NO996308L - Conversion of synthesis gas to lower olefins using modified molecular sieves - Google Patents
Conversion of synthesis gas to lower olefins using modified molecular sievesInfo
- Publication number
- NO996308L NO996308L NO996308A NO996308A NO996308L NO 996308 L NO996308 L NO 996308L NO 996308 A NO996308 A NO 996308A NO 996308 A NO996308 A NO 996308A NO 996308 L NO996308 L NO 996308L
- Authority
- NO
- Norway
- Prior art keywords
- molecular sieves
- conversion
- complexes
- catalyst precursor
- modified molecular
- Prior art date
Links
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical class [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 title abstract 5
- 150000001336 alkenes Chemical class 0.000 title 1
- 230000015572 biosynthetic process Effects 0.000 title 1
- 238000006243 chemical reaction Methods 0.000 title 1
- 238000003786 synthesis reaction Methods 0.000 title 1
- 239000012018 catalyst precursor Substances 0.000 abstract 3
- 239000002808 molecular sieve Substances 0.000 abstract 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 abstract 1
- 229910052804 chromium Inorganic materials 0.000 abstract 1
- 239000011651 chromium Substances 0.000 abstract 1
- 229910017052 cobalt Inorganic materials 0.000 abstract 1
- 239000010941 cobalt Substances 0.000 abstract 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 1
- 238000001704 evaporation Methods 0.000 abstract 1
- 229910052748 manganese Inorganic materials 0.000 abstract 1
- 239000011572 manganese Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 229910052759 nickel Inorganic materials 0.000 abstract 1
- 229910052703 rhodium Inorganic materials 0.000 abstract 1
- 239000010948 rhodium Substances 0.000 abstract 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
- C10G2/334—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing molecular sieve catalysts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/061—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing metallic elements added to the zeolite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0203—Impregnation the impregnation liquid containing organic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
- B01J37/082—Decomposition and pyrolysis
- B01J37/086—Decomposition of an organometallic compound, a metal complex or a metal salt of a carboxylic acid
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/50—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon dioxide with hydrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/82—Phosphates
- B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
- B01J29/85—Silicoaluminophosphates [SAPO compounds]
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Thermal Sciences (AREA)
- Physics & Mathematics (AREA)
- Inorganic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
Fremgangsmåte for inkorporering av en eller flere Fischer-Tropsch-katalysatorer i molekylsikter, omfattende anbringelse av ubehandlede molekylsikter i kontakt med en ¿ katalysatorforløper i en inert atmosfære under første betingelser som er effektive med hensyn til dannelse av komplekser omfattende nevnte katalysatorforløper og nevnte molekylsikter; og eksponering av nevnte komplekser for en inert atmosfære og for andre betingelser som er effektive med hensyn til å dissosiere flyktige komponenter fra nevnte katalysatorforløper og til å fordampe oppløsningsmiddel fra nevnte komplekser, under dannelse av modifiserte molekylsikter omfattende en katalytisk effektiv mengde av en katalysator valgt fra gruppen bestående av j em, kobolt, nikkel, krom, mangan og rhodium.A method of incorporating one or more Fischer-Tropsch catalysts into molecular sieves, comprising placing untreated molecular sieves in contact with a catalyst precursor in an inert atmosphere under initial conditions effective in forming complexes comprising said catalyst precursor and said molecular sieves; and exposing said complexes to an inert atmosphere and to other conditions effective for dissociating volatile components from said catalyst precursor and for evaporating solvent from said complexes, to produce modified molecular sieves comprising a catalytically effective amount of a catalyst selected from the group consisting of em, cobalt, nickel, chromium, manganese and rhodium.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US5014497P | 1997-06-18 | 1997-06-18 | |
| PCT/US1998/012703 WO1998057743A2 (en) | 1997-06-18 | 1998-06-18 | Conversion of synthesis gas to lower olefins using modified molecular sieves |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| NO996308D0 NO996308D0 (en) | 1999-12-17 |
| NO996308L true NO996308L (en) | 2000-02-07 |
Family
ID=21963592
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO996308A NO996308L (en) | 1997-06-18 | 1999-12-17 | Conversion of synthesis gas to lower olefins using modified molecular sieves |
Country Status (8)
| Country | Link |
|---|---|
| EP (1) | EP0989908A2 (en) |
| CN (1) | CN1260823A (en) |
| AR (1) | AR013002A1 (en) |
| AU (1) | AU8151298A (en) |
| CA (1) | CA2289993A1 (en) |
| NO (1) | NO996308L (en) |
| TW (1) | TW482750B (en) |
| WO (1) | WO1998057743A2 (en) |
Families Citing this family (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6331574B1 (en) * | 1999-10-08 | 2001-12-18 | Exxonmobil Research And Engineering Company | Process for the preparation of high activity carbon monoxide hydrogenation catalysts; the catalyst compositions, use of the catalysts for conducting such reactions, and the products of such reactions |
| US7241716B2 (en) | 2003-11-10 | 2007-07-10 | Exxonmobil Chemical Patents Inc. | Protecting catalytic sites of metalloaluminophosphate molecular sieves |
| BG109246A (en) * | 2005-07-29 | 2005-11-30 | АНГЕЛОВ Чавдар | Method for producing hydrocarbons from hydrogen dioxide |
| EP1887071A1 (en) * | 2006-07-31 | 2008-02-13 | Edmund Dr.-Ing. Wagner | Process for the production of synthetic hydrocarbons and derivatives from carbon dioxide and hydrogen used as synthesis gas |
| KR100903439B1 (en) | 2007-10-15 | 2009-06-18 | 한국화학연구원 | Direct Production Method of Light Hydrocarbons from Natural Gas |
| JP2010116328A (en) * | 2008-11-11 | 2010-05-27 | Nippon Oil Corp | Method for producing unsaturated hydrocarbon and oxygen-containing compound, catalyst and method for producing the same |
| TWI473652B (en) | 2008-12-26 | 2015-02-21 | Nippon Oil Corp | Hydrogenated isomerization catalyst, method for producing the same, dewaxing method for hydrocarbon oil and method for producing lubricating base oil |
| PL2512667T3 (en) | 2009-12-18 | 2018-04-30 | Basf Se | Iron zeolites, method for producing iron zeolites, and method for catalytically reducing nitrogen oxides |
| US10239051B2 (en) | 2013-07-04 | 2019-03-26 | Total Research & Technology Feluy | Catalyst compositions comprising small size molecular sieves crystals deposited on a porous material |
| CN107774302B (en) * | 2016-08-26 | 2020-08-14 | 中国科学院大连化学物理研究所 | Method for preparing liquid fuel and co-producing low-carbon olefin by directly converting catalyst and synthesis gas |
| CN109701631B (en) * | 2017-10-26 | 2021-10-01 | 中国石油化工股份有限公司 | Catalyst for directly preparing low-carbon hydrocarbon from synthetic gas and its use method |
| CN109704900B (en) * | 2017-10-26 | 2021-11-30 | 中国石油化工股份有限公司 | Method for preparing olefin by synthesis gas one-step method |
| CN109701634B (en) * | 2017-10-26 | 2021-09-03 | 中国石油化工股份有限公司 | Catalyst composition for preparing low-carbon hydrocarbon from synthesis gas and application thereof |
| CN109701628A (en) * | 2017-10-26 | 2019-05-03 | 中国石油化工股份有限公司 | Composite catalyst containing phosphate aluminium molecular sieve and its application in one-step method from syngas alkene |
| CN109704899B (en) * | 2017-10-26 | 2022-07-08 | 中国石油化工股份有限公司 | Method for preparing olefin from synthesis gas |
| CN111111766A (en) * | 2018-10-30 | 2020-05-08 | 中国石油化工股份有限公司 | Method for utilizing carbon dioxide |
| CN111111763B (en) * | 2018-10-30 | 2022-10-11 | 中国石油化工股份有限公司 | Catalyst for directly preparing low-carbon olefin by carbon dioxide hydrogenation and application method thereof |
| CN111111762B (en) * | 2018-10-30 | 2022-10-11 | 中国石油化工股份有限公司 | Catalyst composition for directly preparing low-carbon olefin by carbon dioxide hydrogenation and application thereof |
| CN111111760B (en) * | 2018-10-30 | 2022-10-11 | 中国石油化工股份有限公司 | Catalyst for preparing low-carbon olefin by carbon dioxide hydrogenation and application thereof |
| CN111346671B (en) * | 2018-12-21 | 2023-03-24 | 中国科学院大连化学物理研究所 | Catalyst and method for preparing low aromatic hydrocarbon liquid fuel by directly converting synthesis gas |
| CN113574037A (en) | 2019-03-28 | 2021-10-29 | 埃克森美孚化学专利公司 | Method and system for converting benzene and/or toluene via methylation |
| CN113574036B (en) | 2019-03-28 | 2024-10-22 | 埃克森美孚化学专利公司 | Method for converting benzene and/or toluene via methylation |
| CN113574038B (en) | 2019-03-28 | 2024-10-22 | 埃克森美孚化学专利公司 | Process for converting benzene and/or toluene via methylation |
| US20250128999A1 (en) | 2021-09-16 | 2025-04-24 | ExxonMobil Technology and Engineering Company | Xylene Isomer Separation Processes |
| WO2023064684A1 (en) | 2021-10-12 | 2023-04-20 | Exxonmobil Chemical Patents Inc. | Staged alkylation for producing xylene products |
| WO2023204947A1 (en) | 2022-04-19 | 2023-10-26 | Exxonmobil Chemical Patents Inc. | Processes for oxidizing p-xylene or p-xylene-containing mixtures |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4431746A (en) * | 1981-06-26 | 1984-02-14 | Mobil Oil Corporation | Preparing metal-exchanged highly siliceous porous crystalline materials |
| US4962269A (en) * | 1982-05-18 | 1990-10-09 | Mobil Oil Corporation | Isomerization process |
| US4502945A (en) * | 1982-06-09 | 1985-03-05 | Chevron Research Company | Process for preparing olefins at high pressure |
| CA1196617A (en) * | 1982-07-14 | 1985-11-12 | George E. Morris | Catalyst composition, method for its production and its use in the production of hydrocarbons from synthesis gas |
| US4552855A (en) * | 1982-12-30 | 1985-11-12 | Ozin Geoffrey A | Metal zeolite catalyst preparation |
| EP0188898B1 (en) * | 1984-12-21 | 1990-09-19 | Mobil Oil Corporation | Cascade dewaxing process |
| DD233555A1 (en) * | 1984-12-29 | 1986-03-05 | Akad Wissenschaften Ddr | PREPARATION OF LOW OLEFINE FROM SYNTHESEGAS MIXTURES |
| US4849575A (en) * | 1987-11-25 | 1989-07-18 | Uop | Production of olefins |
| GB9005964D0 (en) * | 1990-03-16 | 1990-05-09 | Shell Int Research | Catalyst preparation process |
| WO1993015836A1 (en) * | 1992-02-18 | 1993-08-19 | The Broken Hill Proprietary Company Limited | Praseodymium containing cobalt catalysts for the fischer-tropsch process |
-
1998
- 1998-06-18 CN CN 98806239 patent/CN1260823A/en active Pending
- 1998-06-18 CA CA002289993A patent/CA2289993A1/en not_active Abandoned
- 1998-06-18 AU AU81512/98A patent/AU8151298A/en not_active Abandoned
- 1998-06-18 WO PCT/US1998/012703 patent/WO1998057743A2/en not_active Ceased
- 1998-06-18 AR ARP980102915 patent/AR013002A1/en unknown
- 1998-06-18 EP EP98931364A patent/EP0989908A2/en not_active Withdrawn
- 1998-09-16 TW TW87109797A patent/TW482750B/en active
-
1999
- 1999-12-17 NO NO996308A patent/NO996308L/en not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| TW482750B (en) | 2002-04-11 |
| NO996308D0 (en) | 1999-12-17 |
| CA2289993A1 (en) | 1998-12-23 |
| WO1998057743A3 (en) | 1999-05-27 |
| AU8151298A (en) | 1999-01-04 |
| CN1260823A (en) | 2000-07-19 |
| EP0989908A2 (en) | 2000-04-05 |
| WO1998057743A2 (en) | 1998-12-23 |
| AR013002A1 (en) | 2000-11-22 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FC2A | Withdrawal, rejection or dismissal of laid open patent application |