NO983787L - FremgangsmÕte for Õ fremstille alkener ved suspensjonspolymerisasjon - Google Patents

FremgangsmÕte for Õ fremstille alkener ved suspensjonspolymerisasjon

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Publication number
NO983787L
NO983787L NO983787A NO983787A NO983787L NO 983787 L NO983787 L NO 983787L NO 983787 A NO983787 A NO 983787A NO 983787 A NO983787 A NO 983787A NO 983787 L NO983787 L NO 983787L
Authority
NO
Norway
Prior art keywords
carbon atoms
metal
aryl
alkyl
hydrogen
Prior art date
Application number
NO983787A
Other languages
English (en)
Other versions
NO983787D0 (no
Inventor
John Lynch
David Fischer
Rtz Hans Helmut G
G Nther Schweier
Original Assignee
Basf Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Ag filed Critical Basf Ag
Publication of NO983787D0 publication Critical patent/NO983787D0/no
Publication of NO983787L publication Critical patent/NO983787L/no

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

Fremgangsmåte for fremstilling av polymerer av alkener ved suspensjons- polymerisering i nærvær av katalysatorsystemer, idet det som katalysatorsystemer anvendes understøttede katalysatorsystemer som fås ved A) omsetting av et u- organisk bærermateriale med en metallforbindelse med den generelle formel (l) . M1(R1)r(R2).(R3),(R4)u hvor M1 angir et alkalimetall, et jordalkalimetall eller et metall i III. eller IV. hovedgruppe i det periodiske system, R1 angir hydrogen, (^-Cu-alkyl. C6-C15_aryl, alkylaryl eller arylalkyl med i hvert tilfelle 1-10 C-atomer i alkylresten og 6-20 C-atomer i arylresten, R2-R4 angir hydrogen, halogen, C,-C10-alkyl, C6- C15-aryl, alkylaryl, arylalkyl, alkoksy eller dialkylamino med i hvert tilfelle 1-10 C- atomer i alkylresten og 6-20 C-atomer i arylresten, r angir et helt tall fra 1 til 4 og s, t og u angir hele tall på fra O til 3, idet summen r+s+t+u tilsvarer verdien av M1, B) omsetting av materialet oppnådd ifølge A), med et metallocenkompleks i dets metalldihalogenid-form og en metalloceniumion-dannende forbindelse, og C) der- etter omsetting med en metallforbindelse med den generelle formel II M2(R5)0(R8)p(R7)q hvor M2 angir et alkalimetall, et jordalkalimetall eller et metall i III. hovedgruppe i det periodiske system, R5 angir hydrogen, ^-C^-alkyl, C6-C15- aryl, alkylaryl eller arylalkyl med i hvert tilfelle 1-10 C-atomer i alkylresten og 6-20 C-atomer i arylresten, R6 og R7 angir hydrogen, halogen, ^-C^-alkyl. C6-C15- aryl, alkylaryl, arylalkyl eller alkoksy med i hvert tilfelle 1-10 C-atomer i alkylresten og 6-20 C-atomer i arylresten, o angir et helt tall på 1-3 og p og q angir hele tall på fra O til 2, idet summen o+p+q tilsvarer verdien av M2.
NO983787A 1996-02-20 1998-08-19 FremgangsmÕte for Õ fremstille alkener ved suspensjonspolymerisasjon NO983787L (no)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19606166A DE19606166A1 (de) 1996-02-20 1996-02-20 Verfahren zur Herstellung von Polymerisaten von Alkenen durch Suspensionspolymerisation
PCT/EP1997/000771 WO1997031029A1 (de) 1996-02-20 1997-02-19 Verfahren zur herstellung von polymerisaten von alkenen durch suspensionspolymerisation

Publications (2)

Publication Number Publication Date
NO983787D0 NO983787D0 (no) 1998-08-19
NO983787L true NO983787L (no) 1998-10-19

Family

ID=7785835

Family Applications (1)

Application Number Title Priority Date Filing Date
NO983787A NO983787L (no) 1996-02-20 1998-08-19 FremgangsmÕte for Õ fremstille alkener ved suspensjonspolymerisasjon

Country Status (13)

Country Link
US (1) US6326444B2 (no)
EP (1) EP0882069B1 (no)
JP (1) JP2000504776A (no)
KR (1) KR100471333B1 (no)
CN (1) CN1128814C (no)
AT (1) ATE200784T1 (no)
AU (1) AU713739B2 (no)
BR (1) BR9707565A (no)
CA (1) CA2246389A1 (no)
DE (2) DE19606166A1 (no)
ES (1) ES2156359T3 (no)
NO (1) NO983787L (no)
WO (1) WO1997031029A1 (no)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19703502A1 (de) 1997-01-31 1998-08-06 Basf Ag Nicht selbstentzündlicher Feststoff
DE19757262A1 (de) * 1997-12-23 1999-07-01 Targor Gmbh Verfahren zur Herstellung von Olefinpolymerisaten mit erhöhtem Schmelzpunkt
DE19806435A1 (de) 1998-02-17 1999-08-19 Basf Ag Verfahren zur Herstellung eines geträgerten Katalysatorsystems
WO2005108442A1 (en) 2002-10-15 2005-11-17 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
US7541402B2 (en) 2002-10-15 2009-06-02 Exxonmobil Chemical Patents Inc. Blend functionalized polyolefin adhesive
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
US7223822B2 (en) 2002-10-15 2007-05-29 Exxonmobil Chemical Patents Inc. Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom
US7550528B2 (en) 2002-10-15 2009-06-23 Exxonmobil Chemical Patents Inc. Functionalized olefin polymers
US7119153B2 (en) 2004-01-21 2006-10-10 Jensen Michael D Dual metallocene catalyst for producing film resins with good machine direction (MD) elmendorf tear strength
EP4050014B1 (en) 2014-10-23 2026-08-19 Inpria Corporation Method for forming a film for high resolution patterning and film formed thereby
KR20250019125A (ko) 2022-06-02 2025-02-07 젤리스트 인코퍼레이티드 고순도 알킬 주석 화합물 및 이의 제조 방법
TW202413383A (zh) 2022-08-12 2024-04-01 美商蓋列斯特股份有限公司 含不飽和取代基之高純度錫化合物及其製造方法
US12606577B2 (en) 2022-09-28 2026-04-21 Gelest, Inc. Iodoalkyl tin compounds and preparation methods thereof
CN119998302A (zh) 2022-10-04 2025-05-13 盖列斯特有限公司 环状氮杂锡烷和环状氧杂锡烷化合物及其制备方法
WO2025115332A1 (ja) 2023-12-01 2025-06-05 三菱ケミカル株式会社 スズ化合物およびそれを用いたレジスト溶液、パターン形成方法、薄膜、パターン化された薄膜、並びにスズ化合物の製造方法

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3242150A (en) 1960-03-31 1966-03-22 Phillips Petroleum Co Method and apparatus for the recovery of solid olefin polymer from a continuous path reaction zone
US3248179A (en) 1962-02-26 1966-04-26 Phillips Petroleum Co Method and apparatus for the production of solid polymers of olefins
JPH05502906A (ja) * 1990-01-02 1993-05-20 エクソン・ケミカル・パテンツ・インク オレフィン重合用の担持イオン性メタロセン触媒
CA2066247C (en) * 1990-07-24 1998-09-15 Ryuichi Sugimoto Polymerization catalyst for .alpha.-olefin and method for preparing poly-.alpha.-olefin by using it
US5444134A (en) * 1991-07-11 1995-08-22 Idemitsu Kosan Co., Ltd. Process for producing olefin based polymers and olefin polymerization catalyst
DE69334188T2 (de) 1992-08-05 2008-10-23 Exxonmobil Chemical Patents Inc., Baytown Verfahren zur Herstellung von einem geträgertem Aktivatorkomponenten
JP3202349B2 (ja) * 1992-09-22 2001-08-27 三菱化学株式会社 触媒組成物およびそれを用いるオレフィンの重合法
BE1006880A3 (fr) 1993-03-01 1995-01-17 Solvay Precurseur solide d'un systeme catalytique pour la polymerisation d'olefines, procede pour sa preparation, systeme catalytique comprenant ce precurseur solide et procede de polymerisation d'olefines en presence de ce systeme catalytique.
DE69403928T2 (de) * 1993-04-09 1997-12-18 Tosoh Corp Katalysator und Verfahren zur Olefin-Polymerisation
JP2882241B2 (ja) * 1993-06-07 1999-04-12 東ソー株式会社 オレフィン重合用触媒およびオレフィンの重合方法
WO1995014044A1 (en) * 1993-11-19 1995-05-26 Exxon Chemical Patents Inc. Polymerization catalyst systems, their production and use
US5498582A (en) * 1993-12-06 1996-03-12 Mobil Oil Corporation Supported metallocene catalysts for the production of polyolefins
DE4344672C1 (de) * 1993-12-27 1995-06-14 Basf Ag Verfahren zur Herstellung von Polymerisaten des Ethylens durch Suspensionspolymerisation
DE4431838A1 (de) * 1994-09-07 1996-03-14 Basf Ag Geträgerte Metallocen-Katalysatorsysteme
DE4431837A1 (de) * 1994-09-07 1996-03-14 Basf Ag Geträgerte Metallocen-Katalysatorsysteme
RU2160283C2 (ru) * 1995-03-10 2000-12-10 Дзе Дау Кемикал Компани Компонент катализатора на носителе, катализатор на носителе, аддукт, применяемый в качестве компонента катализатора полимеризации олефинов, способ полимеризации олефинов

Also Published As

Publication number Publication date
NO983787D0 (no) 1998-08-19
US6326444B2 (en) 2001-12-04
KR100471333B1 (ko) 2005-05-16
KR19990087067A (ko) 1999-12-15
AU713739B2 (en) 1999-12-09
ES2156359T3 (es) 2001-06-16
AU1792197A (en) 1997-09-10
JP2000504776A (ja) 2000-04-18
EP0882069A1 (de) 1998-12-09
ATE200784T1 (de) 2001-05-15
DE19606166A1 (de) 1997-08-21
WO1997031029A1 (de) 1997-08-28
US20010001796A1 (en) 2001-05-24
CN1128814C (zh) 2003-11-26
CA2246389A1 (en) 1997-08-28
BR9707565A (pt) 1999-07-27
EP0882069B1 (de) 2001-04-25
CN1211992A (zh) 1999-03-24
DE59703435D1 (de) 2001-05-31

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