-02-18 BE BE0/203829A patent/BE887565A/fr not_active IP Right Cessation
- 1981-02-18 LU LU83146A patent/LU83146A1/fr unknown
- 1981-02-18 JP JP2162481A patent/JPS56131644A/ja active Pending
- 1981-02-19 DE DE3106217A patent/DE3106217C2/de not_active Expired
- 1981-02-19 NL NL8100835A patent/NL8100835A/nl not_active Application Discontinuation
1983
- 1983-06-20 GB GB08316728A patent/GB2129813B/en not_active Expired

Also Published As

Publication number	Publication date
FR2476105B1 (fr)	1984-02-24
GB2129813B (en)	1984-11-21
US4325864A (en)	1982-04-20
GB2069507B (en)	1984-02-08
FR2476105A1 (fr)	1981-08-21
NL8100835A (nl)	1981-09-16
SE8100746L (sv)	1981-08-20
IT8020001A0 (it)	1980-02-19
GB8316728D0 (en)	1983-07-20
GB2069507A (en)	1981-08-26
BE887565A (fr)	1981-08-18
IT1174663B (it)	1987-07-01
CH652730A5 (it)	1985-11-29
IE810322L (en)	1981-08-19
IE50926B1 (en)	1986-08-20
JPS56131644A (en)	1981-10-15
DE3106217C2 (de)	1985-03-28
LU83146A1 (fr)	1981-09-11
DE3106217A1 (de)	1982-01-21
DK56081A (da)	1981-08-20
GB2129813A (en)	1984-05-23

Publication	Publication Date	Title
US4321190A (en)	1982-03-23	Polyolefin compositions stabilized against UV light radiations with open-chain hindered amines
US4069195A (en)	1978-01-17	Substituted decahydroquinolines and their use as ultraviolet light stabilizer
US4346188A (en)	1982-08-24	Polyolefin compositions stabilized against UV-radiations by pyrrolidine derivatives
US4325864A (en)	1982-04-20	Pyrrolidine-ring-containing compositions for use as anti-UV stabilizers in plastics materials
SU940646A3 (ru)	1982-06-30	Способ получени производных бензо/с/-хинолинов или их солей
DE1593750A1 (de)	1970-12-10	Substituierte Benzophenone als Lichtstabilisatoren
Jones et al.	1955	Nucleophilic substitution in vinylic halides
DE1520171A1 (de)	1970-01-22	Verfahren zur Herstellung von Polymerisaten des Propylens
IE50927B1 (en)	1986-08-20	Polymers containing pyrrolidine-ring-containing compounds as stabilizers against uv-radiation;and method of stabilizing polymers
DE1570808A1 (de)	1970-06-04	Polymerisate und Verfahren zu deren Herstellung
JPH03281515A (ja)	1991-12-12	新規な線状ブロック共重合体の製造方法
DE2111444C3 (de)	1974-08-08	Substituierte Dibenzofurane bzw. Dibenzothiophene und Verfahren zu deren Herstellung sowie deren Verwendung als Stabilisatoren
DE1418997A1 (de)	1968-11-28	Verfahren zur Herstellung von organischen Fluorverbindungen
SU520380A1 (ru)	1976-07-05	Стабилизированна полимерна композици
Calleja-Rubio et al.	2003	An improved procedure for the synthesis of perfluoroalkylacetylenes
SU36009A1 (ru)	1934-04-30	Способ получени смол из веществ, содержащих крахмал
McCarthy et al.	1964	Cyclic Analogs and Congeners of Succinyl Dicholine1, 2
Bukac et al.	1973	Polymerization of laurinolactam. I. Impurities in industrial laurinolactam and their influence on anionic polymerization
Negishi et al.	1967	Polymerization of vinylbenzamides
Badger et al.	1964	Synthetical applications of activated metal catalysts. XXII. The desulphurization of 2, 5-Diphenyl-1, 4-dithiin
SU63682A1 (ru)	1943-11-30	Способ получени смешанного винилэтилового эфира целлюлозы
RU2373184C2 (ru)	2009-11-20	Способ получения фенилендиаминного антиоксиданта для каучуков эмульсионной полимеризации
DE68911562T2 (de)	1994-05-19	Stabilisatorverbindungen und Verfahren zu ihrer Herstellung.
JPS5938940B2 (ja)	1984-09-20	バニリルアシルアミドおよびそれからなる抗酸化剤
Snyder et al.	1944	Non-Markownikoff Addition in Reactions of 3, 6-Divinyl-2, 5-diketopiperazine