NO990546L - 3-heteroatom substituerte cyklopentadienyl-inneholdende metallkomplekser og olefinpolymerisasjonsprosess - Google Patents

3-heteroatom substituerte cyklopentadienyl-inneholdende metallkomplekser og olefinpolymerisasjonsprosess

Info

Publication number
NO990546L
NO990546L NO990546A NO990546A NO990546L NO 990546 L NO990546 L NO 990546L NO 990546 A NO990546 A NO 990546A NO 990546 A NO990546 A NO 990546A NO 990546 L NO990546 L NO 990546L
Authority
NO
Norway
Prior art keywords
metal complexes
heteroatom
olefin polymerization
substituted cyclopentadienyl
polymerization process
Prior art date
Application number
NO990546A
Other languages
English (en)
Other versions
NO990546D0 (no
Inventor
Jerzy Klosin
Jr William J Kruper
Peter N Nickias
Jasson T Patton
David R Wilson
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Publication of NO990546D0 publication Critical patent/NO990546D0/no
Publication of NO990546L publication Critical patent/NO990546L/no

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/10—Compounds having one or more C—Si linkages containing nitrogen having a Si-N linkage
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

Denne oppfinnelse angår heteroatom-substituerte cyklopentadienyl-holdige ligan- der, metallkomplekser inneholdende disse ligander, samt katalysatorsystemer fremstilt ut fra katalysatorkomponenter omfattende disse metallkomplekser. Metallkompleksene inne- holder en heteroatom-Cp-binding eller en ring-heteroatom-Cp-binding i 2-stillingen på Cp. I foretrukne metallkomplekser er liganden en 2-heteroatom-substituert indenylgruppe. Ka- talysatorsystemene for olefinpolymerisering kan anvendes ved høye temperaturer, er meget aktive og gir polymer med høy molekylvekt.
NO990546A 1996-08-08 1999-02-05 3-heteroatom substituerte cyklopentadienyl-inneholdende metallkomplekser og olefinpolymerisasjonsprosess NO990546L (no)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US2376896P 1996-08-08 1996-08-08
PCT/US1997/013171 WO1998006728A1 (en) 1996-08-08 1997-07-28 2-heteroatom substituted cyclopentadienyl-containing metal complexes and olefin polymerization process

Publications (2)

Publication Number Publication Date
NO990546D0 NO990546D0 (no) 1999-02-05
NO990546L true NO990546L (no) 1999-03-29

Family

ID=21817090

Family Applications (1)

Application Number Title Priority Date Filing Date
NO990546A NO990546L (no) 1996-08-08 1999-02-05 3-heteroatom substituerte cyklopentadienyl-inneholdende metallkomplekser og olefinpolymerisasjonsprosess

Country Status (21)

Country Link
EP (1) EP1021454A1 (no)
JP (1) JP2000516608A (no)
KR (1) KR20000029853A (no)
CN (1) CN1231668A (no)
AR (1) AR009034A1 (no)
AU (1) AU716659B2 (no)
BR (1) BR9711115A (no)
CA (1) CA2262377A1 (no)
CO (1) CO4870709A1 (no)
CZ (1) CZ42499A3 (no)
HU (1) HUP9904148A3 (no)
ID (1) ID18005A (no)
NO (1) NO990546L (no)
NZ (1) NZ333877A (no)
PL (1) PL331526A1 (no)
RU (1) RU2196776C2 (no)
SA (1) SA97180735B1 (no)
SK (1) SK15299A3 (no)
TR (1) TR199900589T2 (no)
WO (1) WO1998006728A1 (no)
ZA (2) ZA976998B (no)

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CA2368111A1 (en) 1999-05-13 2000-11-23 The Dow Chemical Company Di- and tri-heteroatom substituted indenyl metal complexes
EP1194431B1 (en) 1999-06-04 2005-06-22 Dow Global Technologies Inc. Boron-substituted cyclopentadienes and metal complexes thereof
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ES2239665T3 (es) 2000-01-18 2005-10-01 Basell Polyolefine Gmbh Procedimiento para producir polimeros aa base de propileno, substancialmente amorfos.
GB0001232D0 (en) * 2000-01-19 2000-03-08 Borealis Polymers Oy Polymerisation catalysts
EP1248806A1 (en) * 2000-01-19 2002-10-16 Borealis Technology Oy Metallocene catalysts comprising monocyclic siloxy substituted cyclopentadienyl group(s) for the polymerisation of olefins
JP4062929B2 (ja) 2002-02-08 2008-03-19 住友化学株式会社 遷移金属錯体、配位子、オレフィン重合用触媒およびオレフィン重合体の製造方法
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BRPI1015130B1 (pt) 2009-07-28 2019-11-26 Univation Tech Llc processo de polimerização usando um catalisador de geometria limitada suportado
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CN102101897B (zh) * 2010-12-24 2013-02-06 上海化工研究院 侧链含杂环的茂金属催化剂及其在烯烃聚合中的应用
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PL3245258T3 (pl) 2015-01-06 2020-01-31 Scg Chemicals Co., Ltd. MIKROSFERY SiO₂ Z WARSTWOWYM PODWÓJNYM WODOROTLENKIEM I SPOSOBY ICH OTRZYMYWANIA
KR102010630B1 (ko) * 2016-01-20 2019-08-13 한화토탈 주식회사 올레핀 중합촉매 및 이를 이용한 올레핀 중합방법
GB201608384D0 (en) 2016-05-12 2016-06-29 Scg Chemicals Co Ltd Unsymmetrical metallocene catalysts and uses thereof
WO2018175073A1 (en) * 2017-03-23 2018-09-27 Exxonmobil Chemical Patents Inc. Catalyst systems and methods for preparing and using the same
KR102643986B1 (ko) 2017-09-29 2024-03-07 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 신규한 인덴계 전이금속 화합물, 이를 포함하는 전이금속 촉매 조성물, 및 이를 이용한 에틸렌 단독중합체 또는 에틸렌과 α-올레핀의 공중합체의 제조방법
WO2020174346A1 (ko) 2019-02-28 2020-09-03 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 신규한 테트라아릴보레이트 화합물, 이를 포함하는 촉매 조성물, 및 이를 이용한 에틸렌 단독중합체 또는 에틸렌과 α-올레핀의 공중합체의 제조방법
KR102714698B1 (ko) 2019-02-28 2024-10-10 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 신규한 테트라아릴보레이트 화합물, 이를 포함하는 촉매 조성물, 및 이를 이용한 에틸렌 단독중합체 또는 에틸렌과 α-올레핀의 공중합체의 제조방법
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Also Published As

Publication number Publication date
HUP9904148A2 (hu) 2000-03-28
ZA976998B (en) 1999-02-08
NZ333877A (en) 2000-08-25
RU2196776C2 (ru) 2003-01-20
SA97180735B1 (ar) 2006-10-08
PL331526A1 (en) 1999-07-19
WO1998006728A1 (en) 1998-02-19
EP1021454A1 (en) 2000-07-26
ZA976999B (en) 1999-02-08
ID18005A (id) 1998-02-19
AU3964797A (en) 1998-03-06
AU716659B2 (en) 2000-03-02
SK15299A3 (en) 2000-03-13
CA2262377A1 (en) 1998-02-19
JP2000516608A (ja) 2000-12-12
HUP9904148A3 (en) 2003-03-28
AR009034A1 (es) 2000-03-08
BR9711115A (pt) 1999-08-17
CN1231668A (zh) 1999-10-13
CO4870709A1 (es) 1999-12-27
NO990546D0 (no) 1999-02-05
CZ42499A3 (cs) 1999-07-14
KR20000029853A (ko) 2000-05-25
TR199900589T2 (xx) 1999-07-21

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