NO982240L - Process for oxidizing organic substrates in the presence of metal complexes of tetra-, penta- and hexacoridinated ligands, as well as oxidation catalysts containing these - Google Patents

Process for oxidizing organic substrates in the presence of metal complexes of tetra-, penta- and hexacoridinated ligands, as well as oxidation catalysts containing these

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Publication number
NO982240L
NO982240L NO982240A NO982240A NO982240L NO 982240 L NO982240 L NO 982240L NO 982240 A NO982240 A NO 982240A NO 982240 A NO982240 A NO 982240A NO 982240 L NO982240 L NO 982240L
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NO
Norway
Prior art keywords
metal complex
hexacoridinated
penta
ligands
tetra
Prior art date
Application number
NO982240A
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Norwegian (no)
Other versions
NO982240D0 (en
Inventor
Laurent Fraisse
Jean-Jacques Girerd
Fruduric Perie
Alain Rabion
David Tetard
Jean-Baptiste Verlhac
Alexander Nivorozhkin
Original Assignee
Elf Aquitaine
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Elf Aquitaine filed Critical Elf Aquitaine
Publication of NO982240D0 publication Critical patent/NO982240D0/en
Publication of NO982240L publication Critical patent/NO982240L/en

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C409/00—Peroxy compounds
    • C07C409/16—Peroxy compounds the —O—O— group being bound between two carbon atoms not further substituted by oxygen atoms, i.e. peroxides
    • C07C409/18—Peroxy compounds the —O—O— group being bound between two carbon atoms not further substituted by oxygen atoms, i.e. peroxides at least one of the carbon atoms belonging to a ring other than a six-membered aromatic ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1815—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1815—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine
    • B01J31/182—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine comprising aliphatic or saturated rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B41/00—Formation or introduction of functional groups containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
    • C07C29/50—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C407/00—Preparation of peroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/28—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of CHx-moieties
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/29—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/29—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups
    • C07C45/294—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups with hydrogen peroxide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/385—Saturated compounds containing a keto group being part of a ring
    • C07C49/417—Saturated compounds containing a keto group being part of a ring polycyclic
    • C07C49/423—Saturated compounds containing a keto group being part of a ring polycyclic a keto group being part of a condensed ring system
    • C07C49/453—Saturated compounds containing a keto group being part of a ring polycyclic a keto group being part of a condensed ring system having three rings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/70—Complexes comprising metals of Group VII (VIIB) as the central metal
    • B01J2531/72—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/842—Iron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2603/00—Systems containing at least three condensed rings
    • C07C2603/56—Ring systems containing bridged rings
    • C07C2603/58—Ring systems containing bridged rings containing three rings
    • C07C2603/70—Ring systems containing bridged rings containing three rings containing only six-membered rings
    • C07C2603/74—Adamantanes

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Selektiv oksidasjonsprosess for organiske substrater ved å bringe substratene i berøring med et oksidasjons- middel utvalgt, fra hydroperoksd der og/eller hyd^ogen- peroksid i nærvær av en katalysator som inneholder et metallkompleks av minst en multikoordinerende nitroge- nert ligand, kjennetegnet ved at det molare metallkom- pleks/peroksid-forhold ligger mellom l og 10"10, idet temperaturen er lavere enn 120°C, og tnetallkomplekset har den generelle formel: [LxMyXj"Yq, hvor M betyr et mangan- eller jernatom i oksidert tilstand, X er en bro mellom metaller, Y er et motion, x og y er > l, O < u < 3, z er ladningen av metallkcmplekset, q = z/ladningen av Y, og L er en ligand med formel: RjA^N- (CH2)r-NAr2R2, hvor A^ og Ar3 er rettkjedede C^- til C6- karbonkjeder, forbundet med en nitrogenert hetero- cyklus, Rt og R2 er hydrogen eller en C^-Cs-alkylkjede som valgfritt kan være forbundet med en nitrogenert heterocyklus, og 2 < r <. 4.Selective oxidation process for organic substrates by contacting the substrates with an oxidizing agent selected, from hydroperoxide there and / or hydrogen peroxide in the presence of a catalyst containing a metal complex of at least one multi-coordinating nitrogenous ligand, characterized in that the molar metal complex / peroxide ratio is between 1 and 10 "10, the temperature being lower than 120 ° C, and the metal complex having the general formula: [LxMyXj" Y X is a bridge between metals, Y is a motion, x and y are> l, O <u <3, z is the charge of the metal complex, q = z / the charge of Y, and L is a ligand of the formula: R - (CH 2) r -NaR 2 R 2, where A 1 and Ar 3 are straight chain C 1 - to C 6 carbon chains linked by a nitrogenated hetero cycle, R t and R 2 are hydrogen or a C 1 a nitrogenized heterocycle, and 2 <r <. 4.

NO982240A 1995-11-16 1998-05-15 Process for oxidizing organic substrates in the presence of metal complexes of tetra-, penta- and hexacoridinated ligands, as well as oxidation catalysts containing these NO982240L (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR9513580A FR2741340B1 (en) 1995-11-16 1995-11-16 PROCESS FOR OXIDIZING ORGANIC SUBSTRATES IN THE PRESENCE OF METAL COMPLEXES OF TETRA-, PENTA- AND HEXACOORDINANTS AND OXIDATION CATALYSTS CONTAINING THEM
PCT/FR1996/001804 WO1997018035A1 (en) 1995-11-16 1996-11-15 Oxidation process of organic substrates in the presence of metal complexes of tetra-, penta- and hexacoordinating ligands, and oxidation catalysts containing them

Publications (2)

Publication Number Publication Date
NO982240D0 NO982240D0 (en) 1998-05-15
NO982240L true NO982240L (en) 1998-07-16

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Family Applications (1)

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NO982240A NO982240L (en) 1995-11-16 1998-05-15 Process for oxidizing organic substrates in the presence of metal complexes of tetra-, penta- and hexacoridinated ligands, as well as oxidation catalysts containing these

Country Status (7)

Country Link
EP (1) EP0914205A1 (en)
JP (1) JP2000500151A (en)
AU (1) AU7628996A (en)
CA (1) CA2235764A1 (en)
FR (1) FR2741340B1 (en)
NO (1) NO982240L (en)
WO (1) WO1997018035A1 (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19605688A1 (en) * 1996-02-16 1997-08-21 Henkel Kgaa Transition metal complexes as activators for peroxygen compounds
DE69825166T2 (en) * 1998-11-10 2004-11-25 Unilever N.V. Washing and bleaching compositions
ES2206853T3 (en) * 1998-11-10 2004-05-16 Unilever N.V. WHITENING AND OXIDATION CATALYSTS.
US6573409B1 (en) 1999-07-02 2003-06-03 The Nutrasweet Company Process for the preparation of 3,3-dimethylbutanal
JP2005194244A (en) * 2004-01-09 2005-07-21 Shigenobu Yano Zinc ion fluorescence sensor
WO2013183591A1 (en) * 2012-06-06 2013-12-12 保土谷化学工業株式会社 Method for producing adamantanetriol

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4326084A (en) * 1979-10-11 1982-04-20 E. I. Du Pont De Nemours And Company Process for producing a mixture containing cyclohexanol and cyclohexanone from cyclohexane
US4459427A (en) * 1981-10-31 1984-07-10 The British Petroleum Company P.L.C. Process for the conversion of an alkane to a mixture of an alcohol and a ketone
FR2573087B1 (en) * 1984-11-09 1987-07-10 Inst Francais Du Petrole METHOD OF SOFTENING OIL CUTTINGS CARRIED OUT IN THE ABSENCE OF AN ALKALINE COMPOUND
US5990363A (en) * 1987-01-02 1999-11-23 Sun Company, Inc. Method for oxidizing alkanes using novel porphyrins synthesized from dipyrromethanes and aldehydes
FR2692499B1 (en) * 1992-06-22 1994-08-26 Atochem Elf Sa Process for delignification and bleaching of a lignocellulosic material.
US5329024A (en) * 1993-03-30 1994-07-12 National Starch And Chemical Investment Holding Corporation Epoxidation of olefins via certain manganese complexes

Also Published As

Publication number Publication date
JP2000500151A (en) 2000-01-11
AU7628996A (en) 1997-06-05
CA2235764A1 (en) 1997-05-22
FR2741340B1 (en) 1997-12-26
NO982240D0 (en) 1998-05-15
WO1997018035A1 (en) 1997-05-22
EP0914205A1 (en) 1999-05-12
FR2741340A1 (en) 1997-05-23

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