NO861068L - Oksygenanriket claus-system med svovelsyreinjeksjon. - Google Patents
Oksygenanriket claus-system med svovelsyreinjeksjon.Info
- Publication number
- NO861068L NO861068L NO861068A NO861068A NO861068L NO 861068 L NO861068 L NO 861068L NO 861068 A NO861068 A NO 861068A NO 861068 A NO861068 A NO 861068A NO 861068 L NO861068 L NO 861068L
- Authority
- NO
- Norway
- Prior art keywords
- oxygen
- sulfuric acid
- sulfur
- reaction furnace
- gas
- Prior art date
Links
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 title claims description 149
- 229910052760 oxygen Inorganic materials 0.000 title claims description 136
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title claims description 135
- 239000001301 oxygen Substances 0.000 title claims description 135
- 238000002347 injection Methods 0.000 title description 19
- 239000007924 injection Substances 0.000 title description 19
- 238000006243 chemical reaction Methods 0.000 claims description 108
- 239000007789 gas Substances 0.000 claims description 74
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 68
- 229910052717 sulfur Inorganic materials 0.000 claims description 61
- 239000011593 sulfur Substances 0.000 claims description 61
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 46
- 238000000034 method Methods 0.000 claims description 34
- 239000002253 acid Substances 0.000 claims description 19
- 230000003647 oxidation Effects 0.000 claims description 19
- 238000007254 oxidation reaction Methods 0.000 claims description 19
- 230000003197 catalytic effect Effects 0.000 claims description 18
- 238000002485 combustion reaction Methods 0.000 claims description 18
- 238000009833 condensation Methods 0.000 claims description 17
- 230000005494 condensation Effects 0.000 claims description 17
- 229910000037 hydrogen sulfide Inorganic materials 0.000 claims description 12
- 238000011084 recovery Methods 0.000 claims description 12
- 238000001816 cooling Methods 0.000 claims description 9
- 238000003303 reheating Methods 0.000 claims description 9
- 238000000926 separation method Methods 0.000 claims description 6
- 238000005804 alkylation reaction Methods 0.000 claims description 5
- 238000000605 extraction Methods 0.000 claims description 5
- 239000007864 aqueous solution Substances 0.000 claims description 4
- 230000036961 partial effect Effects 0.000 claims description 2
- 239000010802 sludge Substances 0.000 claims 1
- 241000196324 Embryophyta Species 0.000 description 50
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 24
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 16
- 238000000354 decomposition reaction Methods 0.000 description 11
- 230000009467 reduction Effects 0.000 description 11
- 230000002829 reductive effect Effects 0.000 description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- 239000007788 liquid Substances 0.000 description 10
- 229930195733 hydrocarbon Natural products 0.000 description 8
- 150000002430 hydrocarbons Chemical class 0.000 description 8
- 229910052757 nitrogen Inorganic materials 0.000 description 8
- 239000002918 waste heat Substances 0.000 description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 6
- 239000001257 hydrogen Substances 0.000 description 6
- 229910052739 hydrogen Inorganic materials 0.000 description 6
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 6
- 239000002994 raw material Substances 0.000 description 6
- 238000006555 catalytic reaction Methods 0.000 description 5
- 239000003085 diluting agent Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 241000894007 species Species 0.000 description 5
- 239000004215 Carbon black (E152) Substances 0.000 description 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical group O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- 230000033228 biological regulation Effects 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 238000000746 purification Methods 0.000 description 4
- 239000011819 refractory material Substances 0.000 description 4
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical class [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 3
- 239000005864 Sulphur Substances 0.000 description 3
- 230000029936 alkylation Effects 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 229910021529 ammonia Inorganic materials 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 229910001882 dioxygen Inorganic materials 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000003345 natural gas Substances 0.000 description 3
- 230000001603 reducing effect Effects 0.000 description 3
- 230000002152 alkylating effect Effects 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 description 2
- 238000004581 coalescence Methods 0.000 description 2
- 230000003750 conditioning effect Effects 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 239000010779 crude oil Substances 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 150000003464 sulfur compounds Chemical class 0.000 description 2
- 239000013589 supplement Substances 0.000 description 2
- 239000008400 supply water Substances 0.000 description 2
- 230000006978 adaptation Effects 0.000 description 1
- 230000002730 additional effect Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910002090 carbon oxide Inorganic materials 0.000 description 1
- JJWKPURADFRFRB-UHFFFAOYSA-N carbonyl sulfide Chemical compound O=C=S JJWKPURADFRFRB-UHFFFAOYSA-N 0.000 description 1
- 238000004523 catalytic cracking Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004939 coking Methods 0.000 description 1
- 239000000567 combustion gas Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- -1 nitrogen Chemical compound 0.000 description 1
- 230000009972 noncorrosive effect Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 238000013022 venting Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/02—Preparation of sulfur; Purification
- C01B17/04—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/02—Preparation of sulfur; Purification
- C01B17/04—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides
- C01B17/0404—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process
- C01B17/0413—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process characterised by the combustion step
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Environmental & Geological Engineering (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Treating Waste Gases (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/714,146 US4826670A (en) | 1985-03-20 | 1985-03-20 | Oxygen enriched claus system with sulfuric acid injection |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| NO861068L true NO861068L (no) | 1986-09-22 |
Family
ID=24868909
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO861068A NO861068L (no) | 1985-03-20 | 1986-03-19 | Oksygenanriket claus-system med svovelsyreinjeksjon. |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US4826670A (fr) |
| EP (1) | EP0195447B1 (fr) |
| JP (1) | JPS61222908A (fr) |
| KR (1) | KR890003672B1 (fr) |
| BR (1) | BR8601468A (fr) |
| CA (1) | CA1290921C (fr) |
| DE (1) | DE3666410D1 (fr) |
| MX (1) | MX163361A (fr) |
| NO (1) | NO861068L (fr) |
| ZA (1) | ZA862000B (fr) |
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2613250A1 (fr) * | 1987-04-03 | 1988-10-07 | Air Liquide | Procede de recuperation de soufre du type claus a capacite augmentee et installation pour sa mise en oeuvre |
| DE3735599A1 (de) * | 1987-10-21 | 1989-05-11 | Messer Griesheim Gmbh | Vorrichtung und verfahren zur gesamtschwefelbestimmung |
| US5022332A (en) * | 1990-08-15 | 1991-06-11 | Union Carbide Industrial Gases Technology Corporation | Combustion method for improved endothermic dissociation |
| GB9205877D0 (en) * | 1992-03-18 | 1992-04-29 | Boc Group Plc | Treatment of waste or other material |
| EP0633219A1 (fr) * | 1993-07-06 | 1995-01-11 | Shell Internationale Researchmaatschappij B.V. | Procédé d'élimination de composés soufrés d'un courant de gaz |
| CA2147195C (fr) * | 1994-04-15 | 2005-04-05 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Proced Es Georges Claude | Traitement de gaz sulfures |
| US7695701B2 (en) * | 2008-03-07 | 2010-04-13 | Du Pont | Process for treating acid gas in staged furnaces with inter-stage heat recovery |
| US20090226364A1 (en) * | 2008-03-07 | 2009-09-10 | E. I. Du Pont De Nemours And Company | Process for treating acid gas in staged furnaces with inter-stage heat recovery and inter-stage sulfur production |
| US8206669B2 (en) | 2010-07-27 | 2012-06-26 | Air Products And Chemicals, Inc. | Method and apparatus for treating a sour gas |
| US8518356B2 (en) | 2010-07-27 | 2013-08-27 | Air Products And Chemicals, Inc. | Method and apparatus for adjustably treating a sour gas |
| ITUA20164554A1 (it) * | 2016-06-21 | 2017-12-21 | Saipem Spa | Processo integrato per la produzione di acido solforico e zolfo |
| CN108211781A (zh) * | 2017-12-29 | 2018-06-29 | 萍乡市德润科技有限责任公司 | 一种油气催化分解净化系统及方法 |
| CN108675271B (zh) * | 2018-06-07 | 2020-01-31 | 万华化学集团股份有限公司 | 一种含h2s酸性气焚烧制硫酸的方法及焚烧炉气体混合进料装置 |
| MY208837A (en) | 2019-05-03 | 2025-06-01 | Haldor Topsoe As | Revamping of a claus plant with a sulfuric acid plan |
| CN113860267B (zh) * | 2020-06-30 | 2023-06-20 | 中国石油化工股份有限公司 | 一种高效处理烷基化废酸制备硫磺的系统及工艺 |
| CN113860265B (zh) * | 2020-06-30 | 2023-06-16 | 中国石油化工股份有限公司 | 一种高效处理烷基化废酸制备硫磺的系统及工艺 |
| US11548784B1 (en) | 2021-10-26 | 2023-01-10 | Saudi Arabian Oil Company | Treating sulfur dioxide containing stream by acid aqueous absorption |
| US12116326B2 (en) | 2021-11-22 | 2024-10-15 | Saudi Arabian Oil Company | Conversion of hydrogen sulfide and carbon dioxide into hydrocarbons using non-thermal plasma and a catalyst |
| US12179129B2 (en) | 2021-12-14 | 2024-12-31 | Saudi Arabian Oil Company | Synergetic solvent for crude oil emulsion breakers |
| US11926799B2 (en) | 2021-12-14 | 2024-03-12 | Saudi Arabian Oil Company | 2-iso-alkyl-2-(4-hydroxyphenyl)propane derivatives used as emulsion breakers for crude oil |
| US12595171B2 (en) | 2022-09-16 | 2026-04-07 | Saudi Arabian Oil Company | Co-production of hydrogen and sulfuric acid by partial oxidation of sulfur |
| US20240109772A1 (en) | 2022-09-16 | 2024-04-04 | Saudi Arabian Oil Company | Hydrogen Production by Sulfur Steam Reforming |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB445171A (en) * | 1934-10-20 | 1936-04-03 | Ig Farbenindustrie Ag | Improvements in the manufacture and production of sulphur |
| GB712907A (en) * | 1950-08-08 | 1954-08-04 | Basf Ag | Improvements in the production of gases rich in sulphur dioxide suitable for working up into sulphuric acid |
| DE1193019B (de) * | 1963-06-20 | 1965-05-20 | Reinluft G M B H | Verfahren zur Adsorption von Schwefeloxyden sowie gleichzeitig von einer oder mehreren reduzierenden Schwefelverbindungen aus industriellen Gasen, insbesondere Abgasen |
| US3366455A (en) * | 1966-08-17 | 1968-01-30 | Pan American Petroleum Corp | Use of inert gas for sulfur plant startup and shutdown |
| US3681024A (en) * | 1970-08-10 | 1972-08-01 | Amoco Prod Co | Method for production of sulfur from hydrogen sulfide using oxygen |
| US3822341A (en) * | 1972-09-01 | 1974-07-02 | Marsh V | Method of producing sulfur from acid gases |
| DE2245002C3 (de) * | 1972-09-14 | 1981-08-20 | Davy International Ag, 6000 Frankfurt | Verfahren zur Herstellung schwefeldioxidhaltiger Gase |
| DE2430769A1 (de) * | 1974-06-26 | 1976-01-15 | Linde Ag | Verfahren zur durchfuehrung einer stark exothermen chemischen reaktion |
| DE2430909A1 (de) * | 1974-06-27 | 1976-01-08 | Adsorptionstech Lab | Verfahren zur reinigung von clausofen-abgasen |
| DE2448676A1 (de) * | 1974-10-12 | 1976-04-22 | Hoechst Ag | Verfahren zur herstellung von schwefeldioxid |
| JPS5188494A (ja) * | 1975-02-03 | 1976-08-03 | Iokaishusochi | |
| US4011822A (en) * | 1975-08-11 | 1977-03-15 | Occidental Petroleum Corporation | Burner for decarbonizing organic char |
| GB1563251A (en) * | 1976-12-07 | 1980-03-26 | Shell Int Research | Process for working hydrogen suphidecontaining gases |
| DE2725432C3 (de) * | 1977-06-04 | 1980-02-21 | Davy International Ag, 6000 Frankfurt | Verfahren zur Herstellung von konzentrierter Schwefelsäure |
| US4279882A (en) * | 1979-04-27 | 1981-07-21 | Ralph M. Parsons Company | Process for sulfur production |
| US4479926A (en) * | 1983-12-19 | 1984-10-30 | Exxon Research & Engineering Co. | Treatment of residual bottoms from fluorosulfuric acid regeneration |
| US4552747A (en) * | 1984-06-20 | 1985-11-12 | Gaa Engineered Systems, Inc. | Temperature moderation of an oxygen enriched Claus sulfur plant |
-
1985
- 1985-03-20 US US06/714,146 patent/US4826670A/en not_active Expired - Lifetime
-
1986
- 1986-03-14 CA CA000504115A patent/CA1290921C/fr not_active Expired - Lifetime
- 1986-03-18 ZA ZA862000A patent/ZA862000B/xx unknown
- 1986-03-19 MX MX1919A patent/MX163361A/es unknown
- 1986-03-19 NO NO861068A patent/NO861068L/no unknown
- 1986-03-20 EP EP86103797A patent/EP0195447B1/fr not_active Expired
- 1986-03-20 DE DE8686103797T patent/DE3666410D1/de not_active Expired
- 1986-03-20 JP JP61063814A patent/JPS61222908A/ja active Pending
- 1986-03-20 BR BR8601468A patent/BR8601468A/pt unknown
- 1986-03-20 KR KR1019860002060A patent/KR890003672B1/ko not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| EP0195447A3 (en) | 1987-08-12 |
| US4826670A (en) | 1989-05-02 |
| EP0195447B1 (fr) | 1989-10-18 |
| ZA862000B (en) | 1987-11-25 |
| KR860007012A (ko) | 1986-10-06 |
| MX163361A (es) | 1992-04-30 |
| EP0195447A2 (fr) | 1986-09-24 |
| BR8601468A (pt) | 1986-12-09 |
| CA1290921C (fr) | 1991-10-22 |
| KR890003672B1 (ko) | 1989-09-30 |
| DE3666410D1 (en) | 1989-11-23 |
| JPS61222908A (ja) | 1986-10-03 |
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| ART | TECHNICAL FIELD OF THE INVENTION 5 |