NO944982L - Reaktor for dehydrogenering av hydrokarboner med selektiv oksidasjon av hydrogen - Google Patents
Reaktor for dehydrogenering av hydrokarboner med selektiv oksidasjon av hydrogenInfo
- Publication number
- NO944982L NO944982L NO944982A NO944982A NO944982L NO 944982 L NO944982 L NO 944982L NO 944982 A NO944982 A NO 944982A NO 944982 A NO944982 A NO 944982A NO 944982 L NO944982 L NO 944982L
- Authority
- NO
- Norway
- Prior art keywords
- oxygen
- hydrocarbon
- zone
- containing stream
- pct
- Prior art date
Links
- 229930195733 hydrocarbon Natural products 0.000 title abstract 8
- 150000002430 hydrocarbons Chemical class 0.000 title abstract 8
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title abstract 2
- 238000006356 dehydrogenation reaction Methods 0.000 title abstract 2
- 239000001257 hydrogen Substances 0.000 title abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 title abstract 2
- 230000003647 oxidation Effects 0.000 title abstract 2
- 238000007254 oxidation reaction Methods 0.000 title abstract 2
- 239000004215 Carbon black (E152) Substances 0.000 abstract 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 5
- 239000003054 catalyst Substances 0.000 abstract 5
- 239000001301 oxygen Substances 0.000 abstract 5
- 229910052760 oxygen Inorganic materials 0.000 abstract 5
- 239000007789 gas Substances 0.000 abstract 3
- 230000003197 catalytic effect Effects 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
- B01J8/0492—Feeding reactive fluids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
- B01J8/0446—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical
- B01J8/0449—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more cylindrical beds
- B01J8/0457—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more cylindrical beds the beds being placed in separate reactors
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
- C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
- C07C5/333—Catalytic processes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
- C07C5/48—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with oxygen as an acceptor
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
Priority Applications (12)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NO944982A NO300117B1 (no) | 1994-12-22 | 1994-12-22 | Reaktor for dehydrogenering av hydrokarboner med selektiv oksidasjon av hydrogen |
| CA002207038A CA2207038C (en) | 1994-12-22 | 1995-12-18 | A reactor for catalytic dehydrogenation of hydrocarbons with selective oxidation of hydrogen |
| BR9510515A BR9510515A (pt) | 1994-12-22 | 1995-12-18 | Reator para desidrogenação de hidrocarbonetos desidrogenáveis |
| PCT/NO1995/000236 WO1996019424A1 (en) | 1994-12-22 | 1995-12-18 | A reactor for catalytic dehydrogenation of hydrocarbons with selective oxidation of hydrogen |
| KR1019970704244A KR100258656B1 (ko) | 1994-12-22 | 1995-12-18 | 수소를선택적으로산화시키면서탄화수소를촉매적으로탈수소화하기위한반응용반응기 |
| AT95942322T ATE190302T1 (de) | 1994-12-22 | 1995-12-18 | Apparatur zur katalytischen dehydrogenierung von kohlenwasserstoffen mit selektiver oxidation von wasserstoff |
| RU97112487A RU2140895C1 (ru) | 1994-12-22 | 1995-12-18 | Реактор для каталитического дегидрирования дегидрируемых углеводородов |
| EP95942322A EP0799169B1 (en) | 1994-12-22 | 1995-12-18 | A reactor for catalytic dehydrogenation of hydrocarbons with selective oxidation of hydrogen |
| AU43575/96A AU691715B2 (en) | 1994-12-22 | 1995-12-18 | A reactor for catalytic dehydrogenation of hydrocarbons with selective oxidation of hydrogen |
| DE69515511T DE69515511D1 (de) | 1994-12-22 | 1995-12-18 | Apparatur zur katalytischen dehydrogenierung von kohlenwasserstoffen mit selektiver oxidation von wasserstoff |
| CN95196944A CN1070832C (zh) | 1994-12-22 | 1995-12-18 | 通过有选择地氧化氢使烃被催化脱氢的反应器 |
| US08/860,069 US5997826A (en) | 1994-12-22 | 1995-12-18 | Reactor for catalytic dehydrogenation of hydrocarbons with selective oxidation of hydrogen |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NO944982A NO300117B1 (no) | 1994-12-22 | 1994-12-22 | Reaktor for dehydrogenering av hydrokarboner med selektiv oksidasjon av hydrogen |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| NO944982D0 NO944982D0 (no) | 1994-12-22 |
| NO944982L true NO944982L (no) | 1996-06-24 |
| NO300117B1 NO300117B1 (no) | 1997-04-14 |
Family
ID=19897780
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO944982A NO300117B1 (no) | 1994-12-22 | 1994-12-22 | Reaktor for dehydrogenering av hydrokarboner med selektiv oksidasjon av hydrogen |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US5997826A (no) |
| EP (1) | EP0799169B1 (no) |
| KR (1) | KR100258656B1 (no) |
| CN (1) | CN1070832C (no) |
| AT (1) | ATE190302T1 (no) |
| AU (1) | AU691715B2 (no) |
| BR (1) | BR9510515A (no) |
| CA (1) | CA2207038C (no) |
| DE (1) | DE69515511D1 (no) |
| NO (1) | NO300117B1 (no) |
| RU (1) | RU2140895C1 (no) |
| WO (1) | WO1996019424A1 (no) |
Families Citing this family (56)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2359884T3 (es) * | 1998-07-08 | 2011-05-27 | Toyota Jidosha Kabushiki Kaisha | Aparato para la reforma de combustibles. |
| DE19840018A1 (de) * | 1998-09-02 | 2000-03-09 | Fraunhofer Ges Forschung | Verfahren und Vorrichtung zur Herstellung von Distickstoffpentoxid |
| NO310807B1 (no) * | 1999-05-28 | 2001-09-03 | Norske Stats Oljeselskap | Forbehandling av katalysator |
| US6969506B2 (en) * | 1999-08-17 | 2005-11-29 | Battelle Memorial Institute | Methods of conducting simultaneous exothermic and endothermic reactions |
| NO316512B1 (no) * | 2000-01-25 | 2004-02-02 | Statoil Asa | Fremgangsmate og reaktor for autoterm dehydrogenering av hydrokarboner |
| EP1166864A1 (en) * | 2000-06-30 | 2002-01-02 | Casale Chemicals SA | Method for the production of formaldehyde |
| FR2813024B1 (fr) * | 2000-08-17 | 2004-02-13 | Inst Francais Du Petrole | Dispositif d'injection d'un fluide place entre deux lits successifs permettant de realiser et de distribuer simultanement un melange polyphasique |
| FR2813023B1 (fr) * | 2000-08-17 | 2003-10-24 | Inst Francais Du Petrole | Dispositif de distribution permettant de realiser un melange polyphasique et reacteur associe |
| CA2478333C (en) * | 2002-03-11 | 2013-10-15 | Battelle Memorial Institute | Microchannel reactors with temperature control |
| US8206666B2 (en) * | 2002-05-21 | 2012-06-26 | Battelle Memorial Institute | Reactors having varying cross-section, methods of making same, and methods of conducting reactions with varying local contact time |
| US7402719B2 (en) * | 2002-06-13 | 2008-07-22 | Velocys | Catalytic oxidative dehydrogenation, and microchannel reactors for catalytic oxidative dehydrogenation |
| US7195742B2 (en) * | 2002-07-26 | 2007-03-27 | Utc Fuel Cells, Llc | Preferential oxidation reactor and process |
| US9192929B2 (en) | 2002-08-15 | 2015-11-24 | Velocys, Inc. | Integrated combustion reactor and methods of conducting simultaneous endothermic and exothermic reactions |
| US7250151B2 (en) | 2002-08-15 | 2007-07-31 | Velocys | Methods of conducting simultaneous endothermic and exothermic reactions |
| DE10251135B4 (de) * | 2002-10-31 | 2006-07-27 | Uhde Gmbh | Verfahren zur katalytischen Dehydrierung von leichten Paraffinen zu Olefinen |
| DE10251262A1 (de) * | 2002-11-04 | 2004-05-13 | Basf Ag | Verfahren zur Herstellung von Aldehyden aus Alkanen |
| US6989134B2 (en) * | 2002-11-27 | 2006-01-24 | Velocys Inc. | Microchannel apparatus, methods of making microchannel apparatus, and processes of conducting unit operations |
| TW200422289A (en) | 2003-02-18 | 2004-11-01 | Bp Chem Int Ltd | Auto thermal cracking reactor |
| US7405338B2 (en) * | 2003-04-07 | 2008-07-29 | Velocys | Dehydrogenation reactions in narrow reaction chambers and integrated reactors |
| US7294734B2 (en) * | 2003-05-02 | 2007-11-13 | Velocys, Inc. | Process for converting a hydrocarbon to an oxygenate or a nitrile |
| US7470408B2 (en) | 2003-12-18 | 2008-12-30 | Velocys | In situ mixing in microchannels |
| US8378163B2 (en) * | 2004-03-23 | 2013-02-19 | Velocys Corp. | Catalysts having catalytic material applied directly to thermally-grown alumina and catalytic methods using same, improved methods of oxidative dehydrogenation |
| US7304198B2 (en) | 2004-05-14 | 2007-12-04 | Battelle Memorial Institute | Staged alkylation in microchannels |
| CN101023068B (zh) | 2004-08-12 | 2013-02-13 | 万罗赛斯公司 | 使用微通道工艺技术将乙烯转化成环氧乙烷的方法 |
| EP1804964A1 (en) | 2004-10-01 | 2007-07-11 | Velocys Inc. | Multiphase mixing process using microchannel process technology |
| US7468455B2 (en) * | 2004-11-03 | 2008-12-23 | Velocys, Inc. | Process and apparatus for improved methods for making vinyl acetate monomer (VAM) |
| FR2877589B1 (fr) * | 2004-11-09 | 2007-01-12 | Inst Francais Du Petrole | Reacteur a plusieurs zones en lit fixe ou mobile avec echangeur thermique integre |
| DE102004054657A1 (de) | 2004-11-11 | 2006-05-18 | Uhde Gmbh | Verfahren zur katalytischen Dehydrierung von Propan zu Propylen |
| CN101128257B (zh) | 2004-11-12 | 2010-10-27 | 万罗赛斯公司 | 使用微通道技术进行烷化或酰化反应的方法 |
| KR20100038476A (ko) | 2004-11-16 | 2010-04-14 | 벨로시스, 인코포레이티드 | 마이크로채널 기술을 사용하는 다중상 반응 과정 |
| US7507274B2 (en) | 2005-03-02 | 2009-03-24 | Velocys, Inc. | Separation process using microchannel technology |
| US9101890B2 (en) | 2005-05-25 | 2015-08-11 | Velocys, Inc. | Support for use in microchannel processing |
| US20070004810A1 (en) * | 2005-06-30 | 2007-01-04 | Yong Wang | Novel catalyst and fischer-tropsch synthesis process using same |
| EP1904223A2 (en) | 2005-07-08 | 2008-04-02 | Velocys Inc. | Catalytic reaction process using microchannel technology |
| KR101004487B1 (ko) | 2005-09-08 | 2010-12-31 | 가시오게산키 가부시키가이샤 | 이동형 전자 장치의 전원공급용 개질기 |
| DE102005052923A1 (de) * | 2005-11-03 | 2007-05-10 | Basf Ag | Verfahren zum stabilen Betreiben eines kontinuierlich ausgeübten Herstellprozesses zur Erzeugung von Acrolein, oder Acrylsäure oder deren Gemisch aus Propan |
| DE502006003491D1 (de) | 2005-11-03 | 2009-05-28 | Basf Se | Verfahren zum stabilen betreiben eines kontinuierlich ausgeübten herstellprozesses zur erzeugung von acrolein, oder acrylsäure oder deren gemisch aus propan |
| DE102005061626A1 (de) * | 2005-12-21 | 2007-06-28 | Basf Ag | Verfahren der kontinuierlichen heterogen katalysierten partiellen Dehydrierung wenigstens eines zu dehydrierenden Kohlenwasserstoffs |
| RU2448080C2 (ru) * | 2006-03-30 | 2012-04-20 | Басф Се | Способ гетерогенного каталитического парциального дегидрирования по меньшей мере одного подлежащего дегидрированию углеводорода |
| US7842846B2 (en) * | 2006-03-30 | 2010-11-30 | Basf Aktiengesellschaft | Process for heterogeneously catalyzed partial dehydrogenation of at least one hydrocarbon to be dehydrogenated |
| EP2004578B1 (de) * | 2006-03-30 | 2014-09-03 | Basf Se | Verfahren einer heterogen katalysierten partiellen dehydrierung wenigstens eines zu dehydrierenden kohlenwasserstoffs |
| DE102006029790A1 (de) * | 2006-06-27 | 2008-01-03 | Basf Ag | Verfahren der kontinuierlichen heterogen katalysierten partiellen Dehydrierung wenigstens eines zu dehydrierenden Kohlenwasserstoffs |
| US7999144B2 (en) | 2006-09-01 | 2011-08-16 | Velocys | Microchannel apparatus and methods of conducting catalyzed oxidative dehydrogenation |
| DE102007006647A1 (de) | 2007-02-06 | 2008-08-07 | Basf Se | Verfahren zur Regenerierung eines im Rahmen einer heterogen katalysierten partiellen Dehydrierung eines Kohlenwasserstoffs deaktivierten Katalysatorbetts |
| US8262755B2 (en) | 2007-06-05 | 2012-09-11 | Air Products And Chemicals, Inc. | Staged membrane oxidation reactor system |
| US7745667B2 (en) * | 2008-04-07 | 2010-06-29 | Velocys | Microchannel apparatus comprising structured walls, chemical processes, methods of making formaldehyde |
| CA2753127C (en) * | 2009-03-05 | 2016-07-05 | Uop Llc | Hydrocarbon dehydrogenation process |
| CN103805234B (zh) * | 2012-11-07 | 2015-09-02 | 中国石油化工股份有限公司 | 一种径流式渣油加氢处理反应器 |
| US20140371503A1 (en) * | 2013-06-18 | 2014-12-18 | Uop Llc | Single stage reactor system with oxidative preheat for dehydrogenation of hydrocarbons |
| CA2833822C (en) * | 2013-11-21 | 2020-08-04 | Nova Chemicals Corporation | Inherently safe odh operation |
| WO2018037315A1 (en) * | 2016-08-22 | 2018-03-01 | Sabic Global Technologies B.V. | Integrated method and system for hydrogen and ethylene production |
| KR102563776B1 (ko) * | 2017-07-28 | 2023-08-04 | 다우 글로벌 테크놀로지스 엘엘씨 | 불균일 촉매를 사용하여 산화적 에스터화에 의해 메틸 메타크릴레이트를 제조하는 방법 |
| EP3476471A1 (de) * | 2017-10-25 | 2019-05-01 | Linde Aktiengesellschaft | Verfahren und reaktor zur bildung und zur katalytischen umsetzung eines eduktgemischs |
| EP3848113A1 (en) | 2020-01-07 | 2021-07-14 | SABIC Global Technologies B.V. | Systems, devices, and methods of a reactor feed distribution system |
| US12540109B2 (en) | 2020-06-30 | 2026-02-03 | Shell Usa, Inc. | Ethane oxidative dehydrogenation process |
| CN113380431A (zh) * | 2021-06-03 | 2021-09-10 | 哈尔滨工程大学 | 一种氢气复合器催化单元 |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3502737A (en) * | 1968-06-07 | 1970-03-24 | Badger Co | Ethylbenzene dehydrogenation |
| BE789153A (fr) * | 1971-09-23 | 1973-03-22 | Aquitaine Petrole | Perfectionnement a la fabrication du styrene |
| SU1257069A1 (ru) * | 1984-01-02 | 1986-09-15 | Предприятие П/Я В-8296 | Способ управлени процессом дегидрировани углеводородов |
| US4739124A (en) * | 1985-09-16 | 1988-04-19 | Uop Inc. | Method for oxygen addition to oxidative reheat zone of ethane dehydrogenation process |
| US4891464A (en) * | 1985-12-26 | 1990-01-02 | Uop | Control method for oxygen addition to oxidative reheat zone of hydrocarbon conversion process |
| US4731924A (en) * | 1986-08-04 | 1988-03-22 | American Telephone And Telegraph Company | Method and apparatus for inserting multi-leaded articles into a substrate |
| US4806624A (en) * | 1987-06-17 | 1989-02-21 | Uop Inc. | Dehydrogenation of dehydrogenatable hydrocarbons |
| US4778941A (en) * | 1988-01-19 | 1988-10-18 | Uop Inc. | Eduction of intermediate effluent in dehydrogenation process having oxidative reheat |
| GB8807732D0 (en) * | 1988-03-31 | 1988-05-05 | Bp Chem Int Ltd | Hydrocarbon dehydrogenation reactions |
| US4827066A (en) * | 1988-05-23 | 1989-05-02 | Uop Inc. | Dehydrogenation of dehydrogenatable hydrocarbons |
| US4914249A (en) * | 1988-12-29 | 1990-04-03 | Uop | Dehydrogenation of dehydrogenatable hydrocarbons |
| US5043500A (en) * | 1989-12-20 | 1991-08-27 | Uop | Use of steam eductor to supply oxygen for oxidative reheating in dehydrogenation of C3 + hydrocarbons |
-
1994
- 1994-12-22 NO NO944982A patent/NO300117B1/no unknown
-
1995
- 1995-12-18 EP EP95942322A patent/EP0799169B1/en not_active Expired - Lifetime
- 1995-12-18 AT AT95942322T patent/ATE190302T1/de not_active IP Right Cessation
- 1995-12-18 DE DE69515511T patent/DE69515511D1/de not_active Expired - Lifetime
- 1995-12-18 CA CA002207038A patent/CA2207038C/en not_active Expired - Fee Related
- 1995-12-18 US US08/860,069 patent/US5997826A/en not_active Expired - Fee Related
- 1995-12-18 RU RU97112487A patent/RU2140895C1/ru not_active IP Right Cessation
- 1995-12-18 AU AU43575/96A patent/AU691715B2/en not_active Ceased
- 1995-12-18 WO PCT/NO1995/000236 patent/WO1996019424A1/en not_active Ceased
- 1995-12-18 KR KR1019970704244A patent/KR100258656B1/ko not_active Expired - Fee Related
- 1995-12-18 BR BR9510515A patent/BR9510515A/pt not_active IP Right Cessation
- 1995-12-18 CN CN95196944A patent/CN1070832C/zh not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| EP0799169B1 (en) | 2000-03-08 |
| NO944982D0 (no) | 1994-12-22 |
| RU2140895C1 (ru) | 1999-11-10 |
| DE69515511D1 (de) | 2000-04-13 |
| CA2207038C (en) | 2002-02-12 |
| AU691715B2 (en) | 1998-05-21 |
| ATE190302T1 (de) | 2000-03-15 |
| CN1070832C (zh) | 2001-09-12 |
| BR9510515A (pt) | 1998-07-07 |
| NO300117B1 (no) | 1997-04-14 |
| US5997826A (en) | 1999-12-07 |
| AU4357596A (en) | 1996-07-10 |
| WO1996019424A1 (en) | 1996-06-27 |
| KR980700943A (ko) | 1998-04-30 |
| EP0799169A1 (en) | 1997-10-08 |
| KR100258656B1 (ko) | 2000-06-15 |
| CA2207038A1 (en) | 1996-06-27 |
| CN1170397A (zh) | 1998-01-14 |
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